• 제목/요약/키워드: acid strength

검색결과 1,668건 처리시간 0.031초

The Evaluation of Thermal Aging Characteristics in Insulating Materials of the Pole Transformers (가속열화 방법에 의한 주상변압기 절연물의 열 열화 특성 평가)

  • 이병성;송일근;이재봉;한상옥
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • 제16권12호
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    • pp.1136-1141
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    • 2003
  • The primary insulation materials used in an oil filled transformer are kraft paper, wood, porcelain and oil. Modern transformers use chemically treated paper to improve its tensile strength and resistance to aging caused by immersion in oil. But these insulation papers are mainly aged by thermal stress. Over the life time of the insulation paper and oil, it is exposed to high temperatures, oxygen and water. Its interaction with the steel of the tank and core plus the copper and aluminium of the windings will eventually cause the chemical properties of the oil to decay. High temperature have an effect on mechanical strength of cellulous paper used in the layer insulation. We made two aging cells in which insulation papers and mineral oil are conducted to test thermal properties. It is measured dielectric strength, number of acid, moisture, etc. of insulation paper and oil aged in the aging cells.

Measurement of Degree of Hydrolysis of a PA66/GF Composite using a py-GC/MS analysis

  • Lee, Jong-Young;Kim, Kwang-Jea
    • Elastomers and Composites
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    • 제52권1호
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    • pp.59-68
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    • 2017
  • The effect on the hydrolysis resistance properties by the addition of maleic anhydride grafted EMDM (MA-g-EPDM) and PP (MA-g-PP) to a PA66/GF composite was investigated with respect to the mechanical properties, thermal properties, and morphology. The degree of hydrolysis of the PA66/GF composite was measured using py-GC/MS analysis. When compared to the PA66/GFcomposite in MEG/water solution, the composites where MA-g-EPDM and MA-g-PP were added to PA66/GF showed a higher degree of hydrolysis resistance, impact strength, and thermal properties, whereas their tensile strength, tensile modulus, flexural strength and flexural modulus decreased. As immersion time in the solution increases, the rate of tensile strength drop of the MA-g-PP added composite appeared lower than that of the PA66/MA-g-EPDM/GF and PA66/GF composites. The py-GC/MS analysis confirmed the formation of PA66 hydrolysis reaction by products such as carboxylic acid and alkylamine with increasing immersion time.

A Study on The Tracking Resistance and Mechanical strength of Epoxy Composites due to Boiling Absorption (비등에 따른 에폭시 복합체의 내트래킹성과 기계적강도에 관한 연구)

  • 김경민;김탁용;이덕진;강태오;홍진웅;김재환
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 한국전기전자재료학회 2000년도 하계학술대회 논문집
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    • pp.165-168
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    • 2000
  • This paper presents the tracking resistance and mechanical strength due to boiling absorption of epoxy resin. The single network structure specimen(E series) formed of epoxy alone and interpenetrating polymer network(IPN) structure specimen(EM series) which epoxy resin was taken as first network and methacrylic acid resin as second network were manufactured. As adding $SiO^2$ filler classified by o[phr], 50[phr] and 100[phr] to those specimens, six kinds of specimens were manufactured and boiled in water during 2, 4, 8, 16, 32 and 64[hours]. As a result, it was confirmed that the tracking breakdown time of E series showed a abrupt decrease with boiling time increasing, but that of EM series was decreasing smoothly. Also, it was verified that the degrading rates of mechanical strength was lowerd according to improvement of adhension strength in case of EM series.

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Stability Constants of Copper Sulfa-Drug Complexes in Dimethylformamide Aqueous Solution (Dimethylformamide 수용액중에서의 Sulfa제-Cu 착화합물의 안정도정수)

  • 이왕규
    • YAKHAK HOEJI
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    • 제9권1_2호
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    • pp.4-7
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    • 1965
  • Acid dissociation constants of sulfamethoxypyridazine, sulfadimethoxine, sulfamerazine, sulfathiazole and sulfadiazine, and stability constants for formation of copper chelate were calculated from their titration curves in 80% dimethylformamide with ionic strength 0.1 at $25{\deg}$ It was found that the acid dissociation constants (pKa) of sulfa-drugs were in the range of 9.33 - 10.05, and the stability constants (log $k_{1}$, $k_{2})$ of their copper chelates were in the range of 9.33-9.71.

