• Title/Summary/Keyword: activated clay

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Pruification of Yellow Color from Gardenia(Gardenin jasminoides Ellis) for Development of Natural Food Color (천연식용색소 개발을 위한 치자 황색색소의 정제도)

  • 김희구;이상준
    • The Korean Journal of Food And Nutrition
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    • v.11 no.1
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    • pp.68-71
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    • 1998
  • In order make natural food color from gardenia(Gardenia jasminoides), we investigated optimal conditions of color extraction, in case of water extraction, optimal conditions for color extraction were 7$0^{\circ}C$, 48hrs, pH 7.0 and substrate 10%, respectively. And extracted crude color was purified by activated white clay, were isolated glycoside peak (238nm) and yellow color peak(40nm) from extracted crude color. The pruified color was increased by 27-fold and the yield was 96%.

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Prediction of Sorption/Desorption Parameters of Halogenated Aliphatic Compounds Using QSAR (QSAR을 이용한 지방족 할로겐화합물 흡착 및 탈착 계수의 예측)

  • 김종오;박증석;최연돈
    • Journal of Environmental Science International
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    • v.11 no.7
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    • pp.737-742
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    • 2002
  • Sorption and desorption is an important phenomenon to determine the fate of halogenated aliphatic hydrocarbons in the aqueous phase. This study was conducted to develope a predictive equation capable of estimating the sorption and desorption potentials of halogenated aliphatic hydrocarbons onto the sludge from activated process, sediment, and clay. It has shown that the sorption and desorption parameters can be accurately estimated using Quantitative Structural Activity Relationship(QSAR) models based on molecular connectivity indexes of test compounds. The QSAR model could be applied to predict the sorption and desorption capacity of the other halogenated aliphatic hydrocarbons. The QSAR modeling would provide a useful tool to predict the sorption and desorption capacity without time-consuming experiments.

The Effects of Silica-Alumina Type Inorganic Compounds on the Pyrolysis Reaction of EVA to Produce Fuel-Oil (EVA 수지 이용 연료유 생성을 위한 열분해 반응에서 실리카-알루미나 계열 무기물의 영향)

  • Bak, Young-Cheol;Choi, Joo-Hong;Oh, Se-Hui
    • Transactions of the Korean hydrogen and new energy society
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    • v.22 no.5
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    • pp.706-713
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    • 2011
  • The effects of silica-alumina type catalysts addition on the thermal decomposition of ethylene vinyl acetate (EVA) resin have been studied in a thermal analyzer (TGA, DSC) and a small batch reactor. The silica-alumina type compounds tested were kaolinite, bentonite, perlite, activated clay and clay. As the results of TGA experiments, pyrolysis starting temperature for EVA resin had the 1st pyrolysis temperature range of 300~$400^{\circ}C$ and the 2nd pyrolysis temperature range of 425~$525^{\circ}C$. The silica-alumina type catalysts did not affect the pyrolysis rate in EVA pyrolysis reaction. In the DSC experiments, addition of kaolinite and bentonite catalysts reduced the heat of fusion and heat of 2nd pyrolysis reaction. In the batch system experiments, the mixing of silica-alumina type catalysts enhanced the yield of fuel oil, and affected to the distribution of carbon numbers. In the silica-alumina type inorganic material used in this experiments, bentonite was the most effective from the pyrolysis heat, yields, and the characteristics of fuel oil.

Treatment Characteristics and Application of DAF Process for Effective Solid Separation in BNR Municipal Wastewater Treatment System (BNR 하수처리시스템에서 효과적 고형물 분리를 위한 DAF 공정의 적용과 처리특성)

