• 제목/요약/키워드: active materials

검색결과 2,529건 처리시간 0.031초

Binder-Free Synthesis of NiCo2S4 Nanowires Grown on Ni Foam as an Efficient Electrocatalyst for Oxygen Evolution Reaction

  • Patil, Komal;Babar, Pravin;Kim, Jin Hyeok
    • 한국재료학회지
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    • 제30권5호
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    • pp.217-222
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    • 2020
  • The design and fabrication of catalysts with low-cost and high electrocatalytic activity for the oxygen evolution reaction (OER) have remained challenging because of the sluggish kinetics of this reaction. The key to the pursuit of efficient electrocatalysts is to design them with high surface area and more active sites. In this work, we have successfully synthesized a highly stable and active NiCo2S4 nanowire array on a Ni-foam substrate (NiCo2S4 NW/NF) via a two-step hydrothermal synthesis approach. This NiCo2S4 NW/NF exhibits overpotential as low as 275 mV, delivering a current density of 20 mA cm-2 (versus reversible hydrogen electrode) with a low Tafel slope of 89 mV dec-1 and superior long-term stability for 20 h in 1 M KOH electrolyte. The outstanding performance is ascribed to the inherent activity of the binder-free deposited, vertically aligned nanowire structure, which provides a large number of electrochemically active surface sites, accelerating electron transfer, and simultaneously enhancing the diffusion of electrolyte.

구형 활성탄소의 합성 및 응용 (Synthesis and Applications of Spherical Active Carbon Materials)

  • 김홍경
    • 융복합기술연구소 논문집
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    • 제3권1호
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    • pp.45-49
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    • 2013
  • Spherical active carbon materials have been used for the removal of pollutants in the area of food processing, water treatment, air purification, oral administration. Moreover, they are now expected to make an epoch in the areas of electronics, life science, environmental technology, and so on due to their superior physical properties. Carbon particles should be requested for the edgeless spherical shapes in order to minimize the loss due to the abrasion during the process and/or practical use, but the carbon particles manufactured from petroleum-based pitch do not meet these needs. Nowadays, thus, the spherical active carbon particles carbonized from various spherical polymer beads are studied with thermoplastic and/or thermosetting polymers. In this paper, the synthesis of spherical phenolic beads and furan beads, which are thermosetting polymers, and their carbonization techniques are examined.

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분산제 PVA에 따른 수퍼커패시터용 이산화망간전극의 전기 화학적 특성 (Electrochemical Properties of MnO$_2$electrode for supercapactor wish a Diffuser (Polyvinylalcohol))

  • 이상오;김한주;박수길
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 하계학술대회 논문집
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    • pp.753-756
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    • 2001
  • This research made a study of MnO$_2$electrode for supercapacitor with a diffuser (Polyvinyl alcohol). Manganese dioxide was used as active material. We tried to increase specific surface area by adding PVA. Manganese dioxide was synthesized by a sol-gel method using fumaric acid and oxalic acid in low temperature with high yield. Therefore, We prepared Manganese dioxide powder. This powder was used by active materials. The electrode was made by a mixture of active material, ketjen-black which is a large specific surface area, and PVdF-co-HFP as binder agent with using Nickel mesh as current collector. Here we reported on the synthesis and electrochemical performance of a enhanced material. All active materials have been submitted to X-ray diffraction and Scanning electron microscopy.

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미생물 모방대사를 이용한 천연물의 생물전환 (Microbial Mimic Metabolism of Natural Products)

  • 고학룡;안순철
    • 한국해양바이오학회지
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    • 제2권1호
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    • pp.11-22
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    • 2007
  • This aims to review natural products transformed by mimic intestinal metabolisms with microorganisms and hydrolytic enzymes, which exhibit enforced biological activity, higher extraction yield and identification of active components. In the process, transformation to the smaller active compounds with enzymes and microbes mimics the pharmacological action of natural products by intestinal bacteria. In order to establish conditions for the fermentation and enzyme reaction, it is required to choose several natural products for biotransformation and investigate the optimal conditions for the fermentation or the enzyme reaction such as composition, temperature, pH, inoculum, and cultivation time. It is expected an increase of the internal absorption of the active materials without regard to the intestinal microbes or its ability through biosynthesis of the active materials by the microbes and enzymes. And this techniques can be applied to biotransformation of natural products such as sesaminol, resveratrol, 1-deoxy nojirimycin, naringenin, quercetin, and baicalin and to the metabolism study using the animal model.

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Active and Morphing Aerospace Structures-A Synthesis between Advanced Materials, Structures and Mechanisms

  • Baier, Horst;Datashvili, Leri
    • International Journal of Aeronautical and Space Sciences
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    • 제12권3호
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    • pp.225-240
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    • 2011
  • Active and shape morphing aerospace structures are discussed with a focus on activities aimed at practical implementation. In active structures applications range from dynamic load alleviation in aircraft and spacecraft up to static and dynamic shape control. In contrast, shape morphing means strong shape variation according to different mission status and needs, aiming to enhance functionality and performance over wide flight and mission regimes. The interaction of required flexible materials with the morphing structure and the actuating mechanisms is specifically addressed together with approaches in design and simulation.

