• Title/Summary/Keyword: alumina coating

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Effect of Colloidal Silica on the Solidification of Galvanized Coatings (용융아연 도금층의 응고에 미치는 콜로이달 실리카의 영향)

  • 김상헌;정원섭;김형인
    • Journal of the Korean institute of surface engineering
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    • v.33 no.5
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    • pp.381-386
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    • 2000
  • It was found that colloidal silica sprayed to the galvanized steel sheet apparently made the molten zinc layer solidified to be the randomly oriented fine grains. Its spraying effect was also little affected by steel temperature that had been considered as one of the major operating factors in this process. From the results of surface analysis, it is considered that aluminum dissolved in coating layer reduces silica to silicon by the oxidation-reduction reaction, and that the reduced silicon acts as a more effective nucleus in solidification reaction than phosphate salt, siica and alumina.

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Development of Ceramic Composite Membranes for Gas Separation: III. Examination of Membrane Characteristics by the Gas Permeation Model (기체분리용 세라믹 복합분리막의 개발: III. 기체투과 모델에 의한 막의 특성 규명)

  • 현상훈;윤성필;강범석
    • Journal of the Korean Ceramic Society
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    • v.29 no.11
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    • pp.905-911
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    • 1992
  • Model equations for the gas permeation through a ceramic composite membrane were derived for examining the existence of crack, the reproducibility, and the microstructural properties of composite membranes. From the results of analyzing the nitrogen permeability data through alumina-tube supported TiO2 and SiO2 composite membranes, the extent of cracking, and the formation and structure of membrane top-layers were modelled. It was proved that the crack-free and reproducible composite membranes could be easily prepared only by the pore-filled coating within pores of the support in the sol-gel coating process.

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Characteristics and Preparation of CNT:ZnO Gas Sensors (CNT:ZnO 가스 센서의 제조와 특성 연구)

  • Yoon, So-Jin;Yu, Il
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.27 no.7
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    • pp.468-471
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    • 2014
  • The effects of ZnO coating on the sensing properties of CNT:ZnO based gas sensors were studied for $H_2S$ gas. The nano ZnO sensing materials were grown by hydrothermal reaction method. CNT:ZnO was prepared by ball-mill method. The mole range of nano ZnO coating on CNT surface was from 0 to 10%. The CNT:ZnO gas sensors were fabricated by a screen printing method on alumina substrates. The structural and morphological properties of the CNT:ZnO sensing materials were investigated by XRD, EDS, SEM and TEM. The XRD patterns showed that CNT:ZnO powders with hexagonal structure were grown with (002) dominant peak. The diameter of CNT from TEM was about 28 nm.

Development of Ceramic Composite Membranes for Gas Separation: II. Preparation and Coating Characteristics of Nanoparticulate $TiO_2$ Sols (기체분리용 세라믹 복합분리막의 개발: II. 극미세 입자 $TiO_2$ 졸의 제조 및 코팅 특성)

  • 현상훈;박준수;최세영
    • Journal of the Korean Ceramic Society
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    • v.29 no.9
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    • pp.739-749
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    • 1992
  • The sols prepared by dialyzing solutions, in which the hydrolyzed precipitates of TEOT or directly Ti(OC3H7)4 were resolved, were the nanoparticulate sol with the average particle size less than 7 nm and the anatase crystal phase. In the pH range of 1.5 to 2.9, the particle size of the nanoparticulate TiO2 sols (0.09 mol/ι) increased gradually upto 15 nm~26nm with the increase of pH in the initial aging state but the sols were transparent all the time, and stable without growin any more after 30 days. When the slipcasted porous alumina tubes were coated by the sol-gel dipping method, the minimum particle size and the aging time for forming the coated gel layer at the given pH were optimized. For obtaining the very thin crack-free and reproducible membrane coating, the use of a nanoparticulate TiO2 sol (0.09 mol/ι) aged for about 30 dyas at pH=2.0 was found to be the best.

