• Title/Summary/Keyword: air foam

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Effect of Cetyltrimethyl Ammonium Bromide on Foam Stability and SiO2Separation for Decontamination Foam Application (거품제염을 위한 실리카 나노입자와 CTAB (Cetyltrimethyl Ammonium Bromide)의 거품안정성 및 분리특성 평가)

  • Choi, Mansoo;Kim, Seung-Eun;Yoon, In-Ho;Jung, Chong-Hun;Choi, Wang-Kyu;Moon, Jei-Kwon;Kim, Seon-Byeong
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.16 no.2
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    • pp.173-182
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    • 2018
  • As part of planning for waste minimization, decontamination foam has been considered as a potential application for the cleaning of radioactive contaminant. In this study, we synthesized silica particles to improve foam stability by varying synthesis parameters. Cetyltrimethylammonium bromide (CTAB) was found to influence the stability of the decontamination foam. The reason was that higher interaction between $SiO_2$ nanoparticles and surfactant at the air-water interface in aqueous solution is beneficial for foam stability. CTAB can also be used as an additive for the aggregation of silica nanoparticles. In the separation of $SiO_2$ nanoparticles, CTAB plays a critical role in the nanoparticles flocculation because of the charge neutralization and hydrophobic effects of its hydrocarbon tails.

The Prediction of Time-Dependent Thermal Conductivity of Polyurethane Foam with Cell Gas Analysis (셀 가스분석을 이용한 우레탄폼의 열전도도 장기변화 예측)

  • Lee, Hyo-Jin;Chun, Jong-Han;Kim, Jin-Seon;Lee, Jin-Bok;Kang, Nam-Goo
    • Proceedings of the SAREK Conference
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    • 2009.06a
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    • pp.1367-1372
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    • 2009
  • A proprietary device is adopted to break out the membrane of cell in the rigid polyurethane foam. As it is known, the membrane of cell is hardly tearing-off thoroughly in a mechanical way due to both its elastic characteristic and micro sized pores. In this study, a novel experimental approach is introduced to burst out all gases inside the cells of the rigid polyurethane foam by abrasively grinding micro-cells completely into fine powder. The biggest advantage of this approach is to be capable of releasing all gases out from the cell even in the micro pores. As clearly reflected from the repeatability, the accuracy of the result is highly improved and high confidence in the data sets as well. For the measurements of not only gas composition but partial pressure for each gas simultaneously as well, a precision gas mass spectrometer is used in-line directly to the abrasive grinding device. To control the starting point of the polyurethane foam, all samples were prepared on site in the laboratory. Manufactured time is one of the most critical factors in characterization of cell gas composition because it is known that one of gas composition, especially, carbon dioxide, is diffused out dramatically in a short period of time as soon as it is foamed.

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Theory study on thermal performance of metal foam

  • Jin, Meihua;Kim, Pil-Hwan;Lee, Hae-Jong;Jeong, Hyo-Min;Chung, Han-Shik
    • Proceedings of the SAREK Conference
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    • 2008.11a
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    • pp.239-243
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    • 2008
  • In many literatures the researchers pointed out that the using metal foam will significantly enhance the performance of heat exchanger. This paper focuses on theory study of metal foam, including calculation method of properties of foam (permeability ��K, inertial coefficient f, fiber diameter $d_f$, and effective conductivity $k_e$), model of pressure drop and model of heat transfer. Theory analysis on the performance of heat exchanger will be presented here. Finally the optimal material will be obtained from theory calculation.

