• Journal of the Korean Applied Science and Technology
• /
• v.24 no.3
• /
• pp.253-263
• /
• 2007

Three different weather-resistant coatings were fabricated with the various weight ratios of a mill-base silicone/acrylic resin to let-down silicone /acrylic resin at 2:8, 3:7, and 4:6 respectively. The prepared coatings were tested to investigate the effect of composition of weather-resistant coatings on the physical properties. The thermal stability, salt spray exposure, and weather-resistance were improved with the increased silicone content. It was concluded that the optimum retio of mill-base silicone/acrylic resin to let-down silicone/acrylic resin would be 2:8 and the coating with 30 wt% of silicone content would have high weather-resistance.

• Proceedings of the Korean Institute of Building Construction Conference
• /
• 2021.11a
• /
• pp.162-163
• /
• 2021

To prepare the waterborne silicone acrylic resin coatings, acrylic resin was prepared by a radical polymerization. Glass transition temperature(Tg) of the acrylic copolymer was fixed at 30℃ and the contents of tertiary amine monomer(DMAEMA), were varied to be 5, 10, 15 and 20 wt%, hydroxyl monomer, and carboxyl monomer were fixed 10 wt%, and 4 wt% respectively. γ-Glycidoxypropyltrimethoxysilane(GPTMS) containing epoxy group was used for curing agents. The eqivalent ratio of amine to epoxy was 1:1. The prepared coatings exhibited excellent adhesion to various substrates, and various physical properties of the coatings were satisfactory. The gloss retension and color difference were improved at low tertiary amine concentration. The coatings containing 10wt% tertiary amine concentration have especially good weather resistant properties.

• Polymer(Korea)
• /
• v.30 no.4
• /
• pp.350-356
• /
• 2006

In order to investigate the effect of the composition of weather-resistant coatings on physical properties, three different weather-resistant coatings were prepared by varying the ratio of a mill-base silicone/acrylic resin and let-down silicone/acrylic resin in weight ratios of 2 : 8, 3 : 7, and 4 : 6. The physical properties and weather-resistance of the prepared coatings were tested. It was found that the thermal stability, salt spray exposure, and weather-resistance were improved with increasing the amount of silicone. The optimum mixing ratio of mill-base silicone/acrylic resin to the let-down silicone/acrylic resin was 2 : 8. The coating containing silicone component of 30 wt% was found to be suitable as high weather-resistant coatings.

• Polymer(Korea)
• /
• v.26 no.5
• /
• pp.615-622
• /
• 2002

Weather-resistant coatings were prepared by mixing a synthesized mill-base and let-down silicone/acrylic resin in weight ratios of 4 : 6, 3 : 7, and 2 : 8. The weatherability of the prepared coatings was tested. The thermal stability, general physical properties, and weatherability of the films of the coatings were improved with silicone content. Among the three mixing ratios mentioned, the ratio of 2 : 8 was the most suitable for the preparation of weather-resistant Coatings. The coatings containing 30 wt% of silicone proved to be a high weather-resistant coating.

• Journal of the Korean Applied Science and Technology
• /
• v.24 no.1
• /
• pp.10-22
• /
• 2007

To prepare weather-resistant silicone/acrylic resin coatings for an architectural purpose, tetrapolymers were synthesized by a radical polymerization. 3-Methacryloxypropyltrimethoxysilane (MPTS) as a silicone monomer and n-butyl acrylate, methyl methacrylate, and n-butyl methacrylate as acrylic monomers were used. The compositions of monomers were adjusted to fix the glass transition temperature of acrylic polymer for $20^{\circ}C$. The composition of MPTS in the synthesized polymer were varied from 10 wt% to 30 wt%. On the basis of synthesized resin amber paints were prepared and their physical properties and effects for weatherability were examined. The presence of MPTS in silicone/acrylic resins generally resulted in low molecular weight and broad molecular weight distribution, and also lowered the viscosity of the copolymers. The coated films prepared from these resins showed good and balanced properties in general. Adhesion to the substrate was outstanding in particular. Weatherability tests were carried out in three different types such as outdoor exposure, QUV, and SWO. The test results showed that the silicone/acrylic resins containing 30 wt% of MPTS had weather-resistant properties.

