• Journal of Environmental Health Sciences
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• v.32 no.5 s.92
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• pp.485-491
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• 2006

It is widely known that Environmental Tobacco Smoke(ETS) is not good for health. ETS is composed of a lot of chemicals. So indicators are needed to evaluate the risk of ETS in air. One of the indicators is Nicotine. Active sampler has been used to measure nicotine concentration in air. The experiments were conducted to compare the active sampler method with diffusive sampler in exposure chamber and smoking areas, respectively. Sampling rate was 40.5 ml/min in exposure chamber. Experimental sampling rate (40.5 ml/min) was more than theoretical sampling rate (33.52 ml/min). And the higher was the concentration in air, the higher was experimental sampling rate. The average desorption, rate was 113.6%. The overall precision was 7.31 %. The overall accuracy was 18.96%, which were under NIOSH criteria. The average(GM) concentrations of nicotine by two sampling methods were $8.29{\mu}g/m^{3}$ (active sampler), $7.54{\mu}/m^{3}$ (diffusive sampler) in smoking area and smoking room. There was no regression between active sampler and diffusive sampler ($R^{2}=0.2397$). But slope, coefficient of determination was 1.017, 0.9292, respectively after removing outliers. And the slope (1.017) was close to the theoretical slope (1). In conclusion, this study indicated that diffusive sampler can be used to evaluate concentration of nicotine in air instead of active sampler.

• Proceedings of the Korean Environmental Health Society Conference
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• 2005.06a
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• pp.371-372
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• 2005

Active sampler has been widely used to measure nicotine concentration in air. The experiments were conducted to compare the active sampler method with diffusive sampler in exposure chamber and smoking areas, respectively. The result of these tests that indicated that passive sampler can be used instead of active sampler in ETS, because coefficient of determination was 0.9292 between active and passive sampling in smoking area

• Journal of Korean Society of Environmental Engineers
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• v.33 no.11
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• pp.790-796
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• 2011

In this study, we measured the concentrations of volatile organic compounds (VOCs) in Shiwha area by using active and passive sampler. We did a comparative analysis of the characteristics of the active sampler and passive sampler. In the case of the passive sampler, the average TVOC concentration of the industrial area was 1.86 times higher than that of the residential area. In the case of the active sampler, the average TVOC concentration of the industrial area was 1.07 times higher than that of the residential area. When using the passive sampler, the concentration of VOCs in the industrial area was noted to be higher than the concentration found in the residential area. However, when we used the thermal desorption tube, the concentration of residential area was higher rather than that of industrial area in some substances such as trichloroethylene, toluene, ethylbenzene, and xylene. Toluene was a larger percentage of the overall BTEX ratio. In case of the passive sampler, the relative ratio of toluene, ethylbenzene, and xylene was higher in the industrial area than in the residential area. In contrast in case of the thermal desorption tube, the ratio of these substances was higher in the residential area rather than in the industrial area. The passive sampling in this study showed an appropriate method to analyze the temporal and spatial concentrations of air contaminants. This assessment would prove to be useful for its observance of standards or epidemical study.

• Journal of Korean Society for Atmospheric Environment
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• v.29 no.1
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• pp.56-63
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• 2013

This study was aimed at developing and evaluating a diffusive sampling method using a barium hydroxide solution as an absorbent for measuring carbon dioxide ($CO_2$) in ambient air. The collected $CO_2$ concentration was calculated by the change of conductivity resulted in the reaction of $CO_3{^{2-}}$ and $Ba^{2+}$ in aqueous solution. The sampling rate for the diffusive sampler was determined 0.218 mL/min, as obtained from the slope of the linear correlation between the $CO_2$ mass collected by the diffusive sampler and the time-weighted $CO_2$ concentration with the active sampling method. The unexposed blank sampler sealed in aluminium foil-polyethylene laminated packets has remained stable during at least one-month storage period. A good correlation was observed between the diffusive sampler and active sampler with a coefficient of determination of 0.956. This diffusive sampler would be suitable for the indoor $CO_2$ concentration monitoring.

