• 제목/요약/키워드: acid resistance of concrete

검색결과 114건 처리시간 0.024초

Mechanical and durability properties of fly ash and slag based geopolymer concrete

  • Kurtoglu, Ahmet Emin;Alzeebaree, Radhwan;Aljumaili, Omar;Nis, Anil;Gulsan, Mehmet Eren;Humur, Ghassan;Cevik, Abdulkadir
    • Advances in concrete construction
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    • 제6권4호
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    • pp.345-362
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    • 2018
  • In this paper, mechanical and short-term durability properties of fly ash and slag based geopolymer concretes (FAGPC-SGPC) were investigated. The alkaline solution was prepared with a mixture of sodium silicate solution ($Na_2SiO_3$) and sodium hydroxide solution (NaOH) for geopolymer concretes. Ordinary Portland Cement (OPC) concrete was also produced for comparison. Main objective of the study was to examine the usability of geopolymer concretes instead of the ordinary Portland cement concrete for structural use. In addition to this, this study was aimed to make a contribution to standardization process of the geopolymer concretes in the construction industry. For this purpose; SGPC, FAGPC and OPC specimens were exposed to sulfuric acid ($H_2SO_4$), magnesium sulfate ($MgSO_4$) and sea water (NaCl) solutions with concentrations of 5%, 5% and 3.5%, respectively. Visual inspection and weight change of the specimens were evaluated in terms of durability aspects. For the mechanical aspects; compression, splitting tensile and flexural strength tests were conducted before and after the chemical attacks to investigate the residual mechanical strengths of geopolymer concretes under chemical attacks. Results indicated that SGPC (100% slag) is stronger and durable than the FAGPC due to more stable and strong cross-linked alumina-silicate polymer structure. In addition, FAGPC specimens (100% fly ash) showed better durability resistance than the OPC specimens. However, FAGPC specimens (100% fly ash) demonstrated lower mechanical performance as compared to OPC specimens due to low reactivity of fly ash particles, low amount of calcium and more porous structure. Among the chemical environments, sulfuric acid ($H_2SO_4$) was most dangerous environment for all concrete types.

화학적 환경에 노출된 콘크리트 보강용 FRP 보강근의 장기 효과 (Long-Term Effect of Chemical Environments on FRP Reinforcing Bar for Concrete Reinforcement)

  • 박찬기;원종필;유정길
    • 콘크리트학회논문집
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    • 제15권6호
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    • pp.811-819
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    • 2003
  • 철근의 부식은 철근콘크리트 구조물의 주요파괴 원인이다. 철근의 부식에 대한 문제점을 해결할 가능성이 있는 재료 중 FRP 보강근은 그 가능성이 높다. 그렇지만 FRP 보강근은 보강철근과 다른 파괴 매카니즘으로 의하여 현저하게 성능이 저하될 가능성을 가지고 있다. 이와 같은 환경에는 알칼리, 산, 염해 및 물과 수분 등이 있다. 따라서 본 연구에서는 FRP 보강근의 화학적 환경하에서의 내구성능을 평가하고자 하였으며 사용된 FRP 보강근은 2가지 종류의 CFRP 보강근 및 GFRP 보강근, 한가지 종류의 AFRP 보강근으로 알칼리용액, 산용액, 염해환경 및 중성용액에 노출시켰다. FRP 보강근의 역학적 특성 및 내구특성은 인장, 압축 및 전단시험을 통하여 평가하였으며 시험결과 FRP 보강근은 매우 혹독한 화학적 환경에서 우수한 내구성을 가지고 있음을 알 수 있었다.

초속경성 PCM의 내산성 (Acid-proof Test of PCM using the Ultre Rapid Hardening Cement)

  • 소양섭;박홍신;조영국
    • 콘크리트학회지
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    • 제2권4호
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    • pp.83-90
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    • 1990
  • 최근 개발되어 사용되고 있는 초속경시멘트는 그 조성광물중에 Cakcium-aluminate(11 Cao \ulcorner7Al2O3\ulcornerCaF2) 및 그 수화물이 존재하고 있어 이것들이 산과 극렬반응을 일으켜 시멘트 경화체에 균열과 붕괴현상을 가져온다. 본 연구는 이러한 초속경 시멘트를 사용한 경화체가 Polymet에 의한 개길로 어느 정도의 내산성을 발휘할 수 있는지를 실험한 내용으로 P/C=15 및 20%에서는 다른 시멘트를 사용한 경우와 비슷한 내산성이 있음을 알 수 있었다.

