• 한국응용과학기술학회지
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• 제30권3호
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• pp.451-460
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• 2013

NOx from the thermal power plants are NO and $NO_2$. This work investigated the chemical/physical characteristics and SCR efficiency of newly prepared catalysts including tungsten ($WO_3$), molybdenum ($MoO_3$) and antimony ($SbO_3$) based on vanadia($V_2O_5$) over titania($TiO_2$). As a result of the examination, the surface area of the catalysts promoted with additional metals was larger and the de-NOx efficiency also was enhanced with temperature. The most efficient catalytst was $V_2O_5/TiO_2-WO_3$(10%) at $200^{\circ}C$. Such a high efficiency could contribute to reduce the ammonia slip.

• 연구논문집
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• 통권23호
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• pp.93-107
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• 1993

The chemistry and performance characteristics of the EBDS process have been introduced, in which experimental results from laboratory, test plant, and pilot plant studies agree very well and can be understood from detailed kinetic models. The parametric dependencies of the NOx and $SO_2$, removal yields on the input conditions have been discussed and formulated quantitatively. The process is best suited for flue gas with high $SO_2$, loadings. The operation conditions, such as dose, ammonia, and water additions, can be adjusted fast upon load changes. The process works waste water free and the major product is a mixture of ammonium nitrate and sulfate that can be used as fertilizer. The up-date results show that the EBDS technology is safe and competitive with other already well-established technologies. Due to these interesting features, the electron beam process has gained much international recognition. Demonstration units of 100MW have been proposed in the United States and Japan. Further pilot plants are under construction in Poland and China, countries that make abundant use of highsulfur coal. Additional research activities are under way to further improve the energy efficiency of process, and accelerator prices have been decreasing during the past 10 years. So the EBDS process has a good chance to start a new generation of emission-control technology.

• Membrane and Water Treatment
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• 제4권1호
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• pp.11-25
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• 2013

Emulsion liquid membrane (ELM) process suffers from emulsion instability problem. So far, emulsion produced by mechanical methods such as stirrer and homogenizer has big size and high emulsion breakage. This paper discussed the application of emulsion produced by sonicator to extract cadmium in a batch ELM system. The emulsions consist of N,N-Dioctyl-1-octanamine (trioctylamine/TOA), nitrogen trihydride (ammonia/NH4OH), sorbitan monooleate (Span 80), and kerosene as carrier, stripping solution, emulsifying agent, and organic diluent, respectively. Effects of comprehensive parameters on extraction efficiency of Cd(II) such as emulsification time, extraction time, stirring speed, surfactant concentration, initial feed phase concentration, carrier concentration, volume ratio of the emulsion to feed phase, and pH of initial feed phase were evaluated. The results showed that extraction efficiencies of Cd(II) greater than 98% could be obtained under the following conditions: 15 minutes of emulsification time, 4 wt.% of Span 80 concentration, 4 wt.% of TOA concentration, 15 minutes of extraction time, 250 rpm of stirring speed, 100 ppm of initial feed concentration, volume ratio of emulsion to feed phase of 1:5, and initial feed pH of 1.53.

• 한국물환경학회지
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• 제22권4호
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• pp.711-719
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• 2006

The effluent from anaerobic digestion process of slurry-type piggery waste has a characteristic of very low C/N ratio. Because of high nitrogen content, it is necessary to evaluate nitrogen removal alternative rather than conventional nitrification-denitrification scheme. In this study, two parallel treatment schemes of SBR-like partial nitritation reactor coupled with anaerobic ammonium oxidation (ANAMMOX) reactor, and a nitritation reactor followed by nitrite denitrification process were evaluated with a slurry-type piggery waste. The feed to reactors adjusted with various $NH_4-N$ and organics concentration. The nitrite accumulation was successfully accomplished at the loading rate of about $1.0kgNH_4-N/m^3-day$. The $NO_2-N/NH_4-N$ ratio 1~2.6 in nitritated effluent that operated at HRT of 1 day indicated that SBR-like partial nitritation was applicable to ANAMMOX operation. Meanwhile, the nitrite accumulation of 87% was achieved at SBR operated with HRT of 3 days and $0.4mgO_2/L$ for denitritation. Experimental results further suggested that HRT (SRT) and free ammonia(FA) rather than DO are an effective control parameter for nitrite accumulation in piggery waste.

