• Journal of Microbiology and Biotechnology
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• 제13권2호
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• pp.301-304
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• 2003

In this study, hydrogen sulfide ($H_2S$), ammonia ($NH_3$), and benzene, which represent the major odor from a natural leather process plant, were removed using a fluidized bed bioreactor and biofilter including Thiobacillus sp. IW and a MY microbial consortium. The critical removal rate was $12g m^{-3}h^{-1}\;for\;H_2S,\;11g m^{-3}h^{-1}\;for\;NH_3\;and\;28 g m^{-3}h^{-1}$ for benzene by the fluidized bed bioreactor, and $8.5g m^{-3}h^{-1}\;for\;H_2S\;7g m^{-3}h^{-1}\;for\;NH_3,\;and\;25 g m^{-3}h^{-1}$ for benzene in the biofilter. The average removal efficiency of $H_2S$, $NH_3$, and benzene by continuous operation for over 30 days with the fluidized bed bioreactor was $95{\pm}3\%,\;99{\pm}1\%,\;and\;98{\pm}5\%$, respectively, whereas that with the biofilter was $96{\pm}4\%,\;95{\pm}4\%,\;and\;97{\pm}3\%$, respectively. Therefore, the critical removal rate of $H_2S$, $NH_3$, and benzene was higher in the fluidized bed bioreactor, whereas the removal efficiency on the continuous operation was similar in both bioreactors.

• 한국생물공학회:학술대회논문집
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• 한국생물공학회 2000년도 춘계학술발표대회
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• pp.339-342
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• 2000

황화수소와 암모니아 함유악취의 동시처리를 위해 Thiobacillus sp.IW가 함유된 3상 생물막유동층반응기를 사용하였다. 본 연구에서 황화수소는 미생물에 의해 산으로 전환되었으며 이어서 유입된 암모니아와 반응하여 황산암모늄이 생성됨으로서 양성분은 제거되었다. 황화수소의 경우 45 mg/l h의 유입량에서도 거의 완전한 처리 효율을 보여주었으나, 암모니아의 경우 유입량이 10 mg/l h에서 증가함에 따라 처리효율은 점차 감소하였다.

• 한국물환경학회지
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• 제21권5호
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• pp.505-510
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• 2005

The objective of this study was to remove non-biodegradable matters and ammonia ion in livestock wastewater using Fenton oxidation and Zeolite adsorption process. After coagulation process as 1st treatment, non-biodegradable matters remained after 1st treatment were removed by using OH radical produced in Fenton oxidation process. Zeolite as cation adsoption process was used to remove ammonia ion in 2nd treatment water. As a result of treatment using these processes, NBDCOD removal efficiency was over 90% and ammonia ion was almost removed. Most aromatics or polynuclear aromatics like benzene, phenol and scatol in livestock wastewater wasn't detected after Fenton oxidation process.

• KSBB Journal
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• 제16권2호
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• pp.140-145
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• 2001

To treat piggery wastewater containing refractory compounds including nitrogen, physical treatments using zeolite and biological processes were investigated. In biogical treatment, the removal efficiencies of organics and nitrogen in bioreador using BACC (Biological Activated Carbon Cartridge) media filled with granule activated carbon were examined. The best removal efficiencies achieved for TKN and COD(sub)cr were 82% and 53% respectively, when zeolite dosage was 300 g/L. Specific nitrogen removal ability was 3.2 mg/g at a zeolite dosage of 50 g/L, whereas specific nitrogen removal ability was 1.8 mg/g at a zeolite dosage of 300 g/L. The increased of C/N ratio resulting from the removal of nitrogen using zeolite led to an increase in removal efficiency of organics. As C/N ratio was increased to 2.0, 2.44 and 6.58 at a HRT of 48 hours in a BACC bioreactor, removal efficiencies of COD(sub)cr were increased to 53.5%, 57.4% and 80.6%. The removal efficiency of wastewater using a zeolite dosage of 399 g/L was increased by 27.1% compared to that of control treatment.

