• Journal of Korean Society for Atmospheric Environment
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• v.29 no.1
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• pp.74-85
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• 2013

Since the underground transportation system is a closed environment, indoor air quality problems may seriously affect many passengers' health. The purpose of this study was to understand $PM_{10}$ characteristics in the underground air environment and further to quantitatively estimate $PM_{10}$ source contributions in a Seoul Metropolitan subway station. The $PM_{10}$ was intensively collected on various filters with $PM_{10}$ aerosol samplers to obtain sufficient samples for its chemical analysis. Sampling was carried out in the M station on the Line-4 from April 21 to 28, July 13 to 21, and October 11 to 19 in the year of 2010 and January 11 to 17 in the year of 2011. The aerosol filter samples were then analyzed for metals, water soluble ions, and carbon components. The 29 chemical species (OC1, OC2, OC3, OC4, CC, PC, EC, Ag, Al, Ba, Cd, Cr, Cu, Fe, Mn, Ni, Pb, Si, Ti, V, Zn, $Cl^-$, $NO_3{^-}$, $SO_4{^{2-}}$, $Na^+$, $NH_4{^+}$, $K^+$, $Mg^{2+}$, $Ca^{2+}$) were analyzed by using ICP-AES, IC, and TOR after proper pretreatments of each sample filter. Based on the chemical information, positive matrix factorization (PMF) model was applied to identify the $PM_{10}$ sources and then six sources such as biomass burning, outdoor, vehicle, soil and road dust, secondary aerosol, ferrous, and brakewear related source were classified. The contributions rate of their sources in tunnel are 4.0%, 5.8%, 1.6%, 17.9%, 13.8% and 56.9% in order.

• Journal of Korean Society for Atmospheric Environment
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• v.23 no.6
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• pp.675-688
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• 2007

To characterize organic and elemental carbon (OC and EC), and water-soluble organic carbon (WSOC) contents, daily $PM_{2.5}$ measurements were performed in August 2006 (summer) and Jan $11{\sim}Feb$ 12 2007 (winter) at an urban site of Gwangju. Daily size-segregated aerosol samples were also collected for WSOC analysis. No clear seasonal variations in EC and WSOC concentrations were observed, while seasonal differences in OC concentration, and OC/EC and WSOC/EC ratios were shown. The WSOC/OC ratio showed higher value in summer (0.56) than in winter (0.40), reflecting the greater enhancement of secondary WSOC formation at the site in summer. Secondary WSOC concentrations estimated using EC tracer method were in the range $0.0{\sim}2.1\;{\mu}g/m^3$ (average $0.42\;{\mu}g/m^3$) and $0.0{\sim}1.1\;{\mu}g/m^3\;(0.24\;{\mu}g/m^3)$, respectively, accounting for $0{\sim}51.6%$ (average 16.8%) and $0{\sim}52.5%$ (average 13.1 %) of the measured WSOC concentrations in summer and winter. Sometimes higher WSOC/OC ratio in winter than that in summer could be attributed to two reasons. One is that the stable atmospheric condition often appears in winter, and the prolonged residence time would strengthen atmospheric oxidation of volatile organic compounds. The other is that decrease of ambient temperature in winter would enhance the condensation of volatile secondary WSOC on pre-existing aerosols. In summertime, atmospheric aerosols and WSOC concentrations showed bimodal size distributions, peaking at the size ranges $0.32{\sim}0.56\;{\mu}m$ (condensation mode) and $3.2{\sim}5.6\;{\mu}m$ (coarse mode), respectively. During the wintertime, atmospheric aerosols showed a bimodal character, while WSOC concentrations showed a unimodal pattern. Size distributions of atmospheric aerosols and WSOC with a peak in the size range $0.32{\sim}0.56\;{\mu}m$ were observed for most of the measurement periods. On January 17, however, atmospheric aerosols and WOSC exhibited size distributions with modal peaks in the size range $1.0{\sim}1.8\;{\mu}m$, suggesting that the aerosol particles collected on that day could be expected to be more aged, i.e, longer residence time, than the aerosols at other sampling periods.