  • Kwak, Dong-Heui;Rhu, Dae-Hwan
    • Journal of Korean Society of Water and Wastewater
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    • v.24 no.3
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    • pp.267-276
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    • 2010
  • Many plants have been improved to adapt the target of the biological treatment processes changed from organics to nutrients since the water quality criteria of effluent was reinforced and included T-N and T-P for the municipal wastewater treatment plant. To meet the criteria of T-N and T-P, the conventional biological reactor such as aeration tank in activated sludge system is changed to the BNR (biological nutrient removal) processes, which are typically divided into three units as anaerobic, anoxic and oxic tank. Therefore, the solid separation process should be redesigned to fit the BNR processes in case of the application of the DAF (dissolved air flotation) process as an alternatives because the solid-liquid separation characteristics of microbial flocs produced in the BNR processes are also different from that of activated sludge system as well. The results of this study revealed that the microbial floc of the anaerobic tank was the hardest to be separated among the three steps of the unit tanks for the BNR processes. On the contrary, the oxic tank was best for the removal efficiency of nutrients as well as suspended solid. In addition, the removal efficiency of nutrients was much improved under the chemical coagulation treatment though coagulation was not indispensable with a respect to the solid separation. On the other hand, in spited that the separation time for the microbial floc from the BNR processes were similar to the typical particles like clay flocs, over $2.32{\times}10^3$ ppm of air volume concentration was required to keep back the break-up of the bubble-floc agglomerates.

Experimental Study on the Properties of Concrete by the Kinds of Admixture and the Replacement Ratios of Activated Hwangtoh (혼화재 종류 및 활성황토 대체율별 콘크리트의 공학적 특성에 관한 실험적 연구)

  • 최희용;김무한;김문한;황혜주;최성우
    • Journal of the Korea Concrete Institute
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    • v.13 no.2
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    • pp.123-129
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    • 2001
  • Pozzolan is to improve the strength and the durability of concrete as a result of the pozzolanic reaction, Broadly speaking, pozzolanic materials can be artificial materials, such as slica fume and fly ash, and natural material, such as rice husk ash, clay, volcanic ash, clayish pozzolan. Hwangtoh is a mineral which belongs to a group of matakaolin, especially halloysite, and the main elements is SiO$_2$, Al$_2$O$_3$, Fe$_2$O$_3$. The purpose of this study is to examine the application of Hwangtoh for the concrete admixtures, the composition of this study is shown as follows. Chapter I is analysis for properties of concrete as the kinds of admixture, and Chapter H is analysis for properties of concrete as the replacement ratio of activated Hwangtoh. As a result of this study, Hwangtoh is found to have high practical use as pozzolanic material, and the pertinent range of replacement ratios of Hwangtoh on cement are 10∼20 %.

Reactivated Timings of Inje Fault since the Mesozoic Era (인제단층의 중생대 이 후 재활동 연대)

  • Khulganakhuu, Chuluunbaatar;Song, Yungoo;Chung, Donghoon;Park, Changyun;Choi, Sung-Ja;Kang, Il-Mo;Yi, Keewook
    • Economic and Environmental Geology
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    • v.48 no.1
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    • pp.41-49
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    • 2015
  • Recently developed illite-age-analysis(IAA) approach was applied to determine the fault-reactivated events for the Inje fault that cut through Precambrian biotite granitic gneiss with NNE-SSW trend in the middle of Korean peninsula. Three distinct fault-reactivated events of shallow crustal regime were recognized using the combined approach of optimized illite-polytype quantification and K-Ar age-dating of clay fractions separated from 4 fault clay samples: $87.0{\pm}0.12Ma$, $65.5{\pm}0.05$ and $66.6{\pm}1.38Ma$, $45.6{\pm}0.15Ma$, respectively. As well, $2M_1$ illite ages of 193~196 Ma and $254.3{\pm}6.96Ma$ were discernible, which may be related to the fault-activated time in the relatively deep crust. The study results suggest that the Inje fault would be firstly formed at $254.3^{\circ}$ ${\ae}6.96Ma$ and sporadically reactivated in shallow regime since about 87 Ma. These reactivation events in shallow regime might be due to the Bulguksa orogeny that would be strongly influenced in Korean peninsula at that time.

Cation Exchanged Silicate Catalyst for Ethylene Polymerization (에틸렌 중합을 위한 陽이온이 交換된 규산염 觸媒)

  • Jong Rack Sohn;Hyen Bae Park
    • Journal of the Korean Chemical Society
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    • v.26 no.5
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    • pp.282-290
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    • 1982
  • Several cation exchanged-layer silicate catalysts were prepared from acid clay mainly consisted of montmorillonite, and their catalytic activities for the ethylene polymerization were studied at room temperature. It was found that over$Ni^{2+}$ -Mont, dimerization of ethylene to n-butene proceeded selectively.$Ni^{2+}$ -Mont was activated by evacuation at elevated temperature, giving a maximum temperature, 150$^{\circ}$C . The variations in catalytic activities were closely correlated to the acidity of the catalysts.$Cr^{3+}$ -Mont exhibited a high activity for the polymerization, showing, a maximum at the evacuation temperature of 450$^{\circ}C$. The active site in $Cr^{3+}$-Mont was considered to be $Cr^{3+}$ ion.

