• Title/Summary/Keyword: acid sulfate

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A Modeling Study on the Transport of Acid Pollutant by Regional Acid Deposition Model -Spacial Pattern and Variation of Air Pollutants on Eastern Asia and Central Part of Korea- (산성우모델에 의한 산성강하물의 수송에 관한 연구 - 동아시아 및 우리나라 중부지방의 대기오염물질 시공간분포 -)

  • Lee, Chong Bum;Cho, Chang Rae;Byun, Dae Won
    • Journal of Environmental Impact Assessment
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    • v.8 no.1
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    • pp.1-16
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    • 1999
  • The acid deposition and photochemical modeling study was performed on the Eastern Asia using Regional Acid Deposition Model(RADM). The results of this study show that horizontal distribution of $SO_2$, concentration and dry deposition flux was higher in Beking, Shanghai and central part of Korea. However distribution pattern of sulfate and $O_3$ concentration calculated by RADM were not similar to emission pattern. In daytime, $SO_2$, sulfate and $O_3$ were mixed to whole PBL but in nighttime because of inversion layer these pollutants were suppressed to lower level.

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Double Salt Precipitation Behavior of Rare Earth by Sodium Sulfate in Sulfuric Liquor of Waste Permanent Magnet Scrap (폐 영구자석 스크랩 황산침출용액으로부터 황산나트륨에 의한 희토류 원소 복염침전 거동 고찰)

  • Yoon, Ho-Sung;Kim, Chul-Joo;Chung, Kyeong Woo;Kim, Ji-Hye;Lee, Eun-Ji;Yoo, Seung-Joon
    • Resources Recycling
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    • v.26 no.5
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    • pp.39-47
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    • 2017
  • In this study, the precipitation of rare earth-sodium sulfate with sodium sulfate was conducted in order to separate rare earth from Fe in rare earth sulfate solution. Neodymium (Nd) was easily precipitated as Nd-sulfate salt with sodium sulfate, on the other hand, excessive sodium sulfate was needed for the precipitation of Dy-sulfate salt. Also neodymium not only promoted the precipitation of dysprosium sulfate salt but also increased recovery of dysprosium sulfate salt in sulfuric acid solution. At the condition of $60^{\circ}C$ precipitation temperature, 3 h reaction time, 7 equivalents sodium sulfate, the recovery of neodymium and dysprosium sulfate salt was 99.7% and 94.3% respectively from the sulfuric acid solution containing Nd of 23.39 mg/ml and Dy of 8.67 mg/ml. Lastly, from the results of separation of Dy to Nd by the method of sulfate double salt, the effect of salting out with NaCl is important to increase the grade of Dy, and 98.7% of Dy grade could be obtained in this study.

Recovery of Zine sulfate from zine sulfate waste water contain organic compound (유기물이 포함된 황산아연폐수로부터 황산아연의 회수)

  • Yoon, Guk-Joung;Lee, Tack-Hyuck
    • The Journal of Natural Sciences
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    • v.14 no.2
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    • pp.33-40
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    • 2004
  • The eliminating of organic compound is essential process of the recovery of zinc sulfate from zinc sulfate waste water contained organic compound. The ozone oxidation and adsorption treatment is good for eliminating of organic compound in waste water. The zinc oxide treated an excess of sulfuric acid for zinc sulfate. We got zinc sulfate 740g from water 1kg.

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The Properties of Hardened Slag by Alkali and Curing Method (알칼리 첨가 및 양생방법에 따른 슬래그 경화체의 특성)

  • 김원기;소정섭;배동인
    • Proceedings of the Korea Concrete Institute Conference
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    • 2002.10a
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    • pp.27-32
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    • 2002
  • In this research influences of type and concentration of alkali activator and curing condition on the hydration, and properties of alkali activated blast furnace slag(AAS) concrete were investigated. Sodium carbonate and sulfate were used as alkali activators and their concentration were 4~10 weight percent with Na$_2$O equivalent to binder. The curing conditions were standard curing using 23$^{\circ}C$ water and activated curing chamber at $65^{\circ}C$. Results show that in case of sodium carbonate addition high early strengths were gained by activation of early hydration, but later strength gained was slight. On the other side sodium sulfate strengths were continuously increased with adding amount and ages. Steam curing activated early hydration so that early strengths were improved but later strengths were similar to standard curing. The strength reduction of AAS mortar with sodium sulfate was less than OPC mortar in 5% sulfuric acid solution so that AAS concrete can be useful for acid-resistance concrete.

