• Title/Summary/Keyword: adsorbed amount

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Characteristics of methane sorption in surface modified activated carbon (표면개질 된 활성탄의 메탄흡장 특성)

  • Yun, Seok-Min;Kim, Ju-Wan;Jo, Won-Jun;Kim, Young-Ho;Lee, Young-Seak
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.73-76
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    • 2007
  • In this study, methane gas adsorption ability of activated carbon (AC) with surface functional group effect, adsorbed methane amount was evaluated after nitric acid and ureatreatment of AC surface. Specific surface area and pore distribution of AC were studied though nitrogen adsorption isotherm at 77 K. Micro pore volume was calculated through H-K method. Adsorbed methane amount was evaluated through volume method at room temperature by using auto adsorption apparatus. Adsorbed methane amount of AC was found to increase with to specific surface area increase.Correlation proposed between the methane adsorption amount and surface nature indicates that the surface nature plays an important role on the adsorption amount at a given temperature.

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Dyeing Behavior of Silk Dyed with Indigo Leaf Powder Using Reduction and Nonreduction Dyeing and Its Relationship with the Amount of Indigotin and Indirubin Adsorbed in Silk

  • Yoo, Wansong;Ahn, Cheunsoon
    • Journal of the Korean Society of Clothing and Textiles
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    • v.43 no.5
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    • pp.753-767
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    • 2019
  • Dyeing behavior of indigo leaf powder was examined in regards to the effect of the amount of pigments on color and dye adsorption for silk dyed by reduction and nonreduction dyeing. The amount of indigotin and indirubin pigments adsorbed in dyed silk was examined by HPLC-DAD analysis. The color of dyed silk showed 7.7BG - 2.7B hue when silk was dyed at $50^{\circ}C$, and 3.5G - 4.9BG when dyed at $70^{\circ}C$. Blue ($b^*$) and green ($a^*$) color decreased as the pH of dyebath increased. When silk was dyed using nonreduction, R (red) and RP (red purple) hue and R hue was more apparent in samples dyed at $90^{\circ}C$. In reduction dyeing, amount of indigotin detected from silk exceeded the amount that was initially contained in the input dye. The amount of indirubin was lower than indirubin that was initially in the powder. In nonreduction dyeing, silk showed a higher amount of indirubin adsorption compared to silk dyed by reduction. The amount of indigotin adsorbed in silk was lower than the amount initially contained in the input dye. The amount of indigotin and indirubin adsorption was primarily dependent upon the dyeing method-reduction or nonreduction along with dyeing temperature and the pH of dyebath.

Adsorption of cationic birchwood xylan on Hw-BKP and its effect on paper properties (양이온성 자일란의 Hw-BKP에의 흡착특성과 이에 따른 종이 물성 변화)

  • Lee, Sang-Hoon;Lee, Hak-Lae;Youn, Hye-Jung;Xiang, Zhu Hong
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.42 no.2
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    • pp.1-11
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    • 2010
  • The possibility of applying birchwood xylan in papermaking process to improve dry strength of paper was investigated. Unmodified xylan barely adsorbed onto pulp fibers while cationically modified xylan adsorbed substantially. Adsorption of cationically modified xylan by quaternarization with 3-chloro-2-hydroxypropy trimethylammonium chloride improved dry strength of paper. Chemical structure and degree of substitution of the cationically modified xylan was determined by 400 MHz 13CNMR spectroscopy and elemental analyzer. The amount of adsorbed xylan on cellulose fibers was greater when the cationicity was moderate, and it was interpreted that the conformation of this cationic xylan adsorbed on fiber surface was more favorable for greater adsorption due to its greater loop formation tendency while highly cationic xylan tends to adsorbed in stretched conformation. The physical properties of handsheets increased as the amount of adsorbed cationic xylan increased. On the other hands, the optical properties decreased with xylan adsorption.

The Adsorption of Phosphate Son Using Hydroxyapatite synthesized by Wastewater Sludge of Semiconductor Fabrication Process (반도체 제조공정의 폐수슬러지로 합성된 Hydroxyapatite를 이용한 인산이온의 흡착)

  • 강전택;정기호;신학기
    • Journal of Environmental Science International
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    • v.11 no.3
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    • pp.257-262
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    • 2002
  • The hydroxyapatite(HAp) for the present study was prepared with the wastewater sludge from semiconductor fabrication process and it was crystallized in an electric furnace for 30 min at 90$0^{\circ}C$. The adsorption characteristics of HAp for phosphate ion in aqueous solution has been investigated. The adsorbed ratio of phosphate ion for HAp were investigated according to the reaction time, amount of HAp, concentration of standard solution, pH of solution, and influence of concomitant ions. The amount of adsorbed phosphate ion decreased with the increase of pH due to the mutual electrostatic repulsion between adsorbed phosphate ions and competitive adsorption between phosphate ion and OH- ion in aqueous solution. The maxium amount of the adsorption equilibrium for phosphate ion was about 24 mg/g of HAp. The HAp would likely to be a possible adsorbent for the removal of phosphate ion in the waste water.

