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Water - Assisted Efficient Growth of Multi-walled Carbon Nanotubes by Thermal Chemical Vapor Deposition

  • Choi, In-Sung;Jeon, Hong-Jun;Kim, Young-Rae;Lee, Nae-Sung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.06a
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    • pp.418-418
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    • 2009
  • Vertically aligned arrays of multi-walled carbon nanotube (MWCNT) on layered Si substrates have been synthesized by water-assisted thermal chemical vapor deposition (CVD). We studied changes in growth by parameters of growth temperature, growth time, rates of gas and annealing time of catalyst. Also, We grew CNTs by adding a little amount of water vapor to enhance the growth of CNTs. $H_2$, Ar, and $C_2H_2$ were used as carrier gas and feedstock, respectively. Before growth, Fe served as catalyst, underneath which AI were coated as an underlayer and a diffusion barrier, respectively, on the Si substrate. The water vapor had a greater effect on the growth of CNTs on a smaller thickness of catalyst. When the water vapor was introduced, the growth of CNTs was enhanced than without water. CNTs grew 1.29 mm for 10 min long by adding the water vapor, while CNTs were 0.73 mm long without water vapor for the same period of time. CNTs grew up to 1.97 mm for 30 min prior to growth termination under adding water vapor. As-grown CNTs were characterized by using scanning electron microscopy (SEM), high resolution transmission electron microscopy (HRTEM), and Raman spectroscopy.

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The Effects of Alphabet Knowledge on Korean Kindergarteners' Reading of Hangul Words (한글 자음과 모음에 대한 유아의 지식이 단어 읽기에 미치는 영향)

  • Choi, Na-Ya;Yi, Soon-Hyung
    • Journal of Families and Better Life
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    • v.25 no.3 s.87
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    • pp.151-168
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    • 2007
  • The purpose of this study was to investigate the causal relationship of kindergarteners' alphabet knowledge to their ability to read words, in connection with the features of the Korean alphabet 'Hangul'. A total of 289 children aged four to six from three kindergartens in Busan participated in the study. The main results are as follows. To begin with, the participants showed continuous development in the knowledge of consonant names, vowel sounds, the vowel stroke-adding principle, and the alphabet composition principle. Meanwhile, discontinuous development was found in the knowledge of consonant sounds and the consonant stroke-adding principle, which indicated that kindergartners could show differential speed in various sub-skills of literacy development. The kindergartners' naming of consonants developed before their recall of consonant sounds, and the knowledge of consonant sounds had an effect on the knowledge of vowel sounds. Children had difficulty in treating more complicated letters of the alphabet stroke-adding principle test, and eve syllables of the alphabet composition principle test. Most importantly, the children's alphabet knowledge was strongly related to their ability to read words written in Hangul, as kindergarteners with a greater knowledge of alphabet names, sounds, and principles were shown to read words better.

Effect of Size Distribution of Oil Particles with Emulsifiers and Stabilizers on the Emulsion Stability of Mayonnaise (유화.안정제의 종류에 따른 지방구의 입도 분포가 Mayonnaise의 유화안정성에 미치는 영향)

  • 이영엽
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.30 no.2
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    • pp.204-209
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    • 2001
  • The effects of size distribution of oil particles on the emulsion stability of mayonnaise were studied as follows; The stability of mayonnaise has concerned closely with the viscosity and the size distribution of oil particles. Mostly, if the viscosity was increased, the stability was improved, and the distribution of oil particles was uniform and the less the variation, the more the stability. 75% of oil concentration of sample showed the highest viscosity, also the size of sample was the most uniform, compared to other concentration. Mayonnaise prepared with whole egg was unstable, and the size of oil particles was double larger than the case prepared with only the yolk. Addition of xanthan gum increased, the viscosity and the stability by centrifuge so that the more stable mayonnaise could be prepared. The result of using log-normal density function by Heldmann represented that the normal size of sample adding 0.6%-soluble starch and sample N in non-adding control was increased, while those of sample adding xanthan gum and soluble starch at the same time didn't change.

