• Economic and Environmental Geology
• /
• v.35 no.4
• /
• pp.347-353
• /
• 2002

Dominant rock types of stones used presently for cooking utensils in Korea are pyroxenite, breccia and biotite diorite. Pyroxenite and biotite diorite relatively abundant in mafic minerals have higher specific gravities of 3.0 than breccia of 2.5. Breccia shows the highest absorption (2.9%) among three stones used as cooking utensils and pH value of three stone types shows the alkaline range of 9.7 to 9.9. Among the studied stones used for cooking utensils, biotite diorite is the most durable against abrasion and has the highest strength and therefore, it is expected to be used effectively for the longest time except for other specific causes. Heavy metals such as Cu, Pb, Co, Cr and Ni were leached lower than their detection limit (0.1 ppm) regardless of reaction time and initial pH value of solution. But the leached contents of Fe are various with rock types and leaching conditions and those by acidic solution are generally 1.8 to 31 times higher than those by neutral solution. Breccia and biotite diorite show the highest leached content of Fe in cases of neutral and acidic solutions, respectively. Standard criteria of leached heavy metals and macrominerals should be studied thoroughly to utilize stones for cooking utensils of high quality which are harmless to the human body. Also it is required to examine mon detailed abiochemical properties of various stone types used for cooking utensils.

• Resources Recycling
• /
• v.29 no.2
• /
• pp.18-27
• /
• 2020

Chemical experiment KS F 2545 and Physical experiment ASTM C 1260 has been accomplished to estimate the potential of alkali aggregate. Used for testing aggregate samples are forest aggregate and recycled aggregate which collected in Gangwon province Samcheok and Pyeongchang, Jeollabuk province Gimje and Kochang, and Gyeongsangnam province Goryeong. As the results of chemical experiment confirmed that if silicate rock and carbonate rock are mixed, reduction in alkalinity is increase. So it has been identified that case makes a disturb at the result of alkali aggregate reaction. In 9 out of the 62 aggregate samples check dissolved silica exceeding 100 mmol/ℓ. and mortar bar length increase rate confirmed that 5 of 9 chemical method aggregates were 0.1~0.2% and 2 aggregates were 0.2%. As a result of the alkaline aggregate reaction test using the chemical method and the mortar bar method, the aggregates showing alkali aggregate reaction are sandstone and tuff aggregates. Therefore, Alkali aggregate reaction tests are required to use clastic sedimentary rocks and volcanic pyroclastic rocks aggregates.

• Economic and Environmental Geology
• /
• v.22 no.1
• /
• pp.21-34
• /
• 1989

Chindong granites are classified into granodiorite, tonalite and quartz-diorite, and Yucheon - Eonyang granites into monzo-granite by the Streckeisen diagram. These granitic rocks of Cretaceous age show trend of calc-alkaline magma, and the magmatic evolution from basic to acidic rocks is consistant with the general crystallization path of the Cretaceous granitic rocks in the Gyeongsang basin. On the basis of petrological and petrochemical data, variation of major elements (K, Na, Ca, Mg) and trace elements (Rb, Sr, Ba) including ore metals (Cu, Pb, Zn) in the Cretaceous granitic rocks were studied in detail in order to investigate geochemical difference of the granitic rocks in relation to mineralization between Cu province and Pb-Zn province in the Gyeongsang basin. There is clear difference in content of the major elements between Chindong granites and Yucheon-Eonyang granites : Chindong granites have low content of K (1.62%) and Na (2.53%), and high content of Ca (3.75%) and Mg (1.42%) whereas Yucheon-Eonyang granites have high content of K (3.56-3.60%), and low content of Ca (0.96-0.26%) and Mg (0.26-0.21%). There is also clear difference in content of trace lithophile elements between Chindong granites and Yucheon-Eonyang, granites : Chindong granites have low content of Rb (86ppm) and Ba (330ppm), and high content of Sr (405ppm) while Yucheon-Eonyang, granites have high content of Rb (144-161ppm) and Ba (983-1030ppm), and low content of Sr (157-136ppm). The lithophile trace elements of Rb and Sr vary with close relationship to major elements of K and Ca, respectively. Therefore, Chindong granites are much easily distinguished from Yucheon-Eonyang granites by using relationship of K with Rb and Ca with Sr : K<3%, Rb<100ppm, Ca<2% and Sr>200ppm for Chindong granites, and K>3%, Rb>100ppm, Ca<2%, and Sr<200ppm for Yucheon-Eonyang granites. There is not clear difference in content of trace ore metals between Chindong granites and Yucheon-Eonyang granites : Chindong granites of the Cu province have low Cu content (15ppm) which is nearly equal to 13-14ppm of Yucheon-Eonyang granites of the Pb-Zn province, and Yucheon-Eonyang granites have Pb content (29-27ppm) which is rather lower than 37ppm of Chindong granites. But Cu is anomalously high in the mineralized part of Chindong granites in Gunbuk-Haman area, and Zn is apparently higher in Yucheon-Eonyang granites (51-37ppm) than in Chindong granites (29ppm). K/Pb ratio is also c1early distinguishable between Chindong granites (<850) and Yucheon-Eonyang granites (>850). Thus, it may be possible to apply geochemical difference of the granites to distinguish whether a Cretaceous granitic body is Cu related rock or Pb-Zn related rock, and whether it belongs to Cu province or Pb-Zn province in the Gyeongsang basin.