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Preparation of Highly Oriented ZnO Thin Films Prepared by Sol-Gel Method

  • Cheol Jeong;Hwang, Kyu-Seog;Moon, Jong-Ha;Kim, Byung-Hoon
    • The Korean Journal of Ceramics
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    • v.3 no.4
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    • pp.249-252
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    • 1997
  • Highly oriented ZnO thin films were fabricated by dip-coating technique using zinc acetate 2-methoxyethanol 2-aminoethanol solution as starting materials, and effects of substrates on the film's orientation were investigated. Product films were obtained by prefiring at 300, 400, 500 and 550℃ for 10 min, followed by final heat-treatment at the same temperatures as prefiring for 1h. c-axis oriented films on glass substrates were prepared by heat treatment of prefiring films at 300-550℃, while films on alumina showed polycrystalline structure. Films with c-axis orientation exhibited lower specific resistivities than those of polycrystalline films with partial crack and pore.

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Synthesis and Properties of $Al_2O_3-SiC$ Composites from Alkoxide (알콕사이드로부터 $Al_2O_3-SiC$ 복합재료의 제조 및 특성)

  • 이형민;이홍림;조덕호
    • Journal of the Korean Ceramic Society
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    • v.32 no.10
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    • pp.1212-1218
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    • 1995
  • Al2O3-coated SiC composite powder and mechanically mixed Al2O3-SiC composite powder were synthesized using Al-isopropoxide and commercial SiC as the starting materials. Experiment results showed that the sinterability of Al2O3-coated SiC composite powder was more improved than the mechanically mixed Al2O3-SiC composite powder by the effect of homogeneous coating of alumina around SiC particles. Hence, the mechanical properties of the former was also much more improved than the latter.

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The Heat Treatment Characterization of Plasma Sprayed Alumina Coatings (플라즈마 용사법에 의한 $Al_2$O$_3$ 피복층의 열처리효과에 관한 연구)

  • 오익현;김한산;김수식
    • Journal of the Korean institute of surface engineering
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    • v.27 no.3
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    • pp.134-142
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    • 1994
  • $Al_2O_3$coatings on mild steel substrate by plasma spray process were produced to evaluate microstructural characterization and mechanical properties. As-coated $Al_2O_3$coating samplessd were subjected to two heat treat-ment conditions : ⅰ) annealing under vacuum circumstance, ⅱ) hot press treated condition. The two heat treat-ed coatings were investigated in terms of microhardness, adhesion strength, wear resistance, porosity forma-tion, and microstructures. In the case of the coatings which were subject to preparation step ⅰ, the porosity in the coating was decreased with the increase of temperature ($700^{\circ}C$-$1100^{\circ}C$), and the wear resistance, microhardnesss and adhesion strength were increased with the increase of temperature. On the other hand, in the case of the coatings which were subject to preparation step ⅱ, wear resistance and adhesion strength were improved with the increase of temperature and pressure. Experimental measurements of coatings which were produced by both preparation conditions were enhanced compare to those of as-coated coatings.

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Determination of Thermal Conductivity and Numerical Analysis of Al-Cr-N-O Composites Layer Formed by Hydro-thermal Process (수열합성된 Al-Cr-N-O계 도포층의 열전도 측정과 수학적 해석)

  • Kim, Ma-Ro;Yang, So-Eun;Lee, Jong-Jae;Kim, Byeong-Du;Choe, Yong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2014.11a
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    • pp.215-215
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    • 2014
  • Composites layer of Al-Cr-Ni-O system was prepared on a steel plate by hydro-thermal process at $700^{\circ}C$ for 12 hours, which phase identification and thermal conductivity were determined. The composites layer consisted of aluminum nitride, alumina, chromium carbide and aluminium, which density was $3.7kg/m^3$. The thermal conductivity of the coating layer determined by thermal data acquisition system was about 98.0 W/m/ which depended on the AlN content. Numerical modelling of the heat transfer behavior of the coating layer was well agreement with the empirical data.

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