• Title/Summary/Keyword: alkali-free

Search Result 158, Processing Time 0.025 seconds

Effect of micronutritional-element deficiencies on the metabolism of Chlorella cells. (II) On the biosynthetic activities of protein, nucleic acids and phospholipid (Chlorella 의 물질대사에 미치는 미양원소의 결핍효과(제 2 ) -, 리보 및 의 생합성능에 관하여-)

  • Lee, Yung-Nok;Chin, Pyung;Sim, Woong-Seop
    • Korean Journal of Microbiology
    • /
    • v.6 no.1
    • /
    • pp.22-28
    • /
    • 1968
  • Chlorella ellipsoidea cells were cultured in an iron, copper, zinc, manganese, molybdenum or boron-free medium. Biosynthetic activities of nucleic acids, protein and phospholipid in chlorella cells, which were growing in a microelement deficient medium were compared with those of the normal cells by measuring the contents of phosphate, amino acids or UV-absorbing substances in the various cell fractions. When the algae were grown in a molybdenum-free medium, the amounts of phosphate in the acid-soluble fraction of the cells increased, whereas the amounts of alkali-stable protein and RNA decreased compared with the normal cells showing that the synthesis of protein and RNA from the early products of photosynthesis was inhibited. When the algae were grown in a boron-free medium, amounts of alkali-labile protein and phospholipid of the cells decreased, while the amount of phosphate in acid-soluble fraction increased compared with the normal cells showing that the biosynthesis of protein and phospholipid from the early products of photosynthesis was retarded. In general, amounts of protein and RNA in the microelement deficient cells significantly decreased compared with those of the normal cells. Phosphate content in the acid-soluble fraction of the algal cell grown in an zinc, copper, molybdenum, or boron-free medium increased considerably, whereas that of the algal cell grown in an iron or manganese-free medium decreased remarkably compared with that of the control. It is considered, therefore, that molybdenum, zinc, copper and boron etc. play an important role in the biosyntbesis of macromolecule from acid-soluble phosphate compounds, in contrast to the principal action of iron and manganese on the photosynthetic process itself.

  • PDF

Stability of the growth process at pulling large alkali halide single crystals

  • V.I. Goriletsky;S.K. Bondarenko;M.M. Smirnov;V.I. Sumin;K.V. Shakhova;V.S. Suzdal;V.A. Kuznetzov
    • Journal of the Korean Crystal Growth and Crystal Technology
    • /
    • v.13 no.1
    • /
    • pp.5-14
    • /
    • 2003
  • Principles of a novel pulse growing method are described. The method realized in the crystal growing on a seed from melts under raw melt feeding provided a more reliable control of the crystallization process when producing large alkali halide crystals. The slow natural convection of the melt in the crucible at a constant melt level is intensified by rotating the crucible, while the crystal rotation favors a more symmetrical distribution of thermal stresses over the crystal cross-section. Optimum rotation parameters for the crucible and crystal have been determined. The spatial position oi the solid/liquid phase interface relatively to the melt surface, heaters and the crucible elements are considered. Basing on that consideration, a novel criterion is stated, that is, the immersion extent of the crystallization front (CF) convex toward the melt. When the crystal grows at a <> CF immersion, the raised CF may tear off from the melt partially or completely due to its weight. This results in avoid formation in the crystal. Experimental data on the radial crystal growth speed are discussed. This speed defines the formation of a gas phase layer at the crystal surface. The layer thickness il a function of time a temperature at specific values of pressure in the furnace and the free melt surface dimensions in the gap between the crystal and crucible wall. Analytical expressions have been derived for the impurity component mass transfer at the steady-state growth stage describing two independent processes, the impurity mass transfer along the <> path and its transit along the <> one. The heater (and thus the melt) temperature variation is inherent in any control system. It has been shown that when random temperature changes occur causing its lowering at a rate exceeding $0.5^{\circ}C/min$, a kind of the CF decoration by foreign impurities or by gas bubbles takes place. Short-term temperature changes at one heater or both result in local (i.e., at the front) redistribution of the preset axial growth speed.

