• The Korean Journal of Ecology
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• 제27권3호
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• pp.185-192
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• 2004

속리산 국립공원의 산지에는 신갈나무군락, 소나무군락, 굴참나무군락, 상수리나무군락, 서어나무군락, 갈참나무군락 및 졸참나무군락의 자연적 과정을 통해 성립된 식생과 일본잎갈나무 조림지와 리기다소나무 조림지로 이루어진 인위적으로 조성된 식생이 성립하고 있다. 한편, 하천 주변의 저지대에는 농경지, 주거지, 상업시설 등으로 이루어진 개발지가 분포하고 있다. 식생의 공간적 분포에 의하면, 행정구역상 충북 보은군 내속리면과 경북 상주시 화북면에 속하는 공원구역 남부 약 1/3 지역은 자연성과 식생의 다양성이 높았지만 청천면 및 칠성면에 속하는 나머지 지역은 그 대부분을 소나무림이 차지하고 조림지가 차지하는 비율도 높아 식생의 다양성과 자연성이 모두 낮았다. 조사된 식분율 서열법으로 처리한 결과, 식분의 배열은 고도, 사면 등의 지형요인과 그것에서 비롯된 수분요인에 의해 지배되는 경향이었다. 주요 목본식물의 직경 급별 빈도분포를 분석하여 식생의 동태를 분석한 결과, 향후 이 지역의 식생은 서어나무군락, 신갈나무군락 및 소나무군락이 중심을 이루는 식생으로 재편될 전망이다. 그러나 교란의 발생과 그것에 대한 식생의 반응을 고려하면, 이러한 판단은 실제와 다소 차이를 보일 가능성도 있다. 이상의 결과를 종합한 속리산 국립공원의 보전전략이 경관생태, 주요 식물군락의 보전 및 생물다양성 보전의 관점에서 검토되었다.

• 한국토양비료학회지
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• 제38권1호
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• pp.52-57
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• 2005

굴껍질을 주원료로 하는 패화석비료가 토양개량제로서 배추의 생육 및 수량을 증진시키고 토양의 이화학적 특성 개선에 효과가 있는 것으로 알려져 있다. 평택통 (Fine silty, Typic Endoaquepts)의 밭 토양에 굴패화석비료를 0, 4, 8, 12, and $16Mg\;ha^{-1}$ 처리하여 봄배추를 재배하는 과정 중 패화석비료 시용량이 증가함에 따라 토양내 유효인산함량은 일정하게 증가되는 것이 확인되었다. 유효인산 함량의 증가는 1차적으로 패화석비료내 포함된 인산 ($1.5g\;P_2O_5\;kg^{-1}$)의 직접투입이 토양 내 전 인산을 증가시키고 유효인산을 증진시킨 것으로 평가되었다. 그리고 알카리성 제재인 패화석비료가 pH 5.8의 공시토양의 pH를 중성범위로 높이면서 간접적으로 유효인산함량을 증진시킨 것으로 해석되었다. 패화석비료의 시용량이 증가함에 따라 토양내 수용성 인산과 Ca-P 함량을 다소 증가시켰으나, Al-P와 Fe-P의 비율을 크게 감소되었다. 결과적으로 패화석비료는 토양내 유효인산함량 증진에 효과가 있으며, 이렇게 많아진 유효인산을 이용하여 인산시비량을 저감하고 나아가 인산유출을 저감할 수 있는 방법이 될 수 있을 것으로 판단된다.

• Natural Product Sciences
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• 제13권1호
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• pp.33-39
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• 2007

