• Environmental Engineering Research
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• 제22권3호
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• pp.255-265
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• 2017

Polyelectrolytes are commonly used as flocculants in drinking water treatment. However the growing concerns about their toxicity have motivated the search for biocompatible flocculants. Here, we show that gelatin, a natural amphoteric polyelectrolyte, can be effectively adsorbed on clay surfaces and can potentially be a suitable substitute for existing flocculants. The adsorption of gelatin from its aqueous solution onto the mineral clay surfaces at different conditions was systematically investigated using the design of experiments methodology. The gelatin adsorption was found to vary considerately with pH variation showed a maximum adsorption at its isoelectric point. The amount of adsorbed gelation increased with increasing pH from 3 to 5, attained a maximum at pH 5 and then decreased with increasing pH from 5 to 11. Similarly, the amount of adsorbed gelatin showed decreasing trends around salt concentration of 0.05 M and temperature $35^{\circ}C$. On the other hand, the adsorption was continuously increased with time and polymer concentration in the range of 0.1-0.9 mg/dL. Finally, the jar tests confirmed the ability of gelatin for using a natural flocculant for water treatment.

• Journal of Electrochemical Science and Technology
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• 제7권2호
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• pp.153-160
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• 2016

The inhibition ability of N,N-bis(2,4-dihydroxyhydroxybenzaldehyde)-1,3-Propandiimine (DHBP) as a schiff base against the corrosion of API-5L-X65 steel in 1 M HCl solution was evaluated by electrochemical impedance spectroscopy, potentiodynamic polarization and scanning electron microscopy. Electrochemical impedance studies indicated that DHBP inhibited corrosion by blocking the active corrosion sites. The inhibition efficiency increased with increasing inhibitor concentrations. EIS data was analysed to equivalent circuit model and showed that the charge transfer resistance of steel increased with increasing inhibitor concentration whilst the double layer capacitance decreased. The adsorption of this compound obeyed the Langmuir adsorption isotherm. Gibbs free energy of adsorption was calculated and indicated that adsorption occurred through physical and spontaneous process. The corrosion inhibition mechanism was studied by potential of zero charge. Polarization studies indicated that DHBP retards both the cathodic and anodic reactions through adsorption on steel surface. Scanning electron microscopy was used to study the steel surface with and without inhibitor.

• 한국염색가공학회지
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• 제13권1호
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• pp.38-44
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• 2001

The adsorption ability of dyes on chitin, a natural polymer was investigated for decolorization of dye wastewater. Chitin was manufactured in lab by decalcification in dilute aqueous hydrochloric acid solution and deproteination in dilute aqueous sodium hydroxide solution with shrimp shells. Absorbance of residue solution of dyebaths after dye adsorptions of chtin were measured in varieties of dye concentration and dipping periods. Three kinds of Direct dyes -C.I. Direct Red 81 (red 81), C.I. Direct Brown l(brown 1) and C.I. Direct Green 26(green 26) - were used. Red 81 and brown 1 have smaller molecular weight than green 26. The results from experimentals were of]tamed as follows: 1) Adsorption of green 26 was improved in dyebath by addition of salt, but red 81 and brown 1 were not found any improvements. 2) Smaller size of chitin particles could be absorbed much more speedy. In this experiments, the smallest range of chitin particle size was $250\mu{m}$ and less. 3) The most efficient amount of chitin for 20m1 of dyebath was 0.2g, 4) Both of red 81 and brown 1 showed good and speedy adsorption abilities as dyestuffs of over 90 percent in just one minute in dyebath of 0.01% dye concentration. But green 26 was absorbed slowly because of its large molecular weight. It took 40minutes to absorb dyestuffs of over 90 percent in dyebath of 0.01% dye concentration.

