• Title/Summary/Keyword: alkali material

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Electrical Characteristics of Organic Light Emitting Diodes (OLED) using the Alkali Metal Complex as New Electron Injection Layers (알칼리 금속 전자 주입층을 사용한 유기 전기 발광 소자 (OLED)의 전기적 특성)

  • Lee, Hyun-Koo;Kim, Jun-Ho;Kim, Young-Kwan
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07b
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    • pp.1015-1018
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    • 2004
  • We investigate the influence of the New Electron Injection Layers (EIL) on the performance of the Alkali Metal Complex vapor-deposited Organic Light Emitting Diodes(OLED). Two different Alkali Metal Complex were used; Lithium Quinolate (Liq), and Sodium Quinolate (Naq). In all cases, $Alq_3$ was the Electron Transporting Layer (ETL). We measure and compare the current density-voltage (J-V) and luminance-voltage (L-V) characteristics. We concluded that the turn-on voltage, and luminance efficiency are controlled by the type of EIL material used. We show the longer life-time OLED with Alkali Metal Complex EIL than OLED with LiF EIL. And we show the Optimized Alkali Metal Complex thickness is 3nm. Existent LiF to because is inorganic material, there is trouble to do epitaxy into thin layers but regulates the thickness in case of Alkali Metal Complex matter characteristic that is easy be. Alkali Metal Complex also appeared by sensitive thing in thickness than LiF If utilize this material, It is thought much advantages may be at common use of OLED.

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Estimation of Strength and Pore Structure of Alkali-Activated Fire Protection Materials at High Temperature (고온에서의 알칼리 활성화 내화성 결합재의 강도 및 공극구조 평가)

  • Song, Hun;Kim, Young-Ho;Kim, Wan-Ki;So, Hyung-Suk
    • Journal of The Korean Digital Architecture Interior Association
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    • v.12 no.4
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    • pp.59-66
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    • 2012
  • This study is interested in identifying the effectiveness of alkali-activated fire protection material compounds including the alkali-activator such as potassium hydroxide, sodium silicate and fly ash as the fire resistant finishing materials. Also, this paper is concerned with change in compressive strength and pore structure of the alkali-activated fire protection material at high temperatures. The testing methods of fire protection materials in high temperature properties are make use of TG-DSC and mercury intrusion porosimetry measurements. This study results show that compressive strength is rapidly degraded depending on a rise of heating temperature. Porosity showed a tendency to increase irrespective of specimen types. This is due to both the outbreak of collapse of gel comprising the cement and a micro crack by heating. However, alkali-activated fire protection material composed of potassium hydroxide, sodium silicate and fly ash has the thermal stability of the slight decrease of compressive strength and porosity at high temperature. These thermal stability is caused by the ceramic binding capacity induced by alkali activation reaction by the reason of the thermal analysis result not showing the decomposition of calcium hydrate.

Application of Recycled Gypsum on Alkali Soil for Improving Agricultural Productivity in China

  • Akio, Tokuumi;Tsureyasu, Yanagi;Sun, Yi;Gao, Yushan;Zhao, Xiezhe
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.102-105
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    • 2001
  • Gypsum has been known as a prominent material for improving alkali soil, and this material can be supplied easily in large scale by recycling waste gypsum plasterboard from construction and demolition sites in advanced countries. In April 2000, in the part of western Jilin Province in China, where alkali soil spread vastly, we conducted a cultivating experiment of corn and rice after treating with granule recycled waste gypsum at six alkali soil fields which total area were 14000$m^2$. We confirmed that pH of soil decreased in a short period and alkali soil changed soft a desirable condition for farm work, and furthermore, gypsum caused to accelerate the growth of a plant, both corn and rice.