• 한국환경보건학회지
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• 제40권4호
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• pp.322-329
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• 2014

Objectives: The purpose of this study was to investigate the effect of BIO-CLOD on advanced wastewater treatment for enhanced removal efficiency and meeting the stringent discharge water requirements of wastewater treatment plants. Methods: Two experimental apparatuses consisting of anaerobic, anoxic and aeration tanks were operated. One included a BIO-CLOD cultivation tank. Organic and nutrient parameters and removal efficiency were analyzed by pH, BOD, CODcr, SS, T-N and T-P. Results: The average removal efficiencies of BOD, COD and SS from the apparatus with BIO-CLOD tank installation were 95.5%, 88.6% and 92.9%, respectively, and these were higher than the results from the apparatus without BIO-CLOD. The average TP removal efficiency with BIO-CLOD tank marked 56.0%, higher than the 47.3% from the apparatus without one. BIO-CLOD showed a higher performance for TN removal at 49.6%, compared to the result without BIO-CLOD of 34.3% Conclusion: By reaction with BIO-CLOD, ammonia removal was effective in the aeration tank, as was phosphorus release in the anaerobic tank. Phosphorus luxury uptake and nitrification in aeration tank proceeded smoothly. The application of BIO-CLOD can improve the decrease of odor and settleability of activated sludge in a wastewater treatment plant, as well as increase the removal efficiency of organic and nutrient materials in water.

• 한국축산시설환경학회지
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• 제14권2호
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• pp.91-96
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• 2008

The odours from spreading the slurry, manure storage tanks, and the stall are a source of annoyance for the neighbors and sometimes even become a case for civil appeal. Reducing the odourant and ammonia emission is an urgent need to be addressed. It is known that brown coal and oak charcoal have an ability to absorb odour. We designed an experiment set in lab scale and used the brown coal and oak charcoal as additives in the test to reduce odour. The test are divided into two categories; namely aeration and no-aeration. The additives were added to the each sample at a concentration of 5% and 10% of total base solids, besides the control samples. We carried out the Phenate Method for ammonia analyzing. In the non-aerated case, the results showed a reducing efficiency of 23.7% and 26.4% with an addition rate of 5% and 10% of additives, respectively. In the aerated test, the reducing efficiency of ammonia was 17.8% and 21.0% with an addition rate of 5% and 10% of additives, respectively. In case of oak charcoal, non-aeration showed removal efficiencies of ammonia at 15.9% and 16.1% with addition rates of 5% and 10%, respectively, With aeration, they were 11.4% and 26.4% with addition rates of 5% and 10% oak charcoal, respectively. The tests show that brown coal and oak charcoal have a reducing effect on ammonia emissions.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2011년도 춘계학술대회 초록집
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• pp.179.1-179.1
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• 2011

Pretreatment of cellulosic biomass is necessary before enzymatic saccharification and fermentation. The objective of this study was to evaluate the effect of combined aqueous ammonia-dilute sulfuric acid treatment on cellulosic biomass. Miscanthus was pretreated using aqueous ammonia and dilute sulfuric acid solution under high temperature and pressure conditions to be converted into bioethanol. Aqueous ammonia treatment was performed with 15 %(w/w) ammonia solution at $150^{\circ}C$ of reaction temperature and 20 minutes of reaction time. And then, dilute sulfuric acid treatment was performed with 1.0 %(w/w) sulfuric acid solution at $150^{\circ}C$ of reaction temperature and 10 minutes of reaction time. The compositional variations of this combined aqueous ammonia-dilute sulfuric acid treatment resulted in 68.0 % of cellulose recovery and 95.7 % of hemicellulose, 81.3 % of lignin, 89.1 % of ash removal respectively. The enzymatic digestibility of 90.5 % was recorded in the combined pretreated Miscanthus sample and it was 14.7 times higher than the untreated sample. The ethanol yield in the Simultaneous Saccharification and Fermentation was 90.4 % of maximum theoretical yield based on cellulose content of the combined pretreated sample and it was about 98 % compared to the ${\alpha}$-cellulose ethanol yield.