• Particle and aerosol research
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• v.10 no.4
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• pp.169-176
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• 2014

Air samples were collected at various altitudes (from 165 to 1153 m) to observe vertical distribution of particulate PAHs concentrations using a very compact and light particle sampling package developed by Eun et al.(2013). TD-GC-MS developed by Hwang et al.(2014) was applied to PAHs analysis for effective analysis of PAHs contained trace amounts in the samples. The ranges of total PAHs concentrations were from 6.95 to $96.0ng\;m^{-3}$ on the ground and from 3.75 to $21.74ng\;m^{-3}$ at high altitude, respectively. All of particulate PAHs concentrations measured on the ground were higher than those measured at high altitude, while, the profile of individual PAH compounds between the ground and high altitude samples were similar. It means the distribution of particulate PAHs concentrations at high altitude were affected by the emission of PAHs emitted from ground.

• Journal of Korean Society for Atmospheric Environment
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• v.25 no.3
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• pp.219-236
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• 2009

Particle-phase organic tracers (molecular markers) have been shown to be an effective method to assess and quantify the impact of sources of carbonaceous aerosols. These molecular markers have been used in chemical mass balance (CMB) models to apportion primary sources of organic aerosols in regions where the major organic aerosol source categories have been identified. As in the case of all CMB models, all important sources of the tracer compounds must be included in a Molecular Marker CMB (MM-CMB) model or the MMCMB model can be subject to biases. To this end, the application of the MM-CMB models to locations where reasonably accurate emissions inventory of organic aerosols are not available, should be performed with extreme caution. Of great concern is the potential presence of industrial point sources that emit carbonaceous aerosols and have not been well characterized or inventoried. The current study demonstrates that emissions from industrial point sources in the St. Louis, Missouri area can greatly bias molecular marker CMB models if their emissions are not correctly addressed. At a sampling site in the greater St. Louis Area, carbonaceous aerosols from industrial point sources were found to be important source of carbonaceous aerosols during specific time periods in addition to common urban sources (i.e. mobile sources, wood burning, and road dust). Since source profiles for these industrial sources have not been properly characterized, method to identify time periods when point sources are impacting a sampling site, needs to avoid obtaining biases source apportionment results. The use of real time air pollution measurements, along with molecular marker measurements, as a screening tool to identify when point sources are impacting a receptor site is presented.

• Journal of Korean Society of Environmental Engineers
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• v.31 no.2
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• pp.153-160
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• 2009

A PM10 (aerodynamic diameter${\leq}$10 ${\mu}m$) sampler is used to quantify the potential human exposure to suspended particulate matter (PM) and to comply with the governmental regulation. This study was conducted to compare and evaluate the same PM10 cutpoint and different slopes between United States Environmental Protection Agency (USEPA) PM10 sampling criterion and American Conference of Governmental Industrial Hygienists/$Comit\acute{e}$ $Europ\acute{e}en$ de Normalization/International Organization for Standardization thoracic PM10 sampling criterion through theory and experiment. Four PM10 samplers according to the USEPA criterion and one RespiCon sampler in accordance with the thoracic PM10 criterion were used in the present study. In addition, one DustTrak monitor was used to measure real time PM10 mass concentrations. All six aerosol samplers were tested in a PM generation chamber using polydisperse fly ash. Theoretical mass concentrations were calculated by applying the measured particle size distribution characteristics (geometric mean = 6.6 ${\mu}m$, geometric standard deviation = 1.9) of fly ash to each sampling criterion. The measured mass concentrations through a chamber experiment were consistent with theoretical mass concentrations in that a RespiCon sampler with the thoracic PM10 criterion collected less PM than a PM10 sampler with the USEPA criterion. The overall chamber experiment results indicated, when a PM10 sampler was used as a reference sampler, that (1) a RespiCon sampler had a normalizing factor of 1.6, meaning that this sampler underestimated an average 60% of PM10 mass sampled from a PM10 sampler, and (2) a DustTrak real-time monitor using a PM10 inlet had a calibration factor of 2.1.

• Journal of Korean Society for Atmospheric Environment
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• v.19 no.E1
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• pp.11-20
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• 2003

To characterize airborne particulate carbon and its temporal variation in the heavily industrialized metropolitan city, Seoul in South Korea, aerosol sampling was performed from 1986 to 1996. Correlation coefficients of elemental carbon (EC) and organic carbon (OC) with mass concentration of fine particles ($\underline{\leq}$2.1 ${\mu}m$) are 0.73 and 0.51, respectively. EC concentrations of the fine particle mode are 10.1, 5.9, 4.5, and 7.4 ${\mu}g\;m^{-3}$ in winter, spring, summer, and autumn, respectively. On the other hand, OC concentration shows maximum value in winter and followed by autumn, summer, and spring. A seasonal peak in the ratio of OC to EC in fine particles was observed during the summer photochemical season from June to August. Concentrations of EC and OC in Asian dust storm events are generally higher than in non- Asian dust storm events except in 1990. The difference of EC concentrations between Asian dust storm periods and non-Asian dust storm periods are much larger than those of OC concentrations. There are slight increases of EC concentration between 1987 and 1990 and a gradual decrease between 1990 and 1996.

