• 한국환경농학회지
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• 제37권1호
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• pp.49-56
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• 2018

본 연구는 국내에서 다량 취급되고 있는 암모니아 및 톨루엔을 흄 상태로 노출시킨 후 흡수/흡착방법을 달리한 이동형 스크러버를 이용해 각 유해화학물질의 제거효율을 비교 분석하였다. 이동형 스크러버는 기 개발된 장치를 개선하여 와류 세정에 의한 흡수, 유입풍속 조절의 장점을 살리고, 활성탄 및 카본필터를 통한 기체상 유해화학물질의 흡착방법 도입을 통해 단점을 보완하였다. 개선된 장치는 기초성능평가를 통해 적정 제어풍속이 검증되었고, 5% 암모니아수 용액을 흄 상태로 노출시켜 후드 흡입부, 송풍기 배출부 및 세정기가 정상 작동함을 확인하였다. 흡수/흡착방법에 따른 암모니아 제거효율은 90분 경과 후 C${\geq}$PCA>SWA 순으로 가장 우수한 SWA 군의 노출 농도별 제거 효율은 시간이 경과할수록 노출 농도와 무관하게 배출 농도는 증가되었고, 세정액의 pH는 산성에서 염기성으로 변화되었다. 또한, 시간 경과에 따른 노출 농도 별 세정액의 pH 변화와 배출구 농도 변화 사이에 0.9429~0.9491 수준의 정의 상관관계를 나타내었다. 흡착방법에 따른 톨루엔의 제거 효율은 초기 10분 경과 후 배출구농도에서 C>CMA${\geq}$GCA 순을 나타내다 90분 경과까지 일정한 농도로 유지되었다. 가장 우수한 GCA 군의 노출 농도별 제거 효율은 초기 10분 경과 시 노출 농도에 비례하여 배출 농도가 높은 경향이었다. 이와 같은 결과를 통해 개선된 이동형 스크러버는 중화반응에 의해 산성 또는 염기성 유해 화학물질의 제거 뿐 아니라, 활성탄 등의 흡착기능 개선을 통해 VOCs 제거에도 효과적이었다. 하지만, 실제 현장에서 활용이 가능하도록 세정액 pH를 지속적으로 유지하여 연속적으로 흡수 제거할 수 있는 방법과 노출되는 화학물질 농도와 흡착제의 관계에서 파괴점, 포화점, 흡착속도 등의 물리적인 요소가 추가적인 연구를 통해 도출되어야 할 것이다.

• 한국수산과학회지
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• 제20권6호
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• pp.561-567
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• 1987

순환 여과식 양식에 있어서 사육수에 축적되는 암모니아를 여과 재료별로 그 제거 능력을 알아보고, 실제 산업에의 적용에 관한 문제를 검토하였다.. 여과 재료는 첨모직(pile cloth), 스카이 라이트 골판(corrugated skylight roofing plate), 요철 플라스틱판(embossed plastic plate), 및 자갈의 4종류를 사용, $90cm\times60cm\times60cm$(깊이)의 수조에 각각 2개씩 같은 재료를 넣어서 모두 8개를 설치하였다. 주입수는 부산수산대학 순환여과식 양식 시설의 어류사육 탱크에서 나오는 물을 사용하여 그 속에 함유된 암모니아 제거능력을 측정하였다. 정상적 기능을 발휘하는 두 기간의 여과 재료별 1일 $1m^3$의 여과제 설치 용적당 평균 암모니아 제거 능력은 다음과 같았다. 1) 첨모직 8.381g 2) 2) 스카이 라이트 골판 7.834g 3) 요철 플라스틱판 7.797g 4) 자갈 7.051 g 이와 같이 주기능 발휘 기간동안에는 재료별 차이가 별로 없었지만 그 기간의 길이 차이, 청소의 난이도, 설치 비용 등을 고려해야 한다. 특히 대형 여과조의 경우, 자갈 여과조를 청소하는 일은 대단히 어렵고, 첨모직 여과조는 그 설치 작업이 까다롭고, 배수시 그 구조를 유지하는 데 어려운 문제가 따른다. 이러한 관점에서 볼 때 스카이 라이트 곡판과 요철 플라스틱판이 가장 적당하다고 생각된다. 그러나, 실제 설치시는 재료의 입수 가능성, 가격은 물론, 사용중 또는 계획중의 여과 탱크에의 적합 여부도 고려되어야 한다.

