• Title/Summary/Keyword: aluminium CAN

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Polystyrene Supported Al(OTf)3: a Stable, Efficient, Selective, and Reusable Catalyst for Sulfonylation of Arenes with Sulfonic Acids

  • Boroujeni, Kaveh Parvanak
    • Bulletin of the Korean Chemical Society
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    • v.31 no.7
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    • pp.1887-1890
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    • 2010
  • Cross-linked polystyrene supported aluminium triflate (Ps-Al(OTf)$_3$) was found to be an efficient and chemoselective heterogeneous Lewis acid catalyst for the direct conversion of arenes to sulfones using sulfonic acids as sulfonylating agents. The solid acid catalyst is stable (as a bench top catalyst) and can be easily recovered and reused without appreciable change in its efficiency.

A Study of the Springback Reduction in Aluminium Sheet Forming Using Response Surface Method (반응표면분석법을 이용한 알루미늄 판재 성형공정의 스프링백 저감에 관한 연구)

  • 양재봉;전병희;오수익
    • Transactions of Materials Processing
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    • v.9 no.5
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    • pp.526-532
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    • 2000
  • Springback simulation is receiving increasing attention throughout the automotive industry and the academic world. The knowledge of the real springback of stamped parts can help the stamping technicians to modify the process parameters or die geometry in order to reduce the shape defect. This paper presents the results of springback simulation after aluminium square cup deep drawing and trimming simulation, and results of springback optimization using response surface method.

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Polystyrene Supported Al(OTf)3: an Environmentally Friendly Heterogeneous Catalyst for Friedel-Crafts Acylation of Aromatic Compounds

  • Boroujeni, Kaveh Parvanak
    • Bulletin of the Korean Chemical Society
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    • v.31 no.11
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    • pp.3156-3158
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    • 2010
  • Stable and non-hygroscopic polystyrene supported aluminium triflate (Ps-$Al(OTf)_3$), which is prepared easily from cheap and commercially available compounds was found to be an environmentally friendly heterogeneous catalyst for Friedel-Crafts acylation of arenes using acid chlorides in the absence of solvent under mild reaction conditions. The catalyst can be reused up to five times after simple washing with dichloromethane.

A Study on the Precision Machining Characteristics in Heavy Cutting of Al-alloy (Al합금의 중절삭시 정밀가공 특성에 관한 연구)

  • 권용기;김동현
    • Proceedings of the Korean Society of Machine Tool Engineers Conference
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    • 2002.10a
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    • pp.203-208
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    • 2002
  • This paper deals with turning experiments of aluminium alloy using a single crystal diamond with round cutting edge. A face cutting was conducted using a special precision machine to study the characteristic phenomena in heavy cutting of aluminium alloy. In many cases, one of the most important matter on the surface integrity is about a damaged layer remaining just under the surface after machining. A machined surface roughness can be improved at a small geometrical surface roughness under special cutting conditions, even if a steady vibration exists between a tool and a workpiece.

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Aluminium-Pilland Bentonites with Amphoteric Surfactant as a Novel Organoclay for Phosphate Removal (양쪽성 계면 활성제로 치환된 알루미늄 층간가교 유기 벤토나이트를 이용한 수중 인산염 제거)

  • Kim, Soo-Hong;Kim, Ja-Keun;Park, Jae-Woo
    • Journal of Korean Society on Water Environment
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    • v.23 no.6
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    • pp.966-972
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    • 2007
  • A novel organoclay has been developed with aluminium-pillared clay modified with an amphoteric surfactant, N-Dodecyl-N,N-dimethyl-3-ammonio-1-propanesulfonate (DDAPS). This novel organoclay is expected to have phosphorus removal capacity as well as organic and inorganic contaminant removal capacity, due to aluminum inside the clay structure. It also exhibited less surfactant desorption than conventional cation surfactant-based organoclays. Phosphorus in water can be decreased from 0.2 mg/L to 0.0012 mg/L in 27 hours with this organoclay. Also, cadmium could removed from water using this proposed organo-clay. Experiments were performed under various pHs and amphoteric surfactants sorption capability was the highest at pH 5 when more of the amphoteric surfactant head group took on positive charges.

Hot Metal Extru-Bending Process for the Aluminum Curved Tube Product (알루미늄 중공 곡관제품의 열간 압출굽힘가공)

  • 박대윤;진인태
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2003.05a
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    • pp.359-362
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    • 2003
  • The bending phenomenon has been known to be occurred by the different of velocity at the die exit. The difference of velocity at the die exit section can be obtained by the different velocity of billets through the multi-hole container and by the cohesion of billet inside the porthole die chamber. The bending phenomenon can be controlled by the different hole diameter. The experiments using aluminium material for the curved tube product had been done. The results of the experiment show that the curved tube product can be formed by the extru-bending process without the defects such as the distortion of section and the thickness change of the wall of tube and the folding and wrinkling. It is known that the welding and extruding of each billet has done simultaneously although the curved tube is extruded with four billets.

