• 자원환경지질
• /
• 제11권2호
• /
• pp.47-57
• /
• 1978

The study focused on the petrology and petrochemistry of the so called "Ganghwa syenitic rocks" which intruded into metasediment of basement in southeastern part of Ganghwa Island. The geologic sequence of the mapped area was shown in table 1, 10 model analyses and 7 chemical analyses on the rock samples taken from the Ganghwa syenitic rocks and Manisan granite have been used to discuss the nomenclature of the rocks and petrological relationship between rock types. The petrograpical and petrochemical features based on, the analyses are as follows: 1) Ganghwa syenitic rocks consist of Ganghwa alkali syenite and Ganghwa diorite porphyry which based on the classification of the subcommision on systematics of igneous of IGUS. Ganghwa diorite porphyry which occured as dike forms are intruded into Ganghwa alkali syenite. The rock forming minerals of Ganghwa alkali syenite are composed of perthite, plagioclase, quartz, hornblend and chlorite in major, and zircon, apatite, sericite and magnetite in minor. Ganghwa diorite porphyries consist of plagioclase, biotite, hornblend, orthoclase and chlorite, with, porphyritic texture. 2) In silica-oxides variation (Fig. 2) and AMF diagram (Fig_ 3), the Ganghwa alkali syenite is similar to the trend of Daly's average basalt-andesite-dacite-rhyolite than Skaergaard which shows the trend of the fractional crystallization of magma, and equivalent to the alkali rock series by Peacock. 3) The general trend of data points shift to plagioclase, and are superimposed on the alkali rich terminal part of the granodiorite province of SW Finland in normative Q-Kf-Pl(Fig. 4) and Or-Ab-An diagram respectively. The above-mentioned evidences suggested that the Ganghwa syenitic rocks are the differential products resulted by assimilation of intermediated magma and metasedment rock under relatively rapid cooling condition.

• 자원환경지질
• /
• 제23권3호
• /
• pp.329-342
• /
• 1990

The purpose of this study is to clarify the nature of the differentiation and petrogenesis of igneous rocks in comparison with experimental results based on petrological and geochemical criteria. Study area is composed of the Precambrian granitic gneiss complex, Triassic meladiorite and biotite granodiorite, Jurassic biotite granite, and Cretaceous quartz porphyry. According to the data of EPMA, the clinopyroxene and orthopyroxene of meladiorite come under salite and hypersthene, respectively. Such results suggests that meladiorite is incipient differentiated products of basic magma under slow cooling condition. The petrochemical data of variation diagram of major element oxides vs. silica and of trace element oxide vs. silica, AMF triangle diagram and trace elements suggests that igneous rocks of study area are plutonic rocks belong to calc alkali rock series of the source of comagma intruded-emplaced in the order of meladiorite, biotite granodiorite and biotite granite by fractional crystallization of magma.

• 자원환경지질
• /
• 제33권2호
• /
• pp.139-146
• /
• 2000

Development of an effective liner by utilization of the tailings frm the Imcheon mine and polymer has been tried. The tailings piled in the Imcheon mine, whose true specific gravity is about 2.86, are composed mainly of quartz, alkali-feldspar, muscovite and pyrite, and mostly (93.7% in volume) coarser than sand grain size (50${\mu}{\textrm}{m}$). Strength, leaching and permeability tests have been performed on the test specimens of polymer concrete manufactured with various mixing proportions of tailings, unsaturated polyester resins(UPR), calcium carbonates, stone powder sludges and granite soils. Polymer concrete specimens with stone powder sludges or granite soils as fillers and aggregates indicate 2.5 to 3 fold higher flexural and compressive strengths and lower permeabilities than those with calcium carbonates, which shows their usability as a waterproof liner. Also, the polymer concrete liner with stone powder sludge fillers is more advisable in aspects of utilization of waste sludges than that with other fillers.

• 보존과학회지
• /
• 제18권
• /
• pp.63-74
• /
• 2006

경주서악리 삼층석탑의 모든 부재는 정동이 잘 발달된 중립질의 회백색 알카리 화강암으로 구성되어 있다. 이 석탑은 이미 보수되어 전체적으로 안정감을 주며 상륜부를 제외하면 거의 원형을 보존하고 있다. 그러나 석탑에 직접적인 영향을 가하는 주변의 수목과 지반에 서식하는 잔디의 영향으로 지대석과 기단부 및 옥개석의 상부에는 지의류를 비롯한 미생물의 서식이 심각한 상태이다. 따라서 보존처리는 일차 건식세정을 실시하였고 이차로 습식세정을 실시하였다. 이때 잘 제거되지 않는 지의류 및 오염물 등은 고온스팀을 이용하여 제거하였다. 또한 이미 보수에 사용되었던 콘크리트와 에폭시 수지를 제거를 하고 에폭시계 합성수지에 탈크와 알카리 화강암 파우더 등의 충전제를 혼합하여 복원하였다. 부재들의 질감을 맞추기 위해 합성수지와 충전제의 혼합과정에서 색 맞춤을 하였다. 또한 석탑의 동쪽에 있는 사면으로부터 흘러내리는 빗물의 유입을 최소화하기 위해 배수로를 설치하였으며, 석탑주변에 서식하고 있는 수목 및 잔디를 제거하여 습기 발생을 최소화함으로서 향후지의류의 발생을 억제시키고자 하였다.