Eleven polyhydroxyursane triterpenoids (PHUTs) were tested to determine their cytoprotective, immunosuppressive and anti-inflammatory effects. To compare the bioactivities of $19{\alpha}$-hydroxyursane-type triterpenoids {23-hydroxytormentic acid (6), its methyl ester (7), tormentic acid (8), niga-ichigoside $F_1$ (9),euscaphic acid (10) and kaji-ichigoside $F_1$ (11)} of the Rosaceae crude drugs (Rubi Fructus and Rosa rugosae Radix) with PHUTs possessing no $19{\alpha}-hydroxyl$ of Centella asiatica (Umbelliferae), the four PHUTs, asiaticoside (1), madecassoside (2), asiatic acid (3), and madecassic acid (4) were isolated from C. asiatica and 23-hydroxyursolic acid (5) from Cussonia bancoensis. Cytoprotective effects were assessed by measuring cell viabilities against cisplatin-induced cytotoxocity in $LLC-PK_1$, cells (proximal tubule, pig kidney) to determine whether these agents have protective effects against nephrotoxicity caused by cisplatin. The inhibitory effect of 11 PHUTS on nitric oxide (NO) and prostaglandin $E_2\;(PGE_2)$ were evaluated by measuring nitrite accumulation in lipopolysaccharide (LPS)-induced macrophage RAW 264.7 cells, and their anti-inflammatory effects were tested in 12-O-tetradecanoylphorbol-13-acetate (TPA)-induced mouse ear edema model. Six MHUTs (compounds 1, 2, 4, 6, 10, and 11) exhibited higher cell viabilities during cisplatin-induced cytotoxicity testing even at a concentration of $200\;{\mu}g/ml$ than cisplatin only-treated group, suggesting that ese compounds have the potentcytoprotective efffcts. Compounds 1 and 3 of the C. asiatica and niga-ichigoside $F_1$ exhibited no inhibitory effect on NO and/or $PGE_2$ production whereas other PHUTs produced mild to significant NO and/or $PGE_2$ production.The four compounds (2, 5, 9, and 10) potently inhibited mouse ear edema induced by TPA whereas two compounds (1 and 3) had no activity in this test. These results suggest that many PHUTs are potentchemopreventives. Structure-activity relationship (SAR) was also discussed in each assay with regard to the significant role of OHs at the position of 2, 3, 6, 19, and 23 and to the glycoside linkage at the 28-carboxyl.

• Asian-Australasian Journal of Animal Sciences
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• 제30권5호
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• pp.736-742
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• 2017

Objective: Experiments were conducted to clone the sequence of Wild Argali short palate, lung and nasal epithelium clone 1 (SPLUNC1) cDNA, and to lay the foundation for further study the biological function of Wild Argali SPLUNC1. Methods: The complete sequence of Wild Argali SPLUNC1 cDNA was generated by rapid amplification of cDNA ends. The entire coding sequence was inserted into the pPIC9K vector and expressed in Pichia pastoris (P. pastoris) GS115. The recombinant SPLUNC1 protein was detected by Western blot and purified by $Ni^{2+}$ chelate affinity chromatography. The test of effect of the protein on Mycoplasma ovipneumoniae (MO) was performed with real-time polymerase chain reaction. Results: The Wild Argali SPLUNC1 cDNA was 1,076 bp with an open reading frame of 768 bp, which encoded a 26.49 kDa protein composed of 255 amino acids. Its amino acid sequence shared 98.4%, 96.9%, 94.5%, 90.2%, 80.8%, 78.4%, 78.3%, 72.5%, 72.3%, 68.8% identity with those of SPLUNC1 cDNA from Ovis aries (accession no. NP_001288334.1), Capra hircus (accession no. XP_005688516.1), Pantholops hodgsonii (accession no. XP_005979709.1), Bos taurus (accession no. NP_776851.1), Felis catus (accession no. XP_006929910.1), Homo sapiens (accession no. NP_001230122.1), Sus scrofa (accession no. NP_001005727.1), Chinchilla lanigera (accession no. NP_001269294.1), Mus musculus (accession no. NP_035256.2), and Rattus norvegicus (accession no. NP_742028.1), respectively. The recombinant protein corresponded to the expected molecular mass of 25.47 kDa as judged by sodium dodecyl sulfate-polyacrylamide gel electrophoresis, and it was detected in the supernatant of P. pastoris, and it could be purified. The results from the test of inhibition effect of argali recombinant SPLUNC1 protein on MO showed that the product could inhibit MO very well (p<0.01). Conclusion: The amino acid sequence of Wild Argali SPLUNC1 was different from other organisms. The recombinant SPLUNC1 protein has good biological activity.

