• Title/Summary/Keyword: acid strength

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The Quantitative Determination of Hemicelluloses Adsorbed on Hw-BKP Using HPLC (HPLC를 이용한 Hw-BKP 섬유에 흡착된 헤미셀룰로오스의 정량 평가)

  • Lee, Sang-Hoon;Lee, Hak-Lae;Youn, Hye-Jung
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.40 no.4
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    • pp.43-50
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    • 2008
  • Adsorption of xylans extracted from birchwood and oat spelt on Hw-BKP were analyzed using HPLC. The effect of xylan adsorption on paper properties such as tensile, tear index and brightness was also investigated. The constituents of xylan was analyzed with HPLC after hydrolysis with dilute sulfuric acid. It was shown that xylose was the major constituent and small amounts of glucose and galactose were contained in the xylan samples. Adsorption of xylan on hardwood fibers was evaluated using acid hydrolysis and HPLC techniques. Results showed that the adsorption of negatively charged xylan on the fiber surface was negligible probably because electrostatic repulsion between these two materials. Pretreatment of the fiber with alum increased xylan adsorption. The amount of adsorption increased up to 30 mg/g. With the increase of xylan adsorption both tensile and tear strength of the handsheet increased suggesting xylan can be a very effective strength agents for papermaking. Brightness of the handsheets decreased, however, with the use of xylan.

Modification of Starch for Surface Sizing via Etherification and Esterification (에테르화 및 에스테르화를 통한 표면사이징용 변성 전분의 제조)

  • Jeong, Young Bin;Lee, Hak Lae;Youn, Hye Jung;Ji, Kyoung Rak;Kim, Young Seok
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.46 no.6
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    • pp.50-55
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    • 2014
  • An oxidized starch was modified for surface sizing via etherification and esterification. Propylene oxide (PO), sodium monochloroacetate (SMCA), and acrylonitrile (AN) were used as etherification, and vinyl acetate monomer (VAM), maleic anhydride (MA), fumaric acid (FA), and itaconic acid (ITA) were used for esterification. Esterification and etherification of starch decreased both Brookfield viscosity and Brabender viscosity substantially even though the solids level was increased by 2% from 14 to 16%. Surface sizing performance of starches in tensile strength, stiffness and compressive strength was improved by esterification and etherification of the oxidized starch. Especially, SMCA etherification was found to be the most effective modification method.

Improvement of Binding Property of the Alg-Na/PEO Blends (PEO를 이용한 Alg-Na 바인더의 물성향상)

  • Park, Yong Wan;Kim, Eui Hwa;Cho, Ho Hyun
    • Textile Coloration and Finishing
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    • v.26 no.1
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    • pp.32-38
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    • 2014
  • There has been increasing demand to the eco-friendly materials such as phytoncide which is extracted to plants in the textile industry, recently. It is interesting that alginic acid sodium salt(Alg-Na) is used to eco-friendly binder for the functional capsule finishing. In this study, we made PEO/Alg-Na blend solutions of various ratio and observed the changing binding property of the blend solutions according to PEO contents through FT-IR, DSC, contact angle, peel strength, etc. The viscosity of Alg-Na/PEO blend solutions increased with increase of contents and the viscosity quickly increased with increase of PEO content in Alg-Na 5% content, specially. It is shown that the hydrogen bond peak by blend of Alg-Na and PEO found through FT-IR analysis but the peak decreased in PEO above 60% content. And the peel strength was predominant in PEO 50% ratio.

The Effect of Acid Treatment Time for Ni Plating on the Joint of α-Al2O3 and Ni Metal (α-Al2O3와 Ni 금속 접합을 위한 Ni 무전해 도금시 산처리의 영향)

  • YI, EUNJEONG;AN, YONGTAE;CHOI, BYUNGHYUN;JI, MIJUNG;HWANG, HAEJIN
    • Transactions of the Korean hydrogen and new energy society
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    • v.27 no.3
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    • pp.306-310
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    • 2016
  • In Na-base Battery for ESS, ${\alpha}-Al_2O_3$ and metal bonding was used to prevent direct reaction between electrolyte and electrode. The hard metal was metalized at $1600^{\circ}C$ in a flowing hydrogen gas for high bonding strength. In this study, instead of hard metal metalizing, Ni was plated on ${\alpha}-Al_2O_3$ by electroless Ni plating technique and then bonded with metal. To enhance the bonding strength, surface of ${\alpha}-Al_2O_3$ was treated with $H_3PO_4$. The effects of strength and leakage of joining as a function of acid treatment time on ${\alpha}-Al_2O_3$ are described.

