• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.24 no.4
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• pp.492-500
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• 2014

Objectives: The purpose of this study is to estimate the applicability of regional sample collection of environmental samples. The concentration of asbestos fibers were analyzed with two devices. One was an existing commercial air sampling pump that has been proved to be accurate and exact, and the other is a remodeled pump for sample collection which was made from an electric bubble generator originally designed for aquarium fish. Samples were collected with the two devices under the same environmental conditions and collection equipment. A comparative analysis of the concentration of ambient asbestos fiber was then performed. Methods: Based on previous research, six farmhouses with asbestos fiber slate roofs known to have high concentrations of asbestos fiber were selected. Using the existing commercial air sampling pump and the remodeled electric bubble generator, four to seven samples were collected each day one meter downwind from the edge of the slate roof at high volume (about 4 L/min) and low volume (about 1.4 L/min). The analyzer responsible for sample quality control of asbestos fibers counted the number of asbestos fibers with a phase microscope. Results: The rates of flow change of the existed sampler and the remodeled pump at high volume were 0.82% and 0.17%, respectively. The rates of flow change at low volume were 3.83% and 1.09%, but there was not significant difference. The rates of flow change are within the error range (${\pm}5%$) of OSHA analyzing methods. For the high volume sampler, the average asbestos fiber concentration in the air collected by the existed sampler is 6.270 fibers/L and for the remodeled one 5.527 fibers/L, not a significant difference. For the low volume sampler, the average asbestos fiber concentration in the air collected by the existed sampler is 7.755 fibers/L and for the remodeled one 7.706 fibers/L, not a significant difference. The total area of the slate roof of the targeted farmhouse has an effect on the concentration of asbestos fibers in the air from the existing pump and the remodeled one (p<0.01). Conclusions: The sampling function between the existing commercial pump and the remodeled one shows little difference. Therefore, the remodeled pump is considered a pump with a good availability for collecting ambient air asbestos samples.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.15 no.3
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• pp.183-191
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• 2005

This study is designed to compare the performance of established samplers (personal air sampler and MiniVOL portable air sampler) commonly used in the air environment or work environment with that of the sampler made by remodeling the air bubble generator for aquarium fishes. Sampling method used in this study is the filter collection method for PM10 and total suspended particles (TSP), the liquid collection method for sulfur dioxide ($SO_2$) and nitrogen dioxide ($NO_2$), and the solid collection method for toluene, respectively. There is not a significant difference in the average concentration of TSP between the Gilian personal air sampler (1st, $0.316{\pm}0.095$; 2nd $0.191{\pm}0.090$; 3rd, $0.185{\pm}0.073mg/m^3$) and the remodeled sampler (1st, $0.317{\pm}0.106$, 2nd $0.201{\pm}0.050$; 3rd $0.189{\pm}0.081mg/m^3$). There are also not significant differences in the average concentration of PM10 among the Gilian personal air sampler ($0.058{\pm}0.006mg/m^3$), the remodeled sampler ($0.052{\pm}0.008mg/m^3$) and the MiniVOL portable air sampler ($0.054{\pm}0.007mg/m^3$). The average concentration of the SO2 by the established sampler and the remodeled one is $3.79{\pm}0.21ppb$ and $3.45{\pm}0.15ppb$, respectively. In addition, there are not sigmficant differences in the average concentration of the NO2 between the Gilian personal air sampler (1st, $0.325{\pm}0.068$; 2nd $0.341{\pm}0.206$; 3rd, $2.971{\pm}0.078{\mu}g/m^3$) and the remodeled sampler (1st, $0.300{\pm}0.062$; 2nd $0.332{\pm}0.144$, 3rd, $2.968{\pm}0.085{\mu}g/m^3$). There are not significant differences in the average concentration of toluene between the Gilian personal air sampler (1st, $0.499{\pm}0.072$; 2nd $0.598{\pm}0.112$; 3rd $2.284{\pm}0.077{\mu}g/m^3$) and the remodeled sampler (1st, $0.463{\pm}0.133$; 2nd $0.603{\pm}0.082$; 3rd $2.353{\pm}0.115{\mu}g/m^3$). From these results, we can conclude that the performance of the remodeled sampler is not different from that of established samplers. There is possibility that the remodeled sampler can be used as a alternative device for Gilian personal air sampler in area and personal air sampling.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.23 no.4
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• pp.348-355
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• 2013

Objectives: In working environment measurement, sampling is an important stage for obtaining reliable result as analysis. A personal air sampling pump is one of the most fundamental and important element in the work environment measurement, but it remains at the level of calibrating the flow rate of the pump before and after sampling. There is no checking whether the flow rate set at the initial stage would be hold during sampling. The purpose of this study was to develop a method to evaluate the flow rate performance of particulate sampling pump with three-pieces cassette holder containing filters commonly used to sample particulate. Materials and methods: We tested back pressure of particulate sampling pumps commonly used in Korea with three-pieces cassette holder containing various filters, and tried to find out the combination conditions of filters in accordance with back pressure required by ISO standard 13137. Results: We found out the matrix of sampling media such as three-pieces cassette holder containing filters applicable to the pressure drop required by the ISO standard for evaluating the flow rate stability under increasing pressure drop and long term(8 hour) performance. Conclusions: This evaluation method using sampling media matrix for checking flow rate stability proposed by this study could be very useful tool to find out good performance pumps before sampling.

