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Effects of Oxygen Annealing of MgO Thin Films on the Phase Formation and the Electrical Properties of PZT/MgO/Si Structure

  • Song, Han-Wook;No, Kwang-Soo
    • The Korean Journal of Ceramics
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    • v.6 no.1
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    • pp.68-73
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    • 2000
  • The effects of oxygen annealing on the carbon content in MgO thin films were investigated, MgO thin films were deposited on Si(100) substrate at different temperatures of 400 to $700^{\circ}C$ and different deposition rates of 3.4 to 11.6$\AA$/min. Using rf magnetron sputtering method. Carbon content change on the surface of MgO thin films with the oxygen annealing at different temperatures was investigated using various method. The carbon content decreased as the annealing temperature increased. $Pb(Zr_{0.53}Ti_{0.47})O_3$(PZT) thin films were deposited on the MgO/Si(100) substrates. The effects of carbon content on the phase formation and the electrical properties of PZT thin films were also investigated.

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Effect of Se Flux and Se Treatment on the Photovoltaic Performance of β-CIGS Solar Cells

  • Kim, Ji Hye;Cha, Eun Seok;Park, Byong Guk;Ahn, Byung Tae
    • Current Photovoltaic Research
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    • v.3 no.2
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    • pp.39-44
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    • 2015
  • $Cu(In,Ga)_3Se_5$ (${\beta}-CIGS$) has a band gap of 1.35 eV which is an optimum value for high solar-energy conversion efficiency. However, ${\beta}-CIGS$ film was not well characterized yet due to lower efficiency compared to $Cu(In,Ga)Se_2$ (${\alpha}-CIGS$). In this work, ${\beta}-CIGS$ films were fabricated by a three-stage co-evaporation of elemental sources with various Se fluxes. As the Se flux increased, the crystallinity of ${\beta}-CIGS$ phase was improved from the analysis of Raman spectroscopy and a deep-level defect was reduced from the analysis of photoluminescence spectroscopy. A Se treatment of the ${\beta}-CIGS$ film at $200^{\circ}C$ increased Ga content and decreased Cu content at the surface of the film. With the Se treatment at $200^{\circ}C$, the cell efficiency was greatly improved for the CIGS films prepared with low Se flux due to the increase of short-circuit current and fill factor. It was found that the main reason of performance improvement was lower Cu content at the surface instead of higher Ga content.

Study on the Changes in Phyicochemical Propertiesof Seafood Cooking Drips by Gamma Ray Irradiation (수산 자숙액의 감마선 조사에 의한 이화학적 물성 변화 평가)

  • Choi, Jong-il;Kim, Yeon-Joo;Kim, Jae-Hun;Yoon, Yohan;Song, Beom-Seok;Chun, Byung-soo;Ahn, Dong-Hyun;Lee, Ju-Yeoun;Lee, Ju-Woon
    • Journal of Radiation Industry
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    • v.4 no.1
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    • pp.53-57
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    • 2010
  • Cooking drips which were obtained as by-product after seafood processing in the food industries, still contain lots of proteins, carbohydrates, and other functional materials. But, the seafood cooking drips are easily contaminated because of its rich nutrients, and their color are very dark. This study was conducted to investigate the effect of gamma irradiation on the quality of seafood cooking drips including Hizikia fusiformis, Enteroctopus dofleini, and Thunnus thynnus. The Hunter's color values (L, Brightness) of H. fusiformis, and T. thynnus were increased with increasing irradiation doses, showing becoming bright. The crude protein content and crude lipid content were increased by gamma irradiation. These results indicated that gamma irradiation increased extraction efficiency of available compounds in cooking drips.

Polymerizations of Propylene with Unsymmetrical ($\alpha$-Diimine)nickel(II) Catalysts

  • Jeon Man-Seong;Han Chul-Jong;Kim Sang-Youl
    • Macromolecular Research
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    • v.14 no.3
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    • pp.306-311
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    • 2006
  • New unsymmetrical ($\alpha$-Diimine)nickel(II) catalysts having different pendent groups at the ortho positions on aromatic rings were synthesized and subjected to propylene polymerizations with MAO (methylaluminoxane). Structural analyses of the resulting polypropylenes by $^1H\;and\;^{13}C\;NMR$ showed that the ortho substituents on aromatic rings of ($\alpha$-diimine)nickel(II) catalyst affected significantly the polypropylene microstructure. While $C_s$ symmetric catalyst afforded a syndiotactic polypropylene (rr triad content=66%) due to the syndiospecific chain end control, $C_1$ symmetric catalysts produced much less stereoregular polypropylenes (rr triads content <50%), presumably because of collision of the isospecific site control with the syndiospecific chain end control.

