• Title/Summary/Keyword: alkali contents

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A Study on the Reduction of Harmful Compound in Cigarette Smoke [Part II] -Influence of solvont extraction- (담배 연기중(煙氣中)의 유해물감소(有害物減少)에 관한 연구(硏究)[제이보(第二報)] -용매추출(溶妹抽出)의 영향(影響)-)

  • Park, Taek-Kyu;Kim, Ki-Hwan
    • Applied Biological Chemistry
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    • v.22 no.1
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    • pp.58-63
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    • 1979
  • The solvent extracting of the tobacco has been carried out in order to find out any effects for the removal and/or reduction of nicotine from tobacco without affecting the tobacco flavor. We have now completed the physico-chemical characterization of the solvent untreated/treated tobaccos and 2) the contents of the tar and nicotine in the smoke. The results obtained ate like followings; 1. 3% alcohol extraction reduced the total nitrogen content for the Bright by 36.4%. However, it could not reduce the sugar content. 2. Nicotine content in tobacco leaves was inversely proportional to the dipping time Essentially same results were obtained in anacidic solution and even in a solution containing both alkali and acid. 3. Derivative thermogravimetric(DTG) curves indicated test extraction was effective by removing tobacco leaf components which could decompose or volatilize between the temperature of $150^{\circ}C\;and\;350^{\circ}C$. 4. 3% alcohol extracted leaf have the substantial improvements as following; (1) bulk filling power of 10% and 24% for Burley and Bright tobacco, respectively, (2) combustibility shortening of about 3 minute and 2 minute for Burley and Bright tobaccos, respectively, (3) reduction ratio(%) of nicotine was found to be shout 61.5% and 54.5% for Burley and Bright tobacco, respectively, (4) reduction ratio (%) of tar was obtained to he about 25% and 15% for Burley and Bright tobacco, respectively.

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Modeling Study on Deterioration of Stone Monuments in the Gyeongju Namsan Mountain by Acid Rain (산성비에 의한 경주남산지역 석조문화재의 손상 임상연구)

  • Do, Jin-Young;Choi, Gi-Joo;Cho, Hyen-Goo
    • Journal of the Mineralogical Society of Korea
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    • v.22 no.1
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    • pp.35-47
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    • 2009
  • The deteriorations of stone monuments located in Gyeongju area are predicted in a modeling study. Artificial rain and accelerated weathering test are here applied to the Gyeongju Namsan granite and cement mortar. They are reacted with pH 4.0, pH 8.0 and pH 5.6 rain, respectively. The two former values are the limited acidity values in the Gyeongju (the acidity of rain of the Gyeongju were pH $4.93{\sim}6.39$ in 2005) and the latter is the limited acidity of acid rain. The rains of pH 5.6 and pH 8.0 reach close to a value of pH 7.0 after the reaction with the Gyeongju Namsan granite. After application of the artificial rain and weathering test, the weight of specimens were reduced and the contents of soluble ions in the specimens were increased. These results are attributable to solution of minerals in the specimens. At first, the microlithic have dissolved in ground from the reaction with acid rain. And then mainly quartz, plagioclase and orthoclase bound by the microlithic are disintegrated. The cement mortars are dissolved after the reaction with not only acid but alkali rain. The concentrations of ions in the dissolved cement mortar are higher than those in granite.

Petrology of the Cretaceous Volcanic Rocks in Eastern Part of the Kyeongsan Caldera (경산칼데라 동부지역에 분포하는 백악기 화산암류의 암석학적 특징)