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Effect of pH on Successive Foam and Sonic Droplet Fractionation of a Bromelain-invertase Mixture

  • Ko Samuel;Prokop Ales;Tanner Robert D.
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.7 no.1
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    • pp.26-30
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    • 2002
  • A droplet fractionation method was previously developed to concentrate a dilute nonfoaming protein solution. In that earlier study with invertase, it was demonstrated that droplets created by ultrasonic energy waves could be enriched up to 8 times that of the initial dilute invertase solution. In this study, a mixture of bromelain (a foaming protein) and invertase (a nonfoaming protein) is investigated as a preliminary step to determine if droplet fractionation can also be used to separate a non-foaming protein from foaming proteins. The foaming mixture containing bromelain is first removed by bubbling the binary mixture with air. After the foam is removed, the protein rich air-water interfacial layer is skimmed off (prior to droplet fractionation) so as not to interfere with the subsequent droplet production from the remaining bulk liquid, rich in non-foaming protein. Finally, sonic energy waves are then applied to this residual bulk liquid to recover droplets containing the non-foaming protein, presumed to be invertase. The primary control variable used in this droplet fractionation process is the pH, which ranged for separate experiments between 2 and 9. It was observed that the maximum overall protein partition coefficients of 5 and 4 were achieved at pH 2 and 4, respectively, for the initial foaming experiment followed by the post foaming droplet fractionation experiment.

Heat Transfer Characteristics of Aluminium and FeCrAlY Foam

  • Jin, Meihua;Kim, Pil-Hwan;Lee, Hae-Jong;Jeong, Hyo-Min;Chung, Han-Shik
    • Proceedings of the SAREK Conference
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    • 2008.06a
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    • pp.395-401
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    • 2008
  • Since metallic foam will increase the performance of heat exchanger, it have caused many researcher's attention recently. Our research base on the model that metallic foams applied to heat exchanger. In this case, there is three kind of heat transfer mechanisms, heat conduction in fibers, heat transfer by conduction in fluid phase, and internal heat change between solid and fluid phases. In this paper we study both the hydraulic and thermal aspect performance. Pressure drop along air flow direction will be presented. As thermal aspect, we first discuss the acceptance of applying thermal equilibrium among the two phases. then to calculate the dimensionless temperature profile, the heat transfer coefficient and Nu number in 14 metallic foams(7 Aluminium foams, 7 FeCrAlY foams). All these discussion is based on the same velocity u=2 m/s.

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The Determination of Diffusion and Partition Coefficients of PUF (폴리우레탄 폼의 휘발성 유기화합물 확산 및 분배계수 산정)

  • Park, Jin-Soo;Little, John C.;Kim, Shin-Do;Lee, Hee-Kwan;Kong, Boo-Ju
    • Journal of Korean Society for Atmospheric Environment
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    • v.26 no.1
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    • pp.77-84
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    • 2010
  • The diffusion and partition coefficients of polyurethane foam (PUF) are estimated using a microbalance experiment and small chamber test. The microbalance is used to measure sorption/desorption kinetics and equilibrium data. When the diffusion condition is controlled in the chamber of the sample, interactions between volatile organic compounds (VOCs) and PUF can lead to the estimation of a relatively homogenous rate of mass transfer in the interiors and surfaces of PUF. The estimates of the material/air partition coefficient (K) and the material-phase diffusion coefficient (D) are shown to be independent of the concentrations of VOCs. This approach, if applied to a diffusion-controlled or physically-based model, can facilitate more precise prediction of their source/sink behavior. Although further research and more rigorous validation is needed, an emission model applied with the diffusion and partition coefficients from this research holds promise for the improvement of reliability in predicting the behavior of VOCs emitted from porous building materials by D and K.

Measurement of Atmospheric PCDD/Fs Concentrations Using Polyurethane Foam Disk Passive Air Samplers (폴리우레탄 폼 수동형 공기시료채취기를 이용한 대기 중 다이옥신/퓨란 농도 측정)