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Removal of Herbicide Glyphosate in a Drinking Water Treatment System

  • Navee, Angsuputiphant;Kim, Jang-Eok
    • Korean Journal of Environmental Agriculture
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    • v.28 no.2
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    • pp.186-193
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    • 2009
  • The removal efficiency of herbicide glyphosate in a drinking water treatment system was investigated. Four major processes of a drinking water treatment system were selected and experiments were performed separately including; treatments by sodium hypochlorite (NaOCl), a sedimentation process by PAC (polyaluminum chloride), ozonation and a GAC (granular activated carbon) treatment. In the sodium hypochlorite experiment, about 50% of the glyphosate was removed by 2 mg/L of hypochlorite and more than 90% was eliminated when 5 mg/L of NaOCl was applied. Also, AMPA, the main metabolite of glyphosate, was treated with hypochlorite. More than 30% of the AMPA was removed by 2 mg/L of hypochlorite and 50% by 5 mg/L. In the PAC experiment, it was determined that more than 60% could be removed. Further experiments were performed and the results indicated that the removed amount was dependent upon the amount of soil and upon the properties of the soil especially that of clay minerals. Ozonation could oxidize glyphosate to its byproducts at about a level of 50%. In contrast, when 1 mg/L of glyphosate was treated with GAC, the amount removed was negligible. The results of this experiment were conclusive. We confirmed that drinking water, which has been contaminated with water polluted with glyphosate can be effectively purified by the application of the drinking water treatment processes currently used.

Polydispersed Colloid Transport in Porous Media : An Experiment and Modeling (다공성 매질에서의 크기 분포를 갖는 콜로이드 이동 : 실험과 모델)

  • Park, Hee-Ju;Lee, Kon-Jae
    • Nuclear Engineering and Technology
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    • v.27 no.1
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    • pp.1-7
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    • 1995
  • The mechanism of radionuclide colloid transport in porous media was studied through modeling and experiment. A nondestructive column scanning system was developed to improve the traditional destructive core slicing method. With an aid of this system we could get much more results from one experiment. Neutron activated clay soaked with soluble isotopes was used as colloid suspension. Filtration coefficients obtained through the experiments show two families of colloids despite their size distribution. New modeling of polydispersed colloid transport was made with two lumped parameters. This new model simulates well. Among the soluble isotopes $^{l37}$Cs mowed mainly as a form of colloid, but $^{85}$ Sr did not.t.

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Adsorption-DAF Hybrid Process for the Simultaneous Removal of Algae and Organic Compounds (조류와 유기화합물의 동시제거를 위한 흡착 - DAF 복합공정)

  • Lee, Jae-Wook;Kwak, Dong-Heui;Choi, Seung-Phil;Jung, Heung-Joe
    • Journal of Korean Society of Water and Wastewater
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    • v.18 no.2
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    • pp.208-214
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    • 2004
  • Dissolved air flotation (DAF) is an effective solid/liquid separation process for low density floc particles such as algal, color-alum and clay-alum flocs produced from low turbidity water. The removal of taste and odor-causing organics (2-mthylisoboneol and geosmin) originating from algae in drinking water is a local and worldwide concern. Although DAF has been effectively applied for the removal of suspended solid, its application for the treatment of dissolved organic carbon is very limited. In this study, a new hybrid system consisting of adsorption and DAF processes was introduced for the simultaneous removal of algae and taste and odor-causing organics. Powdered activated carbon (PAC) was used as an adsorbent. In this proposed system, the major concern of eliminating the spent PAC from the system was also addressed. It was found that zeta potential of algae and PAC was increased with coagulant dosage, and the removal efficiency in DAF was also enhanced up to 90~95% under the given experimental conditions. Based on this study, the hybrid process was found to be a promising technology for the simultaneous removal of algae and dissolved organic pollutants.