• Natural Product Sciences
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• 제11권2호
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• pp.67-74
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• 2005

The ethanolic extracts of the leaves and bulbs of Allium victorialis var. platyphyllum (Liliaceae) collected from Daegwallyoung (D) and Ullung Island (U) in Korea were obtained using three different extracting methods. The first extracts, DL-1 DB-1, UL-1 and UB-1, were obtained from leaves (L) and bulbs (B) dried at $90^{\circ}C$, respectively, and the second extracts, DL-2, DB-2, UL-2 and UB-2, were obtained by extracting the leaves and bulbs of fresh plant parts. The third extracts DL-3, DB-3, UL-3 and UB-3 were obtained by incubating leaves and bulbs at $36^{\circ}C$. The six extracts obtained from A. victorialis var. platyphyllum at Daegwanllyoung (cultivated site) were orally administered to examine for a possible antihepatotoxic effect in $CCl_4-induced$ rats. DL-1 exhibited the most pronounced effect. The extracts inhibited serum ALT, AST, SDH, ${\gamma}-GT$, ALP and LDH activities elevated by $CCl_4$ injection and attenuated decreased glutathione S-transferase, glutatione reductase and ${\gamma}-glutamylcysteine$ synthetase activities and a decreased hepatic glutathione. However, the extracts obtained from Ullung Is. (native site) were less active than the extracts from Daegwallyoung, suggesting that A. victorialis var. platyphyllum from the cultivated site is more useful for functional food than of native site. These results also suggest that the antihepatotoxic effect is due to a higher content of hepatic glutathione. Gas chromatography of the twelve extracts showed significantly different sulfides, disulfides or trisulfides contents belonging to volatile sulfur substances (VSS). Nine components were identified on the basis of their mass spectra, namely, dimethyl disulfide, dimethyl trisulfide, diallyl disulfide, dipropyl disulfide, allyl methyl sulfide, allyl methyl trisulfide, 2-vinyl-4H-1,3-dithiin, 3,4-dihydro-3-vinyl-1,2-dithiin, and allithiamine. Extract DL-1 had the highest VSS content. Dried plant materials contained larger amounts of the VSSs than other extracts, and the leaves contained larger amount than the bulbs. These results suggest that heat treatment increases the antiheaptotoxic ability of A. victorialis var. platyphyllum by increasing the proportion of VSSs.

• 한국근적외분광분석학회:학술대회논문집
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• 한국근적외분광분석학회 2001년도 NIR-2001
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• pp.1263-1263
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• 2001

The amounts of organic matter present in soil and the rate of soil organic matter (SOM) turnover are influenced by agricultural management practice, such as rotation, tillage, forage plow down direct seeding and manure application. The amount of nutrients released from SOM is highly dependent upon the state of the organic matter. If it contains a large proportion of light fractions (low-density) more nutrients will be available to the glowing crops. However, if it contains mostly heavy fractions (high-density) that are difficult to breakdown, then lesser amounts of nutrients will be available. The state of the SOM and subsequent release of nutrients into the soil can be predicted by NIRS as long as a robust regression equation is developed. The NIRS method is known for its rapidity, convenience, simplicity, accuracy and ability to analyze many constituents at the same time. Our hypothesis is that the NIRS technique allows researchers to investigate fully and in more detail each field for the status of SOM, available moisture and other soil properties in Alberta soils for precision farming in the near future. One hundred thirty one (131) Alberta soils with various levels (low 2-6%, medium 6-10%, and high >10%) of organic matter content and most of dry land soils, including some irrigated soils from Southern Alberta, under various management practices were collected throughout Northern, Central and Southern Alberta. Two depths (0- 15 cm and 15-30 cm) of soils from Northern Alberta were also collected. These air-dried soil samples were ground through 2 mm sieve and scanned using Foss NIR System 6500 with transport module and natural product cell. With particle size above 150 microns only, the “Ludox” method (Meijboom, Hassink and van Noorwijk, Soil Biol. Biochem.27: 1109-1111, 1995) which uses stable silica, was used to fractionate SOM into light, medium and heavy fractions with densities of <1.13, 1.13-1.37 and >1.37 respectively, The SOM fraction with the particle size below 150 microns was discarded because practically, this fraction with very fine particles can't be further separated by wet sieving based on density. Total organic matter content, mechanical texture, ash after 375$^{\circ}C$, and dry matter (DM) were also determined by “standard” soil analysis methods. The NIRS regression equations were developed using Infra-Soft-International (ISI) software, version 3.11.