  • Kim, Taewook;Chun, Man-Young
    • Journal of Environmental Health Sciences
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    • v.42 no.2
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    • pp.102-111
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    • 2016
  • Objectives: This study was conducted to evaluate the use of polyurethane foam disk passive air samplers (PUF PAS) for better measurement of atmospheric polychlorinared dibenzo-p-dioxins/furans (PCDD/Fs) concentrations compared to PUF PAS combined with high volume air samplers (HVS). Methods: Air samples were collected by a low volume air sampler (LVS) and PUF PAS. A total of two pairs were continuously collected for six months, but the PUF was replaced every two months. Results: A good correlation was shown ($R^2=0.8595$, p<0.0001) between atmospheric PCDD/Fs concentration measured by the LVS and PUF PAS. The average air sampling rate ($1.5m^3/day-sampler$) of all PCDD/Fs congeners showed a middle of the means which were measured using a HVS by other researchers in different cities. In addition, the air sampling rates of the LVS for each congener made less difference than did those of the HVS. Conclusion: It was found that measurements using the LVS were less influenced by atmospheric peak PCDD/Fs concentrations. However, trace POPs such as PCDD/Fs may involve relatively large analytical errors in measurement, and as a result the air sampling rate of the respective PCDD/Fs isomer is also likely to involve errors. The method of using a regression straight line between the concentrations obtained from the LVS and those from the PUF PAS was judged higher than the method using the air sampling rate, since the former compensated for the experimental errors in the process of evaluation of atmospheric PCDD/F concentrations using the PUF PAS.

Operation Condition and Characteristics for Treatment of Piggery Slurry using Thermophilic Aerobic Oxidation System (축산분뇨 처리에 적용된 급속액상부숙기술(TAO system)의 운전특성과 운전조건)

  • 이명규;이원일
    • Journal of Animal Environmental Science
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    • v.6 no.3
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    • pp.161-168
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    • 2000
  • The study exploited TAO system for the treatment of piggery slurry and aimed to draw characteristics and conditions of the reactor by differentiating the number of air input pump and foam cutter. The results are: 1. Under different operation condition, Run-3 with three air input pumps and four foam cutters showed the highest efficiency in the change of water level and temperature; 40-70cm and 45-55$^{\circ}C$, respectively. 2. Evaporation volume in Run-3 was the highest; 55.5l/$m^2$ . day in Run-1, 75.0/$m^2$ . day in Run-2, and 120.3/$m^2$ . day in Run-3. 3. Throughout the experimental period, temperature inside the reactor was maintained at around 5$0^{\circ}C$, regardless of seasonal temperature changes.

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Experiment and Analysis on the Heat Transfer Characteristics of a Channel Filled with Metal Form (발포 금속을 사용하는 채널의 열전달 특성 실험 및 해석)

  • Son, Young-Seok;Shin, Jee-Young;Cho, Young-Il
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.22 no.7
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    • pp.448-453
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    • 2010
  • Porous media containing complex fluid passage have especially large surface area per unit volume. This study is aimed to identify the heat transfer characteristics of high-porosity metal foams in a horizontal channel. Experiment is performed under various heat flux, velocity and pore density. Nusselt number decreases with higher pore density. Metal foams shows higher heat transfer coefficients than pin-fin structure with the same porosity. This is due to the more complex flow passage and larger heat transfer area based on the structure of the metal foams. The analysis on the pin-fin structure may not be suitable to the metal foam structure but should be identified extensively through further study.

Synthesis of Oxyethlyene Modified Silixoane Surfactants for Polyurethane Foam and the Characteristics of Fine Cell Formation (폴리우레탄 폼용 옥시에틸렌 변성 폴리실록산계 계면활성제의 합성 및 미세 셀 발포 특성)

  • Kim, Daeheum;Park, Seungwoo;Yeo, Seungbyung
    • Applied Chemistry for Engineering
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    • v.17 no.3
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    • pp.260-266
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    • 2006
  • For the synthesis of polyurethane memory foam stabilizer with fine cells, hydrosilylation reaction with various polyalkyleneoxides and hydrogen functional group of polymethylhydrogensiloxane (D = 75, D' = 15) was conducted. Polyalkyleneoxides (PAO) used in this research were ethylene oxides or ethylene-co-propylene oxides with terminal groups of hydroxides or methyl groups. To analyze the molecular structures and molecular weights as well as the reaction yields (98%), NMR and GPC analysis were executed. Synthesized siloxane surfactants modified with polyalkylene (EO = 12 units) were applied to producing flexible polyurethane fine memory foams from 0.6 pphp to 2.0 pphp. By controlling the amount of the surfactant, physical characteristics, the polyurethane memory foam with cell size (minimum $0.868{\mu}m$), air flows (-78 KPa), and recovery times (8 sec) were achieved.