• Title/Summary/Keyword: activity coefficients

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Applying the Bi-level HMM for Robust Voice-activity Detection

  • Hwang, Yongwon;Jeong, Mun-Ho;Oh, Sang-Rok;Kim, Il-Hwan
    • Journal of Electrical Engineering and Technology
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    • v.12 no.1
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    • pp.373-377
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    • 2017
  • This paper presents a voice-activity detection (VAD) method for sound sequences with various SNRs. For real-time VAD applications, it is inadequate to employ a post-processing for the removal of burst clippings from the VAD output decision. To tackle this problem, building on the bi-level hidden Markov model, for which a state layer is inserted into a typical hidden Markov model (HMM), we formulated a robust method for VAD not requiring any additional post-processing. In the method, a forward-inference-ratio test was devised to detect the speech endpoints and Mel-frequency cepstral coefficients (MFCC) were used as the features. Our experiment results show that, regarding different SNRs, the performance of the proposed approach is more outstanding than those of the conventional methods.

Theoretical Calculation of Hydration Number and Activity Coefficients of Salts in Concentrated Electrolyte Solutions (진한 전해질 용액 중에서 염의 수화수와 활성도 계수에 관한 이론적 연구)

  • Yong Kil Sung;Mu Shik Jhon
    • Journal of the Korean Chemical Society
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    • v.14 no.2
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    • pp.185-192
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    • 1970
  • The extension of the theory of the electrolyte solution to the calculation of the hydration number and the mean activity coefficient of some 1:1 electrolytes in the concentrated solutions has been made. In this derivation, the hydration number has been calculated from the equation of the dielectric constant proposed by Hobbs, Jhon, and Eyring, and the mean activity coefficient from the theoretical formula developed by Jhon and Eyring. The agreement between theory and experiment over a.wide concentration range is quite satisfactory.

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Relations among Preschoolers' Temperament, Mothers' Parenting Behaviors, and Ability to Delay Gratification (유아의 기질 및 어머니의 양육행동과 만족지연능력간의 관계)

  • SunWoo, Hyun-Jung;Doh, Hyun-Sim
    • Korean Journal of Child Studies
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    • v.30 no.5
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    • pp.179-193
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    • 2009
  • The purpose of this study was to examine relationships between preschoolers' temperament, mothers' parenting behaviors, and ability to delay gratification. A sample of 131 preschool children aged from 4 to 5 participated in a delay-of-gratification experiment, as reconstructed by Rodriguez and his colleagues (2005). Mothers answered questionnaires on their parenting behaviors and children's temperament. Data were analyzed by t-test, Pearson's correlation coefficients, and multiple regressions. Children's activity as well as mothers' warmth and control predicted the ability to delay gratification; significant interaction effects were found between children's activity and maternal warmth on the ability to delay gratification. It would be plausible to intervene in children's activity level and improve the ability to delay gratification.

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Effects of Hope and Gratitude on Spirituality among Nursing Students (간호대학생의 희망, 감사성향이 영성에 미치는 영향)

  • Jo, Myoung-Ju;Jun, Won-Hee
    • The Journal of Korean Academic Society of Nursing Education
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    • v.20 no.4
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    • pp.569-576
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    • 2014
  • Purpose: This study investigates the factors affecting spirituality in nursing students. Method: A total of 247 nursing students participated in the study. Data were analyzed by frequencies, t-tests, ANOVA, Pearson correlation coefficients and multiple stepwise regression via SPSS WIN 18.0. Results: The mean scores for hope, gratitude, and spirituality were above-average. However, there were significant mean differences in spirituality according to religion, religious activity, voluntary service, satisfaction with the nursing field, and motivation for entering a college of nursing. Spirituality positively correlated with hope and gratitude. Significant predictors of spirituality included hope, gratitude, voluntary service and religious activity. The regression model explained 51.3% of perceived spirituality. Conclusion: To improve spirituality among nursing students, nursing educators should develop educational intervention programs to promote hope and gratitude, and support participation in voluntary service and religious activity.

