• 한국진공학회:학술대회논문집
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• 한국진공학회 2012년도 제43회 하계 정기 학술대회 초록집
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• pp.411-411
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• 2012

Over the recent years, surface enhanced Raman spectroscopy (SERS) has dramatically grown as a label-free detecting technique with the high level of selectivity and sensitivity. Conventional SERS-active nanostructured layers have been deposited or patterned on rigid substrates such as silicon wafers and glass slides. Such devices fabricated on a flexible platform may offer additional functionalities and potential applications. For example, flexible SERS-active substrates can be integrated into microfluidic diagnostic devices with round-shaped micro-channel, which has large surface area compared to the area of flat SERS-active substrates so that we may anticipate high sensitivity in a conformable device form. We demonstrate fabrication of flexible SERS-active nanostructured substrates based on soft-lithography for simple, low-cost processing. The SERS-active nanostructured substrates are fabricated using conventional Si fabrication process and inkjet printing methods. A Si mold is patterned by photolithography with an average height of 700 nm and an average pitch of 200 nm. Polydimethylsiloxane (PDMS), a mixture of Sylgard 184 elastomer and curing agnet (wt/wt = 10:1), is poured onto the mold that is coated with trichlorosilane for separating the PDMS easily from the mold. Then, the nano-pattern is transferred to the thin PDMS substrates. The soft lithographic methods enable the SERS-active nanostructured substrates to be repeatedly replicated. Silver layer is physically deposited on the PDMS. Then, gold nanoparticle (AuNP) inks are applied on the nanostructured PDMS using inkjet printer (Dimatix DMP 2831) to deposit AuNPs on the substrates. The characteristics of SERS-active substrates are measured; topology is provided by atomic force microscope (AFM, Park Systems XE-100) and Raman spectra are collected by Raman spectroscopy (Horiba LabRAM ARAMIS Spectrometer). We anticipate that the results may open up various possibilities of applying flexible platform to highly sensitive Raman detection.

• 한국표면공학회지
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• 제52권3호
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• pp.180-185
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• 2019

The demands to improve the performance of the vanadium redox flow battery have attracted an intense research on modifying the carbon-based electrode. In this study, the surface of graphite felt was reformed, using cobalt oxide. The cobalt oxide was implanted into graphite felt during hydrothermal and two step heat treatments. The cobalt was deposited by hydrothermal method and the two step heat treatments made lots of holes on the graphite felt surface which is called as porous surface. The porous surface acts as an electrochemically active site for the cathodic reaction of vanadium redox flow battery. The reformed electrode shows the electrochemically improved performance compared with the pristine electrode.

• 한국군사과학기술학회지
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• 제18권5호
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• pp.538-547
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• 2015

The goal of this study is to develop an algorithm to propose optimal deployment of detection sensor nodes in the target area, based on a performance surface, which represents detection performance of active and passive acoustic sonar systems. The performance surface of the active detection system is calculated from the azimuthal average of maximum detection ranges, which is estimated with a transmission loss and a reverberation level predicted using ray-based theories. The performance surface of the passive system is calculated using the transmission loss model based on a parabolic equation. The optimization of deployment configurations is then performed by a hybrid method of a virtual force algorithm and a particle swarm optimization. Finally, the effectiveness of deployment configurations is analyzed and discussed with the simulation results obtained using the algorithm proposed in this paper.

• 공업화학
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• 제3권2호
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• pp.224-229
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• 1992

지방산과 소디움 이세치오네이트로부터 음이온 계면활성제인 소디움 아실 이세치오네이트를 합성하여 이를 정제하고 각 아실기에 따른 계면활성의 경향을 연구하기 위하여 표면장력, 기포도, 기포 안정도, 분산력, 세정력 및 c.m.c 등을 측정하였다. 그 결과 소디움 아실 이세치오네이트는 우수한 계면활성을 나타내었으며, c.m.c 농도는 $1.1{\times}10^{-4}mol/l$에서 $4.8{\times}10^{-3}mol/l$ 부근에서 추정되었고, 이 때의 표면장력은 26.8dyn/cm에서 36.7dyn/cm이었다.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2009년도 제38회 동계학술대회 초록집
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• pp.35-35
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• 2010

Understanding the mechanistic details of heterogeneous catalytic reactions will provide a way to tune the selectivity between various competing reaction channels. In this regard, catalytic decomposition of alcohols over the rutile $TiO_2$(110) surface as a model oxide catalyst has been studied to understand the reaction mechanism employing the temperature-programmed desorption (TPD) technique. The $TiO_2$(110) model catalyst is found to be active toward alcohol dehydration. We find that the active sites are bridge-bonded oxygen vacancies where RO-H heterolytically dissociates and binds to the vacancy to produce alkoxy (RO-) and hydroxyl (HO-). Two protons adsorbed onto the bridge-bonded oxygen atoms (-OH) readily react with each other to form a water molecule at ~500 K and desorb from the surface. The alkoxy (RO-) undergoes decomposition at higher temperatures into the corresponding alkene. Here, the overall desorption kinetics is limited by a first-order decomposition of intermediate alkoxy (RO-) species bound to the vacancy. We show that detailed analysis on the yield and the desorption temperatures as a function of the alkyl substituents provides valuable insights into the reaction mechanism. After the catalytic role of the oxygen vacancies has been established, we employed x-ray photoelectron spectroscopy to further study the surface electronic structure related to the catalytically active defective sites. The defect-related state in valence band has been related to the chemically reduced $Ti^{3+}$ defects near the surface region and are found to be closely related to the catalytic activity of the $TiO_2$(110) surface.

