• Title/Summary/Keyword: aluminium sulfate

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Gas Production of Chemical Leavening Agents and Effects on Textures of Cookies (화학 팽창제의 가스 발생과 쿠키의 텍스쳐 비교)

  • Yang, Seong-Yeon;Kim, Sang-Yong;Jang, Kyu-Seob;Oh, Deok-Kun
    • Korean Journal of Food Science and Technology
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    • v.29 no.6
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    • pp.1131-1137
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    • 1997
  • The production rates of leavening gases and textures of cookies were investigated with various chemical leavening agents(baking powders). The chemical leavening agents could be divided into three group of a fast-acting group such as potassium bicarbonate, tartaric acid, aluminium ammonium sulfate, and fumaric acid, a slow-acting group such as ammonium bicarbonate, sodium bicarbonate, $glucono-{\delta}-lactone$, and ammonium chloride. and a double-acting group such as anhydro monocalcium phosphate, disodium dihydrogenpyrophosphate, and aluminium potassium sulfate according to the different production rate of gases. The leavening rate of ammonium bicarbonate, which was the highest of all leavening agents used in this experiment, was 131.25%. But its after-taste in a cookie was not good due to the residual ammonia. $Glucono-{\delta}-lactone$ only had no after-taste. The higher leavening rate, the more peaks in texture profile graph. Ammonium bicarbonate showed the most peaks in this experiment. It was found that the number of peak had correlation with brittleness of cookies $(r^2=0.8176)$ and brittleness of cookies was different as to various chemical leavening agents.

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Preparation of Ni-doped Gamma Alumina from Gibbsite and Its Characteristics (깁사이트로부터 니켈피착 감마알루미나의 제조 및 특성)

  • Lee, Hyun;Chung, In-Sung;Park, Hee-Chan
    • Korean Journal of Materials Research
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    • v.8 no.12
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    • pp.1158-1164
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    • 1998
  • Aluminium sulfate solution was prepared by sulfuric acid treatment from gibbsite. Aluminium sulfate hydrate [$Al_2(SO_4)_3$ · $nH_2O$] was precipitated from aluminium sulfate solution by adding it into ethylalcohol. From XRD analysis as-prepared $Al_2(SO_4)_3$ · $nH_2O$ was confirmed to have mixed-crystalization water(n=18, 16, 12, 6). The average water of crystalization calculated from thermogravimetry(TG) was 14.7. Aluminium sulfate hydrate [$Al_2(SO_4)_3$ · $nH_2O$] was thermally decomposed and converted to $Al_2(SO_4)_3$ at $800^{\circ}C$, $\gamma-Al_2O_3$ at $900-1000^{\circ}C$, and $\alpha-Al_2O_3$ at $1200^{\circ}C$. Ni-doped $\gamma-Al_2O_3$, was synthesized from the slurry of as-prepared $\gamma-Al_2O_3$, with the ratio of [Ni]/[Al]=0.5. The reaction conditions of synthesis were determined as initial pH 9.0 and temperature $80^{\circ}C$ The basicity(pH) of slurry was controlled by using urea and $NH_4OH$ solution. Urea was also used for deposition-precipitation. For determining termination of reaction, the data acquisition was performed by oxidation reduction potential(ORP), conductivity and pH value in the process of reaction. Termination of the reaction was decided by observing the reaction steps and rapid decrease in conductivity. On the other hand, BET(Brunauer, Emmett and Teller) and thermal diffusity of Ni- doped $\gamma-Al_2O_3$, with various content of Ni were measured and compared. Thermal stability of Ni- doped $\gamma-Al_2O_3$ at $1250^{\circ}C$ was confirmed from BET and XRD analysis. The surface state of Ni-doped $\gamma-Al_2O_3$ was investigated by X-ray photoelectron spectroscopy(XPS). The binding energy at $Ni2P_{3/2}$ increased with increasing the formation of $NiAl_2O_4$ phase.

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Separation of Rare Earth and Aluminium from the Dried Powder of Waste Cerium Polishing Slurry (세륨연마재 폐슬러리 건조분말로부터 희토류와 알루미늄의 분리)

  • Yoon Ho-Sung;Kim Chul-Joo;Kim Sung-Don;Lee Jin-Yaung;Cho Sung-Wook;Kim Joon-Soo
    • Resources Recycling
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    • v.12 no.5
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    • pp.10-15
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    • 2003
  • In this study, the separation of rare earths and aluminium from the dried powder of waste cerium polishing slurry was investigated. Since cerium oxide, 40% of rare earths, is the most stable state in rare earth, the dissolution of cerium oxide in acid solution is not easy. Therefore the dissolution process of cerium oxide by sulfation was examined in order to increase the recovery of rare earth. The rare earths could be separated from aluminum by double salt precipitation using sodium sulfate.