Synthesis and Biopharmaceutical Studies of Cefazolin Butyrolactone Ester, a Novel Prodrug of Cefazolin (Cefazolin Butyrolactone Ester의 합성 및 생물약제학적 연구)

  • 이진환;조행남;최준식
    • YAKHAK HOEJI
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    • v.47 no.5
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    • pp.331-338
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    • 2003
  • A butyrolactone ester of cefazolin (CFZ-BTL) was synthesized by the esterification of cefazolin (CFZ) with $\alpha$-bromo-${\gamma}$-butyrolactone. The synthesis was confirmed by the spectroscopic analysis. The CFZ-BTL was more lipophilic than the CFZ when assessed by n-octanol/water partition coefficients at various pH. The CFZ-BTL itself did not show any antimicrobial activity in vitro, but after oral administration of CFZ-BTL to rabbits, exerted significant anti-microbial activity in serum samples when measured by the inhibion zone method in nutrient agar plates, due to conversion of CFZ-BTL to an active metabolite, probably CFZ, in the body. The CFZ-BTL was also converted into CFZ as confirmed by in vitro incubation study, with tissue homogenates (liver, blood and intestine) of rabbits. The liver showed the fastest conversion rate, probably via the hydrolysis mechanism. In vivo metabolism of CFZ-BTL to CFZ was also confirmed in vivo serum samples by HPLC. The oral bioavailability of CFZ-BTL in rabbits was 1.6-fold increased when compared to CFZ, resulting from followed by enhanced lipophilicity increased passive absorption in the intestine.

Production of Cyclodextrin Homologues Using Aqueous Two-Phase System

  • Chang, Woo-Jin;Koo, Yoon-Mo;Park, Sung-Sik
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.2 no.2
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    • pp.97-100
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    • 1997
  • Cyclodxtrin homologues(CDs), produced by cyclodextrin glycosyltransferase(CGTase), were simultaneously partitioned in aqueous two-phase system(ATPS). Partition coefficients of CDs were measured in PEG/dextran systems. Phosphate, citrate, sulfate were tested as salt. ATPS of PEG/salt and PEG/dextran had the partition coefficients of the CDs, larger than unity. However, PEG/dextran system was observed better than PEG/salt as CGTase activity decreased sharply with salt concentration. Enzymatic rection occurred mainly in PEG-rich bottom phase because of the low partition coefficient of CGTase. The resulting CDs transferred to the PEG-rich top phase, obeying the diffusional partition. In the ATPS of 7% PEG(M.W.40, 000), 7mg/ml of CDs were obtained in top phase at 4.5 hours.

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Solvent Extraction of Zinc from Strong Hydrochloric Acid Solution with Alamine336

  • Lee, Man-Seung;Nam, Sang-Ho
    • Bulletin of the Korean Chemical Society
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    • v.30 no.7
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    • pp.1526-1530
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    • 2009
  • Solvent extraction reaction of Zn(II) by Alamine336 from strong HCl solution up to 10 M was identified by analyzing the data reported in the literature. The equilibrium constant of this reaction was estimated by considering the complex formation between zinc and chloride ion. The necessary thermodynamic parameters, such as equilibrium constant for the formation of complexes and the interaction parameters, were evaluated from the thermodynamic data reported in the literature. The following solvent extraction reaction and the equilibrium constant was obtained by considering the activity coefficients of solutes present in the aqueous phase with Bromley equation. $Zn^{2+}\;2Cl^{-}\;+\;R_3NHCl_{org}\;=\;ZnCl_3R_3NH_{org},\;K_{ex}\;=\;6.33\;{\times}\;10^2$ There was a good agreement between measured and calculated distribution coefficients of Zn(II).

