• Title/Summary/Keyword: alkali materials

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Hydration Mechanism of Alkali Activated Slag Cement

  • Jong Cheol Kim;Keun Ho Auh;Sung Yun Hong
    • The Korean Journal of Ceramics
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    • v.5 no.1
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    • pp.35-39
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    • 1999
  • For many years, alkali activated blast furnace slag cement containing no ordinary portland cement has received much attention in the view of energy saving and its many excellent properties. We examined the structural change of slag glass which was activated by alkali metal compounds using IR spectroscopy. The properties of hydrated products and unhydrated slag grains was characterized by XRD and micro-conduction calorimeter. Ion concentration change in the liquid during the hydration of blast furnace slag was also studied to investigated the hydration mechanism.

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Effect of Washing Treatment of Aged Paper Materials for Better Conservation (열화된 종이자료의 보존성 개선을 위한 세척처리 특성)

  • Lee, Kwi-Bok;Seo, Yung-Bum;Park, So-Yeon;Jeon, Yang;Shin, Jong-Soon
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.38 no.4 s.117
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    • pp.53-60
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    • 2006
  • Paper materials for long term conservation suffer slowly mechanical and chemical deterioration, the extent of which may depend upon their conservation environment. Those deterioration includes discoloring, low moisture content, acidification, and brittleness. To slow deterioration, washing treatment, deacidification, and polymer reinforcement on paper materials are usually used. One easy and simple method of fixing low moisture content and acidification was an washing method, and we used both distilled and alkali water in washing method in this study. Alkali water is electrolyzed cathode water of high pH, and has no alkali metal ions in it. Experiment showed that washing treatment with both distilled and alkali water gave improvement in raising moisture content, pH, and mechanical strength of paper materials even after severe accelerated aging test. Advantageous effect of alkali water over distilled water on preventing deterioation was also shown clearly.

The doping effect and electronic structure of alkali metal doped tris (8-hydroxyquinoline) aluminum

  • Kim, Ki-Soo;Lee, Jong-Lam
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.1059-1060
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    • 2009
  • We have investigated the pristine alkali metal doping effect which is the Fermi level of alkali metal doped Alq3 shifts toward the LUMO. In-situ measurements of synchrotron radiation photoelectron spectroscopy revealed that the interface dipole or bend bending in previous reports are not the pristine alkali metal doping effect

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Estimation of Strength and Pore Structure of Alkali-Activated Fire Protection Materials at High Temperature (고온에서의 알칼리 활성화 내화성 결합재의 강도 및 공극구조 평가)

  • Song, Hun;Kim, Young-Ho;Kim, Wan-Ki;So, Hyung-Suk
    • Journal of The Korean Digital Architecture Interior Association
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    • v.12 no.4
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    • pp.59-66
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    • 2012
  • This study is interested in identifying the effectiveness of alkali-activated fire protection material compounds including the alkali-activator such as potassium hydroxide, sodium silicate and fly ash as the fire resistant finishing materials. Also, this paper is concerned with change in compressive strength and pore structure of the alkali-activated fire protection material at high temperatures. The testing methods of fire protection materials in high temperature properties are make use of TG-DSC and mercury intrusion porosimetry measurements. This study results show that compressive strength is rapidly degraded depending on a rise of heating temperature. Porosity showed a tendency to increase irrespective of specimen types. This is due to both the outbreak of collapse of gel comprising the cement and a micro crack by heating. However, alkali-activated fire protection material composed of potassium hydroxide, sodium silicate and fly ash has the thermal stability of the slight decrease of compressive strength and porosity at high temperature. These thermal stability is caused by the ceramic binding capacity induced by alkali activation reaction by the reason of the thermal analysis result not showing the decomposition of calcium hydrate.

The Compressive Strength Development of Briquette Ash by Alkali Activated Reaction (알칼리 활성반응에 의한 Briquette ash의 강도 발현 특성)

  • Seo, Myeong-Deok;Lee, Su-Jeong;Park, Hyun-Hye;Kim, Yun-Jong;Lee, Su-Ok;Kim, Taik-Nam;Cho, Sung-Baek
    • Korean Journal of Materials Research
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    • v.18 no.9
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    • pp.463-469
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    • 2008
  • Non-sintering cement was manufactured with briquette ash. Alkali activator for compression bodies used a NaOH solution. In order to apply alkali-activated briquette ash and the non-sintering cement to concrete, several experimental studies were performed. It was necessary to study the binder obtained by means of a substitute for the cement. This study concentrated on strength development according to the concentration of NaOH solution, the curing temperature, and the curing time. The highest compressive strength of compression bodies appeared as $353kgf/cm^2$ cured at $80^{\circ}C$ for 28 days. This result indicates that a higher curing temperature is needed to get a higher strength body. Also, geopolymerization was examined by SEM and XRD analysis after the curing of compression bodies. According to SEM and XRD, the main reaction product in the alkali activated briquette ash is aluminosilicate crystal.