Studies on the Residual Bending Strength of burned Douglas-fir and Western Hemlock soaked with Fire Retardant Chemicals (내화처리(耐火處理) 미송(美松) 및 미삼재(美杉材)의 연소후(燃燒後) 잔유(殘留)휨강도(强度)에 관한 연구(硏究))

  • Lee, Phil-Woo;Park, Heon
    • Journal of the Korean Wood Science and Technology
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    • v.12 no.3
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    • pp.15-24
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    • 1984
  • The $3{\times}3{\times}30\;cm^3$ sized specimens of Douglas-fir(Pseudotsuga menziesii) and western hemlock(Tsuga heterophylla) in this study were soaked in four fire-retardant solutions of ammonium sulfate, monoammonium phosphate, diammonium phosphate, and aluminium chloride for 1, 24, 72, 168, and 336 hours. Subsequently they were air-dried and burned at high temperature of ca. $1,800^{\circ}C$ and for short time of 5 minutes. This study estimated the relationship between the adsorbed chemicals and the residual weight ratio or residual bending strength of these partly burned lumbers. The results were as follows; 1) In average amount of chemical adsorption, diammonium phosphate showed the largest and aluminium chloride the smallest regardless of species but monoammonium phosphate was larger in Douglas-fir than that of western hemlock. 2) The amount of chemical adsorption was larger in western hemlock than Douglas-fir on the whole. 3) The amount of chemical adsorption was increased with the increase of soaking time but the rate of increase began to decrease at 200hrs. 4) Residual weight ratios showed no difference between species but showed differences among the chemicals treated i.e. monoammonium phosphate, diammonium phosphate, ammonium sulfate and aluminium chloride in turn from the largest to the smallest. 5) MOR values showed linear increase with the increase of residual weight ratios but showed no difference in species and chemicals respectively. 6) In the relationship between amount of chemical adsorption and MOR, only diammonium phosphate showed the curve of secondary degree with significance in Douglas-fir. 7) The MOE value of burned Douglas-fir lumber increased and showed significance of 99% as the adsorbed chemical amount increased, but among the chemicals only monoammonium phosphate showed significance. The MOE value of burned western hemlock lumber didn't show significance. 8) In only Douglas-fir, the correlation between adsorbed chemical amount and work to proportional limit showed significance in only monoammonium phosphate. And in both Douglas-fir and western hemlock, the correlation between adsorbed chemicals and work to maximum load showed significance in monoammonium phosphate.

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Solubilization of Insoluble Phosphates by Pseudomonas putida, Penicillium sp. and Aspergillus niger Isolated from Korean Soils (한국 토양(土壤)에서 분리(分離)된 Pseudomonas putida, Penicillium sp. 및 Aspergillus niger에 의한 난용성(難溶性), 인산염(燐酸鹽)의 가용화(可溶化))

  • Suh, Jang-Sun;Lee, Sang-Kyu;Kim, Kwang-Sik;Seong, Ki-Young
    • Korean Journal of Soil Science and Fertilizer
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    • v.28 no.3
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    • pp.278-286
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    • 1995
  • Phosphate-solubilizing microorganisms were isolated from agricultural area in Korea, and the solubilizing potential of microorganisms was evaluated in vitro. Of the several microorganisms Pseudomonas putida, Penicillium sp., and Aspergillus niger showed solubilization in all phosphatic compounds such as hydroxyapatite, tricalcium phosphate, aluminium phosphate and rock phosphate tested. Inorganic P solubilization was directly related to the pH drop by each microorganisms. Aspergillus niger was found to be more active in solubilizing phosphate than Pseudomonas putida and Penicillium sp.. The maximum concentration of phosphorus released from each of aluminium phosphate, hydroxyapatite and tri-calcium phosphate by Aspergillus niger in liquid culture was 776ppm, 665ppm and 593ppm, respectively when $KNO_3$ was added as nitrogen source. For rock phosphate, it was 411ppm with ammonium sulfate as nitrogen source.

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Development of Filter Replacement Type Mask by Natural Dyeing of Gallnut (오배자 천연염색을 적용한 필터교체형 면마스크 개발)

  • Kim, Minseo;Song, Hyunjoo;Lee, Sohee
    • Textile Coloration and Finishing
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    • v.32 no.4
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    • pp.199-207
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    • 2020
  • Recently, as the demand for masks increases, the use of filter-replaceable cotton masks is increasing. A filter-replaceable cotton mask is one of the ways to solve the environmental problems of a disposable nonwoven mask because only the filter can be replaced after washing. Cotton fiber products are known to be environmentally friendly, but cotton products dyed with general synthetic dyes are not safe for humans. In this study, to prepare of cotton mask applied with natural dyeing, the optimal dyeing conditions are set when dyeing with gallnut extract. A polychromatic natural dye that changes color by mordant, and the functionalities of gallnut dyeing fabrics are evaluated. The experimental method is dyed the gallnut by temperature and time by concentration to set the optimal conditions. The color fastness rating grade of aluminium potassium sulfate dodecahydrate, copper(ll) sulfate pentahydrate, and iron(ll) chloride tetrahydrate were evaluated after the pre/post mordanting.

