• Title/Summary/Keyword: activated alumina

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Removal of Phosphate by Using Wasted Sludge of Seafood Processing Factory (수산물 가공 폐슬러지를 이용한 인산염인 제거)

  • Choi, Bong-Jong;Lee, Seung-Mok;Kim, Keun-Han
    • Journal of Environmental Health Sciences
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    • v.25 no.3
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    • pp.23-28
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    • 1999
  • Phosphate removal through adsorbent, such as activated alumina, powdered aluminum oxide, flyash, blasted furnace slag and other materials, is commonly and widely practiced. The purpose of this study was to improve the removal efficiency of phosphorus in waste sludge earned at seafood processing factories. To investigate the utility and the feasibility of this sludge disposal process, experiment was carried out with a batch process. As a result, phosphate removal appears to increase with increasing adsorbent does, but shows no changes at an adsorbent does over 5g/l. With increasing ratios of initial phosphate concentration to adsorbent does, the amount of removed phosphate is increased while phosphate removal(%) is decreased. Wasted sludge, treated with zinc chloride chemically, represented a better efficiency than the untreated activated sludge and zinc chloride itself, when they reacted with phosphate solution.

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Sulfate Resistance of Alkali Activated Pozzolans

  • Bondar, Dali;Lynsdale, C.J.;Milestone, N.B.;Hassani, N.
    • International Journal of Concrete Structures and Materials
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    • v.9 no.2
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    • pp.145-158
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    • 2015
  • The consequence of sulfate attack on geopolymer concrete, made from an alkali activated natural pozzolan (AANP) has been studied in this paper. Changes in the compressive strength, expansion and capillary water absorption of specimens have been investigated combined with phases determination by means of X-ray diffraction. At the end of present investigation which was to evaluate the performance of natural alumina silica based geopolymer concrete in sodium and magnesium sulfate solution, the loss of compressive strength and percentage of expansion of AANP concrete was recorded up to 19.4 % and 0.074, respectively.

Properties of Alkali-activated Slag-Red Mud Soil Pavement Using Recycled Aggregate (순환골재를 사용한 알칼리활성화 슬래그-레드머드 흙포장재의 특성)

  • Kang, Suk-Pyo
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.4 no.3
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    • pp.276-283
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    • 2016
  • Red mud is an inorganic by-product produced from the mineral processing of alumina from Bauxite ores. the development of alkali-activated slag-red mud cement can be a representative study aimed at recycling the strong alkali of the red mud as a construction material. This study is to investigate the optimum water content, compressive strength, moisture absorption coefficient and efflorescence of alkali-activated slag-red mud soil pavement according to the recycling fine aggregate content. The results showed that the optimum water content, moisture absorption coefficient and efflorescence area of alkali-activated slag-red mud soil pavement increased but the compressive strength of that decreased as the recycled fine aggregate content increased.

Fabrication of Porous Alumina Mold for the Casting Process of Fine Ceramics (Fine Ceramics의 Casting공정을 위한 다공질 알루미나 몰드의 제조)

  • 박한수
    • Journal of the Korean Ceramic Society
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    • v.36 no.1
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    • pp.89-96
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    • 1999
  • Manufacturing conditions of the porous alumina mold were established to overcome various limits of the gypsum mold. For the preparations of the porous alumina mold, an activated charcoal was added to the Al2O3 with the wt% variation and then mixed. The binary slurry was study dispersed based on the examination of the ESA and rheological behaviro. The cylinder type alumina mold was cast in the gyspum mold and characterized by the shrinkage rate at the variable sintering temperature and the resistance against wear. It was proper to make a sintering of the Al2O3 by the surface diffusion which was non-shrinkage sintering mechansim, and intergranular neck growed stronger while sintering was being made. We studied a sintering by three categories; 1) thermodynamic method below 1,000$^{\circ}C$, 2) kinetic method above 1,000$^{\circ}C$ and 3) combined method. In the results of the respective works, combined method was superiro to the others. The prepared Al2O3 mold had relatively high strength, low drying rate, the resistance against the acid or base and good casting behavior.

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Fabrication of Porous Ceramics for Microorganism Carrier by Hydrothermal Reaction (수열반응을 이용한 미생물 담체용 다공성 세라믹스의 제조)

  • 양성구;정승화;강종봉
    • Journal of the Korean Ceramic Society
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    • v.40 no.12
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    • pp.1213-1219
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    • 2003
  • Porous ceramics for microoganism carriers were prepared with amorphous alumina and pore formers by hydrothermal reaction, burn-out and wash-out method. Activated carbon with average size of 67,222, and 405 $\mu\textrm{m}$, organic polymer and inorganic salt were used as pore formers. Specimens were hydrothermally treated at 200$^{\circ}C$ for 24 h, heat-treated at 650$^{\circ}C$ for 5 h, and washed out at 80$^{\circ}C$ for 48 h. The formation of crystalline phase, porosity, pore size distribution and compressive strength were measured. The specimen with activated carbon was transformed to boehmite phase, but organic polymer and inorganic salt inhibited the aquohydroxoy complex gel and crystalline formation. The porous ceramics for microoganism carriers using activated carbon as a pore formers was successfully prepared, which is composed of ${\gamma}$-alumina phase with porosity of above 70 vol% and the compressive strength of 40 kgf/$\textrm{cm}^2$.