• Journal of Korean Society for Atmospheric Environment
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• v.21 no.6
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• pp.593-603
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• 2005

Passive sampler using 4-amino-3-hydrazino-5-mercapto-1, 2, 4-triazole (AHMT) was developed to determine formaldehyde in indoor environment. The chromatography paper cleaned by $3\%$ hydrogen peroxide solution was experimently determined as a optimum absorbtion filter for the collection of formaldehyde. The passive sampler with a broad cross-sectional area and a short diffusion length was quite good in sensitivity. The passive sampler and the active sampling method with an impinger were strongly correlated with a correlation coefficient of 0.9848. The limits of detection and quantification of the passive sampler for the measurement of formaldehyde in the indoor environment were 7.5 and 10.2 ppb, respectively. Temperature ($19\∼28^{circ}C$) and relative humidity ($30\∼90\%$) had slight influence on the sampling rate of the passive sampler. However, the increase of flow velocity on the surface of sampler resulted in the increase of sampling rate.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.15 no.3
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• pp.261-269
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• 2005

To investigate the field applicability of a diffusive sampler (3M OVM #3500, passive sampling method) authors conducted a simultaneous measurement of personal organic solvents exposure in the air of the workplaces by charcoal tube with low volume sampler (active sampling method) and diffusive sampler. Samples were collected and analyzed by NIOSH method ($NMAM^{(R)}$) from thirty-eight workers in 12 factories who work in 6 different processes. Geometric mean (GM) and geometric standard deviation (GSD) were used to describe the result. To compare the results of the two methods, paired t-test was used. According to the manual of the exposure assessment of the mixed organic solvents (Ministry of Labor, Korea), Em was calculated. Simple linear regression was used to evaluate the relationship between the two methods. Results were as follows; 1. Eight different solvents (ethyl acetate, n-hexane, toluene, xylene, acetone, isopropyl alcohol, methyl ethyl ketone (MEK), and methyl isobutyl ketone) were detected simultaneously in the two methods and the concentrations of the personal exposure were lower than 0.5 TLV level. The concentration of the charcoal tube method was higher than that of a diffusive sampler in n-hexane and MEK (p<0.05). 2. Em of the charcoal tube method was higher than that of diffusive sampler method but not significantly different and was lower than the OEL (Occupational Exposure Limit) in all 6 processes. 3. There was a significant correlation between the two methods in low concentrations of the 8 organic solvents (p<0.05). In conclusion, there was no difference in charcoal tube method and diffusive sampler method in low concentrations of some organic solvents, diffusive sampler can be applied to assess the personal monitoring in low level exposure.

• Journal of Environmental Health Sciences
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• v.41 no.2
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• pp.116-125
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• 2015

Objective: This study was carried out to use pine needles as a passive air sampler (PAS) for atmospheric polychlorinared dibenzo-p-dioxins/furans (PCDD/Fs). Methods: PCDD/Fs concentrations in ambient air ($C_a$, $pg/m^3$) and deposited pine needles ($C_p$, pg/g dry) were analyzed simultaneously from June 1 to December 31. Air samples were taken using two low volume PUF active air samplers with an overall average air volume of approximately $1,200Sm^3$. Pine needles were collected the end of December near the air sampler. PCDD/Fs was analyzed by HRGC/HRMs. Results: A good correlation was shown ($R^2=0.6357$, p=0.0001) between $C_a$ and $C_p$, but a better correlation ($R^2=0.7372$, p<0.0001) existed between the logarithm of octanol-air partitioning coefficient ($LogK_{oa}$) and Log($C_p/C_a$). The average PCDD/Fs sampling rates from air to pine needles were 0.045($0.018-0.185m^3/day-g\;dry$). Conclusion: It was found that pine needles can be used as PAS for atmospheric PCDD/Fs, and they are especially suitable for long time PAS compared to PUF disk PAS.