• Journal of Korean Society for Atmospheric Environment
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• v.16 no.E
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• pp.29-38
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• 2000

For the detailed characterization of atmospheric aerosol, the analysis of single particle is highly valuable. In this study, to investigate the characteristics of single Asian dust storm particles, scanning electron microscope(SEM) coupled with and energy dispersive X-ray microanalyzer(EDX) and micro-PIXE were applied. Sampling was performed at Kyoto University located in Kyoto, Japan, in spring of 1999. Mass concentration during Asian dust storm events was higher roughly 3∼5 times than measured in the season of the highest concentration. Single particles were generally sharp-edged and irregular in shape and contained mostly crustal elements. Significant amount of S in coarse fraction was detected in individual particles. A large particles in coarse fraction existed as the mixture of soil components and S. A good agreement between the result of SEM-EDX analysis and that iof micro-PIXE analysis was obtained in this study.

• Bulletin of the Korean Chemical Society
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• v.29 no.8
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• pp.1525-1532
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• 2008

An instrument was developed for the simultaneous determination of gas- and aerosol-phase nitrous acid (HONO). Gaseous HONO (HONO(g)) was sampled by a diffusion scrubber and particulate nitrite ($NO_2\;^-$(p)) was collected by a particle growth chamber. The collected samples were analyzed in time-sharing manner, based on the peroxynitrite-induced luminol chemiluminescence. The automated system was found to be sensitive with 13 pptv of detection limit, fast with 4 min. of sampling frequency, and simple and affordable to construct and operate. The system was optimized by adjusting the experimental parameters. The system was applied to the field measurement of gas- and particle-phase HONO during the springtime of 2004 in Gwangju, South Korea. HONO(g) concentrations varied diurnally from 200 pptv around 3 P.M. to 800 pptv at 5 A.M. The variation of $NO_2\;^-$(p) was not significant with the maximum of 240 pptv at 11 P.M. and the minimum of 170 pptv at 4 P.M., not displaying distinct characteristics.

• Journal of Korean Society for Atmospheric Environment
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• v.20 no.1
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• pp.17-31
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• 2004

The subway play an important part in serious traffic problems. However, because subway system is a closed environment, many serious air pollution problems occurred in subway stations and injured passenger's health. Therefor, it is a necessary to identify sources and to estimate pollutant sources in order to protect passenger's health and to keep clean subway environment. The purpose of this study was to analyze a air quality in the subway stations and to apply a new receptor methodology for quantitatively estimate of PM10 sources. In this study, the size distributions of particulate matters has been measured by using Aerosizer LD (U.S.A., API, Inc.). It's real time measurement capability of time-of-flight technique offers a significant advantage of user convenience and air pollution management. Also, the mass concentrations of PM 10 has been measured by using mini-vol portable sampler (U.S.A., Airmetrics Co.). The sampling performed in Seoul subway stations during the period of February 2000 and April 2000. The number distribution data used in this study consisted of 26 raw data sets in the Jongno-sam-ga station. Correlation Analysis can be used in subway stations for source separation and identification. Then, number contribution from each source is determined by the particle number balance (PNB). The mass concentration data used in this study consisted of 31 raw data in the 8 different stations. The mass contributions of PM10 sources in the concourse by using PMF/CMB model.

• Asian Journal of Atmospheric Environment
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• v.7 no.3
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• pp.152-160
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• 2013

Seven potentially harmful bifunctional carbonyls were measured in particulate and gaseous phases at a roadside site and a suburban site in an area about 30 km north-northwest from Tokyo metropolitan area in the Kanto region in Japan. For the first time, these compounds were measured in both phases with a time resolution of 2 h. We found that wind direction is an important parameter that affects the collection of these compounds near the source, and it can cover the effects of other important variables. Our results confirmed that motor vehicles and especially diesel fuelled vehicles are important sources of these compounds. Photochemical generation is also an important source of these compounds in the gaseous phase. Transportation from the urban area is also important, particularly in the aerosol phase.