• KSBB Journal
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• v.6 no.2
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• pp.157-166
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• 1991

The structural properties of cellulose are significantly changed with the progress of hydrolysis reaction. The effects of changes on such properties of cellulosic substrate as crystallinity, amicessibility of enzyme to the active site of cellulose surface, and particle size on the kinetics of enzymatic hydrolysis have been studied. Among those physical studies, the apparent surface active site of cellulose particle was found to have the most significant effect on the hydrolysis kinetics. Based on the experimental results, the adsorption affinity of enzyme and hydrolysis rate were mainly influenced by the surface roughness of cellulose particle. The extent of accesssible active site may be expressed as the change of particle diameter. The Langmuir isotherm was proposed in terms of enzyme activity to explain the actual action of enzyme protein.

• Journal of the Korean Geotechnical Society
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• v.20 no.8
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• pp.181-191
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• 2004

For a rigid retaining wall with rough face, the magnitude and distribution of active earth pressure on the wall are affected by the shape of failure surface and arching effect developed in the backfill as well as internal friction angle of the backfill and wall friction angle. Therefore, the practical shape of failure surface and arching effect in the backfill must be considered to acquire accurate magnitude and non-linear distribution of active earth pressure acting on the rigid retaining wall. In this study, a new formulation for calculating the active earth pressure on a rough rigid retaining wall rotating about the top is proposed considering the practical shape of non-linear failure surface and arching effects. Accuracy of the proposed equation is checked through comparisons of calculations from the proposed equations with existing model test results. The comparisons show that the proposed equations produce satisfactory results.

• Journal of Powder Materials
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• v.19 no.6
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• pp.424-428
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• 2012

Nano Pd spot-coated active carbon powders were synthesized by a hydrothermal-attachment method (HAA) using PVP capped Pd colloid in a high pressure bomb at $250^{\circ}C$, 450 psi, respectively. The PVP capped Pd colloid was synthesized by the precipitation-redispersion method. PVP capped Pd nano particles showed the narrow size distribution and their particle sizes were less than 8nm in diameter. In the case of nano Pd-spot coated active carbon powders, nano-sized Pd particles were adhered in the active carbon powder surface by HAA method. The component of Pd was homogeneously distributed on the active carbon surface.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2001.07a
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• pp.753-756
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• 2001

This research made a study of MnO$_2$electrode for supercapacitor with a diffuser (Polyvinyl alcohol). Manganese dioxide was used as active material. We tried to increase specific surface area by adding PVA. Manganese dioxide was synthesized by a sol-gel method using fumaric acid and oxalic acid in low temperature with high yield. Therefore, We prepared Manganese dioxide powder. This powder was used by active materials. The electrode was made by a mixture of active material, ketjen-black which is a large specific surface area, and PVdF-co-HFP as binder agent with using Nickel mesh as current collector. Here we reported on the synthesis and electrochemical performance of a enhanced material. All active materials have been submitted to X-ray diffraction and Scanning electron microscopy.

• Journal of KSNVE
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• v.5 no.3
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• pp.313-325
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• 1995

Two active/passive vibration dampers were designed to control a cantilever beam first mode of vibration. The active element was a piezoelectric polymer, polyvinlidene fluoride (PVDF). The passive damping was provided by the application of a viscoelastic layer on the surface of the steel beam. Two substantially different damper configurations were designed and tested. One damper consisted of a piezoelectric actuator bonded to one face of the beam, with a viscoelastic layer applied to the other surface of the beam. The second one was composed of a layer viscoeastic layer with one surface bonded to the beam, and with other being constrained by nine piezoelectric actuators connected in parallel. A control law based on the sign of the angular velocity of the cantilever beam was implemented to control the beam first mode of vibration. The piezoelectric sensor output was digitally differentiated to obtain the transverse linear velocity, and its sign was used in the control algorith. Two dampers provided the system a damping increase of a factor of four for the first damper and three for the second damper. Both dampers were found to work well at low levels of vibration, suggesting that they can be used effectively to prevent resonant vibrations in flexible structure from initiating and building up.

• Journal of the Korean Applied Science and Technology
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• v.30 no.4
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• pp.726-739
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• 2013

Fischer-Tropsch synthesis (FTS) converts synthesis gas (CO and $H_2$) into longer chain hydrocarbons by a surface polymerization reaction. Cobalt- or iron-based catalysts normally show excellent activity for syngas conversion to petroleum products leading to super clean diesel fuels. The catalytic activities of the catalysts in FTS depend on the number of active sites on the surface. The number of active site was determined by the active metal particle size, loading amount, reduction degree and support-active metal interaction. The investigation adopts new methodology in preparing FT catalyst, which contains the controlled synthesis of active metal. The main focus of this paper is to give an overview of the types of catalysts, also including their preparation and reduction; the types of FT reactors; and also including the reaction conditions.