Copper micro/nanostructures as effective SERS active substrates for pathogen detection

  • Ankamwar, Balaprasad;Sur, Ujjal Kumar
    • Advances in nano research
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    • 제9권2호
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    • pp.113-122
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    • 2020
  • Surface-Enhanced Raman Scattering (SERS) spectroscopy is a multifaceted surface sensitive methodology which exploits spectroscopy-based analysis for various applications. This technique is based on the massive amplification of Raman signals which were feeble previously in order to use them for appropriate identification at qualitative and quantitative in chemical as well as biological systems. This novel powerful technique can be utilized to identify pathogens such as bacteria and viruses. As far as SERS is concerned, one of the most studied problems has been functionalization of SERS active substrate. Metal colloids and nanostructures or microstructures synthesized using noble metals such as Au, Ag and Cu are considered to be SERS active. Silver and gold are extensively used as SERS active substrates due to chemical inertness and stability in air compare to copper. However, use of Cu as a suitable alternative has been taken into account as it is cheap. Herein, we have synthesized air-stable copper microstructures/nanostructures by chemical, electrochemical and microwave-assisted methods. In this paper, we have also discussed the use of as synthesized copper micro/nanostructures as inexpensive yet effective SERS active substrates for the fast identification of micro-organisms like Staphylococcus aureus and Escherichia coli.

배열 압전 능동 센서를 이용한 복합재 보강판의 충격 손상 탐지 (Impact Damage Detection in a Composite Stiffened Panel Using Built-in Piezoelectric Active Sensor Arrays)

  • 박찬익;조창민
    • Composites Research
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    • 제20권6호
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    • pp.21-27
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    • 2007
  • 복합재 보강판에 영구히 부착된 배열 압전 능동 센서를 사용하여 저속 충격 손상을 탐지하였다. 압전 능동센서를 사용하여 구조에 램파를 전파시키기 위한 다양한 진단신호를 생성하였으며, 손상으로 인한 구조 진동의 특성 변화를 탐지하기 위하여 그 응답을 측정하였다. 이 신호 변화 특징을 한 개의 손상 지수로 표현하기 위하여 3가지 알고리즘-ADI(Active Damage Interrogation), TD RMS (Time Domain Root Mean Square), STFT(Short Time Fourier Transform) -이 검토되었다. 손상 탐지시험을 수행하여, 사용한 기법과 진단신호로 저속 충격으로 인한 두 개의 층간분리를 탐지하였으며, 그 위치를 추정하였다.

Fabrication of Thin Film Transistors based on Sol-Gel Derived Oxide Semiconductor Layers by Ink-Jet Printing Technology

  • 문주호;김동조;송근규;정영민;구창영
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 2009년도 춘계학술발표대회
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    • pp.16.1-16.1
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    • 2009
  • We have fabricated solution processed oxide semiconductor active layer for thin film transistors (TFTs). The oxide semiconductor layers were prepared by ink-jet printing the sol-gel precursor solution based on doped-ZnO. Inorganic ZnO-based thin films have drawn significant attention as an active channel layer for TFTs applications alternative to conventional Si-based materials and organic semiconducting materials, due to their wide energy band gap, optical transparency, high mobility, and better stability. However, in spite of such excellent device performances, the fabrication methods of ZnO related oxide active layer involve high cost vacuum processes such as sputtering and pulsed laser deposition. Herein we introduced the ink-jet printing technology to prepare the active layers of oxide semiconductor. Stable sol-gel precursor solutions were obtained by controlling the composition of precursor as well as solvents and stabilizers, and their influences on electrical performance of the transistors were demonstrated by measuring electrical parameters such as off-current, on-current, mobility, and threshold voltage. Microstructure and thermal behavior of the doped ZnO films were investigated by SEM, XRD, and TG/DTA. Furthermore, we studied the influence of the ink-jet printing conditions such as substrate temperature and surface treatment on the microstructure of the ink-jet printed active layers and electrical performance. The mobility value of the device with optimized condition was about 0.1-1.0 $cm^2/Vs$ and the on/off current ratio was about $10^6$. Our investigations demonstrate the feasibility of the ink-jet printed oxide TFTs toward successful application to cost-effective and mass-producible displays.

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Luminescence Properties of Blue Light-emitting Diode Grown on Patterned Sapphire Substrate

  • Wang, Dang-Hui;Xu, Tian-Han;Wang, Lei
    • Current Optics and Photonics
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    • 제1권4호
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    • pp.358-363
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    • 2017
  • In this study, we present a detailed investigation of luminescence properties of a blue light-emitting diode using InGaN/GaN (indium component is 17.43%) multiple quantum wells as the active region grown on patterned sapphire substrate by low-pressure metal-organic chemical vapor deposition (MOCVD). High-resolution X-ray diffraction (HRXRD), atomic force microscopy (AFM), scanning electron microscopy (SEM), Raman scattering (RS) and photoluminescence (PL) measurements are employed to study the crystal quality, the threading dislocation density, surface morphology, residual strain existing in the active region and optical properties. We conclude that the crystalline quality and surface morphology can be greatly improved, the red-shift of peak wavelength is eliminated and the superior blue light LED can be obtained because the residual strain that existed in the active region can be relaxed when the LED is grown on patterned sapphire substrate (PSS). We discuss the mechanisms of growing on PSS to enhance the superior luminescence properties of blue light LED from the viewpoint of residual strain in the active region.