콘크리트-폴리머 복합재료 개발(II) -폴리머(레진) 콘크리트의 물성- (Development of Concrete-Polymer Composite(II) -Physical Properties of Polymer(Resin) Concrete-)

  • 황의환;황택성;길덕수
    • 공업화학
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    • 제10권7호
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    • pp.1066-1072
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    • 1999
  • 고기능성 건설재료로 활용하기 위하여 불포화폴리에스테르수지를 사용한 폴리머 콘크리트의 물성에 대하여 조사하였다. 탄산칼슘(충전제)의 첨가량(5~20 wt %)과 세골재의 첨가량(10~50 wt %)에 따라 다양한 배합의 공시체를 제작하여 압축 및 휨강도, 흡수시험, 내열수성시험, 내산성시험, 세공분포측정 및 SEM에 의한 미세조직 관찰등을 실시하였다. 그 결과 폴리머 콘크리트의 압축강도와 휨강도는 시멘트 콘크리트보다 4배 정도 향상되었고, 흡수율은 1/100로 감소되었으며, 내산성시험에 의한 중량감소율은 1/27로 현저히 감소되었다. 내열수성시험후에 측정한 폴리머 콘크리트의 압축 및 휨강도는 모두 내열수성시험전에 측정한 강도에 비하여 67%, 47%로 각각 감소되었으며 폴리머결합재의 분해에 의하여 세공량과 세공율은 크게 증가되었다.

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세라믹스, 알루미나 및 실리콘 카바이드 혼합물이 첨가된 콘크리트 표면보호재의 성능 평가 (Evaluation of Ceramics, Alumina and Silicone Carbide Added Concrete Surface Protecting Agent)

  • 공진희;김영근;오상근
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2009년도 추계 학술논문 발표대회
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    • pp.43-46
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    • 2009
  • The purpose of this study is to enhance durability of concrete structures that uses this surface protecting material by carrying out the performance test of the surface protecting material of concrete, and as s result, we reached out the conclusion as follow. 1. As a result of the test measuring the stability and adhesive power of conductive film against ultraviolet, freezing & thawing, and damage from seawater that deteriorate the surface protecting material, it was turned out to meet the performance criteria specifying in the KS standard enough to gain a good evaluation to use as a surface protecting material. 2. As a result of the test identifying the neutralization-furtherance, it was assessed to be capable of protecting effectively concrete structures from carbonic acid gas by a very low depth of 0.1mm of neutralization. 3. As a result of the test identifying Penetrated Resistance Properties of chloride ion, as it was turned out to have a very low value of 819 Coulombs, it was assessed that even in the environment where the corrosion by chloride such sea environment is very affective, the film can effectively protect the concrete structure. 4. As a result of the test identifying freezing & thawing, as there was no change in reduction of mass after 400 cycle, it was assessed that the film has a good resistance against freezing & thawing. According to the results of study above, it is expected that this technology can extend its durability of concrete structure and be widely used for concrete structure through means (methods) to prevent the neutralization and damage from seawater as original purposes of the surface protecting material.

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폐콘크리트 미분말을 충전재로 재활용한 폴리머 모르타르의 물성 (Physical Properties of Polymer Mortar Recycling Waste Concrete Powder as a Filler)

  • 황의환;최재진;황택성
    • 공업화학
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    • 제16권3호
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    • pp.317-322
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    • 2005
  • 오늘날 대규모 건설사업에 따른 골재의 고갈과 환경보호 측면에서 폐콘크리트 골재의 재활용이 절실히 요구되고 있다. 본 연구에서는 페콘크리트의 분쇄공정에서 발생되는 페콘크리트 미분말을 폴리머 모르타르의 충전재 대용으로 재활용하고자 하였다. 폴리머 모르타르의 공시체는 폴리머 결합재의 첨가율을 9~15 wt%, 실리카 미분말 충전재 대용의 폐콘크리트 미분말 치환율을 0~20 wt%, 0.1~0.3 mm 잔골재(21~24 wt%)와 0.7~1.2 mm 잔골재(44~47 wt%)의 첨가율을 65~71 wt% 범위로 다양하게 변화시켜 제조하였다. 폴리머 모르타르의 물성을 평가하기 위하여 압축 및 휨강도, 흡수율, 내열수성, 내산성, 세공분포특성, 전자현미경에 의한 미세조직 관찰시험을 행하였다. 시험결과, 폴리머 모르타르의 물성은 폴리머 결합재의 첨가율 증가에 따라 현저히 증가되었으나 페콘크리트 미분말의 치환율 증가에 따라서는 크게 저하되었다.