• Journal of Environmental Science International
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• v.1 no.1
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• pp.41-46
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• 1992

To perform a long-term ambient sampling study at a residential site, an air sampler was constructed to collect 24-hour integrated air samples suitable for the volatile organic compounds (VOCs) analysis. It includes an esthetically acceptance due to proximity to homes, as fell as providing the required sampling specifications. The VOCs sampler accomodates four 5/8 "stainless steel(SS) traps packed with adsorbent(Tenax) and is capable of four flow rates in the range of 5 to 50 cc/min. Sintered metal filters(10 micrometer) were directly connected to the inlet of the trap adapters. Additional specifications include: 1) constructed of organically inert materials, 2) weatherproof, 3) battery operated, 4) collecting of VOCs at a breathing zone level, and 5) quiet operation with micro diaphragm pumps wrapped by the sponge. The pump/battery system was separated from the sampling shelter. Sound levels measured for this system were below permissible sound levels (NJDEP) at a residential site. The sampler has been successfully operated at both ground level in a residential area and on the roof of a one story elementary school.hool.

• Journal of Korean Society for Atmospheric Environment
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• v.21 no.5
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• pp.481-494
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• 2005

The monitoring of persistent organic pollutants (POPs) in the atmosphere is a basis for the study of the fate of POPs in multimedia environments. Recently, passive air samplers (PASs) for POPs have been developed. In this paper, we deal with the principle, properties, and applications of the PAS. The principle of PAS, which has no pump, is physical sorption of semi-volatile organic chemicals on various sorbent materials. The PAS is much smaller than a high-volume air sampler and does not need electricity. These properties of the PAS make it possible to conduct various-scaled environmental monitoring all over the world including the Arctic and Antarctic, but the major disadvantage of PAS is its long sampling periods up to 2 years. To date, four kinds of PAS have been developed: polyurethane foam (PUF), polymer-coated glass (POG), semi-permeable membrane devices (SPMDs), and XAD resin-based PAS. Among them, SPMDs have been commercialized and are most widely used now. Meanwhile, the POPs emitted from China have a large potential to influence the levels and fates of POPs in Korea. Since characteristics of PAS are quite useful to monitor long-range transport of POPs, the use of PAS is highly recommended.

• Journal of Korean Society for Atmospheric Environment
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• v.20 no.6
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• pp.759-771
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• 2004

This study analyzed concentrations of volatile organic compounds (VOCs) produced from incineration of plastic wastes at $600^{\circ}C$. The plastic wastes used in this study included polyethyleneterephthlate (PETE), high density polyethylene (HOPE), polyvinyl chloride (PVC), low density polyethylene (LOPE), polypropylene (PP), polystyrene (PS) and other. Plastic wastes were heated from room temperature upto $600^{\circ}C$ providing the compressed air inside of a small-scale electric furnace for 90 minutes and then they were oxidized (incinerated) for 60 minutes at $600^{\circ}C$ maintaining the same air supply. VOCs emitted from the incineration process were sampled using an air sampling pump and Tedlar air bags for 150 minutes and then the components and concentrations of the VOCs were analyzed by a GC-MS. The most prominent chemical structure of the VOCs obtained from the incineration process of the HOPE, LOPE and PP, which include ethylene groups in their main chains, was identified as aliphatic hydrocarbons such as 1-hexene. However, aromatics such as benzene were major chemical structure from the incineration of PETE, PVC and PS which include benzene rings in their main chains. This study estimated the total VOC production from the incineration of the plastic wastes based on the real plastic waste production and the emission factors. 64% and 27% of the total VOC emissions consisted of aliphatic hydrocarbons and aromatics, respectively, which have double bonds within their molecular structure and thus a high ground level ozone formation potential.

• Ocean and Polar Research
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• v.38 no.4
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• pp.339-345
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• 2016

Stable water vapor isotopes have been utilized as a tracer for studying atmospheric global circulations, climate change and paleoclimate with ice cores. Recently, since laser spectroscopy has been available, water vapor isotopes can be measured more precisely and continuously. Studies of water vapor isotopes have been conducted over the world, but it is the early stage in south Korea. For vapor isotopes study, a cryogenic sampling device for water vapor isotopes has been developed. The cryogenic sampling device consists of the dewar bottle, filled with extremely low temperature material and impinger connected with a vacuum pump. Impinger stays put in the dewar bottle to change the water vapor which passes through the inside of impinger into the solid phase as ice. The fact that water vapor has not sampled completely leads to isotopic fractionation in the impinger. To minimize the isotopic fractionation during sampling water vapor, we have tested the method using a serial connection with two sets of impinger device in the laboratory. We trapped 98.02% of water vapor in the first trap and the isotopic difference of the trapped water vapor between two impinger were about 20‰ and 6‰ for hydrogen and oxygen, respectively. Considering the amount of water vapor trapped in each impinger, the isotopic differences for hydrogen and oxygen were 0.33‰ and 0.06‰, respectively, which is significantly smaller than the precision of isotopic measurements. This work can conclude that there is no significant fractionation during water vapor trapping.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.11 no.1
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• pp.61-72
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• 1999

