• 공업화학
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• 제24권5호
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• pp.562-565
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• 2013

고순도의 알루미늄 호일은 전기화학적 에칭을 통해 표면적을 증가시킨 후 전해 커패시터의 양극으로 사용된다. 그러나 산화 피막의 결함 및 에치 피트의 불규칙 생성에 의해 성장된 에치 피트의 분포는 불균일하며 이러한 불균일 형태는 알루미늄 넓은 표면적 분포에도 불구하고 여러 형태의 적용을 어렵게 만든다. 본 연구에서는 알루미늄의 선택적 에칭을 위해 포토리소그래피 방법으로 제작된 패턴 마스크를 사용하여 알루미늄 표면에 균일성을 갖는 보호층을 형성시켰다. 균일한 패턴을 갖는 알루미늄을 용액의 온도 및 전류밀도 등의 조건을 변경하여 실험하였고, 알루미늄 표면에 다양한 크기($2{\sim}5{\mu}m$)의 균일성을 갖는 에치 피트의 형성을 확인할 수 있었다.

• 한국재료학회지
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• 제11권4호
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• pp.329-334
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• 2001

붕산용액에서 양극산화법으로 장벽형 산화피막을 형성시킨 후 미세조직을 관찰하였다. 양극산화시 인가되는 전압에 따른 피막의 성장속도는 1.54nm/v의 직선적인 관계를 나타냈으며 300v의 인가전압에서 생성된 산화피막의 조직은 50$0^{\circ}C$에서 열처리하였을 경우 피막의 상 전이가 일어나지 않았으나 높은 인가전압에서 생성된 산화피막의 경우는 피막의 조직이 비정질에서 ${\gamma}$-alumina로 변태되는 것이 관찰되었다. 또한 피막이 전자빔 조사에 의해서도 ${\gamma}$-alumina로 전이가 일어났다.

• KIEE International Transactions on Electrophysics and Applications
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• 제11C권3호
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• pp.70-74
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• 2001

Admittance or impedance spectroscopy is one of the powerful tools to study dielectric relaxation and loss processes in organic and inorganic materials. In this study, the frequency dependent properties of an indium tin oxide/tris(8-hydroxyquinoline) aluminum($Alq_3$)/aluminum structure have been studied. The conductance of the $Alq_3$ film increases with the DC applied voltage up to 4V and decreases above 4V in the low frequency region. This indicates that the resistance of the device decreases with the applied bias due to the carrier injection enhancement, thereafter the injected carriers form the space charge and the additional injection of carriers is prevented. The Cole-Cole plot of the admittance takes a one-semicircle shape, which means that the device can be modeled as a parallel resistor-capacitor network. The resistance and capacitance were estimated as 8.62k${\Omega}$ and 2.7nF, respectively, at 3V in the low frequency region. The dielectric constant ( ${\epsilon}'$ ) of the $Alq_3$ film is independent of the frequency in the low frequency region below 100kHz, while the frequency dependency was observed at above 100kHz. The dielectric loss factor ( ${\epsilon}"$ ) of the $Alq_3$ film shows the dielectric dispersion below 100kHz and dielectric absorption in higher frequency domain. The dispersion is thought to be related to the hopping process of the carriers. The ${\epsilon}"$ is proportional to the reciprocal of the frequency. The dielectric relaxation time was extracted to about 0.318${\mu}s$ from the dielectric absorption spectrum.

• Journal of Electrochemical Science and Technology
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• 제14권2호
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• pp.184-193
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• 2023

This study investigates the effects of a carbon fiber layer formed on the surface of an etched aluminum current collector on the electrochemical properties of the activated carbon electrodes for an electric double layer capacitor. A particle size analyzer, field-emission SEM, and nitrogen adsorption/desorption isotherm analyzer are employed to analyze the structure of the carbon fiber layer. The electric and electrochemical properties of the activated carbon electrodes using a carbon fiber layer are evaluated using an electrode resistance meter and a charge-discharge tester, respectively. To uniformly coat the surface with carbon fiber, we applied a planetary mill process, adjusted the particle size, and prepared the carbon paste by dispersing in a binder. Subsequently, the carbon paste was coated on the surface of the etched aluminum current collector to form the carbon under layer, after which an activated carbon slurry was coated to form the electrodes. Based on the results, the interface resistance of the EDLC cell made of the current collector with the carbon fiber layer was reduced compared to the cell using the pristine current collector. The interfacial resistance decreased from 0.0143 Ω·cm² to a maximum of 0.0077 Ω·cm². And degradation reactions of the activated carbon electrodes are suppressed in the 3.3 V floating test. We infer that it is because the improved electric network of the carbon fiber layer coated on the current collector surface enhanced the electron collection and interfacial diffusion while protecting the surface of the cathode etched aluminum; thereby suppressing the formation of Al-F compounds.

