• Title/Summary/Keyword: ammonia removal,

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A development of reactor design software for De-NOx system using the selective catalytic reduction method (선택적 촉매 환원법을 이용한 De-NOx 시스템의 반응로 설계 전산프로그램 개발)

  • 정경열;오상훈;동은석;이수태;류길수
    • Proceedings of the Korean Society of Marine Engineers Conference
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    • 2002.05a
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    • pp.187-191
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    • 2002
  • The exhaust gas from electric power stations, incinerators and industrial boilers contains considerable amount of harmful nitric oxide which causes air pollution. Selective catalytic reduction system with ammonia as a reductant(NH$_{3}$ SCR) have been applied to remove NOx since 1970. it is widely accepted that the NH$_{3}$ SCR process is the best method for the removal of NOx. In this paper the design of SCR reactor based on the NOx displacement is considered and the design program of SCR reactor is developed. The newly developed design program for de-NOx system maybe used in practice.

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Decomposition of Odorous Gases in a Pilot-scale Nonthermal Plasma Reactor

  • Hwang, Yoon-Ho;Jo, Young-Min
    • Journal of Korean Society for Atmospheric Environment
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    • v.21 no.E2
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    • pp.57-65
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    • 2005
  • An experimental study was performed on the decomposition of gaseous ammonia and two selected volatile organic compounds (VOCs: toluene and acetone) in a combined nonthermal plasma reactor with corona and glow discharges. A lab pilot scale reactor (206 liter) equipped with a high electric power pack was used to determine the decomposition efficiency in relation with the inlet concentration and applied voltage. Three different types of discharging electrode such as wired rack, wire strings for corona discharge, and thin plate for glow discharge were put in order in the reactor. While decomposition of ammonia decreased with an increase in the initial concentration, acetone showed an opposite result. In the case of toluene however no explicit tendency was found in toluene and aceton. Negative discharge resulted in high decomposition efficiency than the positive one for all gases. A better removal of gas phase element could be achieved when fume dust were present simultaneously.

Application of magnetic activated sludge process for a milking parlor wastewater treatment with nitrogen and phosphorus recovery

  • Onodera, Toshihito;Sakai, Yasuzo;Kashiwazaki, Masaru;Ihara, Ikko;Lal, Saha Mihir
    • Progress in Superconductivity and Cryogenics
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    • v.23 no.3
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    • pp.20-25
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    • 2021
  • Milking parlor wastewater contains high concentration suspended solid (SS), nitrogen, and/or phosphate as well as organic compounds. A new biological wastewater process by magnetic separation, magnetic activated sludge (MAS) process, was applied to milking parlor wastewater treatment process. A three step wastewater treatment process of coagulation sedimentation / ammonia stripping (C/S), magnetic activated sludge process and contact oxidation (CO) was proposed for removal of these pollutants. First step, C/S process recovered 96% TN and 96% PO43--P as resource for fertilizer from the wastewater. 81% biochemical oxygen demand (BOD) in wastewater was removed after MAS process. As a results, all pollutant concentrations satisfied Japanese effluent standards. Most of residual BOD and SS were removed by the CO process. It was estimated that the proposed process could reduce the process space to 1/7.

Adsorption of phosphate and mitigation of biofouling using lanthanum-doped quorum quenching beads in MBR

  • Hyeonwoo Choi;Youjung Jang;Jaeyoung Choi;Hyeonsoo Choi;Heekyong Oh;Shinho Chung
    • Membrane and Water Treatment
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    • v.15 no.2
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    • pp.51-57
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    • 2024
  • The removal of phosphorus, especially phosphate-form phosphorus, is necessary in wastewater treatment. Biofouling induced by the quorum sensing mechanism is also a major problem in membrane bioreactor (MBR), which reduces membrane flux. This study introduces lanthanum-doped quorum quenching (QQ) beads into MBR, confirming their inhibitory effect on biofouling due to Rhodococcus sp. BH4 and their capacity for phosphorus removal through lanthanum adsorption. A batch test was conducted to access the phosphate adsorption of lanthanum-QQ (La-QQ) beads and lab-scale MBR to verify the effect of inhibition. The study aimed to identify distinctions among the MBR, QQ MBR, and La-QQ MBR. In the batch test, the phosphate removal rate increased as the volume of beads increased, while the unit volume removal rate of phosphate decreased. In the lab-scale MBR, the phosphate removal rates were below 20% in the control MBR and QQ MBR, whereas the La-QQ MBR achieved a phosphate removal rate of 74%. There was not much difference between the ammonia and total organic carbon (TOC) removal rates. Regarding the change in transmembrane pressure(TMP), 3.7 days were taken for the control MBR to reach critical pressure. In contrast, the QQ-MBR took 9.8 days, and the La-QQ MBR took 6.1 days, which confirms the delay in biofouling. It is expected that La-QQ can be used within MBR to design a more stable MBR process that regulates biofouling and enhances phosphate removal.