• Environmental Engineering Research
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• 제18권4호
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• pp.267-276
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• 2013

This study presents a comparison of different protocols for the synthesis of iron-loaded zeolites, and the results of their application, as well as that of zeolite-A (Z-A), to the removal of ammonium and phosphate from aqueous media. Zeolites prepared by three methods were evaluated: iron-incorporated zeolites (IIZ), iron-exchanged zeolites (IEZ), and iron-calcined zeolites (ICZ). The optimal iron content for preparing of IIZ, as determined via scanning electron microscopy and X-ray photoelectron spectroscopy analyses, expressed as molar ratio of $SiO_2:Al_2O_3:Fe$, was below 0.05. Ammonia removal revealed that the iron-loaded zeolites have a higher removal capacity than that of Z-A due, not only to ion-exchange phenomena, but also via adsorption. Greater phosphate removal was achieved with IEZ than with ICZ; additionally, no sludge production was observed in this heterogeneous reaction, even though the coagulation process is generally accompanied by the production of a large amount of undesired chemical sludge. This study demonstrates that the developed synthetic iron-loaded zeolites can be applied as a heterogeneous nutrient-removal materials with no sludge production.

• 상하수도학회지
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• 제21권3호
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• pp.295-303
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• 2007

Nitrogen compounds in municipal wastewater can be divided into biodegradable and nonbiodegradable fractions with biodegradability. Biodegradable nitrogen compounds can be removed through biological nitrification and denitrification processes, and nonbiodegradable nitrogen compounds affect the effluent quality of biological nutrient removal processes. The amount of nitrifiable nitrogen compounds, which are the sum of ammonia and biodegradable organic nitrogen, has been estimated by respirometry. Respirometry shows good estimation of the concentration of nitrifiable nitrogen when a synthetic sample of ammonium chloride is dosed. The estimated concentration of nitrifiable nitrogen compounds in municipal wastewater is close to ammonia concentration in municipal wastewater, but it is lower than that for the synthetic sample. If nitrogen assimilated into cell synthesis of nitrifiers and heterotrophs is considered, the total amounts of nitrifiable nitrogen compounds, which are nitrified and assimilated, could be more accurately estimated. The concentration of nitrifiable nitrogen compounds, which are biodegradable, is about 31 mg N/l, and this is 119% of ammonia and 94% of total nitrogen. Ammonia, nitrate, biodegradable organic nitrogen, and nonbiodegradable nitrogen are about 79%, 1%, 15%, and 5% of the total nitrogen in municipal wastewater, respectively.

• 해양환경안전학회:학술대회논문집
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• 해양환경안전학회 2004년도 춘계학술발표회
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• pp.81-84
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• 2004

Control of Sediment is very important in prawn farm due to the eruption of toxic material such as W1ionized H2S, NH3 and NO2-. In this study, column test study, column with filter media such as activated carbon, zeolite, oyster shell and iron chloride to evaluate the reduction of toxicity from sediment ammonia-N(NH3) was effectively removed by Zeolite and oyster shell. It was indicated that ammonium ion(NH4+) was removed by ion exchange of zeolite. And the ammonia in the column of oyster shell was existed as the form of NH4+, which is not toxic for prawn because oyster shell was stably kept around pH 8. Therefore, some of ammonia(NH3) was reduced by oyster shell. Hydrogen sulfide and COD were effectively removed by adsorption of activated carbon and a partial removal of hydrogen sulfide was accomplished by Oyster shell. Phosphorous was removed by activated carbon, oyster shell and iron chloride. In prawn farm, the concentration of ammonia was increased with increase of pH by algae photosynthesis in the column of activated carbon, zeolite and iron chloride, but it was revealed that pH was stably kept in the column of oyster shell.

