• Title/Summary/Keyword: activity radius

Search Result 66, Processing Time 0.025 seconds

Synthesis, Characterizations, and Applications of Metal-Ions Incorporated High Quality MCM-41 Catalysts (고품질 금속 이온 첨가 MCM-41 분자체 촉매의 제법, 특성화 및 응용 반응)

  • Lim, Steven S.;Haller, Gary L.
    • Korean Chemical Engineering Research
    • /
    • v.51 no.4
    • /
    • pp.443-454
    • /
    • 2013
  • Various metal ions (transition and base metals) incorporated MCM-41 catalysts can be synthesized using colloidal and soluble silica with non-sodium involved process. Transition metal ion-typically $V^{5+}$, $Co^{2+}$, and $Ni^{2+}$-incorporated MCM-41 catalysts were synthesized by isomorphous substitution of Si ions in the framework. Each incorporated metal ion created a single species in the silica framework, single-site solid catalyst, showing a substantial stability in reduction and catalytic activity. Radius of pore curvature effect was investigated with Co-MCM-41 by temperature programmed reduction (TPR). The size of metallic Co clusters, sub-nanometer, could be controlled by a proper reduction treatment of Co-MCM-41 having different pore size and the initial pH adjustment of the Co-MCM-41 synthesis solution. These small metallic clusters showed a high stability under a harsh reaction condition without serious migration, resulting from a direct anchoring of small metallic clusters to the partially or unreduced metal ions on the surface. After a complete reduction, partial occlusion of the metallic cluster surface by amorphous silica stabilized the particles against aggregations. As a probe reaction of particle size sensitivity, carbon single wall nanotubes (SWNT) were synthesized using Co-MCM-41. A metallic cluster stability test was performed by CO methanation using Co- and Ni-MCM-41. Methanol and methane partial oxidations were carried out with V-MCM-41, and the radius of pore curvature effect on the catalytic activity was investigated.

The Preparation of Antibacterial Activated Carbon fibers and Their Application (항균성 탄소섬유의 제조와 그의 응용)

  • 오원춘;김범수;장원철
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.1 no.1
    • /
    • pp.43-48
    • /
    • 2000
  • Upon the Preparation of activated carbon fiber(ACF) using chemical activation method and vapour activation method, the fiber obtained from the vapour activation method shows excellent surface Properties. The preparation of antibacterial activated carbon fiber was tried to open the new areas in application of carbon materials. The BET specific surface area and the average pore radius of the antibacterial ACFs were in the range of 844.27~1575.6 $cm^2$/g and 10.6~12.9 (equation omitted), respectively. From the adsorption studies on the antibacterial ACFs, typical Type I isotherms were obtained. And, from the SEM morphology results, it was observed that the surface of ACFs was partially coated by antibacterial materials after the treatment. Finally, from the antibacterial effects of antibacteral ACFs against E. coli, excellent antibacterial activity was shown. Concerning the above results, antibacterial ACFs can have wide application in the areas of sterilization, anti-fragrant. anti-insects.

  • PDF

Atmospheric Pressure Micro Plasma Sources

  • Brown, Ian
    • Journal of the Korean institute of surface engineering
    • /
    • v.34 no.5
    • /
    • pp.384-390
    • /
    • 2001
  • The hollow cathode discharge is a kind of plasma formation scheme in which plasma is formed inside a hollow structure, the cathode, with current to a nearby anode of arbitrary shape. In this scheme, electrons reflex radially within the hollow cathode, establishing an efficient ionization mechanism for gas within the cavity. An existence condition for the hollow cathode effect is that the electron mean-free-path for ionization is of the order of the cavity radius. Thus the size of this kind of plasma source must decrease as the gas pressure is increased. In fact, the hollow cathode effect can occur even at atmospheric pressure for cathode diameters of order 10-100 $\mu\textrm{m}$. That is, the "natural" operating pressure regime for a "micro hollow cathode discharge" is atmospheric pressure. This kind of plasma source has been the subject of increasing research activity in recent years. A number of geometric variants have been explored, and operational requirements and typical plasma parameters have been determined. Large arrays of individual tiny sources can be used to form large-area, atmospheric-pressure plasma sources. The simplicity of the method and the capability of operation without the need for the usual vacuum system and its associated limitations, provide a highly attractive option for new approaches to many different kinds of plasma applications, including plasma surface modification technologies. Here we review the background work that has been carried out in this new research field.

