• 폴리머
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• 제36권1호
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• pp.29-33
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• 2012

관능성 단량체로서 acrylic acid(AA)를 사용하였고, 기본 단량체로서는 2-ethylhexyl acrylate(2-EHA)를 사용하여 용액중합의 방법으로 점착제를 합성하였다. 점착제의 점착물성 중에 AA와 경화제 함량에 따른 점착제의 표면에너지와 물성변화 연구를 조사하였다. 합성된 점착제의 구조는 FTIR을 통하여 확인하였고 점도와 분자량은 Brookfield 점도계와 GPC를 사용하여 각각 측정하였다. 분자량과 점도는 AA가 6 wt%까지는 함량증가에 따라 증가하였으며 6 wt% 이상에서는 감소하였다. 이러한 경향은 표면에너지 역시 AA 함량증가에 따라 COOH 그룹에 의한 극성 강화로 표면에너지는 증가하였다. 반면, 점착력은 분자량과 반비례 관계를 보였으며 AA 함량과 경화제 함량 증가에 따라 감소하는 경향을 나타내었다.

• 공업화학
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• 제33권4호
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• pp.381-385
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• 2022

유해화학물질의 감지 센서 개발을 위해 기재 필름과 전도성 페이스트의 접착 내구성 확보가 매우 중요하다. 본 연구에서는 폴리에틸렌테레프탈레이트(polyethylene terephthalate, PET) 필름에 폴리아닐린/그래핀나노플레이트(graphene nano plate, GNP) 페이스트를 코팅하여 접착 특성을 평가한 결과 cross cut 0B 또는 1B 등급으로 센서 적용에 문제가 있어 에스테르계 바인더를 이용하여 접착 특성 개선 연구를 수행하였다. 에스테르계 바인더가 10 wt% 이상 첨가되면 센서 적용이 가능한 cross cut 등급이 3B 이상을 나타내었다. 바인더의 과량 첨가는 전도성 페이스트의 전기적 특성에 영향을 줄 수 있으며 실제로 황산에 대한 반응성이 감소함을 확인하였다. 전기적 특성 개선을 위해 카본블랙(carbon black, CB) 함량 변화 시험을 수행하였고 CB 2 wt%에서 최적의 전기적 특성을 보임을 확인하였다.

• Journal of the Korean Wood Science and Technology
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• 제51권6호
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• pp.542-554
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• 2023

This study is a continuation of our previous work, which focused on the resistance of jabon wood to termites after impregnation with wood vinegar (WV) and animal-based adhesive (kak). This paper presents the physicomechanical properties of fast-growing jabon wood impregnated with kak at two concentrations (8% and 10%) in wood vinegar or water as a solvent with and without 4% borax. The physical properties of the impregnation solution, that is, viscosity, density, pH, and solid content, were evaluated according to SNI 06-4567-1998. Some physical parameters, such as weight percent gain (WPG), density, water uptake, anti-swelling efficiency (ASE), crystallinity, and mechanical properties, i.e., modulus of elasticity (MOE), modulus of rupture (MOR), and compression strength parallel to the grain (CS), of the impregnated wood were determined. Based on these results, wood impregnated using a mixture of kak in WV presented better physical (increased WPG, density, dimensional stability, and crystallinity) and mechanical (increased MOE/MOR and compression strength) properties than wood impregnated with a water solvent or untreated wood. The wood impregnated using WV and water solvent improved the physical and mechanical properties. The density of the wood increased by 44%-58% and 32%-47%, ASE radial-tangential increased by 38%-45%; 15%-28% after 24 h of water immersion, crystallinity increased by 59%-74%; 36%, MOE increased by 46%-57%; 28%-31%, MOR increased by 29%-34%; 14%-27%, and compression strength increased by 40%-76%; 38%-72% values to untreated wood.

• 마이크로전자및패키징학회지
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• 제10권3호
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• pp.9-17
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• 2003

In this paper, thermo-mechanical and rheological properties of NCPs (Non-Conductive Pastes) depending on silica filler contents and diluent contents were investigated. And then, thermal cycling (T/C) reliability of flip chip assembly using selected NCPs was verified. As the silica filler content increased, thermo-mechanical properties of NCPs were changed. The higher the silica filler content was added, glass transition temperature ($T_g$) and storage modulus at room temperature became higher. While, coefficient of thermal expansion (CTE) decreased. On the other hand, rheological properties of NCPs were significantly affected by diluent content. As the diluent content increased, viscosity of NCP decreased and thixotropic index increased. However, the addition of diluent deteriorated thermo-mechanical properties such as modulus, CTE, and $T_g$. Based on these results, three candidates of NCPs with various silica filler and diluent contents were selected as adhesives for reliability test of flip chip assemblies. T/C reliability test was performed by measuring changes of NCP bump connection resistance. Results showed that flip chip assembly using NCP with lower CTE and higher modulus exhibited better T/C reliability behavior because of reduced shear strain in NCP adhesive layer.

• 한국표면공학회지
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• 제36권2호
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• pp.116-121
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• 2003

Ti-Si-N coating layers were deposited onto WC-Co substrates by a hybrid system of arc ion plating (AIP) and sputtering techniques. The tribological behaviors of Ti-Si-N coating layers with various Si contents were investigated by the dry sliding wear experiments, which were conducted at three different sliding speeds, 0.1, 0.3, 0.5 m/s, against the steel and alumina balls. In the case of steel ball, the average friction coefficient slightly decreased with increasing the sliding speed regardless of Si content due to adhesive wear behavior between coating layer and steel ball. At constant sliding speed, the average friction coefficient decreased with increase of Si content. On the contrary, in the case of alumina ball, the average friction coefficient increased with increasing the sliding speed regardless of Si content, indicating that the abrasive wear behavior was more dominant when the coating layers slide against alumina ball. Through these experimental results, it was found that the tribological behaviors of Ti-Si-N coating layers were effected by factors such as Si content, sliding speed, and kinds of counterpart materials rather than the hardness of coating layer.

