• 약학회지
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• 제15권3_4호
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• pp.87-92
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• 1971

Fourteen novel N,N'-disubstitued thiourea derivatives were synthesized by Hugershof reaction. Antitubercular activities of ten compounds against Mycobacterium tuberculosis H$_{37}$ Rv were tested and was found tat 1-cyclohexyl-3-(4-benzenesulfonepiperidide)-2-thiourea was considerably active at 1mg/ml and 1-$\alpha$-naphthyl-3-(4-benzenesulfonepiperidide)-2-thiourea was slightly active at 1mg/ml. Antibacterial activity of the newly synthesized compounds against E. coli, Sta. aureus and Streptococcus hemolyticus were also tested. 1-cyclohexyl-3-(4-benzenesulfonepiperidide)-2-thiourea was makedly active against E. coli, Sta, aureus and Streptococcus hemolyticus; Phenol coefficients against E. coli, Sta, aureus and Streptococcus hemolyticus were 30,17.5 and 21.3, respectively. 1,1'-p-phenylene-3,3'bis[N-(2-thiazolyl)-sulfamylphenyl]-2,2'-dithiourea and 1-$\alpha$-naphthyl-3-(4-benzenesulfonepiperidide)-2-thiourea were considerably active against E. coli: phenol coefficients, 18.8 and 37.5 respectively. 1-(4-ethoxyphenyl)3-(4-sulfamylphenyl)-2-thiourea was active against Streptococcus hemolyticus: phenol coefficients, 22.5. 1-$\alpha$-naphthyl-3-(4-sulfamylphenyl)-2-thiourea, 1-$\betha$-naphthyl-3-[4-N-(2-thiazolyl)-sulfamylphenyl]-2-thiourea and 1-$\alpha$-naphthyl-3-(4-benzenesulfonepiperidide)-2-thiourea were active against Sta. aureus: phenol coefficients, 17.5, 20.0 and 18.8 respectively.

• Journal of Positioning, Navigation, and Timing
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• 제13권1호
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• pp.63-73
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• 2024

NeQuick G is the ionosphere model utilized by Galileo single-frequency users to estimate the ionospheric delay on each user-satellite link. The model is characterized by the effective ionization level (Az) index, determined by a modified dip latitude (MODIP) and broadcast coefficients derived from daily global space weather observations. However, globally fitted Az coefficients may not accurately represent ionosphere within local area. This study introduces a method for regional ionospheric modeling that searches for locally optimized Az coefficients. This approach involves fitting TEC output from NeQuick G to TEC data collected from GNSS stations around Korea under various ionospheric conditions including different seasons and both low and high solar activity phases. The optimized Az coefficients enable calculation of the Az index at any position within a region of interest, accounting for the spatial variability of the Az index in a polynomial function of MODIP. The results reveal reduced TEC estimation errors, particularly during high solar activity, with a maximum reduction in the RMS error by 85.95%. This indicates that the proposed method for NeQuick G can effectively model various ionospheric conditions in local areas, offering potential applications in GNSS performance analyses for local areas by generating various ionospheric scenarios.

• 대한화학회지
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• 제17권4호
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• pp.229-234
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• 1973

非水溶液 에틸렌디아민中에서, K-Hg,KI($C_1$) II ($C_2$)KI, Hg-K의 農談電位를 構成하여, 電位差法으로 電位差를 測定하여, Debye-Huckel型의 活性係數式으로 計算한 理論値와 比較한 결과 Marshall-Grunwald 식이 잘 適用되었다.

• Bulletin of the Korean Chemical Society
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• 제7권3호
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• pp.163-166
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• 1986

A new paraffin salt bridge was developed for the concentration cell in high pressure system. The emf values of the concentration cells were measured to calculate the activity coefficients of the electrolytic ions depending upon the pressure of the system. The activity coefficients of sodium, chloride and bromide ions increase with the temperature of the cell and decreased, nearly half at 2500 bars, $20^{\circ}C$, with the pressure. These results can be explained to be attributed to the volume change of the hydrated ion due to the electrostriction. The volume change decreased with pressure due to an increase in the degree of the hydration.