• Journal of Biomedical Engineering Research
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• v.41 no.6
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• pp.264-271
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• 2020

The purpose of this study was to investigate the effects of active vibration exercise of upper limb on physical capacity index (endurance, grip strength, balance, and flexibility) and vasomotor index (capillary length and body surface temperature) in middle aged women. 20 participants randomly divided into two groups: vibro-swing exercise (VSE) and non vibro-swing exercise (NVSE). Subjects in each group measured the 30 second arm curl test, hand dynamometer, one leg standing test, back scratch test, nail fold capillary microscope (NFM), and digital infrared thermal imaging (DITI) before and after exercise. The results showed that active vibration exercise of upper limb with vibro-swing equipment increased the endurance, balance ability, and the capillary length. In addition, changes in body temperature immediately after exercise were predicted to affect vasomotor. Active vibration exercise of upper limb has the advantage of being able to exercise anywhere regardless of the location by inducing different frequency changes in movement of various ranges and velocity. For this reason, the combination of vibration and active movement can be expected the physiological effects when producing exercise programs for middle aged women.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1994.05a
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• pp.141-143
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• 1994

One of the Principal problems encountered in the use of filer reinforced composites is to establish an active fiber surface to achieve maximum adhesion between resin and fiber surface. Now, we want to develope new process that will overcome the disadvantage of the chemical coupling agent and achieve maximum adhesion at the interface between resin and fiber by active plasma treatment on the glass fiber surface. In this study. we investigated the effect of plasma treatment on the wettability of glans surface .

• Bulletin of the Korean Chemical Society
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• v.20 no.7
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• pp.786-790
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• 1999

Relatively inert surface of microcrystalline MgO was modified into chemically active one by carrying out controlled hydration followed by dehydration at elevated temperature under dynamic vacuum. Even though the treatment by the first cycle of hydration-dehydration did not alter the porosity of MgO, it largely enhanced surface reactivity of the MgO toward adsorbed water, turning its outer layer into brucite upon rehydration. Treatment by the second cycle of hydration-dehydration generated micropores, and slit-shaped mesopores, raising the porosity of the MgO. The overlayer of Fe2O3 of the core/shell type composite magnesium oxide enhanced this surface modification, turning its surface into more porous and more active one than that of uncoated MgO, after the treatment by the hydration-dehydration.

• Advances in nano research
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• v.13 no.5
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• pp.417-426
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• 2022

Bisphenol A (BPA) is one of the chemicals used in monomer epoxy resins and polycarbonate plastics. The surface-enhanced Raman spectroscopy (SERS) method is precise for identifying biological materials and chemicals at considerably low concentrations. In the present article, the substrates coated with gold nanoparticles have been studied to identify BPA and control the diseases caused by this chemical. Gold nanoparticles were made by a simple chemical method and by applying gold salt and trisodium citrate dihydrate reductant and were coated on glass substrates by a spin-coat approach. Finally, using these SERS substrates as plasmonic sensors and Raman spectroscopy, the Raman signal enhancement of molecular vibrations of BPA was investigated. Then, the molecular vibrations of BPA in some consumer goods were identified by applying SERS substrates as plasmonic sensors and Raman spectroscopy. The fabricated gold nanoparticles are spherical and quasi-spherical nanoparticles that confirm the formation of gold nanoparticles by observing the plasmon resonance peak at 517 nm. Active SERS substrates have been coated with nanoparticles, which improve the Raman signal. The enhancement of the Raman signal is due to the resonance of the surface plasmons of the nanoparticles. Active SERS substrates, gold nanoparticles deposited on a glass substrate, were fabricated for the detection of BPA; a detection limit of 10-9 M and a relative standard deviation (RSD) equal to 4.17% were obtained for ten repeated measurements in the concentration of 10-9 M. Hence, the Raman results indicate that the active SERS substrates, gold nanoparticles for the detection of BPA along with the developed methods, show promising results for SERS-based studies and can lead to the development of microsensors. In Raman spectroscopy, SERS active substrate coated with gold nanoparticles are of interest, which is larger than gold particles due to the resonance of the surface plasmons of gold nanoparticles and the scattering of light from gold particles since the Raman signal amplifies the molecular vibrations of BPA. By decreasing the concentration of BPA deposited on the active SERS substrates, the Raman signal is also weakened due to the reduction of molecular vibrations. By increasing the surface roughness of the active SERS substrates, the Raman signal can be enhanced due to increased light scattering from rough centers, which are the same as the larger particles created throughout the deposition by the spin-coat method, and as a result, they enhance the signal by increasing the scattering of light. Then, the molecular vibrations of BPA were identified in some consumer goods by SERS substrates as plasmonic sensors and Raman spectroscopy.