Effects of Organic Loading Rates on Treatment Performance in a Polyvinylidene Media Based Fixed-Film Bioreactor

  • Ahmed, Zubair;Oh, Sang-Eun;Kim, In S.
    • Environmental Engineering Research
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    • v.14 no.4
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    • pp.238-242
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    • 2009
  • This study investigated the effects of organic loading rates on simultaneous carbon and nitrogen removal in an innovative fixed-film aerobic bioreactor. The fixed-film bioreactor (FFB) was composed of a two-compartment aeration tank, in which a synthetic filamentous carrier was submerged as biofilm support media, and a settling tank which polyvinylidene media (Saran) was used as settling aid for suspended solids. Three different organic loading rates, ranging from 0.92-2.02 kg chemical oxygen demand/$m^3$/day were applied by varying hydraulic retention time (HRT). The total soluble organic carbon removal efficiencies were in the range of 90-97%. The removal efficiency of ammonia was found to be in the range of 70-84%. Total nitrogen removal efficiency was found to be in the range of 40-45%, which indicates that denitrification reactions occurred simultaneously in the attached biofilm on the fibrous media in the aeration tank. The settling performance of suspended solids was significantly improved due to the presence of Saran media in the settling compartment, even for a short HRT. The fixed-film aerobic bioreactor used in this study demonstrated efficient treatment efficiency even at higher organic loading rates and at short HRTs.

Combination of air stripping and biological processes for landfill leachate treatment

  • Smaoui, Yosr;Bouzid, Jalel;Sayadi, Sami
    • Environmental Engineering Research
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    • v.25 no.1
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    • pp.80-87
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    • 2020
  • Landfill waste decomposition generates a dark effluent named, leachate which is characterized by high organic matter content. To minimize these polluting effects, it becomes necessary to develop an effective landfill leachate treatment process. The objective of this study was to evaluate the performance of an innovative approach based on air stripping, anaerobic digestion (AD) and aerobic activated sludge treatment. A reduction of 80% of ammonia and an increase of carbon to nitrogen ratio to 25 were obtained, which is a suitable ratio for AD. This latter AD was performed in fixed bed reactor with progressive loading rate that reached 2 and 3.2 g COD/L/d for the raw and diluted leachate (1:2), respectively. The anaerobic treatment led to significant removal of chemical oxygen demand (COD) and biogas production, especially for the diluted leachate. The COD removal was of 78% for the raw leachate and a biogas production of 4 L/d with 70% methane content. The use of the diluted leachate led to 81% of COD removal and 7 L/d biogas with 75% methane content. It allowed a removal of 77% COD and more than 97% of the organic compounds present in the initial leachate sample.

Performance Evaluation of Subsurface-flow Wetland with Media Possessing Different Adsorption Capacities for Nitrogen and Phosphorus (질소 및 인에 대한 흡착특성이 다른 여재를 사용한 지하흐름형 인공습지 효율 평가)

  • Seo, Jun-Won;Jang, Hyung-Suk;Kang, Ki-Hoon
    • Journal of Korean Society on Water Environment
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    • v.23 no.1
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    • pp.155-160
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    • 2007
  • Constructed wetland has been widely used for the treatment of sewage, stormwater runoff, industrial wastewater, agricultural runoff, acid mine drainage and landfill leachate. For the removal of nitrogen and phosphorus, uptake by plants and adsorption to media material are the major processes, and, therefore, the selection of media with specific adsorption capacity is the critical factor for the optimal design of wetland along with the selection of appropriate plant species. In this study, two media materials (loess bead and mixed media) possessing different adsorption characteristics for ammonium and phosphate were selected, and their adsorption characteristics were evaluated. In addition, the performance of subsurface-flow wetland systems employing these media was evaluated in both batch and continuous flow systems. With LB medium, beter phosphorus removal was observed, while better ammonia removal was obtained with MM medium. In addition, enhanced removal efficiencies were observed in the wetland systems employing both media and aquatic plants, mainly due to the better environment for microbial growth. As a result, appropriate selection or combination of media with respect to the inflow water quality maybe important factors for the successful design and operation of wetland systems.