• Economic and Environmental Geology
• /
• v.35 no.6
• /
• pp.533-544
• /
• 2002

In order to investigate the relative mobility (RM) of dissolved elements during processes controlling major and trace element content, the concentrations of major, minor and trace elements were reviewed from the previous data of $CO_2$-rich waters and granites from Kangwon Province. The relative mobility of elements dissolved in $CO_2$-rich waters is calculated from $CO_2$-rich water/granite ratio with normalizing by sodium. The results show that gaseous input of magmatic volatile metals into the aquifer is negligible in this study area, being limited by cooling of the rising fluids. Granite leaching by weakly acidic, $CO_2$-charged water is the overwhelming source of metals. Poorly mobile element (Al) is preferentially retained in the solid residue of weathering, while alkalis, alkaline earth and oxo-hydroxo anion forming elements (especially As and U) are mobile and released to the aqueous system. Transition metals display an intermediate behavior and are strongly dependent on either the redox conditions (Fe and Mn) or solid surface-related processes (adsorption or precipitation) (V, Zn and Cu).

• Journal of Applied Biological Chemistry
• /
• v.58 no.2
• /
• pp.157-174
• /
• 2015

Stabilization of metals in contaminated soils using various waste materials has been reported. Alkaline materials (limes, shells, industrial byproducts, etc.), phosphorous (P) containing materials (animal bones, phosphate rock, etc.), organic materials (composts, manures, biochars, etc.) and others (zerovalent iron, zeolite, etc.) were widely evaluated to ensure its effectiveness/applicability of stabilization of metals in soils. Stabilization mechanisms of those materials above were partially revealed, but the related literatures are still lacked and not sufficient for approaching to long-term stability/applicability in the field. The aims of this review are to summarize current knowledge of metal stabilization in contaminated soils using various waste materials and to suggest a direction for future field research.

• Ocean and Polar Research
• /
• v.24 no.4
• /
• pp.465-482
• /
• 2002

Petrological, geochemical, and geochronological studies of Dokdo volcanic rocks, East Sea, have been carried out to understand their petrogenesis. Dokdo volcanic activity is divided into three stages according to occurrences and eruption ages of rocks. The second-stage activity is accompanied by large volume of pyroclastics and lavas of intermediate composition, and occupies most of the East and West islets. K-Ar biotite and whole-rock ages indicate that Dokdo volcanic activity occurred during late Pliocene and became systematically younger toward later stages: namely, 2.7-2.4 Ma for the first-stage trachyte, 2.4-2.3Ma for the second-stage trachyandesite and 2.2-2.1 Ma for the last-stage trachyte and dikes. Dokdo volcanic rocks are of intermediate to felsic compostions, and have OIB-like alkaline nature. The geochemical similarities between Dokdo and Ulleungdo volcanic rocks suggest that they were formed from the same mantle plume. However, considering the difference of eruption ages between Dokdo (2.7-2.1 Ma) and Ulleungdo (1.4-0.01 Ma) volcanic rocks, the former seems to have been formed by earlier hot spot activity.

