• Journal of the Korean institute of surface engineering
• /
• v.56 no.2
• /
• pp.125-136
• /
• 2023

Recently, ammonia has emerged as an alternative energy source that can reduce carbon emissions in various industries. Ammonia is used as a fuel in internal combustion engines because it contains no carbon in its components and does not emit any carbon when burned. It is also used in various fields such as fertilizer production, refrigeration, cleaning and disinfection, and drug manufacturing due to its unique characteristics, such as high volatility and easy solubility in water. However, it is highly corrosive to metals and is a toxic gas that can pose a risk to human health, so caution must be exercised when using it. In particular, stress corrosion cracking may occur in containers or manufacturing facilities made of carbon-manganese steel or nickel steel, so special care is needed. As ammonia has emerged as an alternative fuel for reducing carbon emissions, there is a need for a rapid response. Therefore, based on a deep understanding of the causes and mechanisms of ammonia corrosion, it is important to develop new corrosion inhibitors, improve corrosion monitoring and prediction systems, and study corrosion prevention design.

• Korean Journal of Environmental Agriculture
• /
• v.34 no.2
• /
• pp.134-138
• /
• 2015

BACKGROUND: In recent years, several researchers have focused on odour control methods to remove the harmful chemicals from chemical accidents and incidents. The present work deals with the system development of the hazardous. METHODS AND RESULTS: For on-site removal of hazardous gaseous materials from chemical accidents, mobile vortex wet scrubber was designed with water vortex process to absorb the gas into the water. The efficiency of the mobile vortex wet scrubber was evaluated using water spray and 25% ammonia solution. The inlet air velocity (gas flow rate) was according to the damper angle installed within the hood and with increase of gas flow rate, consequently the absorption efficiency was markedly decreased. In particular, when 25% ammonia solution was exposed to the hood inlet for 30 min, the water pH within the scrubber was changed from 7 to 12. Interestingly, although the removal efficiency of ammonia gas exhibited approximately 80% for 5 min, its efficiency in 10 min showed the greatest decrease with 18%. Therefore, our results suggest that the ammonia gas may be absorbed with the driving force of scrubbing water in water vortex process of this scrubber. CONCLUSION: When chemical accidents are occurred, the designed compact scrubber may be utilized as effective tool regarding removal of ammonia gas and other volatile organic compounds in the scene of an accident.

• Asian Journal of Atmospheric Environment
• /
• v.10 no.3
• /
• pp.125-136
• /
• 2016

In this study, the effects of the mesh barrier on the free dispersion of ammonia were numerically investigated under different atmospheric conditions. This study presents the detail and flow feature of the dispersion of ammonia through the mesh barrier on various free stream conditions to decline and limit the toxic danger of the ammonia. It is assumed that the dispersion of the ammonia occurred through the leakage in the pipeline. Parametric studies were conducted on the performance of the mesh barrier by using the Reynolds-averaged Navier-Stokes equations with realizable k-${\varepsilon}$ turbulence model. Numerical simulations of ammonia dispersion in the presence of mesh barrier revealed significant results in a fully turbulent free stream condition. The results clearly show that the flow behavior was found to be a direct result of mesh size and ammonia dispersion is highly influenced by these changes in flow patterns in downstream. In fact, the flow regime becomes laminar as flow passes through mesh barrier. According to the results, the mesh barrier decreased the maximum concentration of the ammonia gas and limited the risk zone (more than 500 ppm) lower than 2 m height. Furthermore, a significant reduction occurs in the slope of the upper boundary of $NH_3$ risk zone distribution at downstream when a mesh barrier is presented. Thus, this device highly restricts the leak distribution of ammonia in the industrial plan.

