• Bulletin of the Korean Chemical Society
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• 제33권6호
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• pp.1845-1850
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• 2012

Layered metal hydroxides (LMHs) containing calcium were synthesized by coprecipitation in solution having two different trivalent metal ions, iron and aluminum. Two mixed metal solutions ($Ca^{2+}/Al^{3+}$ and $Ca^{2+}/Fe^{3+}$ = 2/1) were added to sodium hydroxide solution and the final pH was adjusted to ~11.5 and ~13 for CaAl-and CaFe-LMHs. Powder X-ray diffraction (XRD) for the two LMH samples showed well developed ($00l$) diffractions indicating 2-dimensional crystal structure of the synthesized LMHs. Rietveld refinement of the X-ray diffraction pattern, the local structure analysis through X-ray absorption spectroscopy, and thermal analysis also confirmed that the synthesized precipitates show typical structure of LMHs. The chemical formulae, $Ca_{2.04}Al_1(OH)_6(NO_3){\cdot}5.25H_2O$ and $Ca_{2.01}Fe_1(OH)_6(NO_3){\cdot}4.75H_2O$ were determined by inductively coupled plasma-atomic emission spectroscopy (ICP-AES). Particle morphology and thermal behavior for the synthesized LMHs were examined by field emission scanning electron microscopy and thermogravimetricdifferential scanning calorimetry.

• Nuclear Engineering and Technology
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• 제49권4호
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• pp.734-743
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• 2017

In order to investigate the swelling behavior and fuel-cladding interaction mechanism of U-10Zr alloy metallic fuel at very low burnup, an irradiation experiment was concisely designed and conducted on the China Mianyang Research Reactor. Two types of irradiation samples were designed for studying free swelling without restraint and the fuel-cladding interaction mechanism. A new bonding material, namely, pure aluminum powder, was used to fill the gap between the fuel slug and sample shell for reducing thermal resistance and allowing the expansion of the fuel slug. In this paper, the concise irradiation rig design is introduced, and the neutronic and thermal-hydraulic analyses, which were carried out mainly using MCNP (Monte Carlo N-Particle) and FLUENT codes, are presented. Out-of-pile tests were conducted prior to irradiation to verify the manufacturing quality and hydraulic performance of the rig. Nondestructive postirradiation examinations using cold neutron radiography technology were conducted to check fuel cladding integrity and swelling behavior. The results of the preliminary examinations confirmed the safety and effectiveness of the design.

• 한국전자파학회논문지
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• 제20권3호
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• pp.303-312
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• 2009

본 연구에서는 초고주파를 사용하여 플라즈마 가시광을 발생시키기 위한 전계 집속형 도파관 시스템을 제안하였다. 이 시스템은 초고주파 전력 공급기인 마그네트론, 전력 전송을 위한 도파관부 및 메쉬형 공동으로 이루어진 반응기로 구성된다. 소량의 황 분말과 버퍼 가스인 Ar이 봉입된 석영 벌브를 반응기 내에 위치시키고, 강한 전계를 집속시킴으로써 황 플라즈마가 생성 및 여기되도록 하였다. 즉, 도파관과 반응기의 내벽에 각각 도체팁을 장착시키고, 그 사이에 플라즈마 벌브를 위치시킴으로써 벌브에 강한 전계가 집중되도록 하였다. 또한 플라즈마 생성 과도기에서, 플라즈마의 전기적 도전성 변화에 따른 정합 특성의 열화를 최소화할 수 있는 도파관부를 설계하여 안정적으로 동작되도록 하였다. 최종적으로 2.45 GHz 알루미늄 도파관 시스템을 제작하고, 400W급 마그네트론을 사용한 가시광 방출 실험을 통해 설계된 시스템의 타당성을 검증하였다.

