• 제목/요약/키워드: acrylic fiber

검색결과 126건 처리시간 0.035초

아크릴계 이온교환섬유를 이용한 수중 크롬(VI) 제거 (Chromium(VI) Removal from Aqueous Solution using Acrylic Ion Exchange Fiber)

  • 남아름;박정안;도태구;최재우;최웅수;김경남;윤성택;이상협
    • 대한환경공학회지
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    • 제39권3호
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    • pp.112-117
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    • 2017
  • PAN 기반 아크릴계 섬유와 DETA 및 $AlCl_3{\cdot}6H_2O$를 반응시켜 아민기($-NH_2$)를 가진 이온교환섬유 PADD를 합성하였다. 개발된 섬유상 소재는 FT-IR과 SEM을 이용하여 그 특성을 확인해 보았다. 회분식 실험으로 수행된 PADD를 이용한 크롬제거 실험 결과는 Langmuir 등온흡착모델에 잘 적용되었으며, 이때 계산된 이론적 최대흡착능 ($Q_{max}$)은 6.93 mmol/g으로 나타났다. 한편 동적흡착실험은 Lagergren 유사이차속도모델에 잘 부합되었다. PADD의 크롬 흡착능은 pH 2에서 가장 높은 값인 4.11 mmol/g을 나타내었고 pH 변화에 많은 영향을 받는 것으로 확인되었다. 또한, 인산과 비소(V)에 대한 공존이온 실험을 통해 PADD가 크롬에 대한 높은 선택성을 갖고 있음을 확인할 수 있었다. 산-염기 역적정으로 구한 PADD의 총이온교환능 (4.70 mmol/g)을 통해 소재의 선택적 제거 가능성을 검증하였다.

화이버 글라스가 의치상 레진의 기계적 특성에 미치는 영향 (Effect of fiber glass on the physical properties of denture base resins)

  • 박연경
    • 대한치과기공학회지
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    • 제35권2호
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    • pp.97-103
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    • 2013
  • Purpose: The purpose of this study was to investigate the effect of addition of fiber glass on the physical properties of silanized fiber mesh and non silanized mesh of denture base resins. Methods: The denture base resins were used in this study heat curing acrylic resins(Vertex Rs, Lucitone 199, $20{\times}80mm$) and fiber glass(SES, Green B&D co., Ltd, $20{\times}80mm$) were used as reinforcement. The specimens were stored in distilled water at $37{\pm}2^{\circ}C$ for 72 hours before test. Bending strength and tensile strength were measured by an universal testing machine(Instron 4301, Instron Corp.). Penetration distribution on fiber was observed by scanning electron microscopy(JSM 840A, Jeol Ltd). Results: The bending strength and modulus were increased by 30% after adding fiber glass on denture base resins. Tensile strength showed significant increasing by adding fiber glass on denture base resins. Conclusion: In this study, Addition of silanized fiber in denture base resins were improved physical properties. we confirmed the fiber glass possibility of the replacement about conventional materials.

치주지지가 감소된 상태에서 섬유강화형 포스트로 수복한 치아의 실패양상 분석 (AN ANALYSIS OF FAILURE MODE OF TEETH RESTORED WITH FIBER-REINFORCED POSTS UNDER THE CONDITION OF BONY RESORPTION)

  • 이병우;이양진;조리라;박찬진
    • 대한치과보철학회지
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    • 제41권2호
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    • pp.232-242
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    • 2003
  • Statement of problem : Fiber-reinforced posts have lower modulus of elasticity than titanium post or cast post-core. With this similar elasticity to that of dentin, fiber-reinforced posts have been known to have a tendency to reduce the risk of root fracture. However, there were few studies on the teeth restored with fiber-reinforced posts under the condition of reduced periodontal support. Purpose : The purpose of this study was to evaluate the fracture strength and failure mode of endodontically treated teeth restored with fiber-reinforced posts and titanium posts under the condition of reduced periodontal support. Material and method : Extracted human maxillary incisor roots were divided into 3 groups (group 1 carbon fiber post, group 2 : glass fiber post, and group 3 : titanium alloy post). After coronectomy and endodontic treatment, teeth were restored with each post systems and resin core according to the manufacturer's recommendation. Then, teeth with simulated periodontal ligament were embedded in the acrylic resin blocks at the level of 4 mm below the cemento-enamel junction. Each specimen was exposed to $10^5$ load cycles with average 30 N force in $36.5^{\circ}C$ water using a computer-controlled chewing simulator. Loads were applied at $45^{\circ}$ angle to the long axis of the teeth. After cyclic loading, teeth were subjected a compressive load until failure at a crosshead speed of 0.5 mm/min. Fracture strength (N) and failure mode were examined. The fracture strength was analyzed with one-way ANOVA and the Scheffe adjustment at the 95% significance level. Results and conclusion : The results were as follows. 1. There was no statistically significant difference in the mean fracture strength among the groups (P<.05). 2. Carbon fiber post and glass fiber post group showed less root fracture tendency than control group. 3. All specimens with root fractures showed fracture lines above the level of acrylic resin block, except for only one specimen in group 3.