• Journal of the Korean earth science society
• /
• v.27 no.5
• /
• pp.528-538
• /
• 2006

Main aspect of this study is to clarify the petrochemistry and petrogenesis of intermediated-basic plutons located in the southwestern part of the Korean peninsula. These Intermediated-basic plutons consist of Pre-Cambrian anorthosite-gabbro, Triassic hornblende gabbro (Jirisan area), Jurassic diorite-syente (Jirisan and north area) and Cretaceous gabbro-diorite (south area). The Massif type anorthosite has multi intrusions, where each one intruded by gabbroic rocks, composed of gabbro, norite, troctolite and leucogabbro. In the variation diagram of the major-minor composition, AMF and Pl-Px-Ol diagrams, we suggest that intermediated-basic plutons in the southwestern part of the Korea show a trend consistent to Daly's value and calc-alkaline rock series. Accoding to REE (La/Yb)cw and Eu/Sm, these plutons are enriched with LREE than HREE, and emplaced by the tectonic setting in continent and/or continental margin.

• Korean Journal of Poultry Science
• /
• v.23 no.3
• /
• pp.135-144
• /
• 1996

This study was carried out to clarify the genetic constitution of biochemical polymorphic loci controlling blood protein and enzymes as genetic rnarkers in Korean native chicken(KNG) population Blood samples were collected from 230 KNG representing three colored-lines(reddish-, yellowish- and blackish- brown) raised in Daejeon branch of National Livestock Research Institute. Eight blood marker loci, transferrin(Tf), post-albumin(Pas), albumin(Alb), amylase-1(Arny-1), es-terase-1(Es-1), alkaline phosphatase(Akp), catalase(Cat) and hemoglobin(Hh) were analyzed by using starch, agarose and polyacrylamide gel electrophoresis. Based on the gene frequencies of polymorphic marker loci, the genetic characteristics of KNF population was analyzed, and the genetic ariability within population was quantified. The genetic relationships between KNC and other native fowls or improved breeds were also estimated. The gene frequencies of Tf, Pas and AIb loci were similar to those of improved breeds among the seven biochemical polymorphic loci, while gene frequencies of Cat and Es-i loci were remarkably different between KNC and improved breeds. Gene frequencies of amy-i and Akp loci were similar to those of New Hampshire and Rhode Island Red and White Leghorn, respectively. However in comparison with other improved breeds, great differences were observed in gene frequencies of these loci The average heterozygosity, effective number of alleles and homogeneity index for the seven loci combined were estimated to be .334, 1.639 and .373, respectively. Based on the dendrogram and genetic distances, the KNC was genetically closer to New Hampshire, Plymouth Rock and Rhode Island Red breeds than to the White Leghorn breed.

• The Journal of the Petrological Society of Korea
• /
• v.2 no.2
• /
• pp.156-166
• /
• 1993

The volcanic stratigraphy and geochemistry of the Cretaceous volcanic rocks in the southern part of the Pusan showed that the volcanic rocks of the study area consist of alternating pyroclastic rocks and andesitic lavas, apparently constituting a thick volcanic sequence of a stratovolcano. The andesitic rocks contain augite, plagioclase, and hornblende as phenocrysts. Matrix minerals are augite, magnetite, hornblende, apatite. Mafic minerals, such as chlorite, epidote, sericite, and iron oxides occur as alteration products. Dacitic volcanic breccia and rhyolitic welded ash-flow tuff locally overlie the andesitic rocks. The rocks reported in the previous studies as andesitic breccia and andesite plot in the field of basalt, basaltic andesite, andesite, dacite and rhyolite, based on their chemical compositions. The volcanic rocks of the study area belong to the calc-alkaline series, and the andesitic rocks which are predominant in the area plot to the field of orogenic andesite.

• Journal of the Mineralogical Society of Korea
• /
• v.19 no.2 s.48
• /
• pp.99-109
• /
• 2006

Igneous rocks occurring in the northwesern part of Keumsan area, Chungcheongnam-do were studied petrogeochemically. The geology of this area is composed mainly of the Precambrian biotite gneiss, age-unknown Ogchon supergroup, Jurassic biotite granite, and Cretaceous volcanic rocks, pink feldspar granite and quartz porphyry. The biotite granite is gradually changes to leucocratic nature by going from center to periphery of the rock mass. It shows variation, with distance from the center, in chemical components: $SiO_2,\;Na_2O\;and\;K_2O$ increase, whereas $Fe_2O_3,\;CaO,\;P_2O_5,\;MgO,\;and\;TiO_2$ decrease. Based on geochemical data, the biotite granite and quartz porphyry belong to subalkaline series and I-type. They show calc-alkaline differentiation trend. The biotite granite shows little negative Eu-anomaly pattern, whereas quartz porphyry show marked negative Eu-anomaly pattern, indicating that quartz porphyry was evolved further, when compared with biotite granite.