• Journal of the Korean Institute of Gas
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• v.25 no.6
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• pp.22-28
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• 2021

Combustion characteristics were examined experimentally for a swirl-stabilized double cone premixed burner nozzle used for industrial gas turbines for power generation. An original model and a variant with a different fuel injection pattern are tested to compare their combustion characteristics such as NOx, CO and stability in pressurized conditions with single burner-flame and in an ambient multi-flame conditions with multi-burners. Test results show that NOx emissions are smaller for the variant, whose number of fuel holes is reduced with the same total area of fuel holes, in ambient and pressurized single-flame conditions with single burner, which results from enhanced fuel/air mixing due to a higher penetration of fuel into the air stream. The multi-burnerflame test results show that NOx emissions are smaller for the variant due to reduced flame interactions, which, on the contrary, slightly reduces the stability margin. On-site test results fromin an actual power plants also show that NOx emissions are reduced for the variant, compared with the original one, which is in agreement with the lab test results stated above.

• Transactions of the Korean Society of Automotive Engineers
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• v.14 no.1
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• pp.100-108
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• 2006

Time-resolved current and voltage measurements for an inductive automotive spark system were made. Also presented are measurements of the total energy delivered to the spark gap. The measurements were made in air for a range of pressures from 1-18atm, at ambient temperatures. The measured voltage and current characteristics were found to be a function of many ignition parameters; some of these include: spark gap distance, internal resistance of the spark plug and high tension wire, and pressure. The voltages presented were measured either at the top of the spark plug or at the spark gap. The measurements were made at different time resolutions to more accurately resolve the voltage and current behavior throughout the discharge process. This was necessary because the breakdown event occurs on a time scale much shorter than the arc and glow phases. The breakdown, are, and glow voltages were found to be functions of spark plug resistance, gas density, and spark plug gap as expected from the literature. Spark duration was found to decrease as either pressure or gap was increased. The transition from the arc to glow phase is usually distinguished by a sudden rise in the voltage across the gap. At pressures above about 7atm this transition was not observed suggesting that a glow phase was not present. Energy delivered to the gap increased with increasing pressure. The effective resistance of the spark gap during discharge was about twice as large for the glow phase as the arc phase.

• Proceedings of the KSME Conference
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• 2001.06d
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• pp.66-70
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• 2001

The combustion characteristics have been investigated to develop the low $NO_{x}$ gas turbine combustor. The lean premixed combustion technology was applied to reduce the $NO_{x}$ emission. Also, the conventional combustor was designed and tested for the baseline of low $NO_{x}$ combustor performance. The test was conducted at the condition of high temperature and ambient pressure. The combustion air which has the temperature of 500K were supplied to the combustor through the air preheater. The temperature and emissions of $NO_{x}$ and CO were measured at the exit of combustor. The premixing chamber can be operated very lean condition of equivalence ratio around 0.35. The $NO_{x}$ was decreased with decreasing the equivalence ration. The CO was decreased with decreasing the equivalence ratio, but the CO was increased with decreasing the equivalence ratio below 0.45. But, at the very lean condition of equivalence ratio below 0.35 both NOx and CO were increased because of the flame unstability. The $NO_{x}$ was decreased slightly and CO was increased with increasing inlet air flowrate. This results can be used to determine the size of combustor. The low $NO_{x}$ combustor has lower values of $NO_{x}$ and CO compared with conventional one. Consequently the performance of combustor shows the possibility of the application to the gas turbine system.

• Advances in nano research
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• v.5 no.3
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• pp.193-201
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• 2017

ZnO, ZnO: Cu, Ga, and ZnO: Cu, Ga, Ag thin films were obtained by oxidization of ZnS and ZnS: Cu, Ga films deposited onto glass substrates by electron-beam evaporation from ZnS and ZnS: Cu, Ga targets and from ZnS: Cu, Ga film additionally doped with Ag by the closed space sublimation technique at atmospheric pressure. The film thickness was about $1{\mu}m$. The oxidation was carried out at $600-650^{\circ}C$ in air or in an atmosphere containing water vapor. Structural characteristics were investigated by X-ray diffraction (XRD) and atomic force microscopy (AFM). Photoluminescence (PL) spectra of the films were measured at 30-300 K using the excitation wavelengths of 337, 405 and 457.9 nm. As-deposited ZnS and ZnS: Cu, Ga films had cubic structure. The oxidation of the doped films in air or in water vapors led to complete ZnO phase transition. XRD and AFM studies showed that the grain sizes of oxidized films at wet annealing were larger than of the films after dry annealing. As-deposited doped and undoped ZnS thin films did not emit PL. Shape and intensity of the PL emission depended on doping and oxidation conditions. Emission intensity of the films annealed in water vapors was higher than of the films annealed in the air. PL of ZnO: Cu, Ga films excited by 337 nm wavelength exhibits UV (380 nm) and green emission (500 nm). PL spectra at 300 and 30 K excited by 457.9 and 405 nm wavelengths consisted of two bands - the green band at 500 nm and the red band at 650 nm. Location and intensities ratio depended on the preparation conditions.