Efficiency Characteristics by Mixed Absorbents for the Removal of Odor Compounds in the Wet Scrubber (습식세정탑 내 악취가스 제거를 위한 복합흡수제의 효율 특성)

  • Park, Young G.;Kim, Jeong-in
    • Applied Chemistry for Engineering
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    • v.22 no.1
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    • pp.48-55
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    • 2011
  • It was found that the absorbent mixed with 2-aminoethanol and others has been applied to remove them via chemical neutralization. The absorbent of natural second metabolites was achieved by a removal efficiency of 20~30% by itself depending on treatment conditions, but the complex absorbent mixed with 0.2% amine chemical provides the removal efficiency of over 98%. Optimal removal efficiencies have been examined against two major parameters of the temperature and pH to remove ammonia and hydrogen sulfide gases. The chemical analysis was also performed to analyze the composition of an essential oil by GC-MS. The monoterpenes in an essential oil reacted with odorous compounds by neutralization and their reaction mechanism was partially elucidated.

Analysis of CA Certification Performance Test Results and Improvement of CA Test Method for a Better Differentiation of Gas Removal Performances for Room Air Cleaners (공기청정기 CA 규격성능시험 결과 분석 및 가스시험 변별력 향상 방안연구)

  • Kim, Hak-Joon;Han, Bangwoo;Kim, Yong-Jin;Cha, Sung-Il
    • Particle and aerosol research
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    • v.7 no.3
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    • pp.87-97
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    • 2011
  • In this study, we organized the test results obtained from the performance tests for the CA certificated air cleaners which had been commercially available in Korea since 2003, and analyzed the correlation among the test parameters such as flow rate, particle collection efficiency, clean air delivery rate (CADR), ozone emission, odor removal efficiency and noise level etc. The noise level of 267 air cleaners were increased as concentrated at the 45, 50, 55 dB, which are the required noise level for CA certification according to flow rate, and ozone emissions from the CA air cleaners were significantly lower than the requirement limit, 50 ppb for 24 hour operation. The average particle collection efficiency and odor removal efficiency were 89.3 and 80.8%, approximately 20% higher than the requirement of CA certification, regardless of flow rates. The particle removal performance of an air cleaner was clearly discriminated by its CADR, and the CADR was obtained with a simple calculation: 0.79 x flow rate. The low differentiation of gas removal performance of air cleaners by the current CA gas test method was improved by 3.2, 751.3, 13.4 times for ammonia, acetic acid, respectively, by adopting the CADR concept and the real time measurement method, FTIR, for gas removal performance test.

A Study on the Treatment of Ammonia-Nitrogen in the Septic Tank Effluent Using Biological Fluidized Bed (생물학적(生物學的) 유동층(流動層)을 이용(利用)한 정화조유출수(淨化槽流出水)의 암모니아성(性) 질소제거(窒素除去)에 관한 연구(研究))

  • Kim, Hwan Gi;Kwon, Moon Sun
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.6 no.2
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    • pp.35-44
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    • 1986
  • This paper is a basic study of the experimental results for the treatment of ammonia-nitrogen in the septic tank effluent. The substrates in this experiment are actual septic tank effluent and synthetic waste-water which is similar to septic tank effluent containing a considerable amount of nitrogenous component. Experiments were conducted for organic removal and nitrification using various recycle ratio and hydraulic retention time at each stage. The results obtained show that organic removal rate was above 80% in the 1st and 2nd stage, but as nitrification process was proceeded, above 90% of ammonia-nitrogen was removed in the 3rd and 4th stage. In these cases, the recycle ratio and HRT were found 30 and 7 hrs respectively. In the relation of $NH_4{^+}-N$ removal to $NO_3{^-}-N$ formation in the synthetic waste-water and septic tank effluent, when $1mg/{\ell}$ of $NH_4{^+}-N$ was removed, $NO_3{^-}-N$ formations were $0.95mg/{\ell}$ and $0.82mg/{\ell}$ respectively. And kinetics of nitrification using Biological Fluidized Bed was discussed also.

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