  • Park Sung-Ok;Jang Yun-Deuk;Hwang Sang-Koo;Kim Jeong-Jin
    • The Journal of the Petrological Society of Korea
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    • v.15 no.2 s.44
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    • pp.90-105
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    • 2006
  • The Cretaceous volcanic rocks in the study area represented by andesitic rocks occupy eastern part of the Kyeongsan Caldera. The volcanic rocks comprise andesite I, andesitic tuff, andesite II, and andesitic tuff breccia in their stratigraphic succession, and andesitic porphyry. Andesite I is distinguished from andesite II in their color, texture, phenocryst mineralogy and petrochemisty. In outcrops, andesite I is compact and dark-green, and andesite II is brick red in color and porphyritic in texture. In their phenocryst mineralogy, andesite I contains olivine phenocryst in addition to plagioclase and pyroxene which occur in both of andesites. Compared to andesite II, andesite I is higher in $SiO_2$ and $K_2O$ contents and lower in CaO, MgO, MnO, $TiO_2,\;Fe_2O_3$, and $P_2O_5$. Major elements petrochemistry shows that magma series of the volcanic rocks spread widely from calc-alkaline to alkaline series. On the other hand, immobile trace elements petrochemistry shows that the magma series is calc-alkaline without exception, suggesting that the volcanics has experienced more or less alkali enrichment after their eruption. Trace element diagrams for discrimination of tectonic setting show that the volcanics of the study area might be originated from calc-alkaline continental volcanic arc.

Toughness of Polyurethane-Modified Unsaturated Polyester Resin (폴리우레탄으로 개질한 불포화 폴리에스테르 수지의 강인성)

  • Hwang, Yeong-Geun;Min, Kyung-Eun;Choi, Gwan-Young;Kim, Woo-Sik;Lee, Dong-Ho;Park, Lee-Soon;Seo, Kwan-Ho;Kang, Inn-Kyu;Jun, Il-Ryun
    • Polymer(Korea)
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    • v.25 no.1
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    • pp.71-77
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    • 2001
  • Unsaturated polyester(UP) resin is one of the major thermosetting resins. It is very useful as the matrix resin of the composite material because of its low viscosity. The polymer resin, however, has several drawbacks; The volume shrinkage occurs during the crosslinking reaction of the UP resin with styrene monomer and the resulting polymer is weak to the alkali and also brittle. The mechanical properties of UP resin can be improved by blending various materials. In this study, polyurethane(PU) was used as a modifier in order to enhance the toughness of the UP resin. The goal of the research is to study the effect of the polyol molecular weight as a PU soft segment and the PU contents on the toughness of PU-modified UP resins. UP/PU polymer network may occur through the reaction between isocyanate group in the methyldiisocyanate(MDI) and hydroxyl group in the UP molecules. The maximum toughness value was shown at 2 wt% of the PU content. This effect results from the incorporation of the PU segment into the UP resin.

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Introduction of Several Albitite-greisen Type Deposits of Korea (한국 알비타이트-그라이젠형 광상의 소개)

  • Yoo, Jang Han;Koh, Sang Mo;Moon, Dong Hyeok
    • Journal of the Mineralogical Society of Korea
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    • v.25 no.4
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    • pp.221-231
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    • 2012
  • Uljin cassiterite deposit had been known to be a pegmatitic origin derived from the Wangpiri (Buncheon) granitic gneiss of Precambrian period. Lithium ore also shows the same origin and its lithium bearing mineral was ascertained to be a taeniolite. But the presence of leucocratic granites which played the role of host rocks haven't been clearly designated yet in these provinces. Even though Bonghwa and Youngweol sericite deposits situated in the vicinities of Hambaeg syncline had been known to have their host rocks as Hongjesa Granites of Precambrian period and Pegmatitic migmatite of unknown age respectively. But younger leucocratic granites are characterized by more amounts of albite and sericite (muscovite-3T type) than those of the older granitic rocks which contain plenty of biotite and chlorites. Although the younger granites show rather higher contents of alkalies such as $Na_2O$ (0.13~8.03 wt%) and $K_2O$ (1.71~6.38 wt%), but CaO (0.05~1.21 wt%) is very deficient due to the albitization and greisenization. Manisan granite, which is assumed to be Daebo granite which intruded the Gyunggi Gneiss Complex was again intruded by leucocratic granite whose microclinized part changed into kaolins. Taebaegsan region shows a wide distribution of carbonate rocks which are especially favorable to the ore depositions. And the presence of alkali granites which formed in the later magmatic evolution are well known to be worthwhile to the prospections of various rare metals and REEs resources.