• 한국농공학회지
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• 제19권1호
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• pp.4296-4311
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• 1977

This study was conducted to derive an Instantaneous Unit Hydrograph for the accurate and reliable unitgraph which can be used to the estimation and control of flood for the development of agricultural water resources and rational design of hydraulic structures. Eight small watersheds were selected as studying basins from Han, Geum, Nakdong, Yeongsan and Inchon River systems which may be considered as a main river systems in Korea. The area of small watersheds are within the range of 85 to 470$\textrm{km}^2$. It is to derive an accurate Instantaneous Unit Hydrograph under the condition of having a short duration of heavy rain and uniform rainfall intensity with the basic and reliable data of rainfall records, pluviographs, records of river stages and of the main river systems mentioned above. Investigation was carried out for the relations between measurable unitgraph and watershed characteristics such as watershed area, A, river length L, and centroid distance of the watershed area, Lca. Especially, this study laid emphasis on the derivation and application of Instantaneous Unit Hydrograph (IUH) by applying Nash's conceptual model and by using an electronic computer. I U H by Nash's conceptual model and I U H by flood routing which can be applied to the ungaged small watersheds were derived and compared with each other to the observed unitgraph. 1 U H for each small watersheds can be solved by using an electronic computer. The results summarized for these studies are as follows; 1. Distribution of uniform rainfall intensity appears in the analysis for the temporal rainfall pattern of selected heavy rainfall event. 2. Mean value of recession constants, Kl, is 0.931 in all watersheds observed. 3. Time to peak discharge, Tp, occurs at the position of 0.02 Tb, base length of hlrdrograph with an indication of lower value than that in larger watersheds. 4. Peak discharge, Qp, in relation to the watershed area, A, and effective rainfall, R, is found to be {{{{ { Q}_{ p} = { 0.895} over { { A}^{0.145 } } }}}} AR having high significance of correlation coefficient, 0.927, between peak discharge, Qp, and effective rainfall, R. Design chart for the peak discharge (refer to Fig. 15) with watershed area and effective rainfall was established by the author. 5. The mean slopes of main streams within the range of 1.46 meters per kilometer to 13.6 meter per kilometer. These indicate higher slopes in the small watersheds than those in larger watersheds. Lengths of main streams are within the range of 9.4 kilometer to 41.75 kilometer, which can be regarded as a short distance. It is remarkable thing that the time of flood concentration was more rapid in the small watersheds than that in the other larger watersheds. 6. Length of main stream, L, in relation to the watershed area, A, is found to be L=2.044A0.48 having a high significance of correlation coefficient, 0.968. 