• Title/Summary/Keyword: adhesion property

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Improvement of the adhesion and resistivity of low-pressure chemical vapor deposited tungsten films by controlling deposition parameters (LPCVD로 증착한 텅스텐 박막의 증착 조건 제어에 의한 접착성 및 저항 특성 향상)

  • 노관종;윤선필;윤영수;노용한
    • Journal of the Korean Vacuum Society
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    • v.9 no.4
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    • pp.321-327
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    • 2000
  • Tungsten(W) thin films with good adhesion property and low resistivity (~10 $\mu$\Omega$$.cm) were deposited directly on $SiO_2$ by LPCVD. The adhesion property of W thin films on $SiO_2$ improves as the temperature and/or $SiH_4/WF_6$ gas ratio increase. Specifically tungsten thin films could be deposited on $SiO_2$ even at $350^{\circ}C$ if the gas ratio of 2 was employed. The resistivity of tungsten thin films deposited at $350^{\circ}C$ was high due to the presence of $\beta$-W. However, the resistivity can be minimized by increasing the amount of $H_2$ gas flow. Therefore, it is shown in this work that the adhesion of tungsten thin films on $SiO_2$ can be improved simply by controlling the process parameters (e.g., temperature, gas ratio and $H_2$ flow rate) without employing complex deposition methods or additional glue layers.

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Investigation of Adhesion property between Glass Fiber Reinforced Plastic and Polyurethane adhesives on Peel strength under Gyogenic tempernture (극저온에서 유리섬유강화플라스틱 표면의 유리섬유와 폴리우레탄 접착제간의 접착특성이 전체 박리강도에 미치는 영향에 대한 연구)

  • Shon, Min-Young;Lee, Jae-Kwang;Hong, Jeong-Lak
    • Composites Research
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    • v.22 no.4
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    • pp.13-19
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    • 2009
  • Adhesive joints are widely used for structural joining applications in various fields and environmental conditions. Polyurethane adhesive is using for LNG carrier with cryogenic temperature condition. Even if similar polyurethane adhesive is used for different substrate, it shows different adhesion properties. Specially, variation of adhesion properties depending on the resin system or fiber is very important factor for selection of adhesive on industrial application. In present study, we got different peel strength according to the different test temperature when different polyurethane adhesive was used for same fiber reinforced composite. The main cause was investigated using by SEM and it was proven that the different adhesion property between glass fiber on composite surface and polyurethane adhesives at cryogenic temperature.

Evaluation of the Change in Adhesion Strength of GFRP and CFRP with Carbon Nanotube Contents in Epoxy Adhesive with Moisture Change during Curing (에폭시 접착제의 탄소나노튜브 함량과 경화시 습도 변화에 따른 GFRP 및 CFRP의 접착강도 변화 평가)

  • Park, Hee-Woong;Kim, Jong-Hyun;Park, Joung-Man
    • Journal of Adhesion and Interface
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    • v.23 no.1
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    • pp.1-7
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    • 2022
  • As the wind blades become larger, they tend to be made by mixing glass fiber and carbon fiber, and it is important to increase the properties of the adhesive which adheres the two materials. The physical properties of the adhesive vary depending on the content of the additive and curing conditions. In this study, the change in adhesion strength with the difference between the CNT (Carbon Nanotube) content of the epoxy adhesive and the humidity during curing was evaluated. GFRP and CFRP specimens were prepared and adhered using an epoxy adhesive, and to examine changes in characteristics with carbon nanotube contents and with the humidity during curing of the epoxy adhesive, adhesion strength was evaluated by dividing the difference between carbon nanotube content and humidity. To find out the change with the CNT contents, the intelaminar shear strength (ILSS) test was performed by dividing the contents of the CNT into 0, 0.1, 0.3, 0.5, and 1 wt%, and to confirm the change with the humidity conditions, the adhesive was cured by dividing the humidity by 20, 50, and 80%. From the result of the experiment, the adhesive force decreased when the content was excessively large, although the adhesive property was enhanced by adding CNT to the epoxy adhesive. In addition, it was confirmed that the adhesion characteristics were not changed as the humidity increased.

Alternative Finishing Process for Poly(ethylene terephthalate)(PET) Tire Cord using Atmospheric Plasma

  • Kim, Sam-Soo;Song, Eun-Young;Cho, Dong-Lyun;Park, Jun;Park, Sung-Ho;Lee, Jae-Woong
    • Textile Coloration and Finishing
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    • v.22 no.4
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    • pp.300-305
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    • 2010
  • Poly(ethylene terephthalate)(PET) tire cord has relatively lower adhesion properties caused by limited reacting sites. In order to improve the adhesion force between PET tire cord and rubber, an additional process to activate surface of PET has been employed. Atmospheric plasma was used to substitute the chemical finishing process of PET tire cord as a green dipping process. Contact angle was measured to confirm surface change of PET after plasma treatment. The treated PET tire cords with/without resorcinol-formaldehyde-latex(RFL) and unvulcanized rubber were vulcanized in a testing mold at $160^{\circ}C$. After atmospheric plasma treatment of PET tire cord, adhesion force was somewhat increased under some conditions.