• Journal of Climate Change Research
• /
• v.10 no.3
• /
• pp.237-242
• /
• 2019

Ammonia is main precursor gas of secondary particulate matter and contributes almost 78% of total ammonia emission from the agricultural sector in Korea. The current method of estimating ammonia emission from fertilizer application, which contributes 7% of the total emission, has high uncertainty and needs to be improved to better predict PM2.5 concentration. In this study, we suggest an improvement method for ammonia emission quantification from fertilizer application. The first improvement was in the emission factor of NPK fertilizer by conducting a field study to verify the currently used factor. The improved NPK emission factor of 52.2 kg NH ton-1N was confirmed by comparing with the value from the EEA (European Environment Agency) and adjusting the value for the Korean climate and soil conditions. We also improved the amount of fertilizer usage by including the sales amount to the fertilizer supply amount of the Korean Farmers Association, increasing total fertilizer usage by 39.8%. As the statistical data on fertilizer supply and sales are compiled yearly, we estimated monthly emission of ammonia by considering cultivated areas and timing of fertilization for each crop. In summary, we suggest a novel and practical method to improve estimation methodology of ammonia emission from the field of fertilizer application: 1) emission factor of NPK fertilizer was reconfirmed; 2) total amount of fertilizer use was revised considering fertilizer sales; and 3) monthly emission of ammonia was realized by considering different crop practices. A bottom-up approach to compile activity data is needed to increase the estimation accuracy of monthly emission of ammonia, which is very helpful for predicting PM2.5 concentration.

• Proceedings of the Korea Association of Crystal Growth Conference
• /
• 2000.06a
• /
• pp.143-150
• /
• 2000

Wet-chemical process using ammonia to precipitate aluminum ion dissolved in a zirconia sol solution is examined. Formation of crystalline bayerite is unfavorable for fine dispersion of zirconia nanoparticles in alumina matrix after heat treatment. To avoid the bayerite formation, it was preferred to make a precipitation with a diluted ammonia or with an ammonia gas flow at high temperature. By optimizing the precipitation process and the calcination temperature, we successfully prepared the uniform microstructure in which tetragonal zirconia particles of ∼30nm is finely dispersed within the alumina grains.

• Journal of Environmental Science International
• /
• v.12 no.12
• /
• pp.1309-1313
• /
• 2003

This study was carried out to obtain the optimal ammonia removal efficiency using pyroligenous liquid for the economical and environment-friendly odor removal at a petty livestock farmhouse. The ammonia removal efficiencies were evaluated due to changing dilution rates(${\times}$10, ${\times}$20, ${\times}$30, ${\times}$50 and ${\times}$100 times) and different spray amounts(10$m\ell$ and 20$m\ell$) of pyroligenous liquid. The wet scrubber device was used to remove odor in closed-type livestock farmhouse. According to dilution rate of the pyroligenous liquid, the optimum rate was 20 times and the removal efficiency increased by decreasing dilution rates. In the case of spray amounts with the optimum dilution, the amount was 20 me and the removal efficiency increased by increasing spray amount. Also, the removal efficiency by using wet deodorizing device was 83.0-97.0％ with 20 times diluted liquid.

• Transactions of the Korean hydrogen and new energy society
• /
• v.31 no.4
• /
• pp.363-371
• /
• 2020

Recently, the technologies to utilize the cold energy of liquefied natural gas (LNG) have attracted significant attention. In this paper, thermodynamic performance analysis of combined cycles consisting of ammonia Rankine cycle (AWR) and organic Rankine cycle (ORC) with LNG Rankine cycle to recover low-grade heat source and the cold energy of LNG. The mathematical models are developed and the effects of the important system parameters such as turbine inlet pressure, ammonia mass fraction, working fluid on the system performance are systematically investigated. The results show that the thermal efficiency of AWR-LNG cycle is higher but the total power production of ORC-LNG cycle is higher.