• 한국표면공학회지
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• 제37권2호
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• pp.128-136
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• 2004

Effects of alloying elements on the surface characteristics of Fe-38Al intermetallic compounds were investigated using potentiostat. The specimens were casted by the vacuum arc melting. The subsequent homogenization and the stabilization led to the homogeneous DO$_3$ structure of the specimen. After the corrosion tests, the surface of the tested specimen was observed by the optical microscopy and scanning electron microscopy(SEM). For Fe-38 at.% Al intermetallic compound, the addition of Cr and Mo proved to be beneficial in decreasing the grain boundary attack by decreasing the active current density. Addition of Band Nb resulted in a higher active current density and also a higher passive current density. These results indicated the role of Cr and Mo in improving the pitting corrosion resistance of Fe-38 at.%Al intermetallic compound. Band Nb addition to Fe-38 at.%Al accelerated the granular corrosion. Fe-38 at.%Al containing Cr and Mo showed remarkably improved pitting corrosion resistance in comparison with Band Nb addition to Fe-38 at. %Al.

• 한국응용과학기술학회지
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• 제4권1호
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• pp.45-52
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• 1987

Surface chemical properties including surface tension, Ross-Miles foaming power, foam stabilities, emulsifying properties, emulsion stabilities, effectiveness of dispersion, dispersion stabilites of the quaternary ammonium salt type deoxyaminoimositol derivatives such as sixteen kinds of dimethylafkyl-deoxyscyllo-inosityl- dimethylalkyl-2-deoxy-2-myo-inosityl-, dimethylakyl-2-deoxy-2-epi-inosityl- and dimethylalkyl-4-deoxy-4-myo-inosityl ammonium chlorides are tested. And critical micelle concentration of these compounds are estimated from the curves of surface tension and concentration. The experimental results show that the members of this class of compounds have necessary surface active properties to make them effective surfactants.

• 대한전자공학회:학술대회논문집
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• 대한전자공학회 2003년도 하계종합학술대회 논문집 V
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• pp.2733-2736
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• 2003

This paper proposes a dry-type active surface EMG electrode for the myoelectric prosthetic hand. The designed electrode is small size for embedding in the socket of prosthetic hand, and it has three leads including the reference of signal. To acquire EMG signal rejected the power noise, a precision differential amplifier and various filters such as the band pass filter band rejection filter, low pass and high pass filter are embedded on the electrode. The final output of the electrode is integrated absolute EMG (IEMG) obtained by full rectifier and moving average circuits. From experimental results using the implemented dry-type active surface EMG electrode, the proposed electrode is feasible for the myoelectric prosthetic hand.

• Smart Structures and Systems
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• 제25권6호
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• pp.643-655
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• 2020

Active control of nonlinear vibration of stiffened functionally graded (SFG) cylindrical shell is studied in this paper. The system is subjected to axial and transverse periodic loads in the presence of thermal uncertainty. The material composition is considered to be continuously graded in the thickness direction, also these properties depend on temperature. The relations of strain-displacement are derived based on the classical shell theory and the von Kármán equations. For modeling the stiffeners on the cylindrical shell surface, the smeared stiffener technique is used. The Galerkin method is used to discretize the partial differential equations of motion. Some comparisons are made to validate the SFG model. For suppression of the nonlinear vibration, the linear and nonlinear control strategies are applied. For control objectives, the piezoelectric actuator is attached to the external surface of the shell and the thin ring piezoelectric sensor is attached to the middle internal surface of shell. The effect of PID, feedback linearization and sliding mode control on the suppression of vibration for SFG cylindrical shell is presented.

• 한국결정성장학회지
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• 제22권6호
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• pp.269-273
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• 2012

Ammonia decomposition over titanium carbides were investigated using eight different samples which have been synthesized by TPR (temperature-programmed reduction) method of titanium oxide ($TiO_2$) with pure $CH_4$. The resulting materials which were synthesized using wo different heating rates and space velocity exhibited the different surface areas. These results indicated that the structural properties of these materials have been related to heating rates and space velocity employed. The titanium carbides prepared in this study proved to be active for ammonia decomposition, and the activity changed with the particle size/surface area. These showed the relationship between ammonia decomposition activity and the different active species. Compared to molybdenum carbide, the titanium carbides were one order of magnitude less active, suggesting the correlation between the activity difference and the degree of electron transfer between metals and carbon in metal carbides.