Effects of Solvent Treatment of Bamboo Fiber on Physical Properties of Polypropylene/Glass Fiber/Bamboo Fiber Composite (엔진커버용 폴리프로필렌/유리섬유/대나무섬유 복합체의 물리적 특성에 대한 대나무섬유의 용제 처리의 영향)

  • Lee, Su Kyoung;Lim, Sung Wook;Shin, Hyung Shik;Woo, Seung-Keon;Park, Eun Young
    • Textile Coloration and Finishing
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    • v.31 no.1
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    • pp.42-47
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    • 2019
  • In this study, the effects of surface treatment of bamboo fiber on the physical properties of polypropylene(PP)/glass fiber(GF)/Bamboo fiber(BF) composite for engine cover were investigated. PP, GF and BF were fixed at 40%, 40% and 20% and the surface of bamboo fibers were treated to 0.5, 1.0 and 2.0% as an acid and alkali solution. PP/GF/BR composites using surface treated bamboo fibers were prepared and their tensile strength, bursting strength and impact strength were measured by universal testing machine(UTM). The composites with alkali treated bamboo fiber showed better mechanical properties than the acid treated composites. It was checked that the optimum alkali content was at 1.0% from the results of mechanical properties. The effect of surface treatment on the mechanical properties was confirmed by SEM images of fractured surface.

Effect of Temperature and Water Immersion on Strength Properties of Spot Welded Zincked Steel Plates (점용접 아연도금강판의 강도특성에 미치는 온도 및 침수의 영향)

  • Seo, Do-Won;Choi, Jun-Yong;Lim, Jae-Kyoo
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.28 no.12
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    • pp.1864-1870
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    • 2004
  • A spot welded structures have an influence on a diverse climatic situation, for instance temperature, humidity and precipitation. In addition factors of environmental pollution such as acid rain, that courses corrosion, have the tendency to increase. But spot welded structures strength is affected by humidity and environment temperature. Therefore, it is important to evaluate effect of temperature and water immersion on strength properties of spot welded part. In this study, the strength distribution of spot welded plates is evaluated the environmental temperature of zinc coated steel plates. Test is conducted with welded part immersed in distilled and synthetic sea water. Specimens are immersed into water for 10, 100, 500 and 1000 hours to evaluate the offsets of water immersion time on tensile-shear strength under the conditions of -40, 0, 20 and 5$0^{\circ}C$. From this result, spot welded specimens with 5 mm clearance have lower tensile-shear strength in the distilled water or synthetic sea water than without clearance. And they have lower tensile-shear strength under -4$0^{\circ}C$ and over 5$0^{\circ}C$.

Effect of Temperature and Water Assumtion on Strength of Spot Welded Zine Steel Plates (점용접 아연도금판의 강도특성에 대한 온도 및 침수의 영향)

  • Seo, Do-Won;Yoon, Ho-Chel;Choi, Jun-Yong;Lim, Jae-Kyoo
    • Proceedings of the KSME Conference
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    • 2003.04a
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    • pp.358-363
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    • 2003
  • Spot welded structure is operated in diverse situation because of temperature, humidity and precipitation. In addition factors of environmental pollution such as acid rain, that courses corrosion, have the tendency to increase, But spot welded structure strength is affected by dampness and environment temperatures. Therefore, it is important to evaluate effect of temperature of spot welded part, In this study, the strength distribution of spot welded plates is evaluated about the environmental temperature of zine coated steel plates and test is conducted with welded part immersed in distilled and synthetic sea water. Specimens are immersed into water for 10, 100, 500 and 1000hours to evaluate the effects of water immersion time on tensile-shear strength under the conditions of -40, 0, 20 and $50^{\circ}C$. Strength is evaluated by tensile-shear test. The conditions of spot welding are 240kgf electrode force, 10KA welding current with 0 and 5mm clearance. From this study, spot welded specimens with clearance have lower tensile-shear strength in the distilled water or synthetic sea water comparing with spot welded specimens without clearance. And they have lower tensile-shear strength under $-40^{\circ}C$ and over $50^{\circ}C$.