• Journal of Microbiology and Biotechnology
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• 제12권5호
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• pp.735-739
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• 2002

Large quantities of porcine hepatocyte aggregates with various degrees of aggregation (DA) could be obtained by controlling the suspension periods (0,9,24, and 48 h), and by entrapping the hepatocyte aggregates in model materials of encapsulation such as Ca-alginate and type-I collagen gels. The effects of DA on liver-specific functions of hepatocytes were evaluated in order to obtain optimum DA for the cell source of bioartificial liver (BAL) systems. Irregular rugged aggregates (size $75 \pm 28$ $\mu\textrm{m}$) farmed by 24 h of suspension culturing showed peak viability and hepatic functions such as ammonia removal and albumin secretion in the two types of entrapment systems, thus offering themselves as a stable cell source of a BAL system for hepatic functions and scale-up.

• 공업화학
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• 제24권1호
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• pp.38-43
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• 2013

ETA (ethanolamine)는 원자력 발전소 2차계통의 pH 조절제인 암모니아 대체 물질로 2001년부터 이용되고 있다. 환경적 측면에서 난분해성 유기물이며 현재 운영 중인 원자력 발전소 폐수처리설비로 처리가 불가능하다. 본 연구는 현장 시료를 사용하여 N와 COD 제거하기 위한 최적 공정과 사용 약품에 대하여 조사하였다. 폐수 중에 다량 함유되어 있는 ammonium ion은 diffused aeration system을 이용하여 95% 이상을 제거하고 혼합과산화물(sodium persulfate/sodium percarbonate)을 사용하여 산화시키고 응집제를 사용하여 물리 화학적으로 처리 후 90% 이상의 제거효과를 얻을 수 있었다.

• 대한의용생체공학회:의공학회지
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• 제19권3호
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• pp.215-224
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• 1998

본 논문은 급성 간 부전 환자나 간이식 대기상태에 있는 환자에 이용하기 위한 체외 간 보조장치를 개발하기 위한 기초 실험에 관한 것이다. 밀도 33kg/m, 평균 직경 500um, 60-70%의 window를 가진 폴리우레탄 폼을 15% NCO-프리폴리머로 제조하였다. 폴리우레탄 폼에 접종된 간세포는 3일 후에 거의 모두 100-150um 크기의 구상체를 형성하였다. BSA 코팅을 한 폴리우레탄 폼은 BSA로 코팅하지 않은 폴리우레탄 폼보다 간세포 구상체 형성 시간이 더 짧았다. 폴리우레탄 폼에 형성된 간세포 구상체의 간 기능을 증명하기 위하여 암모니아 제거율과 요소 및 알부민 분비율을 측정하였다. 폴리우레탄 폼은 간세포 구상체 배양에 적합하며, 폴리우레탄 폼 내에서의 간세포 구상체 배양은 체외 간 보조장치로의 개발 가능성이 높다.