• Proceedings of the Korea Association of Crystal Growth Conference
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• 2000.06a
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• pp.1-33
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• 2000

Silicon carbide ceramics with sintering additives from the system AlN-Y$_2$O$_3$ can be gas-pressure sintered to theoretical density. While commonly a combination of sesquioxides is used such as Al$_2$O$_3$-Y$_2$O$_3$, the oxynitrid additives offer the advantage that only a nitrogen atmosphere is require instead of a powder. By starting form a mixture of ${\beta}$-SiC and ${\alpha}$-SiC, and by performing dedicated heat treatments after densification, anisotropic grain growth is obtained which leads to a platelet microstructure showing enhance fracture toughness. In the present work, recent improvement of the mechanical behaviour of these materials at ambient and high temperatures is reported. By means of a surface oxidation treatment in air it is possible to obtain four-point bending strengths in excess of 1 GPa, and the strength retention at high temperatures is significantly improved.

• Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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• 2002.05a
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• pp.45-52
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• 2002

The tribological role of mass transfer layer was studied with silver coatings under various ranges of load and sliding speed. Silver coating was performed with a functionally gradient coating method. Tests were performed in dry sliding conditions, using a ball-on-disk contact configuration, at the load of 0.0196-17.64 N and the sliding speed of 20-1,000 mm/s in ambient air. Optical microscope and EPMA analyses showed that contact surfaces were covered with the mass transfer layers of agglomerated wear particles depending upon the contact conditions, and they greatly influenced the tribological characteristics of the surfaces. However, the formation of mass transfer layer was suppressed as the sliding speed increased, and above a critical sliding speed, no mass transfer layer was able to form. For building up a general framework of tribological behavior of the coated silver films, all test data were summarized on a map whose axes are contact pressure and sliding speed.

• Journal of Hydrogen and New Energy
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• v.29 no.4
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• pp.393-400
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• 2018

To confirm the operating range of two oxygen carriers for chemical looping combustion system, the effects of operating variables on solid circulation rate were measured and discussed using a two-interconnected circulating fluidized bed system at ambient temperature and pressure. Moreover, suitable operating ranges to avoid choking of the fast fluidized bed (air reactor) were confirmed for two oxygen carriers. A continuous long-term operation of steady-state solid circulation more than 24 hours was also demonstrated within the operating windows. Finally we could confirm that those two oxygen carriers are suitable for chemical looping combustion system with high solid circulation rate and smooth solid circulation.

• Journal of Korean Society for Atmospheric Environment
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• v.22 no.4
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• pp.499-508
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• 2006

Atmospheric concentrations of polycyclic aromatic hydrocarbons (PAHs) were measured at the Chonbuk National University located in Jeonju, four times between June and November 2002, each time for five days. Twenty-four compounds including five alkyl PAHs and byphenyl were analyzed. Average total concentration of 24 PAHs was 85 $\pm$ 15 ng/$m^3$ and about 94% of PAHs existed in the gas phase. On an average, naphthalene accounted for about 30% of the total PAHs concentration. The gas/particle partitioning was not much varied during the measurement period. High molecular weight PAHs with five and six rings were primarily associated with fine particles less than 1 $\mu$m. Lower molecular weight PAHs were evenly distributed in fine and coarse particles so that their distribution was similar to that of TSP.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.27 no.9
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• pp.1335-1341
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• 2003

This paper describes the process of nanoparticle synthesis by laser ablation of microparticles and consolidated sample. We have generated nanoparticles by high-power pulsed laser ablation of AI, Cu and Ag microparticles using a Q-switched Nd:YAG laser (wavelength 355nm, FWHM 6ns, fluence $0.8{\sim}2.0J/cm^2$). Microparticles of mean diameter $18{\sim}80{\mu}m$ are ablated in the ambient air. The generated nanoparticles are collected on a glass substrate and the size distribution and morphology are examined using a scanning electron microscope and a transmission electron microscope. The effect of laser fluence, collector position and compacting pressure on the distribution of particle size is investigated. To better understand the process of laser ablation of microparticle(LAM), we investigated the Nd: YAG laser-induced breakdown of Cu microparticle using time-resolved optical shadow images. Nanosecond time-resolved images of the ablation process are also obtained by laser flash shadowgraphy. Based on the experimental results, discussions are made on the dynamics of ablation plume.

• Carbon letters
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• v.13 no.1
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• pp.34-38
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• 2012

Successful application of graphene requires development of various tools for its chemical modification. In this paper, we present a Raman spectroscopic investigation of the effects of UV light on single layer graphene with and without the presence of $O_2$ molecules. The UV emission from a low pressure Hg lamp photolyzes $O_2$ molecules into O atoms, which are known to form epoxy on the basal plane of graphene. The resulting surface epoxy groups were identified by the disorder-related Raman D band. It was also found that adhesive residues present in the graphene samples prepared by micro-mechanical exfoliation using adhesive tape severely interfere with the O atom reaction with graphene. The UV-induced reaction was also successfully applied to chemical vapor deposition-grown graphene. Since the current method can be readily carried out in ambient air only with UV light, it will be useful in modifying the surfaces of graphene and related materials.