7. Watershed lag, Lg, in hrs in relation to the watershed area, A, and length of main stream, L, was derived as Lg=3.228 A0.904 L-1.293 with a high significance. On the other hand, It was found that watershed lag, Lg, could also be expressed as {{{{Lg=0.247 { ( { LLca} over { SQRT { S} } )}^{ 0.604} }}}} in connection with the product of main stream length and the centroid length of the basin of the watershed area, LLca which could be expressed as a measure of the shape and the size of the watershed with the slopes except watershed area, A. But the latter showed a lower correlation than that of the former in the significance test. Therefore, it can be concluded that watershed lag, Lg, is more closely related with the such watersheds characteristics as watershed area and length of main stream in the small watersheds. Empirical formula for the peak discharge per unit area, qp, ㎥/sec/$\textrm{km}^2$, was derived as qp=10-0.389-0.0424Lg with a high significance, r=0.91. This indicates that the peak discharge per unit area of the unitgraph is in inverse proportion to the watershed lag time. 8. The base length of the unitgraph, Tb, in connection with the watershed lag, Lg, was extra.essed as {{{{ { T}_{ b} =1.14+0.564( { Lg} over {24 } )}}}} which has defined with a high significance. 9. For the derivation of IUH by applying linear conceptual model, the storage constant, K, with the length of main stream, L, and slopes, S, was adopted as {{{{K=0.1197( {L } over { SQRT {S } } )}}}} with a highly significant correlation coefficient, 0.90. Gamma function argument, N, derived with such watershed characteristics as watershed area, A, river length, L, centroid distance of the basin of the watershed area, Lca, and slopes, S, was found to be N=49.2 A1.481L-2.202 Lca-1.297 S-0.112 with a high significance having the F value, 4.83, through analysis of variance. 10. According to the linear conceptual model, Formular established in relation to the time distribution, Peak discharge and time to peak discharge for instantaneous Unit Hydrograph when unit effective rainfall of unitgraph and dimension of watershed area are applied as 10mm, and $\textrm{km}^2$ respectively are as follows; Time distribution of IUH {{{{u(0, t)= { 2.78A} over {K GAMMA (N) } { e}^{-t/k } { (t.K)}^{N-1 } }}}} (㎥/sec) Peak discharge of IUH {{{{ {u(0, t) }_{max } = { 2.78A} over {K GAMMA (N) } { e}^{-(N-1) } { (N-1)}^{N-1 } }}}} (㎥/sec) Time to peak discharge of IUH tp=(N-1)K (hrs) 11. Through mathematical analysis in the recession curve of Hydrograph, It was confirmed that empirical formula of Gamma function argument, N, had connection with recession constant, Kl, peak discharge, QP, and time to peak discharge, tp, as {{{{{ K'} over { { t}_{ p} } = { 1} over {N-1 } - { ln { t} over { { t}_{p } } } over {ln { Q} over { { Q}_{p } } } }}}} where {{{{K'= { 1} over { { lnK}_{1 } } }}}} 12. Linking the two, empirical formulars for storage constant, K, and Gamma function argument, N, into closer relations with each other, derivation of unit hydrograph for the ungaged small watersheds can be established by having formulars for the time distribution and peak discharge of IUH as follows. Time distribution of IUH u(0, t)=23.2 A L-1S1/2 F(N, K, t) (㎥/sec) where {{{{F(N, K, t)= { { e}^{-t/k } { (t/K)}^{N-1 } } over { GAMMA (N) } }}}} Peak discharge of IUH) u(0, t)max=23.2 A L-1S1/2 F(N) (㎥/sec) where {{{{F(N)= { { e}^{-(N-1) } { (N-1)}^{N-1 } } over { GAMMA (N) } }}}} 13. The base length of the Time-Area Diagram for the IUH was given by {{{{C=0.778 { ( { LLca} over { SQRT { S} } )}^{0.423 } }}}} with correlation coefficient, 0.85, which has an indication of the relations to the length of main stream, L, centroid distance of the basin of the watershed area, Lca, and slopes, S. 14. Relative errors in the peak discharge of the IUH by using linear conceptual model and IUH by routing showed to be 2.5 and 16.9 percent respectively to the peak of observed unitgraph. Therefore, it confirmed that the accuracy of IUH using linear conceptual model was approaching more closely to the observed unitgraph than that of the flood routing in the small watersheds.