Chemical Characteristics of Commercial Korean Soy Sauce Produced by Alkali Treatment Following Acidic Hydrolysis

  • Cho, Woo-Jin;Kim, Hun;Jeong, Eun-Jeong;Lee, Young-Mi;Kim, Hyoun-Jin;Lee, Jung-Suck;Cha, Woung-Jun
    • Preventive Nutrition and Food Science
    • /
    • v.7 no.4
    • /
    • pp.427-431
    • /
    • 2002
  • Alkali treatment following acidic hydrolysis (ATAH) is a commonly used practice for reducing the levels of monochloropropanediol in commercial Korean soy sauce. This study investigated the chemical compounds produced in commercial Korean soy sauce made by ATAB. The levels of amino-N, total acidity, pH, salinity and Brix of the soy sauce were 6.66%, 2.52%, 19.81%, 4.57 and 35.01, respectively. The major fatty acids were C18:2n-6, C16:0, Cl8:ln-9 and C18:3n-6. The concentration of polyunsaturated fatty acids were especially high, with of C18:2n-6 (49.8%) being the highest followed by C18:3n-6 (3.8%) and C18:3n-3 (2.4%) in that order. Among the non-volatile organic acids, the concentration of levulinic acid (1,206.28 mg/100 g) was the highest, while the taste value of citric acid was the highest. Among the ATP related compounds, IMP concentration (31.19 mg/100 g) was highest followed by AMP, hypoxanthine and GMP in that order. The concentrations of free and total amino acids in soy sauce were 6,136.94 mg/100 g and 8,702.76 mg/100 g, respectively. On the other hand, the taste value of glutamic acid, a major amino acid flavor determinant in soy sauce, was highest of all the amino acids, which is desirable since most free amino acids such as methionine, histidine and phenylalanine have a bitter taste that detracts from the flavor of soy sauce.

Preparation and Characterization of Bi based frit for Ag Electrode in PDP Application (PDP용 Ag전극 페이스트의 Bi계 프릿 제조 및 특성)

  • 김형수;최정철;이병옥;최승철
    • Journal of the Microelectronics and Packaging Society
    • /
    • v.10 no.4
    • /
    • pp.47-52
    • /
    • 2003
  • A new type of Bi based glass frit was developed for Ag paste in PDP applications and its properties are compared with the commercially used Pb based glass frit. After optimization of the properties of Bi based frits for PDP application such as the softening temperature and the coefficient of thermal expansion (C.T.E), the screen printed electrodes prepared with the Bi based fit contained Ag paste were characterized. In $Bi_2O_3-B_2O_3-Al_2O_3$ glass system with the more than 50% of $Bi_2O_3$, the softening temperature, the thermal expansion coefficient and the line resistivity was 400∼$480^{\circ}C$, 7.31∼$10.02\times 10^{-6}/^{\circ}C$> and 4.1∼4.8$\Omega$ respectively. Properties of the Bi based frits are comparable with the Pb based frits. A printability and an uniformity of the Bi based frits were excellent in screen printed Ag eletrode. The Bi based frit system is an excellent candidate material for Pb free and Alkali free frit in PDP applications.

  • PDF

Technology for the Preparation of Ash-free Coal from Low Rank Coal(LRC) (저등급 석탄으로부터 초청정석탄 제조 기술)

  • Lee, Sihyun;Kim, Sangdo
    • Korean Chemical Engineering Research
    • /
    • v.46 no.3
    • /
    • pp.443-450
    • /
    • 2008
  • Efficient use of low rank coals (LRC) have been investigated as a method to cope with recent high oil price. Among the coals used in industry, lignite and sub-bituminous coals are belong to the LRC, and have abundant deposit and are distributed worldwide, but high moisture contents and self ignition properties inhibits their utilization. In this paper, chemical coal cleaning to produce ash-free coal from LRC has been investigated. Two technologies, that is, UCC(Ultra Clean Coal) process removing ash from coal and Hyper Coal process extracting combustibles from coal were compared with. UCC process has merits of simple and reliable when it compared with Hyper Coal process, but the remaining ash contents werehigher than Hyper Coal. Hyper Coal has ash contents under the 200ppm when raw coal is treated with appropriate solvent and ion exchange materials to remove alkali materials in extracted solution. The ash-free coal which is similar grade with oil can be used as alternate oil in the industry, and also used as a high grade fuel for IGCC, IGFC and other advanced combustion technology.

Studies on the Detergency Characteristics of Free Fatty Acid in Oily Soil. Part 1. Detergency of Palmitic Acid. (오염중의 유이지방산이 세척에 미치는 영향(제일보 팔미트산의 세척 특성))

  • Chung Hae Won;Kim Sung Reon
    • Journal of the Korean Society of Clothing and Textiles
    • /
    • v.1 no.1
    • /
    • pp.31-37
    • /
    • 1977
  • The effects of surfactants and concentration of NaOH in surfactant solution on the removal of free fatty acid soil from cotton fabrics were investigated. Cotton fabrics were soiled with palm itic acid which is the most common fatty acid found in natural oily soil and washed in Lauder-ometer with various types of surfactant with or without NaOH. The rate of soil removal was estimated by analyzing palmitic acid contents in fabric before ar d after washing. Analysis of palmitic contents was made by extracting palmitic acid with azeotropic mixture of alcohol-benzene and the extracts were titrated with standard NaOH solution. It was shown that the types of surfactant are important factor in free fatty acid removal and the efficiency increases in the following order: SLS$90\%$ of initial sorption. In relation to the mechanism of detergency, the suspending and emulsifying power of surfactants were also examined. From the results of this experiments, it could be concluded that the soap formation with alkali and the suspending power of surfactant arc significant factors in free fatty acid soil removal, but the emulsifying power of it is neglizible.

