• Title/Summary/Keyword: alkali leakage

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A Study on the Engineering Properties of Micro Fine Hybrid Silicate Based Grout (마이크로 복합실리카 그라우트의 공학적 특성에 관한 연구)

  • 천병식;김진춘;최영철;정종주;신상재;이홍재
    • Proceedings of the Korean Geotechical Society Conference
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    • 2000.11a
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    • pp.63-70
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    • 2000
  • In 1925, H.J. Joosten was the first in the world to use chemical injection grouts composed of sodium silicate and calcium chloride. This unique development prompted the introduction of other chemical grouting techniques. Among these chemical grouting techniques, sodium silicate based grout has been the most widely used in the world, but it has not been generally considered to be a permanent material. Therefore, studies to improve the weak points of sodium silicate based grout have been conducted, and new applications of grout were recently developed. We also developed the micro fine hybrid silicate grout of suspention type which properties are sepecialized as the high strength and durability, according to the reactant of special sodium silicate grout and the high strength hardener. As the results of this study we could derive the 2 times over high strength of Micro fine hybrid Silicate grouting method(MS method) more than that of the ordinary sodium silicate grout. And also we could confirm that the alkali leakage of micro fine hybrid silicate grout is less than that of ordinary sodium silicate grout. So we could get the high strength and durability of hybrid silicate grout are superior to those of ordinary sodium silicate grout.

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Rapid microcement and glycidylacrylate a Case Study on the Improvement of Water Leakage Site Applied to Mixed-use (급결마이크로시멘트 및 글리시딜아크릴레이트를 복합 적용한 누수현장 보수사례)

  • Cho, Il-Kyu;Yuh, Jae Hyung;Oh, Sang-Keun
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2019.11a
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    • pp.241-242
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    • 2019
  • This technology is a water leak repair technology using composite materials of concrete structures that block leakage of structures by injecting rapid microcement into the face of underground concrete to block water and injecting flexible glycidylacrylate. Rapid micro cement system repair materials are mixed with fine fibers to improve the flexural sensitivity of the material and to form a layer that blocks stabilized water at the back of the structure by allowing rapid and tight spatial filling during injection with high cohesion The glycidylacrylate repair material can control the expansion rate, and the external stress also has the characteristic that the form of the material is not destroyed or separated, which can also be applied to vibrating induced structures that produce repetitive fatigue loads, and has an effective durability in saline, alkali, acid (chloric acid, sulfuric acid, nitric acid).

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A Study on the Engineering Properties of Micro Fine Hybrid Silicate Grout Materials (마이크로 복합실리카 그라우트재의 공학적 특성에 관한 연구)

  • Chun, Byung-Sik;Kim, Jin-Chun;Choi, Young-Chul;Jung, Jong-Ju;Yoon, Nam-Sik;Shin, Sang-Jae
    • Journal of the Korean GEO-environmental Society
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    • v.2 no.1
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    • pp.67-79
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    • 2001
  • The objective of this study is to determine the engineering properties of micro fine hybrid silicate grout materials that were developed recently. In this study, MSG-N type was mainly used as grout materials, and the chemical components, grain size distribution, mineral characteristics were analyzed. Moreover, the properties of active silica and ordinary portland cement acting as coagulating agent were analyzed and compared with each other. To determine the engineering properties, the bleeding test, viscosity test, coagulation test, examination with naked eye, photographing by using SEM, uniaxial compression test and in-situ application test for reclaimed ground were carried out. A series of test results showed that the strength of micro fine hybrid silicate grout materials was about twice that of ordinary sodium silicate grout materials, and alkali leakage decreased dramatically when MSG method was utilized. Especially, based on the evaluation of the application of the MSG method to field, this method would be very effective in reducing coefficient of permeability due to its excelent permeability.

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Clinical Experience of Stenotic Anastoma of Neck after Reconstuctive Surgery for Corrosive Esophageal Stricture (재수술을 요한 식도재건술 환자의 원인분석과 임상적 고찰)

  • 안욱수
    • Journal of Chest Surgery
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    • v.25 no.2
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    • pp.183-187
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    • 1992
  • Reconstructive surgery for corrosive esophageal stricture was performed in 392 patients at National Medical Center from 1959 to 1990 Between Jan. 1971 and Dec. 1990, 23 cases were experienced stenotic anastoma of neck after reconstructive surgery for corrosive esophageal stricture. The major procedure of esophageal reconstruction was colon interposition without resection of the strictured esophagus except jejunal interposition in 1 case. There were 12 males % 11 females, and mean age was forty years. The caustic materials were 16[70%] alkali and 7[30%] acid. Half of the cases had hypopharyngeal injury. After reconstructed surgery, dysphagia was developed immediate in 65%, from 2 months to 5 months in 31%, and from years in 4%[1 case]. The complications were anastomatic leakage in 13 cases, anastomatic stenosis in 8 cases, graft gangrene in 1 case, and cancer development in 1 case. The therapeutic procedures were end-to-end anstomolis & partial resection of stenotic anastoma in 18 cases, bourgination in 2 cases, and coin interposition with graft removal in 3 cases. The therapeutic results were excellent in 16 cases, mild discomfort in 3 cases, poor in 3 cases, and death in 1 cases.