Deodorization of Fish Oil Using Adsorption Method (흡착법을 이용한 어유의 탈취)

  • 김귀식;배태진
    • Journal of Life Science
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    • v.13 no.3
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    • pp.365-373
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    • 2003
  • Instead of deodorization appararus of fish oil, an adsorbent such as activated charcoal, activated alumina, silicagel, bamboo charcoal was packed in column alone or mixed with preparative ratio, and then test the effective deodorization with bleaching. In the progress of degumming, the effective method was 18 ml of 2.5% oxalic acid per 100m1 of crude large anchovy oil. The optical condition to deacidified was treating for 30 min at $40^{\circ}C$ with 2.5% sodium hydroride solution. The effective deodorization was added with 3% silicagel under the alone treating adsorbent, and mixed treating was 30% activated alumina and 10% silicagel but added to green tea powder was not effective. The major fatty acid of total lipid were 16:0, 20:5n-3, 18:1n-9, 16:1n-7 and 22:6n-3 after treatment of degumming, deacidfication and deodorizing in the large anchovy oil. The oxidative stability of refined anchovy oil added to $\alpha$-tocopherol was validated 20 days under the control, and 30 days in the case of $\alpha$-tocopherol. The 0.01% $\alpha$-tocopherol was more effective than 0.02% $\alpha$-tocopherol.

Polymker Adsorption Model Using the Flory-Huggins Equation and Asdsorption of Starch (Flory-Huggins 식을 이용한 고분자 흡착 모델 및 전분의 흡착)

  • 현상훈;정한남
    • Journal of the Korean Ceramic Society
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    • v.23 no.3
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    • pp.35-43
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    • 1986
  • The equilibrium dsorption of starch on activated alumina and kaolin was studied to provide the fundamental data for investigating the effect of polymer adsorption on the flocculation of solid particles. The new polymer adsor-ption model(PAH-FH) predicting the adsorption equilibria of polymers on the solid surface has been developed using the solution theory and the concepts of Gibbs dividing surface in conjunction with the Flory-Huggins eq-uation and the adsorption behaviors of polymers were examined by this model The accurate adsorption equilibrium data of starch on alumina and kaolin were determined within the tempera-ture range of 298-318K by the ignition loss method. Using these experimenta data the model developed in this study was evaluated. It was shown that this model could predict the adsorption isotherm more accura-tely than the Langmuir model as well as could describe the characteristics of the adsorption equilibria through model parameters.

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A Synthesis of Optically Active cis and trans 2-(5-Hydroxypoperidin-2-yl)acetates

  • P.N. Reddy;한상수;정교현
    • Bulletin of the Korean Chemical Society
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    • v.19 no.6
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    • pp.617-618
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    • 1998
  • A simple and reproducible pretreatment method was developed for the determination of dioxins in milk sample. Liquid-liquid extraction (LLE) was used for the initial extraction of the analyte from milk. For the elimination of interferences coextracted from milk, acid treatment followed by multilayer silica gel, and then alumina column clean-up were performed. The clean extract could be obtained without carbon column or high performance liquid chromatographic (HPLC) clean-up procedure. Polychlorinated biphenyles (PCBs) and dioxins were separated on neutral alumina activated at 180 ℃ for 12 hours. The final extract was analyzed by HPLC and high resolution gas chromatography/high resolution mass spectrometry (HRGC/HRMS). The recovery of dioxins spiked in milk at 75-300 ppt level was 83.3-98.9% and their relative standard deviation was 4.1-14%.

Analytical Method for Dioxin and Organo-Chlorinated Compounds : (I) Pretreatment of Milk Samples for Dioxin Analysis

  • 양정수;김진영;최용욱;이대운
    • Bulletin of the Korean Chemical Society
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    • v.19 no.6
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    • pp.619-624
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    • 1998
  • A simple and reproducible pretreatment method was developed for the determination of dioxins in milk sample. Liquid-liquid extraction (LLE) was used for the initial extraction of the analyte from milk. For the elimination of interferences coextracted from milk, acid treatment followed by multilayer silica gel, and then alumina column clean-up were performed. The clean extract could be obtained without carbon column or high performance liquid chromatographic (HPLC) clean-up procedure. Polychlorinated biphenyles (PCBS) and dioxins were separated on neutral alumina activated at 180 ℃ for 12 hours. The final extract was analyzed by HPLC and high resolution gas chromatography/high resolution mass spectrometry (HRGC/HRMS). The recovery of dioxins spiked in milk at 75-300 ppt level was 83.3-98.9% and their relative standard deviation was 4.1-14%.

Solar $CO_2$ Reforming of Methane Using $Ni/{\gamma}-Al_2O_3/Metallic$ foam device ($Ni/{\gamma}-Al_2O_3/Metallic$ device를 이용한 고온 태양열 메탄-이산화탄소 개질반응)

  • Shin, Il-Yoong;Lee, Ju-Han;Lee, Jin-Gyu;Seo, Tae-Beom
    • 한국태양에너지학회:학술대회논문집
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    • 2011.04a
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    • pp.275-281
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    • 2011
  • Solar reforming of methane with $CO_2$ was successfully tested with a direct irradiated absorber on a parabolic dish capable of $5kW_{th}$ solar power. The new type of catalytically activated metallic foam absorber was prepared, and its activity was tested. Ni was applied as the active metal on the gamma - alumina coated Ni metal foam for the preparation of the catalytically-activated metal foam layer. Compared to conventional direct irradiation of the catalytically-activated ceramic foam absorber, this new metallic foam absorber is found to exhibit a superior reaction performance at the relatively low insolation or at low temperatures. In addition, unlike direct irradiation of the catalytically-activated ceramic foam absorber, metallic foam absorber has better thermal resistance, which prevents the emergence of cracks caused by mechanical or thermal shock. The total solar power absorbed reached up to 2.1kW and the maximum $CH_4$ conversion was almost 40%.

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