• 한국농공학회지
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• 제45권2호
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• pp.107-115
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• 2003

Dairy manure amended with crop and forest residues (moisture 69% wet basis, C/N 22) was composted in a 605 L pilot-scale vessel using continuous air flow (56 L/min) for 19 days. Three pilot-scale sawdust biofilters (moisture 63%, pH 5.0) were built to clean biological waste gas from the composting process. For each methods, two replicated experiments were monitored over a period of three weeks. The system was evaluated to determine the biofilter media depth that would be adequate for compost odour reduction. The compost air cleaning was measured based on ammonia gas concentration before and after passing through the biofilter. Ammonia gas removal efficiency over 3 weeks was 42, 75 and 87% at sawdust biofilter media depth levels of 202, 400 and 600 mm, respectively. Each sawdust biofilter was operated at a moisture content in the range of 60~62% (wb), a temperature from 15 to $25^{\circ}C$, an average pressure drop from 240 to 340 Pa and a detention time from 60 to 180 seconds during the biofiltration process.

• 한국물환경학회지
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• 제27권5호
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• pp.563-571
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• 2011

The purpose of this study is to investigate the high strength ammonia oxidation of piggery wastewater. Laboratory scale reactors was operated using influent of piggery wastewater and effluent of anaerobic digester from piggery wastewater at $35^{\circ}C$ and $20^{\circ}C$. Results of various operating conditions were compared and analyzed. After analyzing the results, effluent of anaerobic digester from piggery wastewater required shorter Solid retention time (SRT) than influent of piggery wastewater. In terms of the temperature, stable ammonia removal and denitrification was achieved on the both of the condition. At the temperature of $35^{\circ}C$, nitrite conversion rate was better than $20^{\circ}C$. It can be concluded that treating the piggery wastewater using anaerobic digester on the condition of the temperature at $35^{\circ}C$ is more efficient on the nitritation of the piggery wastewater.

• 한국생물공학회:학술대회논문집
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• 한국생물공학회 2002년도 생물공학의 동향 (X)
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• pp.343-345
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• 2002

This study was performed by the airlift bioreactor using the nitrifier consortium entrapped in polyvinyl alcohol(PVA) for removing low concentration total ammonia nitrogen(TAN). At the aeration rate of 1.5 vvm, TAN removal rate and removal efficiency was 316.6${\pm}$7.2 $g/m^3$ day and 92.8${\pm}$2.2%. Removal rate was continuously increased with decreasing from 0.5hr to 0.05hr of hydraulic residence time(HRT), whereas removal efficiency was decreased with decreasing HRT.

• 한국축산시설환경학회지
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• 제6권2호
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• pp.65-72
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• 2000

This study was conducted to investigate the effects of artificial filaments equipped in the aeration tank of aerobic·fermentation system on the removal efficiency of swine wastes which were fermented an aerobically and thus containing high nitrogen. Two aerobic fermentation system each consist4s of 4 tanks ; storage tank, 1st and 2nd aeration tank and settling tank were run before and one or three weeks after equipment of artificial filament in the aeration tanks. Total solids concentration tended to increase by aerobic fermentation in all running periods. However, decreased(P<0.05) total nitrogen concentration was shown three weeks after the equipment of artificial filament. Ammonia nitrogen concentration also largely decreased(p<0.05) in both running periods of one and three weeks after equipment of artificial filaments. These results suggest that the artificial filaments may improve the removal efficiency of nitrogen in swine wastewater containing high nitrogen during aerobic fermentation.

• 미생물학회지
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• 제44권1호
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• pp.29-36
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• 2008

질소는 하수처리과정에서 제거되어야 하는 주요 오염물질 중의 하나이며, 세균 군집을 이용한 고도처리 시스템에서 생물학적 질소제거는 중요한 기술이다. 질산화반응은 생물학적 질소제거 시스템의 첫 단계로 미생물에 의해 진행된다. 암모니아는 암모니아산화세균에 의해 아질산염으로 산화되며, 그 후에 아질산염은 아질산염 산화세균에 의해 질산염으로 산화된다. 실험실 규모의 생물학적 질소제거 시스템인 변형된 eBAF 시스템, Nutrient removal laboratory 시스템과 반추기법을 적용한 rSBR 시스템의 질산화반응조 시료에서 16S rRNA 유전자를 이용한 terminal restriction fragment length polymorphism (T-RFLP) 방법으로 아질산염 산화세균군집을 분석하였다. 제한효소로 형성된 단편의 클러스터분석에서 Nitrobacter 군집은 각각의 폐수처리 시스템에 따라 군집의 차이가 있음이 나타났다. 그러나 Nitrospira 군집의 클러스터분석에서는 액체와 담체의 서식지 환경 차이에 의해 군집이 구분되었다.