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A Simple Approach to the Ionic-covalent Bond Based on the Electronegativity and Acid Strength of Cations. Part Two:Application to the Description of the Electronic Properties of Oxides

  • Josik Portier;Guy Campet
    • Journal of the Korean Chemical Society
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    • 제41권8호
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    • pp.437-441
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    • 1997
  • The acid strngth of cations, determined with ICP (Ionic Covalent Parameter): ICP=log(P)-1.38x+2.07 where P is the polarizing power and X its electronegativity expresses the competition between the covalent and ionic forces. This concept, together with electronegativity, is used to describe the properties of oxides with various electronic properties (insulators, metals, degenerate semiconductors, superconductors).

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Micro-threads of Cross-linked Hyaluronic Acid Hydrogel using a Microfluidic Chip (미세 유체 칩 기반의 히알루론산 미세 실의 제작)

  • Lee, Yun-Kyung;Lee, Kwang-Ho
    • Journal of Biomedical Engineering Research
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    • 제38권1호
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    • pp.1-8
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    • 2017
  • The successful synthesis of hyaluronic acid micro-threads is very promising approach for the broad application in tissue engineering such as dermal fillers. Because hyaluronic acid has the excellent biocompatibility and ability to maintain the moisture of up to several hundred times its own weight. In order to generate the hyaluronic acid micro-threads in microfluidic system, we employed two-phase flow microfluidic chip to make a rapid synthesis of the hyaluronic acid hydrogel. Hyaluronic acid was mixed with 0.02N NaOH solution and 1, 4-Butanediol diglycidyl ether (BDDE) solution and then injected into core channel. The ethanol was used for the 3-dimensional micro-thread formation in sheath channel. We manipulated the diameter of HA micro-threads using controlling of flow rates in microfluidic chip, and showed the feasibility of immobilization in HA micro-threads with florescent substances. Also, the generated HA micro-threads were evaluated and showed the suitable properties with tensile strength, bending property, and swelling profiles for dermal fillers. As a result, we suggested an innovative method for microfluidic chip-based HA micro-threads which could safely be applied as dermal filler in tissue engineering.

A study of deterioration of reinforced concrete beams under various forms of simulated acid rain attack in the laboratory

  • Fan, Yingfang;Hu, Zhiqiang;Luan, Haiyang;Wang, Dawei;Chen, An
    • Structural Engineering and Mechanics
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    • 제52권1호
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    • pp.35-49
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    • 2014
  • This paper studies the behaviour of deteriorated reinforced concrete (RC) beams attacked by various forms of simulated acid rain. An artificial rainfall simulator was firstly designed and evaluated. Eleven RC beams ($120mm{\times}200mm{\times}1800mm$) were then constructed in the laboratory. Among them, one was acting as a reference beam and the others were subjected to three accelerated corrosion methods, including immersion, wetting-drying, and artificial rainfall methods, to simulate the attack of real acid rain. Acid solutions with pH levels of 1.5 and 2.5 were considered. Next, ultrasonic, scanning electron microscopy (SEM), dynamic, and three-point bending tests were performed to investigate the mechanical properties of concrete and flexural behaviour of the RC beams. It can be concluded that the designed artificial simulator can be effectively used to simulate the real acid rainfall. Both the immersion and wetting-drying methods magnify the effects of the real acid rainfall on the RC beams.

Ursolic Acid-Induced Elevation of Serum Irisin Augments Muscle Strength During Resistance Training in Men