• 암석학회지
• /
• 제8권2호
• /
• pp.81-91
• /
• 1999

옥천화강암은 옥천읍 일대에서 원형상으로 분포하며, 그 북부와 동부 및 남부에서 옥천층군을 관입한 쥬라기 암체이며 그 서부에서 백악기의 석영반암류에 의해 관입된다. 이 암체는 중립질의 흑운모 화강으로서 유색광물부(mafic enclave)가 종종 발달하며 북부 주변에서는 미약한 엽리구조를 이루기도 한다. 구성광물은 석영, 사장석, 알칼리장석, 흑운모, 스펜과 녹리석 등이다. 복부일부에 발달하는 미립질과 줄무늬 석영, 흑운모와 이차광물인 백운모 등이 이루는 엽리는 옥천화강암질 마그마의 유동중에 주변암에 의해 형성된 구조이다. QAP 모드분석에서 몬조화강암-화강섬록암에 도시되는 과알루미나암질로서 캘크 알칼리례열에 속하는 분화경향을 가진다. SiO2 대 주원소 그리고 미향원소 등의 관계도에서 단일 마그마의 분화경향을 뚜렷이 가진다. 콘드라이트로 표준화한 희토류원소는 경(LREE)에서 중(HREE)으로 갈수록 점진적으로 결핍되며 Eu/Eu*는 0.84의 부 이상값(negative anomaly)을 가져 대체로 국내 쥬라기 화강암류와 유사한 특성을 가진다. 동시충돌대의 지구조적환경에서 I-형의 지각물질이 용융하여 형성된 화강암질 마그마가 다소 빠르게 상승하여 옥천층군내에 정치된 암체이다.

• Advances in concrete construction
• /
• 제9권6호
• /
• pp.537-545
• /
• 2020

In order to reduce the usage of cement slurry in grouting engineering and consume the tunnel excavation waste soil, a new geopolymeric grouting material (GGM) was prepared by combine completely weathered granite (CWG) and blast-furnace slag (BFS), which can be applied to in-situ grouting treatment of completely weathered granite strata. The results showed CWG could participate in the geopolymerization process, and GGM slurry has the characteristics of short setting time, high flowability, low viscosity, high stone rate and high mechanical strength, and a design method of grouting pressure based on viscosity evolution was proposed. By adjusted the content of completely weathered granite and alkali activator concentration, the setting time of GGM were ranged from 5 to 30 minutes, the flowability was more than 23.5 cm, the stone rate was higher than 90%, the compressive strength of 28 days were 7.8-16.9 MPa, the porosity were below 30%. This provides a novel grouting treatment and utilizing excavated soil of tunnels in the similar strata.

• 한국광물학회지
• /
• 제7권1호
• /
• pp.40-48
• /
• 1994

남산 화강암의 풍화를 물과 광물작용의 흡착작용의 관점에서 연구하였다. 순수한 증류수만으로도 광물-물의 흡착반응이 일어나며, 그 반응속도는 암석/물의 비율에 따라 수초-수 시간이내로 매우 빠르다. 광물과 물이 반응할 때 가장 영향을 미치는 것은 광물의 표면의 결합상태와 물의 수산이온농도이며, 암석/물의 비율은 용액의 수산이온농도를 좌우한다. 광물 입자의 크기는 반응속도에 큰 영향을 미치지만 암석/물의 비율이 약 7g/200 ml 이상이 되면 큰 변화를 보이지 않는다. 풍화를 받지 않은 화강암은 양의 pH edge (최대 pH 10)를 보이며 pH 7.1~7.5으로 하강하는 양상을 보인다. 그러나, 풍화를 받아서 점토 광물이 섞이 화강암은 음의 pH edge (최소 pH 4.8)를 보이며 pH 6을 넘지 않는다. 흡착반응 동안에 겔이 수면 위에 생성된 후 이것은 후에 깁사이트로 변하고, 암석/물의 비율이 높을수록 그리고 pH 변화가 클수록 많이, 그리고 빨리 형성된다.