• Bulletin of the Korean Chemical Society
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• 제31권11호
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• pp.3283-3290
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• 2010

The gas-phase dehydration of glycerol to acrolein was carried out over 10 wt % HSiW catalysts supported on different supports, viz. $\gamma-Al_2O_3$, $SiO_2-Al_2O_3$, $TiO_2$, $ZrO_2$, $SiO_2$, AC, $CeO_2$ and MgO. The same reaction was also conducted over each support without HSiW for comparison. Several characterization techniques, $N_2$-physisorption, thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), the temperature-programmed desorption of ammonia ($NH_3$-TPD), temperature-programmed oxidation (TPO) with mass spectroscopy and CHNS analysis were employed to characterize the catalysts. The glycerol conversion generally increased with increasing amount of acid sites. Ceria showed the highest 1-hydroxyacetone selectivity at $315^{\circ}C$ among the various metal oxides. The supported HSiW catalyst showed superior catalytic activity to that of the corresponding support. Among the supported HSiW catalysts, HSiW/$ZrO_2$ and HSiW/$SiO_2-Al_2O_3$ showed the highest acrolein selectivity. In the case of HSiW/$ZrO_2$, the initial catalytic activity was recovered after the removal of the accumulated carbon species at $550^{\circ}C$ in the presence of oxygen.

• Membrane and Water Treatment
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• 제6권1호
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• pp.15-26
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• 2015

The compact structure and high-quality effluent of membrane bioreactors make them well-suited for decentralized greywater reclamation. However, the occurrence of membrane fouling continues to limit their effectiveness. To address this concern, a unique membrane module configuration was developed for use in a decentralized greywater treatment system. The module featured local aeration directly below a series of inclined membrane bundles, giving the overall module a twisted appearance compared to a module with vertically orientated fibres. The intent of this design was to increase the frequency and intensity of collisions between rising air bubbles and the membrane surface. Material related to the construction of custom-fit modules is rarely communicated. Therefore, detailed design and assembly procedures were provided in this paper. The twisted module was compared to two commercially available modules with diverse specifications in order to assess the relative performance and marketability of the twisted module with respect to existing products. Contaminant removal efficiencies were determined in terms of biochemical oxygen demand, chemical oxygen demand, ammonia, total nitrogen, total phosphorus, and turbidity for each module. Membrane fouling was monitored in terms of permeate flux, transmembrane pressure, and membrane resistance. Following 168 h of operation, the twisted module configuration demonstrated competitive performance, indicating good potential for further development and commercialization.

• 한국농업기계학회:학술대회논문집
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• 한국농업기계학회 2002년도 동계 학술대회 논문집
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• pp.383-388
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• 2002

본 연구에서 구성한 바이오필터 시스템은 암모니아 가스를 대상으로 여러 조건에서 성능을 구명하였으며, 필터 설계시 중요 인자인 송풍량, 온도, 함수율, 압력강하, 체류시간들간의 관계를 구명하였다. 필터 내부의 온도 변화는 체류시간 및 압력손실에 거의 영향을 주지 않았으며, 함수율의 변화가 체류시간과 압력손실에 미치는 영향은 함수율 값이 증가할수록 체류시간은 감소했으며 반대로 압력손실은 증가하는 결과를 보였다. 이는 필터 내부의 공극률 변화로 생긴 결과라 판단된다. 송풍량은 바이오필터 효율에 절대적으로 영향을 미치며 송풍량이 증가할수록 체류시간은 감소하며 초기 제거율도 떨어진다. 미생물의 투입 여부에 따른 제거율은 미생물 접종을 하지 않은 경우 초기 흡착에 의한 영향으로 제거율이 높다가 시간이 지남에 따라 차츰 낮아져 90% 이하로 떨어지는 경향을 보였고, 균주를 접종한 경우에 있어서는 시운전 기간 동안 거의 100% 가까운 제거 성능을 보였다. 본 연구는 실험실에서 암모니아 가스만을 대상을 하여 실험하였다. 따라서 실제 축사에서 발생하는 다양한 성분의 악취와 농도에 대한 성능 검증과 개선에 대한 연구가 보다 장기간에 걸쳐 이루어져야 할 것이다. 또한 소요되는 에너지와 운전비용의 절감 등의 유지관리, 바이오필터와 타 방식과의 조합, 그리고 다양한 전처리 방식의 개발 등 여러 측면에서 바이오필터 성능 개선에 대한 연구가 병행되어야 할 것으로 판단된다.