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The Effects of the Heavy Metal Ions on the Hydration and Microstructure of the Cement Paste (중금속이온이 시멘트의 수화 및 미세구조에 미치는 영향)

  • 김창은;이승규
    • Journal of the Korean Ceramic Society
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    • v.30 no.11
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    • pp.967-973
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    • 1993
  • The effect on the hydration of cement was that Cu and Pb reacted with alkali to form soluble hydrates at theinitial stage and then there followed a slow reaction forming insoluble metal hydroxides. These hydroxides were deposited on the surface of cement particles providing a barrier against further hydration. But as a slow reaction continued, the insoluble layers were eventually destroyed and the hydration reaction resumed. Thereafter, another retardation occured by restricting the polymerization of silicates, shown by FT-IR spectroscopy analysis. In the case of Cr, as its reaction with cement caused H2O, the coordinator of Cr complex, to replace or polymerize with OH-, the formation of Cr complex promoted the leakage of OH- and increased the heat of dissolution. So the total heat evolution during hydration was larger than that in the case of Pb or Cu. The retarding effect of heavy metal ions was in the order Pb>Cu>Cr.

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Surgical Management of Benign Esophageal Stricture (양성 식도 협착증의 외과적 치료)

  • 김준석
    • Journal of Chest Surgery
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    • v.28 no.11
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    • pp.1032-1037
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    • 1995
  • Between September 1988 and December 1993, 32 cases of benign esophageal stricture, of which 12 males and 20 females, were managed in Seoul National University Hospital hospital. Their age ranged from 2 to 61 years, and the mean age was 33.9 years. The ingestion of caustic agent was the most common cause, and the caustic material was acid in 16 patients [58% and alkali in 11patients [39% . Nearly all of the patients complained of dysphagia, and some of chest pain, epigastric pain, weight loss, vomiting, general malaise, and dyspnea. The most frequent site of stricture was found in the upper thoracic esophagus with 34% incidence followed by the lower thoracic esophagus[28% , whole esophagus[19% , and the mid esophagus[16% . The operations performed were 17[53% ECG[esophagocologastrostomy , 5[16% PCG[pharyngocologastrostomy , 5[16% EG[esophagogastrostomy , 2 EJG [esophagojejunogastrostormy by free jejunal graft , and 1 case each of EJ [esophagojejunostomy , esophageal end to end anastomosis, jejunostomy only, and gastrostomy only. In 23 patients [72% , diseased esophaguses were resected, using transhiatal total esophagectomy in 15 [47% and transthoracic partial esophagectomy in 8 [25% . Of those 23 patients, 3 patients [9.4% were diagnosed as esophageal carsinoma on microscopic examination. The postoperative most common complications were unilateral vocal cord palsy in 6 patients [19% , followed by cervical anastomosis leakage in 4 patients [12.5% , wound infection in 2 patients [6% , and pneumothorax in 2 patients [6% . Late death occurred 8 months after the operation in one patient, which was associated with infection due to anastomotic leakage. Our experience shows that the rate of mortality and the morbidity were low in patients receiving surgical management for esophageal stricture and that the cancer transformation rate was high. We recommend esophageal reconstruction surgery with esophagectomy [transhiatal or transthoracic for the esophageal stricture because it can avoid a chance of prevent cancer transformation.

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Study on Reliability of Vapor Cell by Laser Packaging with Au/Au-Sn Heterojunction (Au/Au-Sn 이종접합 적용 레이저 패키징을 통한 Vapor Cell 신뢰성 연구)

  • Kwon, Jin Gu;Jeon, Yong Min;Kim, Ji Young;Lee, Eun Byeol;Lee, Seong Eui
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.33 no.5
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    • pp.367-372
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    • 2020
  • As packaging processes for atomic gyroscope vapor cells, the glass tube tip-off process, anodic bonding, and paste sealing have been widely studied. However, there are stability issues in the alkali metal which are caused by impurity elements and leakage during high-temperature processes. In this study, we investigated the applicability of a vapor cell low-temperature packaging process by depositing Au on a Pyrex cell in addition to forming an Au-Sn thin film on a cap to cover the cell, followed by laser irradiation of the Au/Au-Sn interface. The mechanism of the thin film bonding was evaluated by XRD, while the packaging reliability of an Ne gas-filled vapor cell was characterized by variation of plasma discharge behavior with time. Furthermore, we confirmed that the Rb alkaline metal inside the vapor cell showed no color change, indicating no oxidation occurred during the process.