방사선 중합법에 의한 Kapok 이온교환 섬유의 합성 (Preparation of Son Exchange Kapok Fiber by Radiation Polymerization)

  • 조인희;강필현;임윤묵;최재학;황택성;노영창
    • 폴리머
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    • 제31권6호
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    • pp.512-517
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    • 2007
  • [ $Co_{60}\;{\gamma}-ray$ ] 방사선 조사법을 이용하여 kapok 섬유에 styrene, glycidylmethacrylate(GMA) 또는 acrylic acid(AAc)를 그래프트 공중합 반응하여 합성한 공중합체의 그래프트율은 단량체의 농도와 방사선 조사량에 따라 증가하는 것으로 나타났으며, 또한 합성된 이온교환 섬유의 도입된 관능기를 확인하고 이온교환 능을 측정하였으며, SEM과 FT-IR을 통하여 이온교환 섬유의 표면과 구조를 분석하였다.

각종 편성소재에 따른 스포츠양말의 위생성과 형태안정성에 관한 연구 (A Study of Sports Socks Varying Knitted Fabrics on Hygienic and stability Properties)

  • 이명자;김칠순
    • 복식문화연구
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    • 제7권5호
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    • pp.165-176
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    • 1999
  • The purpose of this study was to evaluate the effect of various knitted fabrics of sports socks on their properties of hygiene and stability. Seventeen men\`s sports socks to represent five groups with different fiber content, knit structure, yarn fineness, and finishing were used. Properties of hygiene and stability of socks were determined. The results were as follows ; 1. Evaluation of Water, vapor and heat transport properties in socks with varing fiber content showed that cotton 100% socks had the highest drop absorbency, wickability, water absorbency and water retention. Polypropylene 100% socks had an excellent wickability and moisture permeability. Acrylic blend socks had the highest thermal resistance. 2. The greatest knit stretch and knit growth of socks having lower power were found to be with cotton 100% socks had the lowest stretch. Acrylic blend socks had a excellent stretch but low fabric growth, which could give a good fir sensation during wear. 3. The commerical antimicrobial finished socks showed excellent durability after repeated cycles of laundering. 4. Length and width shrinkages were found in all laundered samples during initial cycles due to rearrangement by mechanical relaxation. Shrinkages showed no further changes and reached equilibriums after 5 cycles. Cotton 100% or cotton blend socks showed lower dimensional stability than other socks during fabric care.

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가교제 종류가 PVA-PAN 복합 중공사 분리막의 초산 탈수 거동에 미치는 영향 (Effects of Cross-linking Agents on the Acetic Acid Dehydration Behaviors of PVA-PAN Composite Hollow Fiber Membranes)

  • 강수연;김지선;조은혜;임지원
    • 멤브레인
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    • 제24권4호
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    • pp.311-316
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    • 2014
  • 고농도의 초산수용액을 분리 농축하기 위해 polyacrylonitrile (PAN) 중공사 복합막을 제조한 후 투과증발 분리실험을 통해 제조된 복합막의 분리성능을 확인하였다. 제조된 중공사 복합막의 코팅여부를 알아보고자 SEM 사진을 측정하였으며 코팅두께가 $3.85{\mu}m$로 균일하게 코팅된 것을 확인할 수 있었다. 또한 막의 투과성능평가 실험을 수행한 결과 가교제의 농도와 가교온도가 증가함에 따라 투과도는 감소하고 선택도는 증가하는 경향을 나타내었고, 대표적인 결과로 가교제인 glutaraldehyde 농도 13 wt%, 가교온도 $140^{\circ}C$에서 투과도 $250g/m^2{\cdot}hr$, 선택도 13의 결과를 얻을 수 있었으며, 또 다른 가교제로서 poly (acrylic acid) 농도 9 wt%, 가교온도 $140^{\circ}C$일 때 투과도 $330g/m^2{\cdot}hr$, 선택도 9의 값을 얻을 수 있었다.