• Proceedings of the Korean Institute of Building Construction Conference
• /
• 2021.11a
• /
• pp.164-165
• /
• 2021

To prepare the good-adherent and weather-resistant acrylic resin coatings, acrylic resin was prepared by a radical polymerization. Glass transition temperature(Tg) of the acrylic copolymer was fixed at 30℃ and the contents of tertiary amine monomer(DMAEMA) was varied to be 5, 10, 15, 20 wt% respectively. γ-Glycidoxypropyltrimethoxysilane(GPTMS) containing epoxy group was used for curing agents and di-n-butyltindilaurate(DBTDL) was used for drying accelerator. The equivalent ratio of amine to epoxy was 1:1. The prepared coatings exhibited excellent adhesion to various substrates, and various physical properties of the coatings were satisfactory. The gloss retention and color difference were improved at low tertiary amine concentration. The coatings containing 10wt% tertiary amine concentration have especially good weather resistant properties.

• Journal of the Korean Applied Science and Technology
• /
• v.25 no.1
• /
• pp.1-14
• /
• 2008

To prepare weather-resistant modified silane acrylic resin coatings for an architectural purpose, tetrapolymers were synthesized by radical polymerization. 3-Methacryloxypropyltrimethoxysilane (MPTS) as a silicone monomer and n-butyl acrylate, methyl methacrylate, and n-butyl methacrylate as acrylic monomers were used. The composition of monomers was adjusted to fix the glass transition temperature of acrylic polymer for $20^{\circ}C$. The composition of MPTS in the synthesized polymer were varied from 10 wt% to 30 wt%. On the basis of synthesized resin amber paints were prepared and their physical properties and effects on weatherability were examined. The presence of MPTS in modified silane acrylic resins generally resulted in low molecular weight and broad molecular weight distribution, and also lowered the viscosity of the copolymers. The coated films prepared from these resins showed good and balanced properties in general. Adhesion to the substrate was outstanding in particular. Weatherability tests were carried out in three different types such as outdoor exposure, QUV, and SWO. The test results showed that the modified silane acrylic resins containing 30 wt% of MPTS had superior weathering properties.

• International Journal of Concrete Structures and Materials
• /
• v.2 no.1
• /
• pp.21-25
• /
• 2008

Surface treatments act as a barrier between the environment and the concrete, preventing or retarding the entry of harmful substances and cutting off the transportation path into concrete. The effectiveness of a surface protection preventing the permeation depends on how close and strongly connected are the resin molecules. This work intends to contribute to a better understanding of the performance of protected concrete in chemically aggressive environments, by presenting results of ion diffusion and resistance to aggressive solutions of several hydrophobic agents and coatings used to protect concrete. Three different types of surface protections were tested: silicone hydrophobic agent, acrylic and epoxy coatings. The obtained results indicate that the overall performance of epoxy resin was better than the other selected types of protections.

• Journal of the Korean Applied Science and Technology
• /
• v.16 no.2
• /
• pp.171-177
• /
• 1999

The objectives of this study is to investigate the optimum reaction conditions and to identify the product formula in the synthesis of a silicone/acrylic resin that curing in moisture at room temperature. By the addition polymerization of monomers, n-butyl acrylate, methyl methacrylate, n-butyl methacrylate, and 3-methacryloxypropyltrimethoxysilane. a quarter polymer was obtained. Among various initiators investigated in this study, 2.2'-azobisisobutyronitrille was found to be the most suitable initiator. The optimum reaction conditions found in this study are 70 wt% of initial solvent amount, 120 minutes of dropping time, 3 times of initiator addition, $82{\sim}105^{\circ}C$ of reaction temperature, and 8 hrs of reaction time. Also, number average molecular weight of $11700{\sim}33100$ and molecular weight distribution of $1.81{\sim}3.44$ were obtained.

• Journal of the Korea Institute of Military Science and Technology
• /
• v.14 no.6
• /
• pp.974-978
• /
• 2011

The beam-matter interaction with various coating effects has received continued attention in the high power laser community. Previous works suggest that coatings promote target damage when compared to beaming on uncoated surface. Three types of paint coatings(Acrylic urethane, Silicone alkyd and Stealth blend) and a water coat on metals(Al, Ti and STS) are irradiated with a $CO_2$ laser. Both strain and temperature measurements are provided for assessing the instantaneous response characteristics of each coating on different metals. A selective combination of surface coats with metals has proven effective in either preventing or enhancing damage, both thermal and mechanical, associated with focused beaming on a target.