  • PDF

Hydroacoustic Records and Numerical Models of the Source Mechanisms from the First Historical Eruption of Anatahan Volcano, Mariana Islands

  • Park M.;Dziak R.P.;Matsumoto H.
    • 한국지구물리탐사학회:학술대회논문집
    • /
    • 2004.06a
    • /
    • pp.232-237
    • /
    • 2004
  • Anatahan Volcano in the Commonwealth of the Northern Mariana Islands (CNMI) erupted for the first time in recorded history on 10 May 2003. The underwater acoustic records of earthquakes, explosions, and tremor produced during the eruption were recorded on a sound-channel hydrophone deployed in February 2003. Acoustic propagation models show the seismic to acoustic conversion at Anatahan is particularly efficient, aided by the slope of the seamount toward the hydrophone. The hydrophone records confirm the onset of earthquake activity at 01:53Z on 10 May, as well as the onset (at ${\~}$06:20Z) of continuous, low-frequency (5-40 Hz) acoustic energy that is likely volcanic tremor related to magma intrusion. The hydrophone recorded a total of 458 earthquakes associated with the eruption. To predict the character of acoustic signals generated from Anatahan, we developed a moment-tensor representation of a volcano-seismic source that is governed by the geometry of the source and the physical properties of the magma. A buried magmatic pipe model was adopted, and numerically modeling source parameters such as the pipe radius and magma viscosity enable us to grasp the inward nature of Anatahan Volcano.

  • PDF

Membrane Perturbation Induced by Papiliocin Peptide, Derived from Papilio xuthus, in Candida albicans

  • Lee, June-Young;Hwang, Jae-Sam;Hwang, Bo-Mi;Kim, Jin-Kyoung;Kim, Seong-Ryul;Kim, Yang-Mee;Lee, Dong-Gun
    • Journal of Microbiology and Biotechnology
    • /
    • v.20 no.8
    • /
    • pp.1185-1188
    • /
    • 2010
  • Previously, papiliocin was isolated from the swallowtail butterfly Papilio xuthus and its antimicrobial activity was suggested. In this study, the antifungal mechanism of papiliocin against Candida albicans was investigated. Confocal laser scanning microscopy (CLSM) and 1,6-diphenyl-1,3,5-hexatriene (DPH) fluorescence analysis indicated that papiliocin disturbed the fungal plasma membrane. Moreover, the assessment of the release of FITC-dextran (FD) from liposomes further demonstrated that the antifungal mechanism of papiliocin could have originated from the pore-forming action and that the radius of the pores was presumed to be anywhere from 2.3 to 3.3 nm.

The centroid shift of Sgr A*

  • Cho, Il-Je;Sohn, Bong Won;Jung, Taehyun;Kino, Motoki;Zhao, Guang-Yao;Agudo, Ivan;Rioja, Maria;Dodson, Richard
    • The Bulletin of The Korean Astronomical Society
    • /
    • v.41 no.2
    • /
    • pp.41.1-41.1
    • /
    • 2016
  • The Galactic center, Sagittarius A* (Sgr A*), is the closest supermassive black hole and emits synchrotron radiation. It provides great opportunity to study the origin of mm/sub-mm emission. Currently, two competing models have been suggested as a jet base and a radiatively inecient accretion flow (RIAF). To unveil the properties, the extremely high resolution(${\sim}10{\mu}as$) corresponding to the projected Schwarzschild radius of ~0.1AU is necessary. With KVN, a jet model can be tested by multi- frequency simultaneous observations because the optically thick surface in a jet (i.e. radio core) moves toward the center at a higher frequency. We conducted 8 observations with KVN at 43/86GHz in 2015, and found that the measured positional shift to the reference calibrator, J1744-3116, was ~0.3 mas to the south of Sgr A* using the source frequency phase referencing (SFPR) at Q/W bands for the first time. With the result, in the future, we will attempt to measure the variation of source position shifts that can constrain the direction of approaching jets and the variability of black hole activity of Sgr A*.