Synthesis and spinning of A Novel Poly (acrylonitrile-co-silk fibroin peptide)

  • Zhongmin Chen;Masahiro Suzuki;Kim, Mutsumi ura;Kenji Hanabusa;Hirofusa Shirai
    • 한국섬유공학회:학술대회논문집
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    • 한국섬유공학회 2003년도 The Korea-Japan Joint Symposium
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    • pp.88-89
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    • 2003
  • A series of novel spinning acrylic polymer containing silk protein were synthesized by copolymerization of acrylonitrile (AN) and silk fibroin peptide (SFP) modified by acryloyl chloride (AC) with vinyl groups. The viscosity values of these copolymers showed that the copolymers have good spinnability, which are synthesized under the condition of putting a micro amount of metal ions into synthesizing solvent. The fiber based on the poly (AN-co-SFP) was prepared and characterized by SEM, FTIR measurement of its shell and core flakes, and moisture absorption. The fiber appeared a smooth surface and could be assumed to have excellent adhesive between SFP and PAN. Furthermore, these fibers showed a shell-core structure and excellent moisture absorption.

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New Light Fiber BLU System for Large LCD Display

  • Chung, Man-Young;Park, Tong-Soo
    • 대한전자공학회:학술대회논문집
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    • 대한전자공학회 2002년도 ITC-CSCC -3
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    • pp.1398-1400
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    • 2002
  • A new PLF-BLU (Plastic Light Fiber-Back Light Unit) using side glowing light fiber rods array for the 42" LCD TV display has been evelopedd. The light fibers were 14mm in diameter and 50cm long pure transparent acrylic rods of 1.49 refractive index. Fine seratees were made on the flat side of rod. extremely bright incandscent light from lamp fed into the fiber si scattered at scratches then emerges through the surface of rod. A typical PLF-BLU system consists of 24 PLFs produced side glow of brightness of 4,500cd/㎡ to 6,500cd/㎡. New PLF-BLU is proved to be a BLU of rigid, bright, no heat generation, and low power consumption, hence a prospective BLU system for very and/or ultra large size TVs. A new LED-PLF-BLU system considered to be a revolutionary to break-through of the BLU technologies has also been developed, and is decribed briefly.

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Improved adsorption performance of heavy metals by surface modification of polypropylene/polyethylene media through oxygen plasma and acrylic acid

  • Hong, Jeongmin;Lee, Seungwoo;Ko, Dongah;Gwon, Eunmi;Hwang, Yuhoon
    • Membrane and Water Treatment
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    • 제11권3호
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    • pp.231-235
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    • 2020
  • Industrialization and modern developments have led to an influx of toxic heavy metals into the aquatic environment, and the accumulation of heavy metals has serious adverse effects on humans. Among the various heavy metal treatment methods, adsorption is very useful and frequently used. Plastic materials, such as polypropylene and polyethylene, have been widely used as filter media due to their mechanical and chemical stability. However, the surface of plastic material is inert and therefore the adsorption capability of heavy metals is very limited. In this study, granular media and fiber media composed of polypropylene and polyethylene are used, and the surface modification was conducted in order to increase adsorption capability toward heavy metals. Oxygen plasma generated hydroxyl groups on the surface of the media to activate the surface, and then acrylic acid was synthesized on the surface. The grafted carboxyl group was confirmed by FT-IR and SEM. Heavy metal adsorption capability of pristine and surface modified adsorbents was also evaluated. Overall, heavy metal adsorption capability was increased by surface modification due to electrostatic interaction between the carboxyl groups and heavy metal ions. Fibrous PP/PE showed lower improvement compared to granular PP media because pore blockage occurred by the surface modification step, thereby inhibiting mass transfer.

수지처리에 의한 PET직물의 심색화 (Increase in Color Depth of Polyester Fabric by Resin Treatment)

  • 김재호;김혜진;김동욱;홍승표;김상진;김희동;김현아;허만우
    • 한국염색가공학회지
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    • 제26권3호
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    • pp.187-194
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    • 2014
  • To improve the deep coloring effect of PET fabrics, the alkali treated and black dyed PET fabrics were treated with 2 kinds of low refractive compounds such as acrylic resin and silicone resin. The color depth effect of treated PET fabrics was evaluated as lightness(L) change by UV-visible spectrophotometer. As the weight loss of PET fiber treated with alkali increased, the color depth of PET fabrics increased. Lightness(L) of PET fabrics treated with deep coloring agent was lower than that of untreated PET fabrics. The optimum concentration of treated PET with deep coloring agent was 4% o.w.s. The deep coloring effect of PET fabrics treated with silicone resin was higher than one treated with acrylic resin. PET fabrics treated with silicone resin only might be more appropriate process than PET fabrics treated with acrylic and silicone resin for giving deep coloring effect for polyester fabrics.