The Physicochemical Characteristics of Marinated Beef Galbi under Different Cooking Conditions (양념 소갈비의 조리과정에서의 물리화학적 특성 평가)

  • Hong, Sang-Pil;Kim, Young-Ho;Lee, Nam-Hyouck;Heo, Yeong-Uk
    • Journal of the Korean Society of Food Culture
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    • v.28 no.1
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    • pp.78-88
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    • 2013
  • Marinated beef galbi is a traditional Korean dish cooked with soy sauce, pear juice, onion, sesame oil, and sugar. However, there are many differences in beef galbi, including flavor and physicochemical aspects, depending on cooking conditions. Therefore, the physicochemical characteristics of marinated beef galbi prepared through various recipes was evaluated for its effects on pH, texture, aging, proteolysis, heating conditions, cooking time, and flavor compounds (pyrazines, IMPs, or FAAs). There were significant differences in salt concentration (0.8~3.03%), pH (4.89~6.22), and solid soluble contents (1.34-6.31 Brix) between recipes in this study. In the Pearson assay for sensory evaluation, overall preference correlated well with texture (a well-known sensory attribute in meat evaluation). Controlling the pH of meat through soaking in lemon solution, alkali water, phosphate, and baking powder solution, improved water holding capacity as much as 9 to 15% compared with the control. The myofibril index (MFI) of marinated meat stored at $4^{\circ}C$ increased 32% with 24 hours of aging and reached 39% at 48 hours of aging, and its fragmentation was observed through microscopy. SDS-PAGE showed hydrolysis of acid-soluble collagen by the pear juice, possibly related to meat tenderness. On the basis of surface temperature, the cooking time was estimated to be 8 minutes with pan heating at $170^{\circ}C$, 6 minutes at $270{\sim}300^{\circ}C$, and 4 minutes with charcoal at $700{\sim}900^{\circ}C$. Different pyrazine compounds, such as 2-methyl-3-phenylpyrrol(2,3-b) pyrazine (the typical product of the browning reaction) was mainly detected, and IMP (one of the main taste compounds in beef) was in higher amounts with the charcoal treatment, potentially related to its flavor preference among treatments. Our results demonstrate an effective case study and cooking system for beef galbi.

Petrology of the Volcanic Rocks in the Paekrogdam Crater area, Mt. Halla, Jeju Island (제주도 한라산 백록담 분화구 일대 화산암류의 암석학적 연구)

  • 고정선;윤성효;강순석
    • The Journal of the Petrological Society of Korea
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    • v.12 no.1
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    • pp.1-15
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    • 2003
  • The Paekrogdam summit crater area, Mt. Halla, Jeju Island, Korea, composed of Paekrogdam trachyte, Paekrogdam trachybasalt, and Manseidongsan conglomerate in ascending order. Joint systems show concentric and radial patterns around the summit crate wall. The Paekrogdam crater is a summit crater lake which erupted the tuffs, scorias and lava flows of Paekrogdam trachybasalt after the emplaceent of Paekrogdam trachyte dome. SiO$_2$ contents of mafic and felsic lavas are respectively, 48.0∼53.7 wt.% and 60.7∼67.4 wt.%, reflecting bimodal volcanism. And lavas with SiO$_2$ between 53.7 wt.% and 60.7 wt.% are not found. According to TAS diagram and K$_2$O-Na$_2$O diagram, the volcanic rocks belong to the normal alkaline rock series of alkali basalt-trachybasalt-basaltic trachyandesite and trachyte association. Oxide vs. MgO diagrams represent that the mafic lavas fractionated with crystallization of olivine, clinopyroxene, magnetite and ilmenite and felsic trachyte of plagioclase and apatite. The characteristics of trace elements and REEs shows that primary magma for the trachybasalt magma would have been derived from partial melting of garnet peridotite mantle. In the discrimination diagrams, the volcanic rocks are plotted at the region of within plate basalt (WPB).