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Evaluation of the Properties of a Hot In-Placement Recycled Asphalt Mixture as an Adding Mixer (믹싱기 추가에 따른 현장가열 재생 아스팔트 혼합물의 물성평가)

  • Lee, Kanghun;Park, Jaeyoung;Lee, Hwasun;Kim, Yongjoo;Lee, Jaejun
    • International Journal of Highway Engineering
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    • v.20 no.1
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    • pp.97-105
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    • 2018
  • PURPOSES : Asphalt concrete pavement is damaged by various causes such as traffic and environmental loads. The distressed pavement should be maintained by various methods to provide a comfortable and safe pavement for the driver. This study evaluates the effect of adding a mixing procedure to enhance the mixture quality in the hot in-placement recycled asphalt pavement method, which is an asphalt-pavement maintenance method. METHODS : Various test methods such as Marshall stability and dynamic stability, were employed to estimate the recycled asphalt mixture with and without an additional mixing, using the hot in-placement recycled asphalt pavement method. RESULTS : The mixture samples used in this study were taken before and after the addition of the mixer in the hot in-placement recycled asphalt pavement method (HIR) at field construction sites in GongJu and JinJu in South Korea. The test results of both mixtures satisfied the asphalt-mixture standard specifications. CONCLUSIONS : This study confirmed that adding a mixer in the HIR method results in a well-mixed new asphalt mixture, rejuvenator, and reclaimed asphalt mixture.

Effects of Substrates Supplemented with Crushed Shell, Elvanite and bioceramic on the Growth of Rice(Oryza sativa L.) (패화석, 맥반석 및 바이오세라믹의 혼입처리 벼의 생육에 미치는 영향)

  • 박순기;김홍기;정순주
    • Korean Journal of Organic Agriculture
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    • v.6 no.1
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    • pp.127-132
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    • 1997
  • This experiment was carried out to examine the effect of various functional materials such as bioceramic podwers, crushed shells and elvanites supplemented to the each substrate on the seedlings growth of rices. The rice seedlings were grown in pots filled with substrates supplemented with bioceramic podwers, crushed shells and elvanites. The growth of rice seedlings in terms of plant height, stem diameter, root length and leaf width, plant fresh and dry weight was promoted by adding the bioceramic powders (2 to 3g/kg), crushed shells (10g/kg) or elvanites (20 to 40g/kg). Plant height was also promoted by the adding of bioceramic powder from 16 days after treatment, whereas crushed shells and elvanites from 10 days after treatment. Especially, root growth was greatly influenced by bioceramic powder, whereas the shoot growth(leaves and stem) was stimulated by the crushed shells and elvanites supplemented into each substrate. In the field, plant growth in terms of plant height, leaf length and leaf width were also influenced by crushed shells and elvanites at 74 days after treatment. The growth of rices in terms of tiller number, spikelets, panicles and spikelets/panicle was incresed by adding the crushed shells and elvanites from 100 to 200g per m2.

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Effects of activated carbon on the compressive strength of Portland cement concrete

  • Sungmin Youn;Andrew Ball;Claire Fulks;Sanghoon Lee;Sukjoon Na
    • Geomechanics and Engineering
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    • v.33 no.1
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    • pp.19-27
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    • 2023
  • A series of experiments were performed to evaluate the effects of activated carbon on the compressive strength and air content of Portland Cement Concrete (PCC). Activated carbon/PCC composites were prepared by mixing concrete components with commercial activated carbon granules with weight fractions of 0, 0.5%, 1%, and 2% to cement. All PCC specimens were then tested for compressive strength on 7, 14, 21, and 28 days. The experimental results showed that adding 0.5% of activated carbon increased the compressive strength significantly over the curing periods compared to the normal PCC without activated carbon. For the specimens has 0.5% activated carbon, the 7, 14, 21, and 28-day compressive strengths increased by 28.7%, 22.2%, 26.8%, and 22.9%, respectively. However, adding excessive amounts of more than 1% activated carbon had a minimal effect on the compressive strength or even decreased it, which agrees with other studies. Regarding the air contents of the mixtures, adding activated carbon decreased the air content from 3.6% to around 1.5%. The surface morphologies of fine aggregates and activated carbon particles were compared using a novel image processing technique. The results indicated that the surface of activated carbon significantly differs from that of aggregates.