  • Bang, Hyun Seok;Seo, Dae Yun;Chung, Yong Min;Oh, Kyoung-Mo;Park, Jung Jun;Arturo, Figueroa;Jeong, Seung-Hun;Kim, Nari;Han, Jin
    • The Korean Journal of Physiology and Pharmacology
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    • 제18권5호
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    • pp.441-446
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    • 2014
  • Ursolic acid (UA), a type of pentacyclic triterpenoid carboxylic acid purified from natural plants, can promote skeletal muscle development. We measured the effect of resistance training (RT) with/without UA on skeletal muscle development and related factors in men. Sixteen healthy male participants (age, $29.37{\pm}5.14$ years; body mass index=$27.13{\pm}2.16kg/m^2$) were randomly assigned to RT (n=7) or RT with UA (RT+UA, n=9) groups. Both groups completed 8 weeks of intervention consisting of 5 sets of 26 exercises, with 10~15 repetitions at 60~80% of 1 repetition maximum and a 60~90-s rest interval between sets, performed 6 times/week. UA or placebo was orally ingested as 1 capsule 3 times/day for 8 weeks. The following factors were measured pre-and post-intervention: body composition, insulin, insulin-like growth factor-1 (IGF-1), irisin, and skeletal muscle strength. Body fat percentage was significantly decreased (p<0.001) in the RT+UA group, despite body weight, body mass index, lean body mass, glucose, and insulin levels remaining unchanged. IGF-1 and irisin were significantly increased compared with baseline levels in the RT+UA group (p<0.05). Maximal right and left extension (p<0.01), right flexion (p<0.05), and left flexion (p<0.001) were significantly increased compared with baseline levels in the RT+UA group. These findings suggest that UA-induced elevation of serum irisin may be useful as an agent for the enhancement of skeletal muscle strength during RT.

A COMPARATIVE STUDY OF THE SHEAR BOND STRENGTH AND ADHESIVE FAILURE PATTERN OF METAL BRACKETS BONDED ON NATURAL TEETH AND PORCELAIN TEETH (자연 치관과 포세린 치관상에서 교정용 브라켓 부착시 전단 결합 강도와 파절 양상에 관한 비교 연구)

  • Lee, Hyun-Sun;Kim, Jong-Soo;Yoo, Seung-Hoon
    • Journal of the korean academy of Pediatric Dentistry
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    • 제35권2호
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    • pp.195-204
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    • 2008
  • Orthodontic brackets often need to be bonded to porcelain such as porcelain fused to metal crowns and porcelain jacket crowns. The purpose of this study was to evaluate the clinical usability of direct bonding system on porcelain teeth by measuring shear bond strength according to various conditions and observing adhesive failure patterns. The specimens, 20 maxillary premolars and 80 porcelain teeth that were produced by duplication of the labial surface of a maxillary first premolar were used and randomly divided into four groups of twenty teeth each. The 5 different preparation procedures tested: (1) application of 37% phosphoric acid on natural teeth, (2) sandblasting on porcelain surfaces, (3) sandblasting and application of 9.6% hydrofluoric acid on porcelain surfaces, (4) sandblasting and application of silane on porcelain surface, (5) sandblasting and application of 9.6% hydrofluoric acid and silane on porcelain surfaces. The metal brackets were bonded with Transbond $XT^{(R)}$ bonding material. The shear bond strength was tested by the micro universal testing machine(Kyung-Sung, Korea) and the amount of residual adhesive on the tooth surface after debonding was examined by stereoscope and assessed with an adhesive remnant index. The results of this study suggest that the direct bonding system on porcelain teeth with sandblasting, HF and porcelain primer is clinically useful.

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Synthesis and Application of Sorbic Acid Grafted Hydrogenated Dicyclopentadiene Hydrocarbon Resin (소르빅산 변성 수소첨가 DCPD계 석유수지의 합성 및 응용)

  • Kong, Won Suk;Park, Jun Hyo;Yoon, Ho Gyu;Lee, Jae Wook
    • Journal of Adhesion and Interface
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    • 제16권1호
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    • pp.29-34
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    • 2015
  • Hydrocarbon resins, which are defined as low molecular weight, amorphous, and thermoplastic polymers, are widely used as tackifier for various types of adhesives, as processing aids in rubber compounds, and as modifiers for plastics polymers such as isotactic polypropylene. Typically, hydrocarbon resins are non-polar, and thus highly compatible with non-polar rubbers and polymer. However, they are poorly compatible with polar system, such as acrylic copolymer, polyurethanes, and polyamides. Moreover, recently the raw materials of hydrocarbon resin from naphtha cracking had been decreased because of light feed cracking such as gas cracking. To overcome this problem, in this study, novel hydrocarbon resins were designed to have a highly polar chemical structure which material is sustainable. And, it was successfully synthesized by Diels-Alder reaction of dicyclopentadiene monomer and sorbic acid from blueberry as renewable resources. Acrylic resins were formulated with various tackifiers solution including sorbic acid grafted hydrogenated dicyclopentadiene hydrocarbon resins in acrylic adhesive and rolling ball tack, loop tack, $180^{\circ}$ peel adhesion strength, and shear adhesion strength were measured. The properties depend on the softening point and polar content of tackifiers.