Comparison of Rice Yield and Grain Quality Characteristics between Mature and Reclaimed Paddy Fields in Honam Plain Area (호남평야지 숙답과 간척답의 수량 및 미질 특성 비교)

  • 정진일;이선용;김종호
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.40 no.3
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    • pp.382-390
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    • 1995
  • To compare the rice yield and grain quality characteristics between mature(MPF) and reclaimed paddy field(RPF), grain yield and its components, some physicochemical properties of rice grain and palatability of cooked rice were investigated for Dongjinbyeo grown at three different locations of mature and reclaimed paddy field, respectively, in south western part of Korea. Variation of culm length in mature paddy area was larger than that in reclaimed saline area. Panicle number per m$^2$ in RPF was more then that in MPF but grain number per m$^2$, filled grain ratio and 1, 000-grain weight in RPF were lower than those in MPT. Average yield of milled rice in RPF was 12% lower than that in MPF (5.l1t /ha). Daejeon showed the highest yielding among MPF and Yeongam reveald the highest grain production among RPF. RPF rices had slightly higher carbohydrate content and alkali digestibility but lower protein, fat and amylose content compared with MPF rices. RPF rices also exhibited higher mineral contents, Mg/K ratio, peak and hot viscosity compared with MPF rices. RPF rice showed slightly poor apparent grain quality but a little better eating quality of cooked rice compared with MPF rice.

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A Preliminary Survey Result of Cu Occurrence in Tsogttsetsii Area, Mongolia (몽골 촉트체치 지역 동 산출지 예비조사결과)

  • Kim, In Joon;Lee, Jae Ho;Ryoo, Chung-Ryul;Lee, Bum-Han;Jin, Kwang Min;Davaasuren, Otgon-Erdene;Heo, Chul-Ho;Nam, Hyeong Tae
    • Economic and Environmental Geology
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    • v.50 no.4
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    • pp.313-324
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    • 2017
  • Tsogttsetsii area, an intrusive complex associated with Cu mineralization, is located in the South Gobi, Mongolia. We performed the cross geochemical and extended exploration survey in Tsogttsetsii area. Cu mineralization in Tsogttsetsii area is porphyry Cu type related with alkali granite intruded in Late Carboniferous to Early Permian. In the concentrated occurring to malachite appears extensively prophylitic alteration zone having a chlorite and epidote. As results of the survey, Cu contents of potable XRF and of chemical composition for altered rocks ranges 1.08 to 18.3% in the 30 points and 1.08 to 32.9% in the 13 points, respectively. Ore minerals identified in XRD analysis and polarizing microscope that samples of copper oxides were composed mainly of malachite, azurite, permingeatite and cuprite and the other minerals are pyrite, chalcopyrite, pyrargyrite, dickite, calcite, chlorite and epidote. Mineralization can be considered occurring to selectively some granite of the surrounding aplite and faults in the only upper part coming up the hydrothermal solution of the remaining residual magma after the aplite intrusion.

Analytical Method of Silicon Dioxide in Health Functional Food Products using ICP-OES

  • Ka, Mi-Hyun;Lee, Kwang-Geun;Lim, Heung-Youl;Lee, Gunyoung;Yun, Sang Soon;Lim, Ho Soo;Kim, Yong-Suk
    • Journal of Food Hygiene and Safety
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    • v.32 no.5
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    • pp.343-347
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    • 2017
  • The analytical method of silicon dioxide ($SiO_2$) in health functional food products was developed employing inductively coupled plasma optical emission spectrometry (ICP-OES) method assisted by acid (hydrofluoric acid and boric acid) digestion in open system without alkali fusion. The limit of detection (LOD) and limit of quantification (LOQ) of this method were found to be 0.07 and 0.20 mg/L, respectively. Linearity ($r^2$) and linear range were 0.99 and 0.20~20.0 mg/L, respectively. The accuracy and precision of $SiO_2$ (0.4, 1.0, and 2.0%, w/w) in spiked glucosamine exhibited to be the range of 90.22~94.14% and 0.72~1.67%, respectively. The contents of $SiO_2$ in 11 health functional food products were detected in range of 0.02~1.80% (w/w). Every sample showed below content of the permitted use level (2%, w/w) of $SiO_2$. Therefore ICP-OES method with acid can analyze the content of $SiO_2$ in health functional food products easily and rapidly. Consequently, the application of specification analysis of $SiO_2$ in health functional food products could be a significant work.