• KEPCO Journal on Electric Power and Energy
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• 제1권1호
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• pp.15-20
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• 2015

To examine the magnetic shielding effect for carbon-based materials at extremely low frequencies (60 Hz), two types of carbon black (Super-P and Denka Black) and a natural graphite (HC-198) were mixed into organic binder at 10 wt.% to produce a coating solution, and a powder coating with varying thickness was applied on an aluminum disk measuring 88 mm in radius. A device was developed to measure the sheielding effect at extremely low frequencies. A closed circuit was achieved by connecting a transformer and a resistor. The applied voltage was fixed at 65 V, and the magnetic field was measured to being the range of 4.95~5.10 mG. Depending on the thickness of the coating layer, the magnetic field showed a decreasing trend. The maximum decrease in the magnetic field of 38.3% was measured when natural graphite was coated with specimens averaging $455{\mu}m$. This study confirmed that carbon-based materials enable magnetic shielding at extremely low frequencies, and that the magnetic shielding effect can be enhanced by varying the coating thickness.

• 한국주조공학회지
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• 제17권4호
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• pp.338-346
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• 1997

Mechanical properties of ($10%Al_2O_3{\cdot}SiO_2+5%Ni$)/Al hybrid composites fabricated by the reaction squeeze casting were compared with those of ($15%Al_2O_3{\cdot}SiO_2$)/Ai composites. Al-Ni intermetallic compounds ($10{\sim}20 {\mu}m$) formed by the reaction between nickel powder and molten aluminum were uniformly distributed in the Al matrix. These intermetallic compounds were identified as $Al_3Ni$ using X-ray diffraction analysis and they resulted in beneficial effects on room and high temperature strength and wear resistance. Microhardness values of ($10%Al_2O_3{\cdot}SiO_2+5%Ni$)/Al hybrid composite were greater by about 100Hv than those of ($15%Al_2O_3{\cdot}SiO_2$)/Al composite. Wear resistance of ($10%Al_2O_3{\cdot}SiO_2+5%Ni$)/Al hybrid composites was superior to that of ($15%Al_2O_3{\cdot}SiO_2$)/Al composites regardless of the applied load. While tensile and yield strength of ($10%Al_2O_3{\cdot}SiO_2+5%Ni$)/Al hybrid composites were greater at room temperature and $300^{\circ}C$, strength drop at high temperature was much smaller in hybrid composites.

• 한국재료학회지
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• 제20권3호
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• pp.111-116
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• 2010

Chloride-based fluxes such as NaCl-KCl are used in the refining of Al melt. The vapor pressure of the chloride is one of the fundamental pieces of information required for such processes, and is generally high at elevated temperatures. In order to measure the vapor pressure for chlorides, the apparatus for the transpiration method was assembled in the present study. The vapor pressure of $ZnCl_2$ and $FeCl_2$, which is related with the process of aluminum refining and the recovery of useful elements from iron and steel industry by-products, was also measured. In the measurement of vapor pressure by the transpiration method, the powder of $ZnCl_2$ or $FeCl_2$ in a alumina boat was loaded in the uniform zone of the furnace with a stream of Ar. The weight loss of $ZnCl_2$ and $FeCl_2$ after holding was measured by changing the flow rate of Ar gas (10 sccm -230 sccm), and the partial pressures of $ZnCl_2$ and $FeCl_2$ were calculated. The partial pressures within a certain range were found to be independent of the flow rate of Ar at different temperatures. The vapor pressures were measured in the temperature range of 758-901K for $ZnCl_2$ and 963-983K for $FeCl_2$. The measured results agreed well with those in the literature.

• Journal of the Optical Society of Korea
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• 제18권3호
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• pp.256-260
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• 2014

Columnar-structured cesium iodide (CsI) scintillators doped with thallium (Tl) are frequently used as x-ray converters in medical and industrial imaging. In this study we investigated the imaging characteristics of CsI:Tl films with various reflective layers-aluminum (Al), chromium (Cr), and titanium dioxide ($TiO_2$) powder-coated on glass substrates. We used two effusion-cell sources in a thermal evaporator system to fabricate CsI:Tl films on substrates. The scintillators were observed via scanning electron microscopy (SEM), and scintillation characteristics were evaluated on the basis of the emission spectrum, light output, light response to x-ray dose, modulation transfer function (MTF), and x-ray images. Compared to control films without a reflective layer, CsI:Tl films with reflective layers showed better sensitivity and light collection efficiency, and the film with a $TiO_2$ reflective layer showed the best properties.

