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Preparation of Red Perylene Fluoroionophore Containing Calix[4]azacrown Ether and Their Ionophoric Properties

  • Jeon, Young-Min;Lim, Tae-Ho;Kim, Jong-Gyu;Kim, Jong-Seung;Gong, Myoung-Seon
    • Bulletin of the Korean Chemical Society
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    • v.28 no.5
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    • pp.816-820
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    • 2007
  • Novel new red-light emitting perylene fluoroionophore N,N'-dipropyl-1,7-bis(calix[4]azacrown-5-crown-5)- 3,4,9,10-perylene tetracarboxy diimide (3) was prepared by reacting N,N'-dipropyl-1,7-dibromo-3,4,9,10- perylene tetracarboxy diimide (1) with calix[4]azacrown-5-crown-5. Also the alternating copolymer (4) with similar repeating unit was prepared reacting by calix[4]bisazacrown-5 with 1. Metal ion binding by 3 and 4 leads to a blue-shift of absorption band and emission spectra. When ionophoric characteristics were investigated by binding alkali, alkali earth metal and various metal ions, polymeric ionophores displayed large fluorescence decreasing effects with K+, Ag+ and Ba2+, which was rationalized by photo-induced charge transfer (PCT).

Design of Switchable and Reconfigurable Semi-lumped Wideband Bandpass Filter

  • Xiong, Yang;Wang, LiTian;Zhang, Wei;Pang, DouDou;Zhang, Fan;He, Ming
    • ETRI Journal
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    • v.39 no.5
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    • pp.756-763
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    • 2017
  • A switchable single-wideband (SWB)-to-dual-wideband (DWB) bandpass filter (BPF), which is realized by using lumped switches, is presented in this paper. By alternating the operation modes-ON and OFF-in which the ON mode is achieved by placing the capacitors at the switching spots and the OFF mode is achieved by replacing the capacitors with inductors, DWB-to-SWB BPF can be achieved on the same device. In addition, by changing the capacitor values, the center frequency (CF) of the lower passband of DWB BPF can be easily tuned from 1.69 GHz to 2.22 GHz, while the higher passband stays almost unchanged. As an example, an SWB-to-DWB BPF is designed, fabricated, and measured. This BPF exhibits good performance including wideband, high isolation, compact size, and ability to switch.

Design and Implementation of a Blood-Glucose Meter to Reduce Hematocrit Interference (적혈구 용적률 간섭 보정을 위한 혈당 측정 기기의 설계 및 구현)

  • Cho, Hyuntae
    • IEMEK Journal of Embedded Systems and Applications
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    • v.15 no.4
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    • pp.167-175
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    • 2020
  • A blood-glucose meter is one of the in vitro diagnostic devices to measure and control the glucose concentration of diabetics. In order to measure the glucose level in the blood, the common method is to measure the amount of electrons, that is, the output current generated by glucose oxidation after a blood sample is inserted into the test strip containing an enzyme. The hematocrit is an obstacle in measuring accurate blood glucose concentration. This paper deals with the design and implementation of a blood-glucose meter to correct the hematocrit interference. We propose a sequential method which measures impedance using the alternating current and then measures glucose in the blood using the direct current. In addition, this paper introduces how to use commercial glucose strips based on the proposed system. Finally, we conducted the performance evaluation of the proposed system by comparing the measured current and impedance with those of the references. As a result, the standard deviation of the current measurement is approximately 0.6nA and the impedance measurement error for measuring the hematocrit is approximately within 1%. The proposed system will improve the accuracy of the conventional blood-glucose meter by reducing the hematocrit interference.

Development and Implementation of Measures for Structural and Reliability Importance by Using Minimal Cut Sets and Minimal Path Sets (최소절단집합과 최소경로집합을 이용한 구조 및 신뢰성 중요도 척도의 개발 및 적용)

  • Choi, Sung-Woon
    • Journal of the Korea Safety Management & Science
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    • v.14 no.1
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    • pp.225-233
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    • 2012
  • The research discusses interrelationship of structural and reliability importance measures which used in the probabilistic safety assessment. The most frequently used component importance measures, such as Birnbaum's Importance (BI), Risk Reduction (RR), Risk Reduction Worth (RRW), RA (Risk Achievement), Risk Achievement Worth (RAW), Fussel Vesely (FV) and Critically Importance (CI) can be derived from two structure importance measures that are developed based on the size and the number of Minimal Path Set (MPS) and Minimal Cut Set (MCS). In order to show an effectiveness of importance measures which is developed in this paper, the three representative functional structures, such as series-parallel, k out of n and bridge are used to compare with Birnbaum's Importance measure. In addition, the study presents the implementation examples of Total Productive Maintenance (TPM) metrics and alternating renewal process models with exponential distribution to calculate the availability and unavailability of component facility for improving system performances. System state structure functions in terms of component states can be converted into the system availability (unavailability) functions by substituting the component reliabilities (unavailabilities) for the component states. The applicable examples are presented in order to help the understanding of practitioners.

Fever and Fever Management in Children: A Literature Review (아동의 발열과 발열관리: 문헌고찰)

  • Jeong, Yong-Sun;Kim, Jin-Sun
    • Child Health Nursing Research
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    • v.16 no.1
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    • pp.30-40
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    • 2010
  • Purpose: The purposes of this review were to identify whether available evidence supports the nursing interventions that are commonly used to reduce fever in children and to introduce research findings into practice. Methods: Journal databases and clinical guidelines from 1990 to 2009 were searched. The search terms were fever, febrile convulsion, fever management, fever phobia, child, antipyretics, temperature, external cooling, tepid sponge bath, and physical treatment. Results: Evidence suggests that uncomplicated fever is relatively harmless, but it is an important immunological defense. Antipyretics should not routinely be used with the sole aim of reducing body temperature in children with fever who are otherwise well. Currently a lack of evidence supports the practice of alternating acetaminophen and ibuprofen, and the routine use of tepid sponge bath. Conclusion: Currently, fever management in children does not reflect research evidence. Pediatric nurses can play an important role by encouraging clinical research in this area and also by enhancing research utilization in their practice. Moreover, pediatric nurses can educate parents about evidence-based fever management. Evidence-based educational interventions for pediatric nurses need to be developed and evaluated to improve the quality of nursing care in the management of childhood fever.