Synthesis of Mesoporous Carbons with Controllable N-Content and Their Supercapacitor Properties

  • Kim, Jeong-Nam;Choi, Min-Kee;Ryoo, Ryong
    • Bulletin of the Korean Chemical Society
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    • v.29 no.2
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    • pp.413-416
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    • 2008
  • A synthesis route to ordered mesoporous carbons with controllable nitrogen content has been developed for high-performance EDLC electrodes. Nitrogen-doped ordered mesoporous carbons (denoted as NMC) were prepared by carbonizing a mixture of two different carbon sources within the mesoporous silica designated by KIT-6. Furfuryl alcohol was used as a primary carbon precursor, and melamine as a nitrogen dopant. This synthesis procedure gave cubic Ia3d mesoporous carbons containing nitrogen as much as 13%. The carbon exhibited a narrow pore size distribution centered at 3-4 nm with large pore volume (0.6-1 cm3 g-1) and high specific BET surface area (700-1000 m2 g-1). Electrochemical behaviors of the NMC samples with various N-contents were investigated by a two-electrode measurement system at aqueous solutions. At low current density, the NMC exhibited markedly increasing capacitance due to the increase in the nitrogen content. This result could be attributed to the enhanced surface affinity between carbon electrode and electrolyte ions due to the hydrophilic nitrogen functional groups. At high current density conditions, the NMC samples exhibited decreasing specific capacitance against the increase in the nitrogen content. The loss of the capacitance with the N-content may be explained by high electric resistance which causes a significant IR drop at high current densities. The present results indicate that the optimal nitrogen content is required for achieving high power and high energy density simultaneously.

Effects of Diffusible Hydrogen Content and Hardness on Cold Cracking in High Strength Weld Metal (고강도강 용접금속 저온균열 발생에 미치는 확산성수소량 및 경도의 영향)

  • Seo, Won-Chan;Bang, Kook-Soo
    • Journal of Ocean Engineering and Technology
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    • v.26 no.2
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    • pp.33-38
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    • 2012
  • The effects of the diffusible hydrogen content and hardness on the cold cracking in high strength weld metal were investigated. The diffusible hydrogen contents were influenced by welding parameters such as the voltage and contact tip-to-work distance (CTWD). The diffusible hydrogen content increased with an increase in voltage. However, it was decreased with an increase in CTWD. CTWD also influenced the weld metal hardness,especially when the wire used had a higher strength than the base metal. This showed that weld metal hardness had a more powerful effect on weld metal cold cracking than the diffusible hydrogen content in this experiment.

A Web-Based IPTV Content Syndication System for Personalized Content Guide

  • Yang, Jinhong;Park, Hyojin;Lee, Gyu Myoung;Choi, Jun Kyun
    • Journal of Communications and Networks
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    • v.17 no.1
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    • pp.67-74
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    • 2015
  • In this paper, we propose a web-based content syndication system in which users can easily choose Internet protocol television (IPTV) contents. This system generates personalized content guide to provide a list of IPTV contents with respect to users' interests and statistics information of their online social community. For this, IPTV contents and relevant metadata are collected from various sources and transformed. Then, the service and content metadata are processed by user metadata including audience measurement and community metadata. The metadata flows are separated from content flows of transport network. The implementation of IPTV content syndication system demonstrates how to arrange IPTV contents efficiently from content providers to the end user's screen. We also show that the user metadata including online community information are important for the system's performance and the user's satisfaction.

The Characteristics of Sulfur Electrode with Carbon Nanotube

  • Ryu, Ho-Suk;Lee, Sang-Won;Kim, Ki-Won;Ahn, Joo-Hyun;Cho, Kwon-Koo;Cho, Gyu-Bong;Ahn, Hyo-Jun
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.1216-1217
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    • 2006
  • We investigated on the additive effect of carbon nanotube in the sulfur electrode on the first discharge curve and cycling property of lithium/sulfur cell. The sulfur electrode with carbon nanotube had two discharge plateau potentials and the first discharge capacity about 1200 mAh/g sulfur. The addition carbon nanotube into the sulfur electrode did not affect the first discharge behavior, but improved the cycling property of lithium/sulfur cell. The optimum content of carbon nanotube was 6 wt% of sulfur electrode

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Effect of KF Treatment of Cu(In,Ga)Se2 Thin Films on the Photovoltaic Properties of CIGS Solar Cells (Cu(In,Ga)Se2 박막의 KF 처리가 CIGS태양전지에 미치는 영향)

  • Jeong, Gwang Sun;Cha, Eun Seok;Moon, Sun Hong;Ahn, Byung Tae
    • Current Photovoltaic Research
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    • v.3 no.2
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    • pp.65-70
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    • 2015
  • We applied KF on CIGS film to modify CIGS surface with a wider-bandgap surface layer. With the KF deposition the surface of CIGS film had fine particle on the CIGS surface at 350 and $300^{\circ}C$. No fine particle was detected at 500 and $250^{\circ}C$. With the KF treatment, the Ga and O content increased at the surface, while the In and Cu content decreased. The valence band maximum was lowered with KF treatment. The composition profile and band structure were positive side of applying KF on the CIGS surface. However, the efficiency decreased with the KF treatment due to high series resistance, probably due to too thick surface layer. A smaller amount of KF should be supplied and more systematic analysis is necessary to obtain a reproducible higher efficiency CIGS solar cells.

Effect of the Oxide Glass on the Metal Sintering Behavior in Silver Thick-Film System

  • Chung Young Sir;Kim Ho-Gi
    • Proceedings of the Korean Ceranic Society Conference
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    • 1986.12a
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    • pp.259-267
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    • 1986
  • The sintering behavior of silver-oxide glass composite thick-film has been studied with varing glass content. It is shown that during heat treatment glass became liquid phase to deeply affect the microstructure development of the silver particles and to control the physical properties of the thick-films. As glass content increased, the initial repacking of silver particles took place rapidly but the homogeneities of the microstructure showed different features. When the glass content was over some range, the silver particles exuded glass to decrease net energy and glass formed liquid pools separated from the solid skeletons. Finally the relations between the microstructures and electrical properties of the thick-film were discussed.

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