• 암석학회지
• /
• 제4권2호
• /
• pp.91-103
• /
• 1995

연구지역은 서울에서 포천 북부일대에 분포하며 경기 편마암 복합체를 관입한 대보 화강암질 저반의 중부에 해당한다. 주요 구성암상은 조립질 흑운모 화강암과 세립질 흑운모 화강암이다. 전자는 대체로 주변부와 중앙부를 이룬 회색 화강암(Gg)과 담홍색 화강암(Gp)로 각각 구분되며, 세립질 화강암은 소규모의 암주상으로 Gg를 관입하였다. Gg는 회색을 띠는 각섬석 흑운모 화강암으로서 염기성 분결체(basic clot)와 변성암류의 포획체가 자주 발달하며, Gp는 연한 담홍색을 띠는 석류석 흑운모 화강암으로 산점상의 석류석과 간혹 염기성 분결체를 수반함이 일반적인 특징이다. 이들은 모우드 분석에서 화강암에 도시되며 티탄철석 계열이나 자철석 계열에 해당한다. 흑운모 연령측정(K/Ar법)결과 Gg와Gp는 166와 165Ma, 세립질 화강암은 133Ma로 각각 쥬라기 중기와 백악기 초기에 해당한다. 이들은 뚜렷한 분화경향을 보이는 일부 저(met-)와 과일루미나암질(peraluminous)로서, 칼크-알칼리 계열에 속한다. 광물학적 및 지구화학적 특징에 의하면 이들은 S-형(티틴철석 계열)과 일부 Ⅰ-형(자철석 계열)에 속하며, 섭입과 관련된 대륙 주변 부의 마그마 홍 lwlrn조저 환경에서 비교적 고정된 근원성분의 용융으로 형성된 암체이다.

• 자원환경지질
• /
• 제32권5호
• /
• pp.469-483
• /
• 1999

Two different types of deep groundwaters occur together in the Jungwon area: $CO_2$-rich water and alkali water. Each water shows distrinct hydrogeochemical and environmental isotopic characteristics. The $CO_2$-rich waters are characterized by lower pH(6.0~6.4), higher Eh (25~85mV) and higher TDS content (up to 3,300 mg/l), whereas the alkali type waters have higher pH (9.1~9.5), lower Eh (-136~-128mV) and lower TDS content (168~254 mg/l). The CO2-rich waters ($Pco_2$=up to 1atm) were probably evolved by the local supply of deep $CO_2$ during the deep circulation, resulting in enhanced dissolution of surrounding rocks to yield high concentrations of $Ca^{2+}, Na^+, Mg^{2+}, K^+\; and \;HCO_3\;^-$ under low pH conditions. On the other hand, the alkali type waters ($Pco_2$=about 10-4.6 atm) were evolved through lesser degrees of simple wate/rock (granite) interaction under the limited suppy of $CO_2$. The alkali waters are relatively enriched in F- (up to 14mg/l), whereas the F- concentration of$CO_2$-rich water is lower (2.2~4.8 mg/l) due to the buffering by precipitation of fluorite. The oxygen-hydrogen isotopes and tritium data indicate that compared to shaltion ($\delta$18O=-9.5~-7.8$\textperthousand$),two different types fo deep groudwaters (<1.0TU)were both derived from pre-thermonuclear (more than 40 years old) meteoric waters with lighter O-H isotopic composition ($\delta$18O=-9.5~-7.8$\textperthousand$) and have evolved through prolonged water/rock interaction. The $CO_2$-rich waters also show some degrees of isotopic re-equilibration with $CO_2$ gas. The $\delta^{34}S$ values of dissolved sulfates (+24.2~+27.6$\textperthousand$) in the $CO_2$-rich waters suggest the reduction of sulfate by organic activity at depths. The carbon isotope data show that dissolved carbon in the $CO_2$-rich waters were possibly derived either from dissolution of calcite or from deep $CO_2$ gas. However, strontium isotope data indicate Ca in the $CO_2$-rich waters were derived mainly from plagioclase in granite, not from hydrothermal calcites.

• 한국광물학회지
• /
• 제4권2호
• /
• pp.69-89
• /
• 1991

The anorthositic rocks and the many other plutons which are of different varieties and age were distributed in the northern extremity of the distributed areas of H-S anorthositic rocks. The purpose of this study was to find plutons which had comagmatic relationships, and to make clear the magmatic process of anorthositic magma. The plutons were classified, and the petrological and the geochemical characteristics of the plutons were compared and researched in this study. And, because, like anorthosite, the rocks which intrude in the deep crust accompany assimilation, an AFC model calculation was performed to make the differentiation process of the anorthositic rocks clear. The plutons in this area were classified into three groups, and the three groups were composed of the Precambrian anorthositic rocks and related rocks, the Jurassic gabbro, and the plutons of undnown age. The anorthositic magma was differentiated from the anorthositic rocks through the tonalite to the alkali-feldspar granite, and it was differentiated under K, Mg, Fe free/lack condition. It was found from the result of AFC model that the anorthositic rocks were differentiated by fractional crystallization, but they were assimilated with wall-rocks, and the assimilation was performed at the rate of r$\leq$0.1. The plutons which intruded the anorthositic rocks subsequently consisted of the gabbro, the megacrystic granite, the fine-grained granite, and the gneissose granite. But they were formed by the repeated intrusion of magma, which may, or may not, be of the same origin. According to the result of the RCF model, these plutons were differentiated by simple fractional crystallization, and they were assimilated relatively less than the anorthositic rocks.