• Advances in environmental research
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• 제4권1호
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• pp.49-68
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• 2015

Chemically activated and carbonized adsorbents were prepared from Moringa oleifera pod husks (MOP), characterized and evaluated for their ability to remove a common antibiotic - ofloxacin (OFX) from aqueous solution. The pulverized precursor was steeped in a saturated ammonium chloride solution for a day to give the chemically activated adsorbent (AMOP). A portion of AMOP was pyrolyzed in a muffle furnace at 623 K for 30 min to furnish its carbonized analogue (CMOP). The adsorbents showed favorable physicochemical attributes. The effects of operational parameters such as initial OFX solution pH and concentration, adsorbent dosage, temperature and contact time on OFX removal were investigated. At equilibrium, optimal removal efficiencies of 90.98% and 99.84% were achieved at solution pH 5 for AMOP and CMOP, respectively. The equilibrium adsorption data fitted into both the Langmuir and Freundlich isotherms. Gibbs free energy change (${\Delta}G^o$), enthalpy change (${\Delta}H^o$) and entropy change (${\Delta}S^o$) indicated that the adsorption of OFX was feasible, spontaneous, exothermic and occurred via the physisorption mode. Adsorption kinetics obeyed the Blanchard pseudo-second-order model. The results may find applications in the adsorptive removal of micro-contaminants of pharmaceutical origin from wastewater.

• 방사선산업학회지
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• 제9권3호
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• pp.127-130
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• 2015

Since the accident at the Fukushima Daiichi power plant, Prussian blue (PB) has attracted increasing attention as a material for use in decontaminating the environment. We have focused the fundamental mechanism of specific $Cs^+$ adsorption into PB in order to develop high-performance PB-based $Cs^+$ adsorbents. The ability of PB to adsorb Cs varies considerably according to its origin such as what synthesis method was used, and under what conditions the PB was prepared. It has been commonly accepted that the exclusive abilities of PB to adsorb hydrated $Cs^+$ ions are caused by regular lattice spaces surrounded by cyanido-bridged metals. $Cs^+$ ions are trapped by simple physical adsorption in the regular lattice spaces of PB. $Cs^+$ ions are exclusively trapped by chemical adsorption via the hydrophilic lattice defect sites with proton-exchange from the coordination water. Prussian blue are believed to hold great promise for the clean-up of $^{137}Cs$ contaminated water around nuclear facilities and/or after nuclear accidents.

• 한국산업융합학회 논문집
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• 제27권4_2호
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• pp.981-989
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• 2024

In recent years, there has been a growing focus on preserving the global environment and utilizing resources efficiently. The significance of energy conservation has led to the development of systems that recycle waste heat from factories and use eco-friendly refrigerants. This study aims to enhance the performance of adsorption-desorption systems using thermoelectric devices, which are known for their ability to convert temperature differences into electrical energy. The research focuses on improving the efficiency of these systems by integrating thermoelectric modules to cool the adsorption side and heat the desorption side, thus enhancing overall system performance. The experiments utilized a typical thermoelectric device and silica gel as the adsorbent. Key experimental parameters included varying the inlet air temperature and relative humidity on the desorption side. The results indicated that increasing the relative humidity of the inlet air on the desorption side significantly enhanced the overall mass transfer coefficient while reducing the completion time of the process. Similarly, higher inlet air temperatures led to an increase in the mass transfer coefficient and a decrease in process completion time. These findings suggest that optimizing the operational conditions of thermoelectric devices can substantially improve the performance of adsorption-desorption systems, offering potential benefits for applications in ventilation systems and other related fields.

• KIEAE Journal
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• 제12권5호
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• pp.71-76
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• 2012

As reviewed of developments of Korean earth architecture, earth-made buildings have been dwindled gradually since "the new community movement" and earth have been recognized as materials which are not so good to human health and in result, earth-related techniques have been also forgotten. However, recently the earth architecture has been more attracting back many attentions thanks to the people who are interested in health and wellbeing and the earth related techniques or skills got keenly required. The present study has investigated and reproduced earth finishing materials which are based on natural materials as basic stuffs to use them as the finishing materials of the modern earth architecture. For the test, the finishing materials have been divided roughly into sorts of pastes and oils. In case of applying finishing materials onto earth surfaces, the moisture permeability test was conducted to measure a water-absorbing speed, and at the case of using finishing materials for interior works moisture adsorption/desorption test was performed to verify the indoor humidity regulation ability, and further a test to check whether to be stained when contacted with the finishing materials, was conducted. If there is not any stain it might be recognized to be high quality of moisture adsorption/desorption and so seaweed pastes or starches might be used for paste finishing materials and for natural oils, beans are desirable in practical ways. As low-quantity of moisture adsorption materials, linseed oil is most desirable and also beaned water over75% are thought to be useful.