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The Effect of Alum and Metals on Paper Aging

  • Choi, Kyoung-Hwa;Yoon, Byung-Ho;Lee, Myoung-Ku
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.40 no.5
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    • pp.42-46
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    • 2008
  • The papers in preserved books and archives experience aging which was affected by a variety of factors. Thus, the studies concerning impacts of those factors on paper aging are required. In this research, a simulation of a short-time accelerated paper aging was conducted in order to examine the effects of acid and metals (alum, copper (II) sulfate, copper (II) chloride, and iron (III) chloride) on the natural paper aging for a long time. As a result of experiments, it is found that both acid and metals have impacts on paper aging. Alum resulted in the significant decrease of pH, brightness, folding endurance, and viscosity of paper. Both copper (II) chloride and iron (III) chloride also resulted in the decrease of brightness, folding endurance, and viscosity of paper. In more detail, paper aging by iron (III) chloride showed much more significant than that by copper (II) chloride. The paper aging in case of copper (II) sulfate coexisting sulfate ion, where metal absorbed moisture was higher than in case of paper treated only by alum. This result indicated that metal catalyzes paper aging by acid. Based on these results, it was revealed that both alum and metal are the major factors in paper aging. In particular, paper aging was far more accelerated in case when acid and metals existed in paper at the same time.

On the Sulfur-incorporation into amino acids in germinating Soy Beam seeds using Sulfate-$S^35$ (대두발아종자에 있어서 아미노산에의 유황결합에 관하여)

  • 이민재
    • Journal of Plant Biology
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    • v.8 no.3
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    • pp.1-3
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    • 1965
  • The sulfur-incorporation into amino acids in germinating Soy Bean seeds was studied with the aid of Sulfate-S35. Water imbibition and isotope absorption were almostly pararelled. On the radioautogram $S^35$ was detected in cysteic acids at 90 minutes. Cysteine, cystine and cysteic acid were appeared with radioactivity at 240 minutes after the infiltration of sulfate-$S^35$. Methione was not detected on the radioautogram in the range of 300 minutes. The radioactivity of $S^35$ was detected highly in free amino acids than hydrolyzates.

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Geochemical and S isotopic studies of pollutant evolution in groundwater after acid in situ leaching in a uranium mine area in Xinjiang

  • Zhenzhong Liu;Kaixuan Tan;Chunguang Li;Yongmei Li;Chong Zhang;Jing Song;Longcheng Liu
    • Nuclear Engineering and Technology
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    • v.55 no.4
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    • pp.1476-1484
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    • 2023
  • Laboratory experiments and point monitoring of reservoir sediments have proven that stable sulfate reduction (SSR) can lower the concentrations of toxic metals and sulfate in acidic groundwater for a long time. Here, we hypothesize that SSR occurred during in situ leaching after uranium mining, which can impact the fate of acid groundwater in an entire region. To test this, we applied a sulfur isotope fractionation method to analyze the mechanism for natural attenuation of contaminated groundwater produced by acid in situ leaching of uranium (Xinjiang, China). The results showed that δ34S increased over time after the cessation of uranium mining, and natural attenuation caused considerable, area-scale immobilization of sulfur corresponding to retention levels of 5.3%-48.3% while simultaneously decreasing the concentration of uranium. Isotopic evidence for SSR in the area, together with evidence for changes of pollutant concentrations, suggest that area-scale SSR is most likely also important at other acid mining sites for uranium, where retention of acid groundwater may be strengthened through natural attenuation. To recapitulate, the sulfur isotope fractionation method constitutes a relatively accurate tool for quantification of spatiotemporal trends for groundwater during migration and transformation resulting from acid in situ leaching of uranium in northern China.