  • PDF

Effect of Introducing Chitinase Gene on the Resistance of Tuber Mustard against White Mold

  • Ojaghian, Seyedmohammadreza;Wang, Ling;Xie, Guan-Lin
    • The Plant Pathology Journal
    • /
    • v.36 no.4
    • /
    • pp.378-383
    • /
    • 2020
  • The objective of this research was introduction of chit42 to tuber mustard plants through Agrobacteriummediated transformation against white mold caused by Sclerotinia sclerotiorum. The binary plasmid pGisPEC1 was used in this study. Polymerase chain reaction analysis detected the transgene in 27 transformants with a transformation efficiency of 6.9%. Southern blot test was used to assess the copy number of transgene in tuber mustard plants. One, two, two, and two chit42-related bands were observed in the transformed lines TMB4, TMB7, TMB12, and TMB18, respectively. Enzymatic tests showed a significant increase in the activity of endochitinase in protein isolated from leaf tissues of chit42 transgenic 75-day tuber mustard lines. The pathogenicity of three pathogen isolates was tested on the leaves of transformed plans. The results of current study showed that expression of the gene chit42 in tuber mustard plants markedly reduced infection radius on the leaves 7 days after inoculation with the fungus.

Photodegradation of Volatile Organic Compound (VOC) Through Pure TiO2 and V-Doped TiO2 Coated Glasses

  • Moon, Jiyeon;Kim, Seonmin
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2014.02a
    • /
    • pp.425.2-425.2
    • /
    • 2014
  • $TiO_2$ possesses great photocatalytic properties but absorbs only UV light owing to high band gap energy (Eg = 3.2 eV). By narrowing the band gap through doping a metal ion, the photocatalytic activity can be enhanced in condition of the light of a higher than 365 nm wavelength. Main purpose for this study is to evaluate the activities of metal doped $TiO_2$ for degrading the volatile organic compounds (VOCs); p-xylene is chosen in the VOC removal test. Vanadium is selected in this study because an ionic radius of vanadium is almost the same as titanium ion and vanadium can be easily doped into $TiO_2$. V-doped $TiO_2$ was synthesized by sol-gel methods and compared with pure $TiO_2$. Pure TiO2 powder and V-doped $TiO_2$ powder were coated on glasses by spray coating method. UV-Visible spectrophotometer was used for the measurement of the band gap changes. VOC concentration degradation level was tested with using various UV light sources in an enclosed chamber. Catalytic activities of prepared samples were evaluated based on the experimental results and compared with coated pure $TiO_2$ sample.

  • PDF

A Study on the Spatial Analysis Model to Decide Medical Institutions/Mental Health Centers for Disaster Victims

  • Choi, Eun-Hye;Hwang, Hyun-Suk;Kim, Chang-Soo
    • Journal of information and communication convergence engineering
    • /
    • v.9 no.4
    • /
    • pp.358-362
    • /
    • 2011
  • The National Emergency Management Agency of South Korea has established a Disaster Victims Psychology Support Center. The Disaster Victims Psychology Support Center can enable victims who got psychological damage from disasters to return to their daily lives through healing activity, field visits and advice of experts. The previous Psychology Support Center System managed the information of disaster victims through an independent database. However, this paper proposes a system that is developed to identify medical institutions and mental health centers within a distance of radius, based on the potential Hot-Spot areas of disaster victims using the GIS Systems. The proposed system can efficiently support selection of appropriate institutions for disaster victims using their location and age, classification of damage, and damaged parts of the body. Also, this spatial analysis can assist to decide on a policy based on the location of disaster victims and the extent of damage. Therefore, this paper can provide the required information to support decision making based on the concentrated areas for disaster victims.

High Dose Rate Ir-192 Source Calibration Method with Newly Designed Calibration Jig (고선량 Ir-192선원 교정기의 제작 및 특성)

  • Yi, Byong-Yong;Choi, Eun-Kyung;Chang, Hye-Sook
    • Radiation Oncology Journal
    • /
    • v.7 no.2
    • /
    • pp.299-303
    • /
    • 1989
  • Authors have developed highly reproducible calibration method for the Micro-Selectron HDR Ir-192 system (Nucletron, Motherland). The new jig has a 10cm radius circular hole in the $30cm{\times}30cm{\times}0.2cm$ acrylic plate, and 5F flexible bronchial tubes are attached around the hole. The source moves along the circle in the tubes and the ionization chamber is placed verticaly at the center of the circular hole (center of the jig). Dose distribution near the center was derived theoretically, and measured with the film dosimetry system. Theoretical calculation and measurement show the error margin below $0.1\%$ for 1mm or 2mm position deviation. We have measured at 12 and 24 points of circle with 1, 6, 11 and 21 second dwell time of source in order to calculate the activity of the source. Measurements have been repeated daily for 50 days. The accuracy and the reproducibility are below $1\%$ error margin. The half life of the source from our measurement is estimated $73.4\pm0.4$ days.

  • PDF