• 대한환경공학회지
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• 제27권6호
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• pp.620-625
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• 2005

연속식 흡착장치를 사용하여 활성탄의 세공구조와 아세톤 중기의 흡착특성과의 상관관계를 고찰하였다. 실험에서 비교한 활성탄 중 젠체 세공구조에서 직경 $10{\AA}$ 이하의 세공이 가장 많이 발달한 Takeda의 ACT 활성탄이 가장 긴 파과시간을 가지고 있었다. 평형흡착량은 파과시간에는 비례했지만, BET 비표면적에는 비례한다고 볼 수 없었기 때문에 BET 비표면적 만으로 흡착능을 평가하는 것은 어려웠다. 누적표면적과 평형흡착량과의 상관관계는 $10{\AA}$ 이하에서 가장 컸고, 세공범위가 클수록 감소했다.

• Korean Chemical Engineering Research
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• 제58권4호
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• pp.624-634
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• 2020

The ability of natural and modified clay to adsorb phenol was studied. The clay samples were analyzed by different technical instruments, such as X-ray fluorescence (XRF), X-ray diffraction (XRD) and FT-IR spectroscopy. Surface area, pore volume and average pore diameter were also determined using B.E.T method. Up to 73 and 99% of phenol was successfully adsorbed by natural and activated clay, respectively, from the aqueous solution. The experiments carried out show that the time required to reach the equilibrium of phenol adsorption on all the samples is very close to 60 min. The amount of phenol adsorbed shows a declining trend with higher pH as well as with lower pH, with most extreme elimination of phenol at pH 4. The adsorption of phenol increases proportionally with the initial phenol concentration. The maximum adsorption capacity at 25 ℃ and pH 4 was 29.661 mg/g for modified clay (NaMt). However, the effect of temperature on phenol adsorption was not significant. The simple modification causes the formation of smaller pores in the solid particles, resulting in a higher surface area of NaMt. The equilibrium results in aqueous systems were well fitted by the Freundlich isotherm equation (R² > 0.98). Kinetic studies showed that the adsorption process is best described by the pseudo-second-order kinetics (R² > 0.99). The adsorption of phenol on natural and modified clay was spontaneous and exothermal.

• Korean Chemical Engineering Research
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• 제44권4호
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• pp.393-398
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• 2006

고농도의 1-부텐을 생산하기 위하여 흡착 분리제의 개발이 필수적인데, 본 연구에서는 메조포러스 실리케이트인 MCM-41을 지지체로 하여 $AgNO_3$를 함침시켜 흡착제를 제조한 후, 1-부텐과 n-부탄의 흡착 특성을 연구하였다. 또한, 열처리 조건에 따른 $Ag^+$ 이온의 형성 비율과 1-부텐의 결합 능력을 알아보았다. MCM-41 흡착제의 경우, 13X 제올라 이트에 비하여 매우 높은 흡착량을 보여주었으며, 은이 담지되었을 때, n-부탄의 흡착량은 감소하는 반면에 1-부텐의 흡착량은 증가함으로써 1-부텐과 n-부탄의 흡착 분리에 매우 좋은 성능을 갖음을 확인할 수 있었다. 또한, 진공 분위기에서 373 K로 열처리한 Ag/MCM-41의 경우 가장 높은 1-부텐/n-부탄 흡착비를 보였으며, 특히 저압에서 매우 높은흡착비를 보여주었다.