Effect of Light Metal Ions and Competition among Heavy Metal Ions during the Adsorption of Heavy Metal Ions by Bark (수피에 의한 중금속 흡착시 경금속의 영향과 중금속간의 흡착 경쟁)

  • Paik, Ki-Hyon;Kim, Dong-Ho;Choi, Don-Ha
    • Korean Journal of Environmental Agriculture
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    • v.16 no.2
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    • pp.115-118
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    • 1997
  • When the light metals such as $Ca^{++}$ and $Mg^{++}$ were added to heavy metal solution, the adsorption of heavy metals was increased by 20 to 30% more, but there were no differences between species. $Pb^{++}$ was the most adsorbed metal(99.5%), and the adsorption ratio of $Cd^{++}$ was significantly improved. In addition, when the light metal concentration was increased to 100ppm, the adsoption ratios of all four heavy metals were reached to 92 to 99%, while coniferous barks showed only 85 to 92%. On the mixture of four heavy metals, the adsorbed amount of each metal was significantly reduced, compared with that of one heavy metal, while $Zn^{++}$ showed the adsorption improvement to 95%. On the column experiment, $Pb^{++}$ was almost completely adsorbed in the upper part of column, and the adsorbed amount of $Cu^{++}$ was gradually decreased depending on column depth. However, $Cd^{++}$ and $Zn^{++}$ were not influenced by column height, and constantly adsorbed on various column height. Based on the above results, each heavy metal had different adsorption mechanism.

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Adsorption of $\textrm{Pb}_{2+}$ in the components of bacterial cell membrane

  • Kim, Mal-Nam
    • Journal of Microbiology
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    • v.33 no.4
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    • pp.278-282
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    • 1995
  • S. epidermidis cell was fractionated into cell wall, cell membrane and cytoplasm. The cell membrane adsorbed the most abundant $\textrm{Pb}_{2+}$ per unit dry weight of the three fractions tested. Adsorption behavior of $\textrm{Pb}_{2+}$ in lipid and protein, which are the main components of the cell membrane, indicated that phosphatidylethanolamine and phosphatidylinositol having phosphoryl group and gangliosides containing carboxyl groups adsorbed much more $\textrm{Pb}_{2+}$ than triglycerides lacking any chargeable functional groups. Protein purified from cell membrane adsorbed larger amount of $\textrm{Pb}_{2+}$ than total native cell membrane or cell membrane lipid.

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A Fundamental Study for The Possibility of Charcoal as Green Infrastructure Materials

  • Choi, Jaehyuck;Shin, Soo-Jeong;Kim, Byung-Ro
    • Journal of the Korean Wood Science and Technology
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    • v.43 no.5
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    • pp.691-699
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    • 2015
  • To evaluate the possibility of charcoal as Green Infrastructure (GI) materials, data such as moisture content, amount of adsorbed water, and amount of evaporation were collected. Some data from previous study were referenced to find out if correlations exist between results in this study and previous study. Only porosity was directly related to moisture content. Two mechanical charcoal had better abilities than traditional charcoal in all three categories. Mechanical black charcoal chips produced by National Forestry Cooperative Federation (NFCFC) adsorbed 333.3% of water in thirty minutes, 297.5% in five minutes, and evaporated around 75% water in four days. This ability is much higher than other five charcoal. Even though results of test showed various degrees and NFCFC was the best as GI materials, data of charcoal were also within acceptable range based on generally accepted characteristics of GI materials.

A Study of Mg Capping Inside p-tert-butylcalix[4]arene Adsorbed on a Ge(100) Surface

  • Shin, Minjeong;Lee, Myungjin;Lee, Hangil
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.135-135
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    • 2013
  • The electronic and adsorption structures of Mg and p-tert-butylcalix[4]arene (p-TBCA) adsorbed onto a Ge(100) surface under a variety of sample conditions were characterized using high-resolution photoemission spectroscopy (HRPES) and their corresponding DFT calculation results. Interestingly, after 0.10 ML p-TBCA molecules had been adsorbed onto a Ge(100) surface, subsequent adsorption of a small amount of metallic Mg (~0.10 ML) resulted in the formation of a capped structure inside the pre-adsorbed p-TBCA molecules. The adsorption structures resulting from further deposition of Mg (~0.50 ML) onto the Ge(100) surface were monitored based on the surface charge state and Mg 2s core level spectrum. Work function measurements clearly indicated the electronic structures of the Mg and p-TBCA adsorbed onto the Ge(100) surface. Moreover, we confirmed that three different adsorption structures are experimentally favorable at room temperature through DFT calculation results.

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A Method to Determine Amount of Adsorbed Oil in Hair Washing Using Absorption Spectroscopy (흡수 분광법을 이용한 세정 과정에서 흡착된 오일의 평가)

  • Song, Sang-Hun;Kim, Hyun young;Son, Seong Gil
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.45 no.2
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    • pp.105-116
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    • 2019
  • Oil adsorption during hair or body washing is responsible for the hair conditioning. In this study, we established a method to extract oil from a substrate, and to determine amount of adsorbed oil upon substrate using a conventional absorption spectroscopy. We controlled the mole fraction of a surfactant in a mixture of anionic and amphoteric surfactants because that it induces the coacervate that regulates amount of adsorbed oil through the alteration of oil viscosity. Based on this, we established the optimized condition for adsorption and extraction for oil. UV absorbance were employed to estimate the amount of adsorbed oil using optical absorbance after extraction via adsorption. The estimation was confirmed by comparing with a mass analysis in HPLC and an adhesive energy in AFM. It has been proved that this method can be applied to all cases of oil adsorption from the results with various cationic polymers and a complex system of the polymers which regulate the oil adsorption.

Application of the Distribution Law to Soil-Pesticide Systems (토양농약계(土壤農藥系)에 대(對)한 분배법칙(分配法則)의 적용(適用))

  • Shin, Young Oh;Baker, John H.
    • Korean Journal of Soil Science and Fertilizer
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    • v.7 no.1
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    • pp.1-4
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    • 1974
  • The application of the Distribution Law to soil-pesticide systems yielded the following empirical implications : 1) The amount of the pesticide adsorbed by a soil is negatively proportional to the soil water content. 2) At a given soil water content the amount adsorbed is proportional to the Kd of the soil. 3) The effect of soil water content on the amount of the pesticide adsorbed diminishes with increasing magnitude of the Kd.

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