Effects of Jaeumgenby-tang adding Aurantii FructusㆍGastrodae Rhizoma on the Brain Cell and Changes of Cerebral Hemodynamics (자음건비탕가지각ㆍ천마가 뇌세포 및 뇌혈류역학 변동에 미치는 영향)

  • Im Gwang Mo;Jeong Hyun Woo
    • Journal of Physiology & Pathology in Korean Medicine
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    • v.17 no.1
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    • pp.64-70
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    • 2003
  • Jaeumgenby-tang(JGT) have been used in oriental medicine for many centuries as a therapeutic agent of vertigo caused by deficiency of qi(氣) and blood(血). Effect of Aurantii Fructus(AF) take off the phlegm by promoting the circulation of qi, Gastrodae Rhizoma(GR) has effects treating for headache, vertigo by calming the liver and suppressing hyperactivity of the liver-yang(陽). And, I designed to investigate whether injection of JGT adding AFㆍGR extract(JGTAG) affects cytotoxicity in vitro, cerebral hemodynamics [regional cerebral blood flow(rCBF), pial arterial diameter(PAD), mean arterial blood pressure(MABP)] in normal and cerebral ischemia rats by MCA occlusion method. The changes of rCBF and MABP were determinated by laser-doppler flowmetry(LDF), and the change of PAD was determinated by video microscope and width analyzer. The results were as follows in normal rats; JGTAG was not cytotoxicity in brain cells. And JGTAG was significantly increased rCBF, PAD and MABP. This results suggest that JGTAG increased significantly rCBF by dilating PAD. And the results were as follows in cerebral ischemic rats; The changes of rCBF and PAD were increased stably by treatment with JGTAG(10mg/kg, i.v.) during the period of cerebral reperfusion, and pretreatment with propranolol and indomethacin were increased JGT AG induced increase of rCBF and PAD during the period of cerebral reperfusion. We suggest that JGTAG has an anti-ischemic effect through the improvement of cerebral hemodynamics.

Development of Growing Pig Diets for Environment-Friendly by Using Phytase (Phytase를 이용한 환경친화성 육성돈사료개발)

  • 김인호;홍종욱
    • Korean Journal of Organic Agriculture
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    • v.9 no.1
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    • pp.51-60
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    • 2001
  • An experiment was carried out to evaluate the effects of adding phytase on nutrient digestibility in growing pigs. Three barrow pigs averaging 28.5$\pm$3.1kg of body weight were allotted to three treatments by 3$\times$3 latin square. Treatments included 1) com-soybean meal based-control diet and 2) and 3) control diet with phytase 500 and 1,000 unit. There were no effects of treatments on dry matter and nitrogen digestibility (P〉0.05). Ash, Ca and P digestibility in pigs fed diet with phytase were greater than those in pigs fed control diet(P〈0.05). An increased phosphorus intake was observed from pigs fed diet with treatments compared to that from pigs fed control diet. Pigs fed diet with adding phytase had improved P absorption compared to pigs fed control diet(P〈0.05). There was no significantly effect on fecal and urine excretion(P〈0.05). Ca intake was increased for pigs fed adding phytase compared to pigs fed control diet. No evident effect was observed on Ca fecal excretion among dietary treatments, however, urine excretion of pigs fed diet with treatments was decreased compared to pigs fed control diet. Cystine, isoleucine, tyrosine and phenylalanine digestibility of amino acid were greater for pigs fed diet with treatments than those for pigs fed control diet(P〈0.05). Asparagine, threonine, serine, methionine and leucine digestibility were improved for pigs fed with phytase 500 unit compared to pigs fed control diet. Lysine, histidine, arginine and other animo acids digestibility were higher for pigs fed diet with phytase than control diet, but there were no significant effects by the treatments(P〉0.05). In conclusion, the results of the experiments suggest that phytase supplementation in the diets could be a very beneficial strategy in environmental aspects.