The present study experimentally investigated the effect of refrigeration lubricant on the heat transfer performance in the straight sections and U-bend of a microfin tube evaporator by using R-22/mineral oil and R-407C/POE oil. The apparatus consisted of test section with U-bend, preheater, condenser, oil injection and sampling devices, magnetic pump, mass flow meter etc. The experimental parameters were oil concentration of 0 to 5 wt%, inlet quality of 0.1 to 0.5, mass flux of 219 and $400kg/m^2s$ and heat flux of 10 and $20kW/m^2$. The effects of parameters on the heat transfer coefficients were large in the order of inlet quality, mass flux and heat flux as oil concentration got increased. As oil concentration was increased, heat transfer coefficients were continuously decreased for R-22 and increased by 3% up to the concentration of 1% and then decreased for R-407C under the condition of large inlet quality, and small mass flux and heat flux. But, the heat transfer coefficients were increased up to the concentration of 3% and then decreased for both R-22 and R-407C refrigerants under the opposite conditions. The variation of enhancement factors for R-407C was under 50% of that for R-22 and the variation with respect to the positions in the test section was small. The pressure drops were increased for both R-22 and R-407C refrigerants as oil concentration was increased. The pressure drops for R-407C were smaller by the maximum of 18% than those for R-22.

• Korean Journal of Agricultural and Forest Meteorology
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• v.11 no.1
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• pp.27-38
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• 2009

The multi-level profile system is designed to measure the vertical profile of $H_2O$ and $CO_2$ concentrations in the surface layer to estimate the storage effects within the plant canopy. It is suitable for long-term experiments and can be used also in advection studies for estimating the spatial variability and vertical gradients in concentration. It enables the user to calculate vertical fluxes of water vapor, $CO_2$ and other trace gases using the surface layer similarity theory and to infer their sources or sinks. The profile system described in this report includes the following components: sampling system, calibration and flow control system, closed path infrared gas analyzer(IRGA), vacuum pump and a datalogger. The sampling system draws air from 8 inlets into the IRGA in a sequence, so that for 80 seconds air from all levels is measured. The calibration system, controlled by the datalogger, compensates for any deviations in the calibration of the IRGA by using gas sources with known concentrations. The datalogger switches the corresponding valves, measures the linearized voltages from the IRGA, calculates the concentrations for each monitoring level, performs statistical analysis and stores the final data. All critical components are mounted in an environmental enclosure and can operate with little maintenance over long periods of time. This report, as a practical manual, is designed to provide helpful information for those who are interested in using profile system to measure evapotranspiration and net ecosystem exchanges in complex terrain.

• Journal of Korean Society for Atmospheric Environment
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• v.23 no.5
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• pp.547-556
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• 2007

The release, sampling and analytical methods have been developed and tested for perfluorocarbons (PFCs) atmospheric tracers in order to gain insight into the atmospheric transport and dispersion over the urban conditions of Seoul, Korea. Although PFCs tracer experiments provide unique opportunities to test local and urban scale of transport and dispersion, no previous experiment with PFCs has been conducted in Korea. PMCH and PDCH were chosen as targeted tracers in our study due to their extreme low ambient concentrations and great sensitivities among various PFCs. For PFCs release system, a set of micro-metering pump, electronic balance, vaporizing furnace and high speed blower was constructed for precise and accurate release of tracers. The precision of released rate by this system was estimated to be 1%. Samplings of PFCs were carried out by fabricated portable air samplers with micro pumps and rotameters into glass tubes packed with 150 mg of Carboxen-569. The uncertainty of these sampling system was maintained below 14%. PMCH and PDCH were quantified in GC/ECD with preconditioned injection system to eliminate the interference compounds using traps and subsequent catalytic conversion system prior to column separation. Three intensive field test were undertaken during the springtime of 2002 to 2004 in eastern part of Seoul. Daily background samples were collected to characterize the background levels of PMCH and PDCH prior to their release. The observed background concentrations of PMCH ranged from 3.5 to 10.1 fL/L and varied randomly in location and time in this study. Its mean and standard variation of background concentration ($6.8{\pm}1.9\;fL/L$) are higher than those ($3.2{\sim}5.8\;fL/L$) of other historic tracer studies. Identified uncertainty for background PMCH was $1.7{\sim}2.0\;fL/L$ using this analytical system. Combined relative uncertainty in determining the tracer's concentrations was estimated as 17%. However, its background concentrations and uncertainty in concentration determination were found to be low and stable enough for tracer study.