• 한국전자파학회논문지
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• 제22권12호
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• pp.1069-1077
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• 2011

본 논문에서는 선택적 산화 알루미늄(SAAO: Selectively Anodized Aluminum Oxide) 기판을 이용하여 2.5 GHz 8 W급 소형 GaN HEMT 전력 증폭기 모듈을 설계, 제작하였다. SAAO 기판 공정은 최근 Wavenics사에서 제안한 특허 기술로서, 알루미늄을 웨이퍼로 이용한다. 본 연구에 사용된 능동 소자는 최근 발표된 TriQuint사의 칩 형태 의 GaN HEMT이다. 최적의 임피던스는 수동 조정 소자가 내장된 지그를 사용하여 실험적으로 결정하였다. 결정된 임피던스를 이용하여, 입 출력 임피던스 정합 회로를 EM co-시뮬레이션을 이용하여 F급으로 설계를 수행하였으며, SAAO 기판에 구현하였다. 이때, 소형의 패키지(모듈)에 집적하기 위하여 인덕터와 커패시터는 각각 spiral inductor, single layer capacitor를 사용하였다. 소형으로($4.4{\times}4.4\;mm^2$) 패키지된 전력 증폭기 모듈의 경우, 출력은 8 W, 효율은 40 % 그리고 2차 및 3차 고조파에 대한 고조파 억제는 30 dBc 이상의 특성을 보였다.

• 대한전자공학회논문지
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• 제5권3호
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• pp.9-24
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• 1968

초단계형(Hyperabrupt) p-n접합에서 접합용량의 인가전압에 의한 변화률이 단순물분포에 따라 변화하는 성질을 이용하여 가변용량다이오드의 최적설계방법 유도하고 표준방송수신용 라디오의 동조용 가변용량실리콘 다이오드를 설계하였고 이다이오드의 제작방법에 관하여 연구하였다. 이때 도너 및 액셉터 불순물로서는 안치모니 및 알루미늅을 진공증착한 후 고온확산로에 넣어 처리하므로서 원하는 분포를 얻으려 하였다.

• ETRI Journal
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• 제17권2호
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• pp.11-19
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• 1995

The plasma densities generated from a semiconductor bridge (SCB) device employing a capacitor discharge firing set have been measured by a novel diagnostic technique employing a microwave resonator probe. The spatial resolution of the probe is comparable to the separation between the two wires of the transmission lines (${\approx}$3 mm). This method is superior to Langmuir probes in this application because Langmuir probe measurements are affected by sheath effects, small bridge area, and unknown fraction of multiple ions. Measured electron densities are related to the land material and input energy. Although electron densities in the plasma generated by aluminum or tungsten-land SCB devices show a general tendency to increase steadily with power, at the higher energies, the electron densities generated from tungsten-land SCB devices are found to remain constant.

• 한국자동차공학회논문집
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• 제25권1호
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• pp.60-65
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• 2017

We designed and fabricated the engine oil monitoring sensor to measure engine oil deterioration through increased vehicle mileage. Since the condition of the engine oil can be affected by the state of the vehicle and its operating conditions, it should be directly measured and determined in every vehicle. The fabricated sensor has an aluminum parallel capacitor structure that measures capacitance related with the dielectric constant, which is one of the indices of oil deterioration. The size of the capacitor is small enough that it could be easily adapted on the oil level gauge without introducing any change in the design. The fabricated device is installed in the diesel engine to measure the change in capacitance accurately as the vehicle moved from 0 km (new engine oil state) to 11,364 km. The results showed the maximum value at around 5,000 km, and the values plateaued as mileage increased, corresponding with the measurement result of the TAN (Total Acid Number). Based on the results, the condition of the oil must be monitored regularly though oil change is recommended once the vehicle has traveled the distance of around 10,000 km.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2007년도 하계학술대회 논문집 Vol.8
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• pp.481-481
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• 2007

This work describes the effect of the number of roll pressing and the composition of carbon black on the electric and mechanical properties of carbon-PTFE electrode, in which composition is MSP 20 : carbon black: PTFE = 95-x : x : 5 wt.%. It was found that the best electric and mechanical properties were obtained in sheet electrode roll-pressed for about 15 times and in sheet electrode, in which composition is MSP 20 : carbon black: PTFE = 80 : 15 : 5 wt.%. These behaviors could be explained by the network structure of PTFE fibrils and conducting paths linked with carbon blacks, respectively. On the other hand, cell capacitor using the sheet electrode with 15 wt.% of carbon black attached on aluminum current collector with the electric conductive adhesive, in composition is carbon black : CMC = 70 : 30 wt.%, has exhibited the best rate capability in the current range of $0.5mA/cm^2$ $100mA/cm^2$ and the lowest equivalent series resistance.

• Bulletin of the Korean Chemical Society
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• 제33권7호
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• pp.2207-2212
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• 2012

Dimethylaluminum isopropoxide (DMAI, $(CH_3)_2AlO^iPr$) as a single precursor, which contains one aluminum and one oxygen atom, has been adopted to deposit non-stoichiometric aluminum oxide ($AlO_x$) films by low pressure metal organic chemical vapor deposition without an additional oxygen source. The atomic concentration of Al and O in the deposited $AlO_x$ film was measured to be Al:O = ~1:1.1 and any serious interfacial oxide layer between the film and Si substrate was not observed. Gaseous by-products monitored by quadruple mass spectrometry show that ${\beta}$-hydrogen elimination mechanism is mainly contributed to the $AlO_x$ CVD process of DMAI precursor. The current-voltage characteristics of the $AlO_x$ film in Au/$AlO_x$/Ir metalinsulator-metal (MIM) capacitor structure show high ON/OFF ratio larger than ${\sim}10^6$ with SET and RESET voltages of 2.7 and 0.8 V, respectively. Impedance spectra indicate that the switching and memory phenomena are based on the bulk-based origins, presumably the formation and rupture of filaments.