Comparing the Dyeing Properties of Synthetic Mordants and Hwangsu Spring

  • Ahn, In-Yong;Suh, Hwa-Jin;Song, Eun-Young;Lee, Kyung-Ok;Kim, Jung-Su;Park, Young-Mi;Kwon, Oh-Oun
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2012.03a
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    • pp.121-121
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    • 2012
  • To evaluate the Hwangsu spring as natural mordants effect on dyeing. The natural mordant effect of Hwangsu spring was analyzed by pH, temperature, trace elements and organic matter. Hwangsu spring having pH 2.42 and $14.4^{\circ}C$ was harvested at the end of September, 2011, in Yeongcheon(Gyeongbuk Province, Korea) and left on a $0^{\circ}C$ and $25^{\circ}C$ before use. The Result of ICP analysis, it contain bned Fe(414.9 ppm), Al(88.9 ppm), Mn(4.9 ppm). Dyeing and post-mordant procedure; Fabrics(cotton, silk, rayon) were dyed with natural colorants(Sopbora Japonica L., Caesalpinia sappan L., Allium cepa L.) for 20 min at $80^{\circ}C$. Hwangsu spring, aluminium sulfate $14-18H_2O(Al_2(SO_4)_3{\cdot}14-18H_2O)$, iron sulfate peptahydrate($FeSO_4{\cdot}7H_2O$), copper sulfate pentahydrate($CuSO_4{\cdot}5H_2O$) were used by post mordants. But in the case of Caesalpinia sappan L. was dyed after pre-mordanting with Al(II). The fabrics were dyed with each mordant solutions at $25^{\circ}C$ for 10min. The colorless also was measured by color-differnce meter. Comparison with a synthetic mordants, the K/S values of cotton fabrics dyed with Hwangsu sping were increased.

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Effect of Heat Treatment on the Color Developing of Cotton Fabrics Dyed with Different Combination Methods of Persimmon and Catechu (감물과 아선약의 혼합염색 면직물의 열처리에 의한 혼합발색)

  • Lee, Soo Jung;Jang, Jeong Dae
    • Textile Coloration and Finishing
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    • v.30 no.3
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    • pp.216-226
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    • 2018
  • The combination dyeing have been attempted to get the various color. The objective of this research was to study the color developing effects on cotton fabrics dyed with persimmon, catechu and combination of the both by heat treatment process. These dye were applied on bleached cotton fabrics for the dyeing before post mordanting with aluminium potassium sulfate, copper sulfate, and iron sulfate. The various color changes on cotton fabric were measured by color spectrophotometer. The heat treatment of temperature around $150^{\circ}C$ for an hour can reach the highest color developing. The dyed fabrics with mordanting were heated for specific time period, which was compared without the mordanting. The post mordanted fabrics showed that more various colors can be obtained using combination dyeing. K/S values of dyed fabrics with Al, Fe, and Cu mordants were higher than the cases without mordants. The Cu mordanted fabric showed very effective color developing by the heating process. The fabrics dyed with catechu lowered L* value with little changes in a* and b* values, while the a* and b* values became higher with heat treatment. The fabrics dyed with persimmon has the lowest L* value and more changes in a*, b* value with heating process. Therefore, K/S values can be increased effectively by the combination dyeing of persimmon and catechu. Colorfastness to washing in color change was grade 2-3 in non-mordanted fabric, and grade 3 in mordanted fabric. Lightfastness of the dyed fabrics was above grade 4.

A Study on Combustion Property of Cellulose Insulation according to Particle Size (입도에 따른 셀룰로오스 단열재의 연소특성에 관한 연구)

  • Choi, Jeong-hwa;Kim, Hong;Yoo, Kyong-Ok
    • Proceedings of the Korea Institute of Fire Science and Engineering Conference
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    • 1996.11a
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    • pp.62-67
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    • 1996
  • The smouldering combustion of cellulose Insulation treated with boric acid - borax - aluminium sulfate as combustion retardants are examined by candle type combustibility tester. The flammability behavior of combustion process is LOI, Smouldering region, Smouldering, Flamming spread region and Flame spread region. In this experiment, Particle size of four examined LOI, L.Point, H.Point, at the biggest size show high LOI. The surface area is connected with thermal conduction. The phenomena of combustion transition are governed by quantity of combustible gas generation in heating zone of cellulose insulation.

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Add to activator for physical properties of slag Cement (활성화제를 첨가한 사멘트 및 콘크리트의 물리적 특성)

  • Park, Nam-Kyu;Lee, Jong-Kyu;Chu, Yong-Sik;Song, Hun;Lee, Jung-Hui;Kwon, Choon-Woo
    • Proceedings of the Korea Concrete Institute Conference
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    • 2009.05a
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    • pp.323-324
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    • 2009
  • In this study aluminium sulfate, Ca(OH)$_2$, K-R Slag and Na$_2$SO$_4$ were used as active admixtures. The physical properties of active admixtures cement mortar were investigated by flow test and compressive strength. It was found that the resulting active admixtures exhibited the higher compressive strength than OPC mortar up. From the test results, cement mortars added active admixture have a good fundamental property.

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