Corrosion Characteristics of Reinforced Steel Bar Emedded in Multiple Mortar Specimen(W/C:0.5) Aged 5 Years in Seawater

  • Moon, Kyung-Man;Takeo, Oki;Won, Jong-Pil;Park, Dong-Hyun;Kim, Yun-Hae
    • International Journal of Ocean System Engineering
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    • 제3권1호
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    • pp.33-37
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    • 2013
  • Reinforced concrete structures have been increasingly widely used in numerous industrial fields. These structures are often exposed to severely corrosive environments such as seawater, contaminated water, acid rain, and the seashore. Thus, the corrosion problems that occur with the steel bars embedded in concrete are very important from the safety and economic points of view. In this study, the effects of the cover thickness on the corrosion properties of reinforced steel bars embedded in multiple mortar test specimens immersed in seawater for 5 years were investigated using electrochemical methods such as the corrosion potentials, polarization curves, cyclic voltammograms, galvanostat, and potentiostat. The corrosion potentials shifted in the noble direction, and the value of the AC impedance also exhibited a higher value with increasing cover thickness. Furthermore, the polarization resistance increased with increasing cover thickness, which means that the oxide film that is deposited on the surface of a steel bar surrounded by alkali environment exhibits better corrosion resistance because the water, chloride ions and dissolved oxygen have difficulty penerating to the surface of the steel bar with increasing cover thickness. Consequently, it is considered that the corrosion resistance of reinforced steel can be improved by increasing the cover thickness. However, the corrosion resistance values of a steel bar estimated by measuring the corrosion potential, impedance and polarization resistance were not in good agreement with its corrosion resistance obtained by polarization curves.

Square CFST columns under cyclic load and acid rain attack: Experiments

  • Yuan, Fang;Chen, Mengcheng;Huang, Hong
    • Steel and Composite Structures
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    • 제30권2호
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    • pp.171-183
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    • 2019
  • As China's infrastructure continues to grow, concrete filled steel tubular (CFST) structures are attracting increasing interest for use in engineering applications in earthquake prone regions owing to their high section modulus, high strength, and good seismic performance. However, in a corrosive environment, the seismic resistance of the CFST columns may be affected to a certain extent. This study attempts to investigate the mechanical behaviours of square CFST members under both a cyclic load and an acid rain attack. First, the tensile mechanical properties of steel plates with various corrosion rates were tested. Second, a total of 12 columns with different corrosion rates were subjected to a reversed cyclic load and tested. Third, comparisons between the test results and the predicted ultimate strength by using four existing codes were carried out. It was found that the corrosion leads to an evident decrease in yield strength, elastic modulus, and tensile strain capacity of steel plates, and also to a noticeable deterioration in the ultimate strength, ductility, and energy dissipation of the CFST members. A larger axial force ratio leads to a more significant resulting deterioration of the seismic behaviour of the columns. In addition, the losses of both thickness and yield strength of an outer steel tube caused by corrosion should be taken into account when predicting the ultimate strength of corroded CFST columns.

콘크리트 보강용 FRP 리바의 개발 및 내구 특성 (Development and Durability Characteristics of FRP Reinforcing Bar for Concrete Structures)

  • 원종필;박찬기;윤종환;황금식;조용진
    • 한국농공학회:학술대회논문집
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    • 한국농공학회 2003년도 학술발표논문집
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    • pp.371-374
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    • 2003
  • The corrosion of steel reinforcing bar(re-bar) has been the major cause of the reinforced concrete deterioration. FRP(Fiber-reinforced polymer) reinforcing bar has emerged as one of the most promising and affordable solutions to the corrosion problems of steel reinforcement in structural concrete. In this study, long-term durability performance of FRP re-bar were evaluated. The mechanical and durability properties of two type of CFRP- and GFRP re-bar were investigated; the FRP re-bars were subjected to alkaline solution, acid solution, salt solution and deionized water. The mechanical and durability properties were investigated by performing tensile and short beam tests. Experimental results confirmed the desirable resistance of FRP re-bar to aggressive chemical environment.

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구리 합금 슬래그를 혼합한 시멘트 모르타르의 특성 (Evaluation of cement mortars blended with copper alloy slag)

  • 이정일;홍창우;류정호
    • 한국결정성장학회지
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    • 제25권1호
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    • pp.39-43
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    • 2015
  • 최근 콘크리트의 품질을 향상시키기 위하여 플라이애쉬, 고로슬래그, 실리카퓸과 같은 각종 시멘트 혼화재에 대한 많은 연구가 진행되고 있다. 이에 본 연구에서는 동합금 제련시 발생되는 슬래그의 시멘트 대체재로서의 활용성을 확인하기 위해 동합금 슬래그를 미분쇄하여 상용 포틀란트 시멘트에 첨가하고, 첨가량 변화에 따른 시멘트 모르타르의 유동성, 흡수율, 단위용적중량, 압축강도 및 휨강도 변화를 조사하였다. 또한 5 % 황산용액에서의 동슬래그 함유 시멘트 모르타르의 무게변화를 28일 동안 측정하여 화학적 저항성을 평가하였다.