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Synthesis and Characterization of Dimer Acid-Based Polyamides (다이머산계 폴리아미드의 합성 및 특성에 관한 연구)

  • Park, Hyun Ju;Jeon, Ho Kyun;Oh, Sang Taek
    • Journal of Adhesion and Interface
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    • v.17 no.4
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    • pp.136-140
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    • 2016
  • In this study, a series of dimer acid-based polyamides with different diamines were synthesized by condensation polymerization and the polyamides were characterized by Fourier transform infrared spectroscopy (FT-IR). Effects of diamine structures on mechanical and thermal properties of polyamides were investigated. The tensile strength and lap shear adhesion strength of aromatic-based polyamide (DAP) were higher than those of aliphatic-based polyamide (DAH). In DSC thermogram, DAP has a high $T_g$ and $T_m$ compared with DAH. DAP's and DAH's softening point were $112-115^{\circ}C$ and $98-121^{\circ}C$, respectively.

An Experimental Study on Evaluation of Repair Mortars with CAC (Calcium Aluminate Cement) for Sewer Pipe (하수관거 보수용 CAC 모르타르 성능평가에 대한 실험적 연구)

  • Chung, Jee-Seung;Kang, Weon-Dae
    • Journal of the Korean Society of Safety
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    • v.27 no.4
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    • pp.68-75
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    • 2012
  • The biogenic corrosion of mortars adopted in sewage repair by sulfuric acid-producing bacteria was considered in this paper. Calcium aluminate cement (CAC) was known to resist microbiologically-induced corrosion significantly better than portland and blended portland cement.In this study, CAC as well portland cement mortars were tested as main binder to evaluate the corrosion resistance by the chemical immersion test. Replacement ratios of CAC were changed as 0, 20, 40, 50, 60% of OPC binder and 0, 2, 4, 6% of EVA(Ethylene Vinyl Acetate) were also adopted to increase properties of CAC repair mortars in sewage application. Setting time, compressive strength, acid resistance and adhesive strength were measured for various experiments. As a results of the experiments, the proper formulation of repair mortars was found at 40% of CAC and 4% of EVA. Finally, the CAC mortars adopted in field sewer pipe and were demonstrated to superior in adhesion and workability.

Instrumental Analysis of the Human Hair Damaged by Bleaching Treatments - Focused on ATR FT-IRM -

  • Ha, Byung-Jo
    • Journal of Fashion Business
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    • v.12 no.6
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    • pp.23-33
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    • 2008
  • The physico-chemical characteristics by bleaching treatments were assessed by several instrumental analyses such as surface morphology, chemical structural change, color change as well as tensile strength. The change of morphological characteristic was observed through scanning electron microscope(SEM). The observation of the fine structure on hair surface by SEM showed the bleached hair had much damaged to hair cuticle, and some of cuticle surface were worn away. To investigate the chemical structural changes in hair keratin, the cross-sections of hair samples were directly analysed using Fourier transform infrared microspectroscopy(FT-IRM). The results showed the cysteic acid S=O band intensity was distinctively increased by performing the bleaching treatment. The cleavage of cystine was appeared to proceed primarily through the sulfur-sulfur (-S-S-) fission whereby cysteic acid was formed as a principal oxidation products. The distribution of amide I band in hair keratin was determined by attenuated total reflectance(ATR) FT-IR mapping image. The results showed that the outer side of hair cortex was more damaged than the inner side of the hair cortex. Also, during chemical bleaching of the hair with alkaline peroxide, the hair was turned to reddish yellow due to the oxidative degradation of eumelanin. This means the eumelanin is more unstable than pheomelanin in chemical oxidation. With bleaching, the tensile strength was also reduced as a results of the chemical oxidation.