Effect of Growth Conditions on Lactic acid bacteria Isolated from Kimchi

  • Joe, Lim;Kwun, Kyu-Hyuk;Lee, Jung-Heon
    • 한국생물공학회:학술대회논문집
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    • 2005.04a
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    • pp.124-128
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    • 2005
  • This studies were carried out to investigate optimal conditions for Lactic acid bacteria growth, which was grown in a batch fermenter. The optimal temperature was $30^{\circ}C$, optimal pH was 6.5 and agitation speed was 100rpm and didn't supply the air. Used media compositions were yeast extract 5g/L, peptone 10g/L, sugar 20g/L, beef extract 10g/L, tween 80 1ml/L, ammonium citrate 2g/L, sodium acetate 5g/L, magnesium sulfate 0.1g/L, manganese sulfate 0.05g/L, dipotassium phosphate 2g/L. These results would be useful for enhancing lactic acid bacteria concentration.

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Comparison of the Two in Vitro Cytotoxicity Assays in Primary Cultured Rat Hepatocytes - the Neutral Red (NR) and Lactate Dehydrogenase (LDH) Tests (흰쥐의 배양 간세포를 이용한 세포독성시험에 있어서 뉴트랄레드 및 젖산 탈수소효소법의 비교)

  • Lee, Kyung-Tae;Seo, Seong-Hoon
    • Journal of Pharmaceutical Investigation
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    • v.25 no.4
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    • pp.365-369
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    • 1995
  • The acute cytotoxicities of chloroquine sulfate, propranolol, ascorbic acid, acetylsalicylic acid and acrylamide on cultured adult rat hepatocytes were evaluated by the use of LDH leakage and NR uptake test. On the basis of $IC_{50}$ values, the rank order of cytotoxicities of these drugs in both tests was chloroquine sulfate > propranolol > acetylsalicylic acid > ascorbic acid. The $IC_{50}$ of LDH test was very similar to that of NR uptake test. Thus, we concluded that both tests are reliable and sensitive methods in detecting toxicity in adult cultured rat hepatocytes.

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Experimental Assessment of Forest Soil Sensitivity to Acidification(II) - Application of Extractable Sulfate and Sulfate Adsorption Capacity - (산림토양(山林土壤)의 산성화(酸性化) 민감도(敏感度)에 대(對)한 실험적(實驗的) 평가(評價)(II) - 추출성(抽出性) 황산(黃酸)이온(SO42-) 함량(含量)과 황산(黃酸)이온 흡착능(吸着能)의 활용(活用) -)

  • Lee, Sung Woo;Kim, Young Kul;Lee, Choong Hwa;Byun, Jae Kyoung
    • Journal of Korean Society of Forest Science
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    • v.90 no.4
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    • pp.431-436
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    • 2001
  • The extractable sulfate content and sulfate adsorption capacity in soils of four Pinus densiflora stands were measured to assess the soil acidification sensitivity to acid deposition. The soluble sulfate content in organic horizon which reflects the previous deposition of sulfur oxides was much higher for Namsan and Ulsan than Kanghwa and Hongcheon. In mineral soils, however, the extractable sulfate content was the greatest for Ulsan followed by Kanghwa, Namsan and Hongcheon due to the interactive effect of previous deposition and soil adsorption of sulfate. Adsorption rates of specifically adsorbed sulfate(proportion of insoluble sulfate to total extractable sulfate) for Namsan, Kanghwa and Ulsan affected by acid deposition were 16.6%, 56.8% and 37.4%, respectively, so that the soil in Namsan had the highest acidification sensitivity to acid deposition. For sulfate adsorption isotherm($RE=mX_i-b$), the significantly positive correlations between added sulfate($X_i$) and adsorbed sulfate(RE) were found only in mineral soil(p<0.05) over all regions. The regression coefficient(m) that means soil sulfate adsorption capacity by 0-30cm depth was 0.16, 0.24, 0.25 and 0.32 in $mmol_c\;kg^{-1}$ for Namsan, Kanghwa, Ulsan and Hongcheon, respectively, indicating that soil acidification sensitivity is the highest for Namsan. The added sulfate($X_i$) that could make the adsorbed sulfate(RE) null was 3.81, 2.17, 4.96 and 0.65 in $mmol_c\;kg^{-1}$ for Namsan, Kanghwa, Ulsan and Hongcheon, respectively and the values of former three regions considerably exceeded the realistic sulfate deposition.

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