• 농업과학연구
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• 제3권1호
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• pp.105-119
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• 1976

Caramel 색소(色素)의 원료(原料) 대체(代替)를 위(爲)한 기초연구(基礎硏究)로서 자당(蔗糖), 포도당(葡萄糖), 전분당화액(澱粉糖化液) 및 전분질원료당화액(澱粉質原料糖化液)을 여러 가지 촉매하(觸媒下)에서 Caramel화(化) 시킨 다음 그 제품(製品)을 분석(分析)한 결과(結果)는 다음과 같다. 1. Sucrose syrup에 pH3.5가 되도록 산(酸)($H_2SO_4$)을 가(加)한 다음 Caramel화(化)하면 색력(色力)이 비교적(比較的) 강(强)하고 색조양호(色調良好)하며 내식염성(耐食鹽性), 내(耐)Tannin성(性) 및 내(耐)Alcohol성(性)이 강(强)한 품제(品製)이 되었다. 2. Sucrose syrup에 pH9.5가 되도록 Alkali($Na_2CO_3$)를 가(加)하여 Caramel화(化)한 제품(製品)은 색력(色力)이 매우 강(强)하나 적미(赤味)가 약간(若干) 떨어지며, 내(耐)Alcohol성(性)이 강(强)하였으나 내염성(耐鹽性) 및 내(耐)Tannin성(性)이 약(弱)하였다. 3. Sucrose syrup에 $NH_4Cl$ 및 $(NH_4)_2SO_4$와 같은 Ammonium의 강산염(强酸鹽)을 가(加)하여 Caramel화(化)하면 색력(色力)은 매우 강(强)하나 적미(赤味)가 부족(不足)하고 안정성(安定性)이 대단(大端)히 약(弱)한 제품(製品)이 되었으며 $(NH_4)_2CO_3$ 및 $(NH_4)_2SO_3$와 같은 Ammonium의 약산염(弱酸鹽)을 가(加)하였을때에는 색력(色力)이 비교적(比較的) 강(强)하고 색조양호(色調良好) 하며 내염성(耐鹽性) 및 내(耐)Alcohol이 강(强)하였으나 내(耐)Tannin성(性)은 약(弱)하였다. 4. Glucose syrup에 pH9.5에 달(達)하도록 Alkali($Na_2CO_3$)를 가(加)하여 Caramel화(化)하면 색력(色力)을 매우 강(强)하나 적미(赤味)는 떨어지고 내염성(耐鹽性) 및 내(耐)Alcohol은 강(强)하였으나 내(耐)Tannin성(性)은 약(弱)한 제품(製品)이 되었다. 5. Glucose syrup에 각종(各種) Ammonium염(鹽)을 첨가(添加)하고 Caramel화(化) 시켰을 때 $NH_4Cl$구(區)는 색력(色力)이 극(極)히 약(弱)하고 색조불량(色調不良)하며 내(耐)Tannin성(性)도 약(弱)한 제품(製品)이 되었으나 $(NH_4)_2CO_3$, $(NH_4)_2SO_4$, 및 $(NH_4)_2SO_3$ 구(區)는 모두 색력(色力)이 매우 강(强)하였으나 적미(赤味)는 떨어지고 내(耐)Tannin성(性)도 약(弱)하였으나 $(NH_4)_2SO_3$구(區)는 내염성(耐鹽性) 및 내(耐)Alcohol성(性), $(NH_4)_2SO_3$구(區)는 내(耐)Alcohol성(性), $(NH_4)_2SO_4$구(區)는 내염성(耐鹽性)이 강(强)하였다. 6. 각종전분(各種澱粉)의 산당화액(酸糖化液)을 산성하(酸性下)에서 $(NH_4)_2SO_4$를 첨가(添加)하여 Caramel화(化) 하였을 때 감자 전분당화액구(澱粉糖化液區)가 색력(色力)이 가장 강(强)하여 Glucose Caramel의 그것과 비숫한값(2.385)을 나타내었으며 다음이 고구마 전분당화액구(澱粉糖化液區)(1.665)이고 옥수수 전분당화액구(澱粉糖化液區)의 색력(色力)(0.90)이 가장 약(弱)하였으며 이들은 모두 내염성(耐鹽性)이 강(强)하고 내(耐)Tannin성(性) 및 내(耐)Alcohol성(性)이 약(弱)하였다. 7. 건조(乾燥) 분쇄(粉碎)한 고구마, 도토리, 및 굴발분말(粉末), 물로 7일간(日間) 추출(抽出), 경사(傾斜)시키거나 50% Alcohol 용액(溶液)에 24시간(時間) 추출과정(抽出過)한 도토리 및 굴밤분말(粉末)을 전분당화시(澱粉糖化時) 동일방법(同一方法)으로 산당화(酸糖化)시킨 다음 Caramel화(化)하여 그 제품(製品)을 분석(分析)한 결과(結果), 거의 대부분(大部分) 색력(色力)이 약(弱)하고 적미부족(赤味不足)하며 안정성(安定性)도 매우 떨어져, 전분(澱粉)의 분리(分離), 정제(精製), 또는 당액(糖液)의 정제(精製)가 선행(先行)되어야 할것으로 생각되었다.