Genetic Consideration of Sericite Deposits Derived from Granitic Rocks in the Taebaegsan Region (태백산지역에 분포하는 화강암체 기원 견운모광상의 성인적 고찰)

  • Yoo, Jang-Han;Chi, Sei-Jeong
    • Journal of the Mineralogical Society of Korea
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    • v.21 no.3
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    • pp.239-246
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    • 2008
  • Yeongweol sericite deposit of Gangwon Province is regarded as one of the sericite deposits derived from granitic rocks due to post-magmatic alkali metasomatism, and the other sericite deposit of the same origin is the Daehyun mine of Gyungbug Province. Sericite ores were originated from leucocratic granitic stocks of Cambrian-Triassic age which intruded the pegmatitic migmatite of the unknown age and granite of the Pre-cambrian age, respectivcly. Jangsan quartzite of the lowermost formations of the Paleozoic era, which played as the capping rock protected from the leakage of the hydrothermal solution. It is well known that those sericite deposits arc formed during formation of the geosyncline, and they are also situated in the margins of the Hambaeg Syncline. Leucocratic granites commonly contain pegmatites with tourmaline crystals, and are rich in potassium feldspars, and sodium plagioclase as well. Sericitized ores are mainly found as we go up to the higher elevations or to the margins of the stocks. And some of the Highest grade sericite ores show the monominerallic character composed of nearly pure sericite probably doc to the ultra greisenization. Chemical analysis shows higher $Na_{2}O$ and $K_{2}O$ contents $(2.00\sim7.03wt%)$ as the sericitizations arc preceded and they represent obvious greisenization. But low CaO contents $(0.05\sim4.51wt%)$ indicate that albitizations are so weak. Pyrophyllite of the Youngweol area is often accompanied by the sericite, indicating rather stronger thermal effect than the Daehyun mine. It is known that there are several Sn deposits originated from greisenization in the Taebaegsan region. And greisens are inclined to contain W, Mo and several REE's such as Be, Nb and Li, and so Taebaegsan region interbedded with lots of carbonate formations are still worthwhile to survey for those metallic deposits.

Electrical Properties of YMnO3 Thin Film by Sol-gel Process (졸-겔 공정에 의한 YMnO3 박막의 전기적 특성)

  • Kim, Eung-Soo;Kim, Beng-Gu;Kim, Yoo-Taek
    • Journal of the Korean Ceramic Society
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    • v.39 no.5
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    • pp.511-516
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    • 2002
  • Hexagonal $YMnO_3$ thin films were prepared from $Y(NO_3)_3{\cdot}5H_2O$ and $Mn(CH_3CO_2)_2{\cdot}4H_2O$ as starting materials on the Si(100) substrates by the sol-gel method. The crystal structure and the electrical properties of the $YMnO_3$ thin films were investigated as a function of heat treatment temperature, the amount of water(Rw) of hydrolysis and the addition of catalysis. The crystallization of the $YMnO_3$ thin film began at 700${\circ}C$ and completed at 800${\circ}C$ for 1 h. The c-axis (0001) preferred orientation of hexagonal $YMnO_3$ was detected for the $YMnO_3$ thin films with Rw=6 and that was decreased for the $YMnO_3$ thin films with Rw=1 and Rw=12. The crystallinity and preferred orientation of the $YMnO_3$ thin films were depended on the addition of acid and/or alkali catalysis, which, in turn, the preferred orientation of c-axis was decreased and the orthorhombic phase of $YMnO_3$ was detected to the specimens with the addition of catalysis. The $YMnO_3$ thin film with Rw=6 showed good leakage current density of $1.2{\times}10-8 A/cm^2$ at the applied voltage of 0.2V and the leakage current density was not changed drastically with applied voltage.

Nerve Injury from Overfilled Calcium Hydroxide Root Canal Filling Paste for Maxillary Lateral Incisor Endodontic Treatment (상악 측절치 근관치료 중 수산화칼슘 호제근충제 과충전으로 인하여 발생한 신경손상의 치험례)

  • Na, Kwang Myung;Kim, Jong-Bae;Chin, Byung-Rho;Kim, Jin-Wook;Kim, Chin-Soo;Kwon, Tae-Geon
    • Maxillofacial Plastic and Reconstructive Surgery
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    • v.35 no.4
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    • pp.260-264
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    • 2013
  • Calcium hydroxide root canal filing paste (vitapex) is widely used as canal filling paste for infected canal. However, chemical burn is possible because of the high alkali base of calcium hydroxide. A 57-year old woman was admitted to our clinic for consistent dull pain and paresthesia in the left upper lip, zygoma and buccal cheek area, which developed during an endodontic treatment of the left lateral incisor. Radiographic finding showed radiopaque material, which exits from the left incisor root apex, and was within the left canine and first premolar buccal soft tissue. The overfilled Vitapex extended to the soft tissue was surgically curetted. The result of the surgical curettage was favorable. Though slight hypoesthesia on the upper lip was still remained, paresthesia on zygomatic and buccal cheek area was completely recovered. As far as we know, this is the first case report of infraorbital nerve damage from overfilled Vitapex material.