Effects of Waves and Free-Surface Boundary Conditions on the Flow A Surface-Piercing Flat Plate (수면 관통 평판주위 유동에 미치는 파의 영향 및 자유표면 경계조건에 대한 연구)

  • Choi, Jung-Eun;Stern, F.
    • Journal of the Society of Naval Architects of Korea
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    • v.34 no.1
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    • pp.41-49
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    • 1997
  • Computational results from Navier-Stokes equations are presented for the Stokes-wave/flat-plate boundary-layer and wake for small wave steepness(Ak=0.01), including exact and approximate treatments of the viscous free-surface boundary conditions. The macro-scale flow indicate that the variations of the external-flow pressure gradients cause acceleration or deceleration of the streamwise velocity component and alternating direction of the cross flow. Remarkably, the wake displays a greater response, i.e., a bias with regard to favorable as compared to adverse pressure gradients. The micro-scale flow indicates that the free-surface boundary conditions have a profound influence over the boundary layer and near/intermediate wake. Order-of-magnitude estimates are conformed to the computational results. And appreciable errors are introduced through approximations to the free-surface boundary conditions.

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Chucking Method of Substrate Using Alternating Chuck Mechanism (반도체 기판 교차 파지 방법)

  • Ahn, Young-Ki;Choi, Jung-Bong;Koo, Kyo-Woog;Cho, Jung-Keun;Kim, Tae-Sung
    • Journal of the Semiconductor & Display Technology
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    • v.8 no.1
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    • pp.1-5
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    • 2009
  • Typically, single-wafer wet etching is done by dispensing chemical onto the front and back side of spin wafer. The wafer is fixed by a number of chuck pins, which obstruct the chemical flow and would result in the incomplete removal of the remaining film, which can become a source of contamination in the next process. In this paper, we introduce a novel design of wafer chuck, in which chuck pins are groupped into two and each group of pins fixes the substrate alternatively. Two groups of chuck pins fix the high-speed spin substrate with non contact method using a magnetic material. The actual process has been executed to observe the effectiveness of this new wafer chuck. It was found that the new wafer chuck performed better than the conventional wafer chuck for removing the remaining film from the bevel and edge side of substrate.

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A study on the corrosion fatigue fracture behavior of ion-nitrided SM45C under alternating tension-compression loading (반복인장-압축하중을 받는 이온질화 처리한 SM45C의 부식피로 파괴거동에 관한 연구)

  • 우창기;김희송
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.13 no.3
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    • pp.451-460
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    • 1989
  • This paper dealt with the effect of the ratios N2 to H2 gas on the corrosion fatigue failure behavior of ion-nitrided SM45C steel specimens. The specimens were water cooled after ion-nitriding at 500.deg. C for 3hrs in 5 Torr, 0.8N$_{2}$ and 0.5N$_{2}$ atmospheres. As the nitrogen concentration increases, the higher compressive residual stresses developed in the surface layer and the depth of nitrided layer increased, which in turn gave rise to increases in fatigue strength and corrosion fatigue life. In the region less than 1.5 * 10$^{5}$ cycles, fatigue failure initiated at the brittle nitrided case, whereas in the region higher than 1.5 * 10$^{5}$ cycles crack initiated from the non-metallic inclusions in the subsurface. The initiation of corrosion fatigue failure was mainly attributed to pitting of case hardened surface layer.

A Study on Foundation Methods of Ancient Structures (고대구조물의 기초공법에 관한 연구)

  • 정형식;손영식
    • Geotechnical Engineering
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    • v.8 no.3
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    • pp.75-88
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    • 1992
  • In this study the foundation methods which our ancestors, through a historical age as early as three kingdom's period, adopted for their civil structures and buildings have been reviewed by investigating the discovered relics. It is shown that they already, from about 2000 years ago, had applied various foundation techniques considering the structure types and the foundation soil conditions. The ancient foundation methods are categorized as artificially laid alternating soil and boulder layers under heavy structures, compacted soil base under wide loaded area, stone column under pillars of buildings, stacked long stone footing for special buildings such as palace buildings, and piling for bridges, They are analyzed with respect to current foundation techniques.

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a-Si TFT Integrated Gate Driver Using Multi-thread Driving

  • Jang, Yong-Ho;Yoon, Soo-Young;Park, Kwon-Shik;Kim, Hae-Yeol;Kim, Binn;Chun, Min-Doo;Cho, Hyung-Nyuck;Choi, Seung-Chan;Moon, Tae-Woong;Ryoo, Chang-Il;Cho, Nam-Wook;Jo, Sung-Hak;Kim, Chang-Dong;Chung, In-Jae
    • Journal of Information Display
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    • v.7 no.3
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    • pp.5-8
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    • 2006
  • A novel a-Si TFT integrated gate driver circuit using multi-thread driving has been developed. The circuit consists of two independent shift registers alternating between the two modes, "wake" and "sleep". The degradation of the circuit is retarded because the bias stress is removed during the sleep mode. It has been successfully integrated in 14.1-in. XGA LCD Panel, showing enhanced stability.