• Journal of Environmental Health Sciences
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• v.38 no.4
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• pp.360-368
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• 2012

Objective: This study was carried out to use pine needles as a passive air sampler (PAS) of atmospheric Polychlorinated Biphenyls (PCBs). Methods: PCB concentrations in ambient air ($C_a$, ng/$m^3$) and deposited on pine needles ($C_p$, ng/g dry) were analyzed simultaneously from June 1 to December 31. Air samples were taken using a low volume PUF active air sampler and the overall average air volume was about 900-1,000 $m^3$. Pine needles were collected at the end of August and December near the air sampler. Results: $C_a$ were higher at higher air temperature and lower chlorinated PCB congeners, but $C_p$ showed irregular distribution. The average PCB sampling rates from air to pine needles were 0.116 (0.002-0.389) $m^3$/day - g dry. Conclusions: A poor correlation was shown between $C_a$ and $C_p$. However, a good correlation was shown between the logarithm of octanol-air partitioning coefficient ($logK_{oa}$) and log ($C_p/C_a$), and the interrelation was better with longer sampling time (June to December) than shorter sampling time (June to August). The average PCB sampling rates from air to pine needles were the lowest with respect to PUF disk, XAD-2 resin and semipermeable membrane devices (SPMDs) PAS. The average ratio ($C_{a-calc}/C_{a-meas}$) of calculated ($C_{a-calc}$) and measured ($C_{a-meas}$) PCB concentration was 0.69 with a shorter sampling time and 1.24 with a longer, so $C_{a-calc}$ was close to $C_{a-meas}$. It was found that pine needles can be used as PAS of atmospheric PCBs, and are especially suitable for long-time PAS.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.9 no.1
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• pp.173-186
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• 1999

To utilize diffuse sampling of formaldehyde in air, a new sampler was designed. A glass fiber filter was impegnated with 2,4-dinitrophenylhydrazine(DNP) and phosphoric acid and mounted 37mm cassette. The formaldehyde vapor was sampled in the dynamic chamber and measured by high performance liquid chromatograph and compared with solid sorbent tube. The results were as follows ; 1. The desorption efficiencies of diffusive sampler between 97.0% and 100%. 2. the sampling rate is constant as in $58{\sim}61.8m{\ell}/min$ when sampling times are between 120 and 360 min. 3. There was a significant relationship between concentrations of diffusive samples and active samples with the coefficient of determination(R2) of 0.92. 4. Desorbed amount of formaldehyde diffusive sampler was increased by high relative humidity. 5. Wheth diffusive samplers were stored at room temperature or at refrigerator there was no statistically significant difference in the accuracy of result. 6. When the diffusive samplers, which collected formaldehyde vapor, were exposed to clean air for three hours, there was no significant loss of formaldehyde due to reverse diffusion. In conclusion, this study suggest that developed diffusive samplers will be a reasonable substitute for the solid sorbent tube for sampling formaldehyde and practical comparative study of developed diffusive sampler should be performed at workplaces of manufacturing industry.

• Environmental Analysis Health and Toxicology
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• v.17 no.2
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• pp.147-160
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• 2002

Volatile organic compounds (VOCs) are an important public health issue in Korea and many important questions remain to be addressed with respect to assessing exposure to these compounds. Because they are ubiquitous and highly volatile, special techniques must be applied in their analytic determination Valid Personal exposure assessment methods are needed to evaluate exposure frequency, duration and intensity, as well as their relationship to personal exposure characteristics. Biological monitoring is also important since it may contribute significantly in risk assessment by allowing the estimation of effective absorbed doses. This study was on ducted to establish the environmental measurement, personal dosimetry and biological monitoring methods for VOCs. These methods are needed to compare blood, urinary and exhalation breath VOC levels and to provide tools for risk assessment of VOC exposure. Passive monitors (badge type) and a active samplers (trap) for the VOCs collection were used for air sampling. Methods development included determining the minimum detectable amounts of VOCs in each media, as well as evaluating collection methods and developing analytical procedures. Method reliability was assessed by determining breakthrough volumes and comparing results between laboratories and with other methods. A total capacity of trap used in this study was 60ι. Although variable by compound, the average breakthrough was 20％. Also, there was no loss of compounds in trap even if keep for 45 day in -7$0^{\circ}C$. The recovery of active and passive methods was 69％ ~ 126％ and method detection limit was 0.24 $\mu\textrm{g}$/trap and 0.07 $\mu\textrm{g}$/badge. There was no statistical difference (P > 0.05) between active and passive methods.