A Study on the Properties of the Zn-Cr Alloy Films by Evaporation (진공증착법으로 제조된 Zn-Cr박막의 특성에 관한 연구)

  • Ju, Bong-Hwan;Lee, Gyu-Hwan;Gwon, Sik-Cheol;Baek, Un-Seung
    • 연구논문집
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    • s.23
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    • pp.109-120
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    • 1993
  • A study on corrosion and adhesion properties of evaporated Zn-Cr films were conducted on steel strip by two-source evaporater. Corrosion resistance of Zn-Cr coated steel was evaluated by salt spray test in 5% NaCl. Adhesion property of Zn-Cr films on steel substrate was evaluated by tape test after $180^\circC$ bending. Adhesion was improved with increasing the Cr content and reached the maximum at the Cr content of 6 to 8wt%. Corrosion resistance was enhanced with increasing the Cr content and improved by rolling Zn-Cr coated specimen, as a post-treatment.

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Improvement of Protective Properties of Top Coatings Applied on Zinc-Rich Primer by 3-Aminopropyl-Triethoxysilan and 2-(Benzothialylthio) Succinic acid

  • Trinh, Anh Truc;To, Thi Xuan Hang;Vu, Ke Oanh;Nguyen, Tuan Dung
    • Corrosion Science and Technology
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    • v.3 no.3
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    • pp.107-111
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    • 2004
  • Corrosion resistance of coating system consisting of zinc-rich primer (ZRP) and topcoat based on polyurethane resin with the presence of 3-aminopropyl-triethoxysilan (APS) and 2-(benzothialylthio) succinic acid (BSA) was studied by electrochemical impedance and wet adhesion. The interface metal/primer/topcoat was analyzed by scanning electronic microscopy. It was found that the presence of APS and BSA improved adhesion and barrier property of the topcoats.

Interfacial and Pull-out Properties of PVA and PET Fiber with UV Irradiation in Cementitious Composites (시멘트 복합체 내에서 UV처리에 따른 PVA 및 PET섬유의 계면 및 매입인발특성)

  • Jeon, Esther;Lee, Sang-Soo;Yun, Hyun-Do
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.05b
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    • pp.401-404
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    • 2006
  • Much of requirements to the civil and building structures have been changed in accordance with the social and economic progress. Ductility of high performance fiber reinforced cementitious composites(HPFRCCs), which exhibit strain hardening and multiple crackling characteristics under the uniaxial tensile stress is drastically improved. In HPFRCC application, PVA fiber has been dominantly used as a reinforcement because of its excellent alkali resistant nature as well as high strength. But the inherent strong hydrophilicity of PVA fiber promotes the moisture absorption in cement matrix and thus it may cause the corrosion of steel structure. Therefore, it is necessary to control the interfacial adhesion of cement composites. In present study, to control the interfacial adhesion of the cementitious composites reinforced by PVA fiber, UV irradiation of the PVA fiber were performed and their effects on the adhesion property and general characteristics were investigated extensively.

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Thermal behavior of Flame Retardant Filled PLA-WF Bio-Composites

  • Choi, Seung-Woo;Lee, Byoung-Ho;Kim, Hyun-Joong;Kim, Hee-Soo
    • Journal of the Korean Wood Science and Technology
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    • v.37 no.2
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    • pp.155-163
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    • 2009
  • This study examined the thermal stability of PLA-WF bio-composites. Wood flour (WF)-filled PLA bio-composites were reinforced with the flame retardants, Melamine pyrophosphate (MPP), resorcinol bis (diphenyl phosphate) (RDP) and zinc borate (ZB). The flame retardant was compounded with PLA and natural biodegradable filler. The thermal properties of the biodegradable polymer and bio-composites reinforced with the flame retardant were measured and analyzed by DSC, DMA and TGA. The results showed that the flame retardant-reinforced biodegradable bio-composite exhibited improved thermal properties.

Joining of Polyethylene Polymer by the Ultrasonic Welding (초음파 용접을 이용한 폴리에틸렌 수지의 접합)

  • Lee, Chul-Ku
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.6 no.3
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    • pp.73-81
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    • 1997
  • This study was to find the best adhesive condition comparing mechanical property in case of hot-melt adhesion using glue-gun, ultrasonic welding with adhesion and only ultrasonic welding in order to adhere thermoplastic resin of polyethylene (PE) in which reliable adhesion was resulted in case of ultrasonic welding with same materials of PE. The best welding condition were acquired at welding time 1 second, welding pressure 250kPa for PE-PE where welding time and welding pressure were increased in accordance with the increase of material strength. At the best ultrasonic welding conditions, bonding strength of PE-PE welding was about 21MPa of which material have tensile strength of 24MPa. Through the analysis of microscophic test for ultrasonic welding structure, it was distinguished between well welded structure with higher intermolecule flow and bad welded structure with lower flow, of which result is mostly correspond with the result of tensile strength test.

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A study on the structure and properties of Cr and Cr$_2$O$_3$ films deposited by the vacuum evaporation method (진공 증발법으로 증착한 Cr, Cr$_2$O$_3$ 박막의 조직 및 특성에 관한 연구)

  • 이종민;이정중
    • Journal of the Korean institute of surface engineering
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    • v.27 no.2
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    • pp.74-82
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    • 1994
  • The structure and properties such as adhesion and corrosion resistance of Cr and $Cr_2O_3$ films, deposited on steel plates by the vacuum evaporation method, were investigated. According to the ESCA and AES analy-sis, it could be concluded that chromium oxide with uniform composition could be formed on the steel sub-strate. The deposited Cr and $Cr_2O_3$ films had high adhesion strength, and they did not peeled off by the tape test. The adhesion property, however, was deteriorated as the film thciknes increased. After bending of the deposited specimen many cracks were observed by SEM, and they were assumed to have propagated along co-lumnar boundaries by the bending test. The corrosion resistance of the films was not generally good, which in-dicates that the films had a porous structure with a large number of defects such as pin holes and voids.

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