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Physical Properties of Alkali Resistant-Glass Fibers with Refused Coal Ore in Continues Fiber Spinning Conditions

  • Ji-Sun Lee;Jinho Kim
    • Korean Journal of Materials Research
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    • v.34 no.7
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    • pp.355-362
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    • 2024
  • AR (alkali resistant)-glass fibers were developed to provide better alkali resistance, but there is currently no research on AR-glass fiber manufacturing. In this study, we fabricated glass fiber from AR-glass using a continuous spinning process with 40 wt% refused coal ore. To confirm the melting properties of the marble glass, raw material was put into a (platinum) Pt crucible and melted at temperatures up to 1,650 ℃ for 2 h and then annealed. To confirm the transparent clear marble glass, visible transmittance was measured and the fiber spinning condition was investigated by high temperature viscosity measurement. A change in diameter was observed according to winding speed in the range of 100 to 700 rpm. We also checked the change in diameter as a function of fiberizing temperature in the range of 1,240 to 1,340 ℃. As winding speed increased at constant temperature, fiber diameter tended to decrease. However, at fiberizing temperature at constant winding speed, fiber diameter tended to increase. The properties of the prepared spinning fibers were confirmed by optical microscope, tensile strength, modulus and alkali-resistance tests.

Resistance of Alkali Activated Slag Cement Mortar to Sulfuric Acid Attack (알칼리 활성화 슬래그 시멘트 모르타르의 내황산성)

  • Min, Kyung-San;Lee, Seung-Heun
    • Journal of the Korean Ceramic Society
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    • v.44 no.11
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    • pp.633-638
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    • 2007
  • The setting time of alkali activated slag cement tends to be much faster than ordinary Portland cement, and its compressive strength had been higher from the 1 day but became lower than that of the cement on the 28 days. According to the results of the surface observation, weight loss, compressed strength, and erosion depth tests on the sulphuric acid solution. It has been drawn that alkali activated slag cement has a higher sulphate resistance than ordinary Portland cement, and in particular, the alkali activated slag cement added 5 wt% alumina cement has little deterioration on the sulphuric acid solution. The reason why the alkali activated slag cement has higher sulphate resistance than other hardened cement pastes is that it has no $Ca(OH)_2$ reactive to sulphate ion, and there is little $CaSO_4{\cdot}2H_2O$ production causing volume expansion, unlike other pastes. And it is supposed that $Al(OH)_3$ hydrates with high sulphate resistance, which is produced by adding the alumina cement increases the sulfate resistance.

Microstructural Characteristics of Alkali-Activated Cements Incorporating Fly Ash and Slag (플라이애시와 슬래그 혼합 알칼리 활성 시멘트의 미세구조 특성)

  • Jang, Jeong Gook
    • Journal of Urban Science
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    • v.7 no.1
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    • pp.39-43
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    • 2018
  • This study investigates microstructural characteristics of alkali-activated cements incorporating slag and fly ash. Samples were prepared with four fly ash:slag ratios, i.e., 100:0, 90:10, 70:30 and 50:50, and they were synthesized by using an alkali activator. Microstructural characteristics of the alkali-activated cements were determined by XRD, TGA, SEM, N2 gas adsorption/desorption methods, and compressive strength test. The results showed that properties of alkali-activated fly ash/slag were significantly affected by slag contents. Alkali-activated fly ash/slag with slag content of 30-50% showed higher compressive strength than ordinary Portland cement paste. An increase in slag content resulted in a denser microstructure, which composed of amorphous gel, therefore contributed to strength development of the material.

The Possibility of Alkali-Aggregate Reaction of High Strength Concrete by Concrete Bar Test (콘크리트 시험체 시험법을 통한 고강도 콘크리트의 알칼리골재 반응성)

  • 권영진;김무한
    • Proceedings of the Korea Concrete Institute Conference
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    • 1996.04a
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    • pp.137-140
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    • 1996
  • The deterioration of concrete due to alkali-aggregate reaction is dependent on the total alkali content per unit volume of concrete. It was reported that the expansion of high alkali concrete with the reactive aggregate increased easily due to high alkali of concrete with the reactive aggregate increased easily. And it has been confirmed that the addition of pozzolanic material prevents the concrete with reactive aggregate from deterioration caused by alkali-aggregate reaction. It is the aim of this study to provide the fundamental data on the possibility of alkali-aggregate reaction of high strength concrete and its preventing and repair technic.