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Dynamic numerical simulation of plastic deformation and residual stress in shot peening of aluminium alloy

  • Ullah, Himayat;Ullah, Baseer;Muhammad, Riaz
    • Structural Engineering and Mechanics
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    • v.63 no.1
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    • pp.1-9
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    • 2017
  • Shot peening is a cold surface treatment employed to induce residual stress field in a metallic component beneficial for increasing its fatigue strength. The experimental investigation of parameters involved in shot peening process is very complex as well as costly. The most attractive alternative is the explicit dynamics finite element (FE) analysis capable of determining the shot peening process parameters subject to the selection of a proper material's constitutive model and numerical technique. In this study, Ansys / LS-Dyna software was used to simulate the impact of steel shots of various sizes on an aluminium alloy plate described with strain rate dependent elasto-plastic material model. The impacts were carried out at various incident velocities. The influence of shot velocity and size on the plastic deformation, compressive residual stress and force-time response were investigated. The results exhibited that increasing the shot velocity and size resulted in an increase in plastic deformation of the aluminium target. However, a little effect of the shot velocity and size was observed on the magnitude of target's subsurface compressive residual stress. The obtained results were close to the published ones, and the numerical models demonstrated the capability of the method to capture the pattern of residual stress and plastic deformation observed experimentally in aluminium alloys. The study can be quite helpful in determining and selecting the optimal shot peening parameters to achieve specific level of plastic deformation and compressive residual stress in the aluminium alloy parts especially compressor blades.

A Study on Deduction and Characteristic Analysis of Magnetic Equivalent Circuit Parameters of a Rotary-typed Small-scaled LIM for a Railway Transit (철도차량용 선형유도전동기 축소-회전형모델의 자기등가회로 파라미터 도출 및 특성 분석 연구)

  • Park, Chan-Bae;Lee, Hyung-Woo;Lee, Byung-Song
    • Journal of the Korean Society for Railway
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    • v.13 no.4
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    • pp.404-411
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    • 2010
  • Authors conducted a deduction and characteristic calculation of the some parameters using a magnetic equivalent circuit method to verify a basic design result of a rotary-typed small-scaled linear induction motor for a railway transit. In a LIM, it is possible to express the parameters of the magnetic equivalent circuit into a function of the shape of the secondary aluminium plate and the airgap between the LIM primary core and the secondary aluminium plate. It means that the LIM properties can be changed considerably by the shape of the secondary aluminium plate and the airgap between the LIM primary core and the secondary aluminium plate. So, authors analyzed a tendency of changes of the magnetic equivalent circuit parameters and the LIM characteristics by changing of the airgap, the thickness of the secondary aluminium plate and the overhang length and shape of a rotary-typed small-scaled LIM, and accomplished a basic research to develop a real-scaled LIM for a railway transit.

STUDY ON THE PROPERTIES OF GYPSUM-BONDED DENTAL INVESTMENTS (치과용 석고계 매몰재의 특성에 관한 연구)

  • Kim, Kyoung-Sun;Woo, Yi-Hyung;Choi, Boo-Byung
    • The Journal of Korean Academy of Prosthodontics
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    • v.28 no.1
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    • pp.137-163
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    • 1990
  • The properties of a investment material can be described by the consistency at the slurry state, the setting time, the compressive strength and the thermal expansion during the casting. In this study the effect of the production parameters which are included the ratio of quartz and cristobalite, the content of binder, the water powder ratio and the content and concentration of additives on the Properties of the gypsum-bonded investments has been investigated with help of the consistency test, the vicat needle test, the compressive strength test, the thermal expansion test, x-ray diffraction and DTA thermal differential test. The experimental results showed that the constitution of a investment with W/P ratio of 0.34, 30% of gypsum, 0.8% aluminium sulfate, 2% magnesium sulfate, 0.6% sodium phosphate was adapted for the properties of the KDA Spec. No. 13 type I investment. The important experimental results are summarized as follows. 1. The consistency of the investment decreased with increasing amount of aluminium sulfate and decreasing amount of sodium phosphate. An addition of magnesium sulfate up to 2% an increase of the consistency was shown. But 3% magnesium sulfate in investment showed a decrease of the consistency. The consistency did not vary significantly with a variation of the content of gypsum and cristobalite and the W/P ratio. 2. Aluminium sulfate and the magnesium sulfate promoted the hardening and the aluminium phosphate delayed the hardening. The setting time increased with amount of gypsum. The effect of the matrix on the setting time was insignificant. With the W/P ratio of 0.34 the setting time was 14 min. 3. The compressive strength decreased with the amount of aluminium sulfate up to 0.25% and increased with the amount of aluminium sulfate greater than 3%. The compressive strength decreased as decreasing the amount of magnesium sulfate and gypsum and as increasing the W/P ratio. The effect of the refractory on the compressive strength was also not significant. With the W/P ratio of 0.34 the compressive strength was $34Kg/mm^2$. 4. The 1st thermal expansion was found at the temperature near and the steady state or the contraction stage was found at the temperature between $250^{\circ}C$ and $500^{\circ}C$. After this stage the 2nd thermal expansion took place at the temperature near $500^{\circ}C$. The amount of thermal expansion increased with decreasing the content of magnesium sulfate, aluminium sulfate and gypsum and the W/P ratio. And the amount of thermal expansion increased as the content of sodium phosphate and cristobalite. With the W/P ratio of 0.34 the amount of total expansion was 1.2%.

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