Solvent Extraction of Cobalt Chloride from Strong Hydrochloric Acid Solutions by Alamine336 (진한 염산용액에서 Alamine336에 의한 염화코발트의 용매추출)

  • Lee, Man-seung;Lee, Jin-Young
    • Korean Journal of Metals and Materials
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    • v.46 no.4
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    • pp.227-232
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    • 2008
  • Solvent extraction reaction of cobalt by Alamine336 from strong hydrochloric acid solution was identified by analyzing the solvent extraction data reported in the literature. Analysis of the data by graphical method revealed that Alamine336 took part in the solvent extraction reaction as a monomer in the concentration ranges, [Co(II)] : 0.0169 - 0.102 M, [Alamine336] ; 0.02- 1.75 M, and [HCl ] : 5 - 10 M. The following solvent extraction reaction and equilibrium constant was obtained from the experimental data by considering the activity coefficients of chemical species present in the aqueous phase. $Co^{2+}+2Cl^{-}+R_3NHCl_{org}=CoCl_3\;R_3NH_{org}$, $K_{ex}=2.21$ The distribution coefficients of cobalt predicted in this study agreed well with those reported in the literature.

Implementation of Wearable Heart Activity Monitoring System having Modified Bipolar Electrode and Correlation Analysis with Clinical Electrocardiograph(ECG) (수정된 바이폴라 전극을 갖는 착용형 심장활동 모니터링 시스템 구현 및 임상 심전도와의 상관관계 분석)

  • Lee, Kang-Hwi;Lee, Jeong-Whan;Lee, Young-Jae;Kim, Kyeong-Seop;Yang, Heui-Koung;Shin, Kun-Su;Lee, Myoung-Ho
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.57 no.6
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    • pp.1102-1108
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    • 2008
  • Wearable physiological signal monitoring systems are regarded as an important sensing unit platforms in ubiquitous/mobile healthcare application. In this paper, we suggested the modified bipolar electrodes implemented on the portable heart activity monitoring system, which minimized the distance of electrodes formed on a attachable pad. The proposed electrode configuration is useful in mobile measurement environments, but has a disadvantage of reduced amplitude of the heart action potential. In order to overcome the shortcoming of the suggested electrode configuration, we implemented the amplifying circuit to increase the signal-gain and decrease the artifacts. For evaluations, we analyzed the specificity of measured cardiography using the proposed electrodes through the comparing of heart activity monitoring system with standard clinical ECG(lead2) by pearson correlation coefficients. The result showed that the average correlation coefficient is $0.903{\pm}0.036,\;0.873{\pm}0.072$ at V3, V4 chest lead position, respectively. Thus, the modified bipolar electrode is quite suitable to monitor the electrical activity of the heart in the situation of the mobile environment, and could be considered having high similarity with standard clinical ECG.

Analysis of Orbital Lifetime Prediction Parameters in Preparation for Post-Mission Disposal

  • Choi, Ha-Yeon;Kim, Hae-Dong;Seong, Jae-Dong
    • Journal of Astronomy and Space Sciences
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    • v.32 no.4
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    • pp.367-377
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    • 2015
  • Atmospheric drag force is an important source of perturbation of Low Earth Orbit (LEO) orbit satellites, and solar activity is a major factor for changes in atmospheric density. In particular, the orbital lifetime of a satellite varies with changes in solar activity, so care must be taken in predicting the remaining orbital lifetime during preparation for post-mission disposal. In this paper, the System Tool Kit (STK$^{(R)}$) Long-term Orbit Propagator is used to analyze the changes in orbital lifetime predictions with respect to solar activity. In addition, the STK$^{(R)}$ Lifetime tool is used to analyze the change in orbital lifetime with respect to solar flux data generation, which is needed for the orbital lifetime calculation, and its control on the drag coefficient control. Analysis showed that the application of the most recent solar flux file within the Lifetime tool gives a predicted trend that is closest to the actual orbit. We also examine the effect of the drag coefficient, by performing a comparative analysis between varying and constant coefficients in terms of solar activity intensities.