• 한국염색가공학회지
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• 제34권4호
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• pp.261-271
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• 2022

Waterborne polyurethane(WPU) is greatly affected by its properties depending on the average particle size. In this study, by analyzing the characteristics of WPUs with different average particle sizes according to the DMPA content and we confirmed that the WPU-Ms have different properties from the physical properties of WPU by mixing two types of WPU with different particle sizes in the same volume. At this time, we mixed WPU at an ideal ratio of 7:3 through literature research. In the thermal characteristic analysis, it was confirmed that the thermal decomposition temperature decreased and Tg increased as the content of DMPA, which is the hard segment, increased. In addition, the average particle size of WPU decreased as DMPA increased, and physical properties and adhesive strength were improved due to increased interaction. When mixed with each other in a weight ratio of 7:3, it was observed that adhesion and mechanical properties were improved compared to only WPU.

• Journal of the Korean Wood Science and Technology
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• 제34권2호
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• pp.37-45
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• 2006

The viscoelastic properties of blends of melamine-formaldehyde (MF) resin and poly(vinyl acetate) (PVAc) for engineered flooring used on the Korean traditional ONDOL house floor heating system were investigated by dynamic mechanical thermal analysis (DMTA). Because MF resin is a thermosetting adhesive, the effect of MF rein was shown across all thermal behaviors. The addition of PVAc reduced the curing temperature. The DMTA thermogram of MF resin showed that the storage modulus (E') increased as the temperature was further increased as a result of the cross-linking induced by the curing reaction of the resin. The storage modulus (E') of MF resin increased both as a function of increasing temperature and with increasing heating rate. From isothermal DMTA results, peak $T_{tan{\delta}}$ values, maximum value of loss modulus (E") and the rigidities (${\Delta}E$) of MF/PVAc blends at room temperature as a function of open time, peak $T_{tan{\delta}}$ and maximum loss modulus (E") values were found to increase with blend MF content. Moreover, the rigidities of the 70:30 and 50:50 MF/PVAc blends were higher than those of the other blends, especially of 100% PVAc or MF. We concluded that blends the MF/PVAc blend ratios correlate during the adhesion process.

• Journal of the Korean Wood Science and Technology
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• 제46권2호
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• pp.143-148
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• 2018

The aim of this research was to determine the physical and mechanical properties of glued laminated lumber (glulam) made from jabon (Anthocephalus cadamba) and pine (Pinus merkusii). Three layers of lamina from each wood species were bonded using isocyanate adhesive with a glue spread of $280g{\cdot}m^{-2}$ and then pressed using cold press with a specific pressure of 1.47 MPa. Samples had dimensions of $3cm{\times}6cm{\times}100cm$ (thickness, width, and length, respectively). Glulam properties were tested based on Japanese Agricultural Standard (JAS) 234-2003. The results showed that the density of glulam was $0.36g{\cdot}m^{-3}$ for jabon and $0.73g{\cdot}m^{-3}$ for pine. The moisture content of all glulams fulfilled the JAS standard. The mechanical properties of pine glulam fulfilled the JAS standard in all tests, whereas jabon glulam fulfilled the standard in the modulus of rupture and shear tests.

• Journal of Pharmaceutical Investigation
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• 제29권2호
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• pp.127-136
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• 1999

In order to eliminate demerits of conventional dosage forms, dipotassium glycyrrhizate was formulated as a slim mucoadhesive film type dosage form. The mucoadhesive drug layer gel containing dipotassium glycyrrhizate was prepared using $Noveon^{\circledR}$ AA-1, hydroxypropylcellulose-M, ethylcellulose N 100 and citric acid, and the protective layer gel by using ethylcellulose N 100, $Eudragit^{\circledR}$ RS and castor oil. The viscosity of drug layer gel of mucoadhesive film was enhanced as the increased amount of $Noveon^{\circledR}$ AA-1 or hydroxypropyl cellulose-M. The drug content was unifonnly $1160{\pm}14.6\;{\mu}g$, and was varied within 3.5%. The optimum film dosage form showed a good fluidity and malleability of drug layer, with 179 g of thickness, pH 5.7, 411 min of in vitro adhesion time and 172 g in gravity adhesive strength. The release time of drug from the mucoadhesive film was significantly shorter but was delayed when polymers such as ethylcellulose was added. From these results, the new mucoadhesive film may be effective for the treatment of aphthous stomatitis.

• 멤브레인
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• 제30권5호
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• pp.333-341
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• 2020

본 연구에서는 플렉시블 전기변색 소자(ECD)에 적용하기 위한 고분자 전해질 멤브레인의 최적 설계 조건을 도출하고자 하였다. 전해질 멤브레인의 제조를 위한 기저 고분자로 접착력 및 투명도가 우수한 polyvinyl butyral (PVB)을 선정하였으며 가소제로는 adipate계 고분자를 사용하였다. 실험결과, ECD 성능에 가장 큰 영향을 미치는 인자는 전해질 멤브레인의 이온 전도도 및 투과도임을 확인할 수 있었다. 또한 상기 인자는 리튬염의 해리 특성과 밀접한 관계를 갖고 있음을 알 수 있었다. 종합적으로 다양한 리튬염 중 음이온의 크기가 큰 LiTFSI 염이 25 wt.% 정도의 함량으로 용해될 때 최적의 ECD 성능을 확인할 수 있었다.