• 자원리싸이클링
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• 제27권5호
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• pp.9-13
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• 2018

화학반응의 평형상수는 표준자유에너지변화와 관련된다. 평형상수는 반응물과 생성물의 활동도의 비이며 수용액에서 이온강도의 증가로 인한 용질의 비이상성을 고려할 필요가 있다. 묽은 전해질용액에서 이온의 활동도계수를 구할 수 있는 식인 Debye-$H{\ddot{u}}ckel$ 식의 유도과정과 확장식을 설명하였다. 전해질의 평균활동도계수의 실험값로부터 이온의 활동도계수를 구하는 방법을 설명하였다.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2003년도 추계학술발표회
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• pp.132-135
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• 2003

Solution chemistry, sorbate chemistry, and sorbent chemistry were widely investigated to find important factors that affect PAH sorption on mineral surfaces and to elucidate its microscopic mechanism. The solution chemistry, pH and ionic strength caused measurable change of HOC sorption reaction to minerals. The detectable change of Ka occurred at a pH region crossing the PZC (Point of Zero Charge) of each mineral. The PAH hydrophobicity, one of sorbate chemistry, was observed to have a strong correlation with PAM sorption to mineral. Mineral surface area was not found to be a predominant factor controlling PAH sorption. The mineral type might be more likely to play a crucial role in controlling the PAH sorption behavior. The CEC (Cation Exchange Capacity) of mineral, representing surface charge density, has meaningful correlation with regression slope of sorption coefficients (log $K_{d}$) versus aqueous activity coefficients (log Υ$_{w}$).).).

• 대한화학회지
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• 제18권4호
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• pp.272-277
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• 1974

분배계수와 용매의 용해도 파라미터 도표상의 추출포물선을 검토하여 질산산성에서 유로퓸을 TBP로 추출할 때 유로퓸착물과 TBP의 활동도 계수간의 관계를 알 수 있었고 이에 따라 TBP의 용해도 파라미터를 결정하는 가능성을 제시하였다. 용매로서는 cyclohexane, 벤젠, 톨루엔, chlorobenzene을 사용하였고 TBP의 농도를 용적백분율로 5에서 50까지 변화시켰다.

• Nuclear Engineering and Technology
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• 제43권6호
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• pp.547-556
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• 2011

Two computational methods for determining equilibrium states for the Mark-IV electrorefiner (ER) have been assessed to improve the current computational electrorefiner model developed at University of Idaho. Both methods were validated against measured data to better understand their effects on the calculation of the equilibrium compositions in the ER. In addition, a sensitivity study was performed on the effect of specific unknown activity coefficients-including sodium in molten cadmium, zirconium in molten cadmium, and sodium chloride in molten LiCl-KCl. Both computational methods produced identical results, which stayed within the 95% confidence interval of the experimental data. Furthermore, sensitivity to unavailable activity coefficients was found to be low (a change in concentration of less than 3 ppm).

• 원예과학기술지
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• 제16권3호
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• pp.352-354
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• 1998

정밀 양액제어를 위하여 양액재배시스템 및 고정도의 양액의 계측/제어가 가능한 시스템을 제작하였고, EC 제어하에서 양액중의 각 이온이 EC에 기여하는 비율을 추정하였다. 양액재배시스템에 별도의 측정조를 사용하여 센서의 세척 및 측정이 가능하도록 설계하였고, 1대의 본체로 복수의 양액재배 시스템의 정밀 계측이 가능하였다. 또한 정량조를 이용한 Overflow 방식의 양액공급장치에 의하여 양액제어 결과, $EC{\pm}0.05mS/cm$, $pH{\pm}0.05$ 이하의 범위에서 양액의 정밀 제어가 가능하였다. EC 제어상태에서 양액중의 2가이온의 증가와 활동도계수의 감소가 나타났고, 활동도계수와 당량이온전 도도를 이용한 양액중의 각 이온의 EC기여도의 변화 내용이 확인되었다.

• 품질경영학회지
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• 제46권3호
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• pp.509-522
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• 2018

Purpose: The purpose of this study was to propose more accurate mathematical model which can represent result of government quality assurance activity, especially corrective action and flaw. Methods: The collected data during government quality assurance activity was represented through histogram. To find out which distributions (Poisson distribution, Zero-Inflated Poisson distribution) could represent the histogram better, this study applied Pearson's correlation coefficient. Results: The result of this study is as follows; Histogram of corrective action during past 3 years and Zero-Inflated Poisson distribution had strong relationship that their correlation coefficients was over 0.94. Flaw data could not re-parameterize to Zero-Inflated Poisson distribution because its frequency of flaw occurrence was too small. However, histogram of flaw data during past 3 years and Poisson distribution showed strong relationship that their correlation coefficients was 0.99. Conclusion: Zero-Inflated Poisson distribution represented better than Poisson distribution to demonstrate corrective action histogram. However, in the case of flaw data histogram, Poisson distribution was more accurate than Zero-Inflated Poisson distribution.