An Experimental Study on the Alkali-Silica Reaction of Crushed Stones (Part 3 : The Influence of the Innocuous Aggregate Content and Pozzolanic Materials to the Alkali-Silica Reaction) (쇄석골재의 알칼리-실리카 반응에 관한 실험적 연구 (제3보 : 무해골재 치환량 및 포졸란물질이 알칼리-실리카 반응에 미치는 영향))

  • 이양수;정재동;노재호;조일호;윤재환;이영수
    • Proceedings of the Korea Concrete Institute Conference
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    • 1994.04a
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    • pp.169-173
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    • 1994
  • Recently, the use of crushed stones is increased due to the shortage of natural aggregates. In the previous papers of part 1 and 2, we got the conclusions that some of crushed stones have the characteristic of alkali-silica reaction(ASR). And these reactions are influenced by the amount and type of alkali in cement. The purpose of this paper is how to prepare for the prevention against alkali-silica reaction. As a solution of problems, we have conducted the experiments of two methods. One was the replacement of innocuous aggregates instead of reactive aggregates, the other was the addition of various pozzolanic materials. As a result, we found that the expansion by alkali-silica reaction in mortar bar could be effectively decredsed by upper methods.

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Analysis of Internal Structure in Alkali-Activated Fire Protection Materials Using Fly ash (플라이애시를 활용한 알칼리 활성화 내화성 마감재의 내부구조 분석)

  • Song, Hun;Chu, Yong-Sik;Lee, Jong-Kyu
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.4
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    • pp.104-112
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    • 2012
  • This study involves investigating the correlation between variation of internal structure and heating temperature of alkali-activated fire protection materials using fly ash. Dehydration and micro crack thermal expansion occur in cement hydrates of cementitious materials heated by fire. Internal structure difference due to both the dehydration of cement hydrates and pore solution causes and influences changes in the properties of materials. Also, this study is concerned with change in microstructure and dehydration of the alkali-activated fire protection materials at high temperatures. The testing methods of alkali-activated fire protection materials in high temperature properties are make use of TG-DSC and mercury intrusion porosimetry measurements. The study results show that the alkali-activated fire resistant finishing material composed of potassium hydroxide, sodium silicate and fly ash has the high temperature thermal stability. These thermal stability is caused by the ceramic binding capacity induced by alkali activation reaction.

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Fabrication of Porous 3-Dimensional Ti Scaffold and Its Bioactivity by Alkali Treatment (다공성 3차원 Ti 지지체의 제조 및 알카리처리에 따른 생체활성 평가)

  • An, Sang-Hyun;Kim, Seung-Eon;Kim, Kyo-Han;Yun, Hui-Suk;Hyun, Yong-Taek
    • Korean Journal of Materials Research
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    • v.19 no.7
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    • pp.362-368
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    • 2009
  • Ti scaffolds with a three-dimensional porous structure were successfully fabricated using powder metallurgy and modified rapid prototyping (RP) process. The fabricated Ti scaffolds showed a highly porous structure with interconnected pores. The porosity and pore size of the scaffolds were in the range of 66$\sim$72% and $300\sim400\;\mu$m, respectively. The sintering of the fabricated scaffolds under the vacuum caused the Ti particles to bond to each other. The strength of the scaffolds depended on the layering patterns. The compressive strength of the scaffolds ranged from 15 MPa to 52 MPa according to the scaffolds' architecture. The alkali treatment of the fabricated scaffolds in an aqueous NaOH solution was shown to be effective in improving the bioactivity. The surface of the alkali-treated Ti scaffolds had a nano-sized fibre-like structure. The modified surface showed a good apatite forming ability. The apatite was formed on the surface of the alkali treated Ti scaffolds within 1 day. The thickness of the apatite increased when the soaking time in a simulated body fluid (SBF) solution increased. It is expected that the surface modification of Ti scaffolds by alkali treatment could be effective in forming apatites in vivo and can subsequently enhance bone formation.

Studies on Borassus fruit fiber and its composites with Polypropylene

  • Sudhakara, P.;Obi Reddy, K.;Prasad, C. Venkata;Jagadeesh, Dani.;Kim, H.S.;Kim, B.S.;Bae, S.I.;Song, J.I.
    • Composites Research
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    • v.26 no.1
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    • pp.48-53
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    • 2013
  • This paper summarizes the structural characterization of borassus fruit fibers by means of various characterization techniques, optimization of alkali treatment of borassus fruit fine fibers (BFF) with a 5% concentration sodium hydroxide solution for different time intervals (1, 4, 8 and 12 h) and the changes occurring in borassus fibers. This paper also discusses the manufacturing of BFF/PP compotes using MAPP as a compatibilizer in addition to alkali treatment. Composites were evaluated for their mechanical and morphological properties. The tensile strength and modulus, flexural strength and modulus and impact strength were increased for alkali treated/MAPP composites by 4.5%, 17%, 17.2 %, 9% and 10% respectively.