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Effect of Pretense (Subtilisin Carlsberg) on the Removal of Blood Protein Soil (II) -The Detergency of Hemoglobin from Cotton Fabics- (Protease (Subtilisin Carlsberg) 가 혈액 단백질 오구의 제거에 미치는 영향(II) -헤모글로빈 오구포의 세척성-)

  • 이정숙;김성연
    • Journal of the Korean Society of Clothing and Textiles
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    • v.20 no.4
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    • pp.655-666
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    • 1996
  • The effect of protease (subtilisin Carlsberg) on the removal of hemoglobin as protein soil was studied. The relation between the renloval and the hydrolysis of hemoglobin by subtilisin Carlsberg was discussed. The soiled babric was prepared by spotting of hemoglobin solution evenly on the cotton fabric and was denatured by steaming. The soiled fabric was washed by using Terg-0-Tometer at various conditions. The removal efficiency was evaluated by analysis of protein on the fabrics before and after washing by means of copper-Folin method. 1. The removal of hemoglobin was increased in proportion to increasing of the enzyme concentration up to a certain point, but it began to decrease above the point. 2. The hemoglobin was removed effectively by adding of subtilisin Carlsberg, and more effectively removed by adding of AOS in the enzyme solution. 3. The removal of hemoglobin deviated from the first order reaction in detergency. 4. The renloval of hemoglobin was highest at $50^{\circ}C$ in detergency, Even at low temperature the removal efficiency of enzyme was relatively higher compared with the hydrolysis of hemoglobin by the enzyme. However the removal of hemoglobin was apparently decreased with the increase of temperature over $60^{\circ}C$. 5. The removal of hemoglobin was relatively high at pH 7.0~8.0 and increased continuously with the increase of pH in detergency 6. In detergency, the removal mechanism of hemoglobin by subtilisin Carlsberg could be explained as follows: Fisrt of all, the enzyme hydrolyzed hemoglobin substrates partially by forming E-S complex at the surface of hemoglobin on the cotton fiber, and decomposed cooperative binding of hemoglobin. Subsequently, the fragments of hemoglobin were easily removed by washing. According as the enzyme penetrated to inner part of hemoglobin gradually, the hemoglobin on the cotton fiber was effectively removed by the repetition of these process. The removal of hemoglobin was more effectively increased by adding both the enzyme and AOS in the washing solution. Therefore, it was regarded that AOS molecules were adsorbed at the hydrophobic surface of denatured hemoglobin, subsequently, decomposed more effectively cooperative binding of hemoglobin, and the fragments of hemoglobin were removed more efficiently by means of the interfacial reaction of AOS.

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Effect of Duck Feet Gelatin on Physicochemical, Textural, and Sensory Properties of Low-fat Frankfurters

  • Yeo, Eui-Joo;Kim, Hyun-Wook;Hwang, Ko-Eun;Song, Dong-Heon;Kim, Yong-Jae;Ham, Youn-Kyung;He, Fu-Yi;Park, Jae-Hyun;Kim, Cheon-Jei
    • Food Science of Animal Resources
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    • v.34 no.4
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    • pp.415-422
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    • 2014
  • Duck feet gelatin (DFG) gel was added as a fat replacer to low-fat frankfurters and the effect of DFG on physicochemical, textural, and sensory characteristics of low-fat frankfurters was evaluated. DFG gel was prepared with a 20% duck feet gelatin concentration (w/w). Adding DFG decreased lightness and increased yellowness of the low-fat frankfurters (p<0.05). However, DFG did not affect redness of low-fat frankfurters (p>0.05). The statistical results indicated that adding DFG improved cooking yield of low-fat frankfurters (p<0.05). In addition, replacing pork back fat with DFG resulted in increased moisture content, protein content, and ash content of low-fat frankfurters, and the low-fat frankfurter formulated with 5% pork back fat and 15% DFG gel had the highest moisture content and lowest fat content (p<0.05). Adding of DFG increased all textural parameters including hardness, springiness, cohesiveness, chewiness, and gumminess of low-fat frankfurters (p<0.05). In terms of sensory properties, the low-fat frankfurter formulated with 5% pork back fat and 15% DFG gel showed similar satisfaction scores for the flavor, tenderness, juiciness, and overall acceptance when compared to the regular frankfurters (20% back fat). Therefore, our results suggest that DFG could be an effective novel source, as a fat replacer, for manufacturing of low-fat frankfurters.