• Applied Biological Chemistry
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• 제18권1호
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• pp.30-41
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• 1975

환경요인(環境要因)으로서 일광(日光), 미생물(微生物), 그리고 벼의 추출액(抽出液)에 존재(存在)하는 조효소(粗酵素)에 의(依)한 치환(置換) Diphenyl Ether계(系) 제초제(除草劑)의 일종(一種)인 MC-4379를 분해(分解)하여 그 분해산물(分解産物)을 TLC, GLC, IR등으로 분석확인(分析確認)하고 모화합물(母化合物)과 분해산물(分解産物)의 식물생육(植物生育)에 대(對)한 조해력(阻害力)을 시험(試驗) 하였다. 그 결과(結果)를 요약(要約)하면 다음과 같다. 1. MC-4379는 광분해(光分解) 결과(結果) amino-MC-4379, 2,4-dichloro-3'-carboxyl-4'-nitro-diphenyl ether, Nitrofen, 2,4-dichloro-3'-carboxyl-4'-amino-diphenyl ether, amino-Nitrofen, 3-carboxymethyl-4-nitrophenel, p-nitrophenol, p-aminophenol과 소량(少量)의 미지화합물(未知化合物)이 생성(生成) 되었고 모화합물(母化合物)은 대부분(大部分) 작용(作用)을 받지 않은 채로 남아 있었다. 또한 photosensitizer로 알려진 benzophenone을 가(加)하면 광분해(光分解)가 더욱 촉진(促進)됨을 확인(確認)하였다. 2. 조효소액(粗酵素液)에 의(依)한 MC-4379의 분해시(分解時)에는 Nitrofen과 소량(少量)의 미지화합물(未知化合物)이 확인(確認)되었으며 대부분(大部分)의 모화합물(母化合物)은 작용(作用)을 받지 않은 채로 존재(存在)하고 있음을 알 수 있었다. 3. Pseudomonas cruciviae와 Aspergillus ustus에 의(依)한 분해시(分解時)에는 Nitrofen과 amino-MC-4379 및 소량(少量)의 미지화합물(未知化合物)이 생성(生成)되었으며 대부분(大部分)은 작용(作用)을 받지않은 모화합물(母化合物)의 형태(形態)로 존재(存在)하였다. 4. MC-4379와 그 분해산물(分解産物) 및 타종(他種) Diphenyl Ether제초제(除草劑)가 식물(植物)의 생육(生育)에 미치는 조해력(阻害力)을 시험(試驗)한 결과(結果) 벼에 있어서는 이들 각화합물(各化合物)(1,000 ppm 유화액(乳化液))의 생육조해력(生育阻害力)은 p-nitrophenol> C-6989 > Nitrofen> amino-nitrofen> MC-4379의 순위(順位)이었고 대두(大豆)에 있어서는 Nitrofen> amino-Nitrofen>MC-4379 의 순위(順位)였다. 잡초중(雜草中) 비름(Amantus blitum)과 강아지풀(Setaria viridis)의 발아(發芽)된 종자(種子)를 사용(使用)하여 이들 화합물(化合物)(500ppm)의 현탁액중(懇濁液中)에서 생육(生育)시켜본 결과(結果) 3일후(日後)에 모두 고사(枯死)하는 현상(現象)을 관찰(觀察)할 수 있었다.

• Korean Chemical Engineering Research
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• 제45권2호
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• pp.117-123
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• 2007

농업용 필름을 제조하는데 사용되는 EVA 공중합체, LDPE, LLDPE 혼합물의 접촉 열분해 반응에 있어서 MCM-41 촉매에 aluminium을 첨가가 생성물의 수율, 탄소 수 분포 등에 미치는 영향을 조사하였다. Aluminium은 direct 및 post 방법으로 첨가하였고, 열분해 반응은 액상 접촉과 기상 접촉 반응 결과를 비교하였다. Direct 또는 post 방법으로 aluminium이 첨가된 MCM-41에서 aluminium 첨가량이 증가할수록 Lewis 산점이 증가하여 전체 산점의 양이 증가하였는데 post 방법으로 제조된 촉매에서 산점의 양이 더 많이 증가하였다. 액상 접촉 반응에서 aluminium의 양이 증가하면 가벼운 탄화수소가 많이 생기는데, $C_5-C_{12}$ 범위의 탄소화합물의 생성에 Al-MCM-41-P 촉매가 더 효과가 컸다. 기상 접촉 반응에서는 Al-MCM-41-D와 Al-MCM-41-P사이의 차이가 액상 접촉 반응시보다 상대적으로 적게 나타났으나, 액상접촉 반응에 비해 $C_{13}-C_{32}$ 범위의 탄화수소가 크게 감소했음을 알 수 있다.