• Journal of the Korean Society of Marine Environment & Safety
• /
• v.29 no.7
• /
• pp.964-970
• /
• 2023

As part of the International Maritime Organization ef orts to reduce greenhouse gas emissions, the maritime industry is exploring low-carbon fuels such as liquefied natural gas and methanol, as well as zero-carbon fuels such as hydrogen and ammonia, evaluating them as environmentally friendly alternatives. Particularly, ammonia has substantial operational experience as cargo on transport ships, and ammonia ship engines are expected to be available in the second half of 2024, making it relatively accessible for commercial use. However, overcoming the toxicity challenges associated with using ammonia as a fuel is imperative. Detection is possible at levels as low as 5 ppm through olfactory senses, and exposure to concentrations exceeding 300 ppm for more than 30 min can result in irreparable harm. Using the KORA program provided by the Chemical Safety Agency, an assessment of the potential risks arising from leaks during ammonia bunkering was conducted. A 1-min leak could lead to a 5 ppm impact within a radius of approximately 7.5 km, affecting key areas in Busan, a major city. Furthermore, the potentially lethal concentration of 300 ppm could have severe consequences in densely populated areas and schools near the bunkering site. Therefore, given the absence of regulations related to ammonia bunkering, the potential for widespread toxicity from even minor leaks highlights the requirement for the development of legislation. Establishing an integrated system involving local governments, fire departments, and environmental agencies is crucial for addressing the potential impacts and ensuring the safety of ammonia bunkering operations.

• Journal of Biosystems Engineering
• /
• v.36 no.5
• /
• pp.342-347
• /
• 2011

The effect of SNC(silver nano colloid) on the emission reduction of odors such as ammonia ($NH_3$), hydrogen sulfide ($H_2S$), and methane ($CH_4$) from swine excreta was studied. Silver has been used as an universal antibiotic substance and can reduce the emission of some gases by sterilizing action. Therefore, an apparatus which produces SNC was developed and was conducted its performance test. Also, the SNC made by the apparatus was applied to swine excreta sampled from a piggery in oder to find the effect on the reduction of odor emission. An electrolysis apparatus was developed to produce SNC and its capacity was 0.024 ppm/$hr{\cdot}L$. The effects of SNC on the reduction of odor emission from swine excreta were tested for bad smell gases of ammonia ($NH_3$), hydrogen sulfide ($H_2S$) and methane ($CH_4$). For ammonia gas, factorial experiments were conducted to find the effects of concentration and application rate of SNC. The test results for the different concentrations of 20 ppm, 50 ppm, and 100 ppm showed that the more concentration of SNC was increased, the more emission reduction of ammonia gas increased. From the test results about the effect of application rate, the more SNC was applied, the more emission reduction of $NH_3$ increased. In order to reduce the concentration of $NH_3$ below 5 ppm, SNC of 50 ppm is recommended to be applied at an interval of 6 hours, and is mixed with swine excreta in the volumetric ratio of 4:1. For hydrogen sulfide gas, the concentration was decreased as time went by and was reduced rapidly in the first stage of the tests for all applied concentrations of SNC (20 ppm, 50 ppm, and 100 ppm). Especially, when 100 ml of SNC with 100 ppm was applied, emission of hydrogen sulfide gas was reduced rapidly during early 4 hours after the application of SNC. And, concentration of hydrogen sulfide gas was maintained below 20 ppm after 12 hours. For methane gas, t-test showed that there was no significance on the effect of its application for all applied concentrations of SNC. Therefore, it was concluded that the application of SNC on swine excreta had no effect on the emission reduction of $CH_4$.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.38 no.6
• /
• pp.483-491
• /
• 2014

In this study, a thermodynamic analysis was carried out for a combined power generation system using a low-temperature heat source in the form of sensitive energy and liquefied natural gas cold energy. An ammonia-water mixture, which is a zeotropic mixture, was used as the working fluid, and systems with and without a regenerator were comparatively analyzed. The effects of the mass fraction of ammonia and the condensation temperature of the working fluid on the system variables, including the net work production, exergy destruction, and thermal and exergy efficiencies, are analyzed and discussed. The results show that the performance characteristics of the system varied sensitively with the ammonia concentration or condensation temperature of the working fluid. The system without regeneration was found to be better in relation to the net work per unit mass of the source fluid, whereas the system with regeneration was better in relation to the thermal or exergy efficiency.