  • PDF

Classification of Alkali Activated GGBS Mortar According to the Most Suitable Usage at the Construction Site

  • Thamara, Tofeti Lima;Ann, Ki Yong
    • Journal of the Korean Recycled Construction Resources Institute
    • /
    • v.8 no.1
    • /
    • pp.56-63
    • /
    • 2020
  • The usage of OPC-free alkali activated ground granulated blast furnace slag(GGBS) mortar has been widely studied on the previous years, due to its advantages on sustainability, durability and workability. This paper brings a new view, aiming to classify the best application in situ for each mortar, according to the type and activator content. By this practical implication, more efficiency is achieved on the construction site and consequently less waste of materials. In order to compare the different activators, the following experiments were performed: analysis of compressive strength at 28 days, setting time measured by needles penetration resistance, analysis of total pore volume performed by MIP and permeability assessment by RCPT test. In general, activated GGBS had acceptable performance in all cases compared to OPC, and remarkable improved durability. Following the experimental results, it was confirmed that each activator and different concentrations impose distinct outcome performance to the mortar which allows the classification. It was observed that the activator Ca(OH)2 is the most versatile among the others, even though it has limited compressive strength, being suitable for laying mortar, coating/plaster, adhesive and grouting mortar. Samples activated with NaOH, in turn, presented in general the most similar results compared to OPC.

A Study on Properties of High Blaine Slag Cement for Shotcrete (숏크리트용 고분말도 슬래그 시멘트의 특성)

  • Kim, Jae-Young;Yum, Soo-Kyung;Yoo, Dong-Woo;Choi, Hyun-Kuk
    • Journal of the Korean Ceramic Society
    • /
    • v.47 no.5
    • /
    • pp.357-364
    • /
    • 2010
  • This study was performed to get basic information about properties of high blaine slag cement(HSC) to use shotcrete(or sprayed concrete and mortar). Particle size distribution, setting time and compressive strength test, analysis like as SEM, DSC thermal analysis, XRD was carried out to investigate principle properties of HSC. Setting time of HSC was delayed slightly, but influence of accelerators was more bigger than ordinary portland cement(OPC). Compressive strength of HSC at 28 days was more higher than OPC regardless of using accelerators. Results of analysis showed early period hydration products of HSC is more small and located widely, because of the interface of between cement particle and water is increased as specific surface of cement increase. From the SEM observation and analysis of DSC and XRD results, aluminates accelerators bring on some hydration products like as calcium aluminium hydrates, alkali free accelerators increases ettringite and monosulfates. Aluminates accelerators has a advantage of setting time and early strength, alkali free accelerators increases strength after 7 days.

Potential of Coal Gasification Slag as an Alkali-activated Cement (석탄가스화 복합발전 슬래그의 알칼리 활성 시멘트로서의 가능성)

  • Kim, Byoungkwan;Lee, Sujeong;Chon, Chul-Min;Choi, Hong-Shik
    • Resources Recycling
    • /
    • v.27 no.2
    • /
    • pp.38-47
    • /
    • 2018
  • Integrated gasification combined cycle (IGCC) is a next generation energy production technology that converts coal into syngas with enhanced power generation efficiency and environmental performance. IGCC produces almost coal gasification slag as the solid by-product. IGCC slag is generated about 140,000 tons for a year although recycling of it is still in the early stages. We evaluated the potential of IGCC slag which is generated from a pilot plant in South Korea as an alkali-activated cement. Samples which were activated with the combined activator of sodium silicate solution and caustic soda had an average compressive strength of 4.5 MPa, showing expansion. Expansion of the alkali-activated slag was presumed to be caused by free CaO in the slag, although it was not detected by the ethylene glycol method. Samples that were activated with the combined activator of sodium aluminate and caustic soda had an average compressive strength of 10 MPa. Hydroxy sodalite and $C_3AH_6$ were found to be the new crystalline phases. IGCC slag can be used as an alkali-activated material, but the strength performance should be improved with proper mix design approach to calculate optimum proportions which can alleviate the expansion issue at the same time.