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Cause of Surface voids in Concrete Attached to an Aluminum Form, and Measures for Prevention

  • Noh, Sang-Kyun;Lee, Seung-Hoon;Han, Cheon-Goo
    • Journal of the Korea Institute of Building Construction
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    • v.13 no.5
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    • pp.457-464
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    • 2013
  • Traditionally, the material used for the form in reinforced concrete construction has been wood or steel. But recently, aluminum forms have been widely used in wall structures such as apartment buildings. Aluminum is light, easy to handle, and economically advantageous, but the hydrogen gas created due to its reaction with the alkali component in concrete gives rise to air pockets on the concrete's surface, and deteriorates the surface's finishability. In this research, to determine the influence of aluminum material on concrete, the cement paste W/C and its chemical reactivity in alkali and acid solution were analyzed. As a prevention plan, the influence of the number of applications of calcium hydroxide and various surface coating materials was analyzed. Through the analysis, it was found that the surface voids on the aluminum form are the result of the reaction of hydrogen gas with an alkali such as $Ca(OH)_2$. This can be prevented by the surface treatment of $Ca(OH)_2$, separating material and coating material. However, poor surface form and damages to the form are expected to cause quality degradation because of the aluminum-concrete interaction. Therefore, thorough surface treatment, rather than the type of separating material or coating material, is considered the most important target of management.

Compressive Strength and Shrinkage Strain of Slag-Based Alkali-Activated Mortar with Gypsum (석고가 첨가된 슬래그 기반 알카리활성 모르터의 압축강도 및 건조수축 변형률)

  • Yang, Keun-Hyeok;Sin, Jae-Il
    • Journal of the Korea Institute of Building Construction
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    • v.8 no.1
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    • pp.57-62
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    • 2008
  • Twelve mortars were mixed and tested to explore the effect of gypsum on the compressive strength development and shrinkage strain of alkali-activated mortars. Powder typed sodium silicate and ground granulated blast-furnace slag were employed as alkaline activator and source material, respectively, to produce cementless mortar. The main variables investigated were alkali quality coefficient combining the concentration of activator and main compositions in source material, and the adding amount of gypsum ranged between 1 and 5% with respect to the weight of binder. Initial flow, compressive strength development, modulus of rupture, and shrinkage strain behavior of mortar specimens were measured. In addition, the hydration production of alkali-activated pastes with gypsum was traced using X-ray diffraction and energy-dispersive X-ray analysis combined with scanning electron microscope image. Test results showed that the initial flow of slag-based alkali-activated mortar was little influenced by the adding amount of gypsum. On the other hand, the effect of gypsum on the compressive strength of mortar specimens was dependent on the alkali quality coefficient, indicating that the compressive strength increased with the increase of the adding amount of gypsum until a certain limit, beyond which the strength decreased slowly. Shrinkage strain of mortar tested was little influenced by the adding amount of gypsum because no ettringite as hydration product was generated. However, the adding of gypsum had a beneficial effect on reducing the microcrack in the alkali-activated mortar.

Strength and Pore Characteristics of Alkali-activated Slag-Red Mud Cement Mortar used Polymer According to Red Mud Content (레드머드 대체율에 따른 폴리머 혼입 알칼리활성화 슬래그-레드머드 시멘트모르타르의 강도 및 기공특성)

  • Kwon, Seung-Jun;Kang, Suk-Pyo
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.20 no.2
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    • pp.26-33
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    • 2016
  • The alkali-slag-red mud(ASRC) cement belongs to clinker free cementitious material, which is made from alkali activator, blast-furnace slag(BFS) and red mud in designed proportion. This study is to investigate strength and pore characteristics of alkali-activated slag cement(NC), clinker free cementitious material, and ordinary portland cement(C) mortars using polymer according to red mud content. The results showed that the hardened alkali-activated slag-red mud cement paste was mostly consisted of C-S-H gel, being very fine in size and extremely irregular in its shape. So the hardened ASRC cement paste has lower total porosity, less portion of larger pore and more portion of smaller pore, as compared with those of hardened portland cement paste, and has higher strength within containing 10 wt.(%) of alkali-activated slag cement(NC) substituted by red mud.