• 한국산업융합학회 논문집
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• 제25권5호
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• pp.899-908
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• 2022

In this study, a study was conducted to localize a large aluminum turbo fan used for tank powerpack. The turbo fan was scanned with a 3D scanner and then 3D modeling was performed. Computational fluid dynamics (CFD) were performed from the performance conditions of the fan, and structural analysis was performed using the pressure data obtained from CFD. The fan was reduced to 1/5 size by applying the geometric similarity. A 1/5 size fan has a honeycomb structure inserted into the front shroud and back shroud to reduce the weight by 5.3%. A 1/5 size fan was printed using a PBF 3D printer, and a 1/5 size fan with honeycombs was also printed. The pressure drop of 8.67 kPa and the required power of 138.19 kW, which satisfies the performance conditions of the fan, were confirmed from the results of CFD. The values of the maximum deformation amount of 0.000788 mm and the maximum effective stress of 0.241 MPa were confirmed from the structural analysis results. The fan printed by the PBF 3D printer had the same shape as the modeling, and the shape was perfect. There are no defects anywhere in appearance. However, the condition of the outer surface of the fan's back shroud is rough compared to other locations. The fan in which the honeycomb was inserted was also perfectly output, and the shape of the honeycomb was the same as the modeling.

• Composites Research
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• 제20권4호
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• pp.9-17
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• 2007

분말야금법 및 고온진공가압기술, 열간등가압성형기술을 이용하여 알루미늄 금속기 복합재료를 제작하였으며 이들과 관련한 미시역학 기반 강화공정 모델을 개발하였다. 고온, 가압 성형공정은 기지재료의 비탄성거동과 성형체 내부의 기공 제거를 통한 충진을 수반하게 되며 이러한 공정은 압력, 온도 및 강화재의 체적분률 등과 같은 공정변수의 영향을 받게 된다. 따라서 개발된 강화공정 모델을 유한요소해석 프로그램에 적용함으로써 고온진공가압과 열간등가압 동안 기공의 상대밀도 변화에 따른 충진거동을 예측하였고 다양한 공정조건 하에서 실험결과와 잘 일치함을 확인하였다. 완성된 알루미늄 금속기 복합재료의 건전성 평가와 관련하여 인장시험을 수행하였으며 초기 잔존하는 기공의 영향에 따른 제반 기계적 특성을 고찰할 수 있었다.

• Advances in concrete construction
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• 제15권3호
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• pp.179-190
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• 2023

The effect of glass fibres (GF) and polypropylene fibres (PPF) on the fresh properties and mechanical properties of lightweight concrete (LWC) exposed to high temperatures is investigated in this study. In this study, fifteen LWC mixtures were carried out in three different groups reinforced with PPF or GF fibers by 0%, 0.2%, and 0.4% by volume of concrete. The first group included aluminum powder (AP) as an air agent at 0.03% with the normal weight coarse aggregate (NWCA) by 100% of the weight of coarse aggregate. In the second group, 33% of the NWCA weight was replaced by lightweight coarse aggregate (LWCA). In the third group, 67% of the NWCA weight was replaced by LWCA. The slump, unit weight, Compressive strength (CS), tensile strength (TS), and flexural strength (FS) were examined. For two hours, the CS and FS were subjected to elevated temperatures of 200℃, 400℃, and 600℃, in addition to microstructure analysis of concrete. In comparison to the reference mixture, the fresh properties and bulk density of LWC decreased with the use of the air agent or the replacement of 67% of the NWCA with LWCA. As a result of the fiber addition, both the slump test and the bulk density decreased. The addition of fibers increased the CS; the highest CS was 38.5 MPa when 0.4% GF was added, compared to 28.9 MPa for the reference mixture at the test age of 28 days. In addition, flexural and TS increased by 53% and 38%, respectively, for 0.4% GF mixes. As well as, adding 0.4% GF to LWC maintained a higher CS than other mixtures.