• 폴리머
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• 제31권6호
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• pp.479-484
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• 2007

본 연구는 점착제 분사방식으로 고성능 hybrid ion exchange fiber(HIEF)를 제조하고 이들의 암모니아 흡착성능 및 기본물성을 측정하였다. HIEF의 이온교환용량은 수지 부착량이 증가함에 따라 증가하였으며 단일 수지와 이온교환섬유의 이온교환용량보다 크게 나타났다. 또한 암모니아의 제거율은 HIEF의 충전밀도가 증가할수록 증가하였으며 흡착 파과시간은 270분으로 섬유나 수지에 비해 길게 나타났고 최대 암모니아 흡착량은 94%이었다. 또한 암모니아 흡착 파과시간은 유량 및 농도가 증가함에 따라 빠르게 진행되었다. 암모니아 반응속도 상수(k)는 유입되는 가스농도의 증가에 따라 증가하였으며, 질량이 증가할수록 감소하였으며 가스 유속이 증가할수록 반응속도 상수(k)가 증가하였다.

• 한국자동차공학회논문집
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• 제23권2호
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• pp.199-207
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• 2015

Solid materials of ammonia sources with SCR have been considered for the application of lean NOx reduction in automobile industry, to overcome complex problems of liquid urea based SCR. These solid materials produce ammonia gas directly with proper heating and can be packaged by compact size, because of high volumetric ammonia density. Among ammonium salts and metal ammine chlorides, calcium ammine chloride was focused on this paper due to low decomposition temperature. In order to make calcium ammine chloride in lab-scale, simple reactor and glove box was designed and built with ammonium gas tank, regulator, and sensors. Basic test conditions of charging ammonia gas to anhydrous calcium chloride are chosen from equilibrium vapor pressure by Van't Hoff plot based on thermodynamic properties of materials. Synthetic method of calcium ammine chloride were studied for different durations, temperatures, and pressures with proper ammonia gas charged, as a respect of ammonia gas adsorption rate(%) from simple weight calculations which were confirmed by IC. Also, lab-made calcium ammine chloride were analyzed by TGA and DSC to clarify decomposition step in the equations of chemical reaction. To understand material characteristics for lab-made calcium ammine chloride, DA, XRD and FT-IR analysis were performed with published data of literature. From analytical results, water content in lab-made calcium ammine chloride can be discovered and new test procedures of water removal were proposed.

• 한국환경농학회지
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• 제34권2호
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• pp.134-138
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• 2015

본 연구에서는 기존 스크러버의 분사노즐과 충진층의 폐쇄 위험성 및 장치의 복잡함으로 인한 단점을 극복하고 화학사고 발생 시 현장에서 유해물질의 신속한 처리가 가능하도록 이동형 와류식 세정장치를 제작하였다. 제작된 장치의 성능을 확인하기 위하여 후드 입구에서 유입풍량 조절에 따른 송풍기 배출구에서의 풍속변화를 확인하였으며, 분무연기 및 25% 암모니아 용액을 이용하여 성능평가를 수행하였다. 제작된 장치의 후드 댐퍼 개방 각도를 변화시킴에 따라 유입풍속(유입유량)이 변하는 것을 확인하였으며, 이는 물질의 용해도 특성 및 농도에 따라 유입풍속을 증감시켜 세정기 내에서의 체류시간을 조절하는데 유용할 것으로 판단된다. 제작된 장치의 유해가스 제거성능을 확인하기 위하여 분무연기와 25% 암모니아 용액을 이용하여 실험을 수행하였다. 세정기 후드의 댐퍼를 완전 개방시킨 상태에서 분무연기를 노출시킨 결과, 높은 유입 유량으로 인해 연기 일부는 와류 내에서 체류하지 못하고 송풍기로 배출되었다. 그러므로 암모니아 용액을 이용한 실험에서는 댐퍼 개방 각도를 60도로 설정하여 후드에 노출시켰다. 암모니아 용액을 30분간 세정기에 흡입시킨 후 물의 pH를 측정한 결과 12 이상으로 나타나 염기성의 암모니아 가스가 물에 충분히 흡수된 것을 관찰하였다. 후드 입구 및 송풍기 배출구에서 암모니아 농도 비교시, 체류시간 5분일 때 제거효율 83%로 최대로 나타났으며(pH 10) 이후로 급격히 감소하는 경향을 나타내었다. 이는 유해가스의 물에 대한 용해도외에도 체류시간이 세정액으로의 흡수 및 제거효율에 미치는 중요한 인자임을 나타낸다.