• Journal of Korean Society of Forest Science
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• v.76 no.1
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• pp.11-16
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• 1987

With the purpose of pursuing the increase and decrease of chlorophyll a and chlorophyll b caused by application of the simulated acid rain treatment on Pinus koraiensis seedlings and Ligustrum obtusifolium cuttings, the experimental design of randomized block arrangement with three replications was implemented in the experimental field of Yesan National Agricultural Junior College, during the growing season of 1985. Pinus koraiensis seeds stratified in cool and moist condition were sown on pots, and in case of Ligustrum obtusifolium, C1/1 cuttings were potted for experimental use in the early spring. The regime of artificial acid rain, based upon precipitation frequency and density, was simulated from the learning of climatological data averaged from 30 years records. The spray of acid water containing pH values of 4.0 and 2.0 was initiated from the 1st of May and ended on the 31st of August. As control, ground water was also treated at the same time. To analyse the chlorophyll content, those leaves looking representative and unaffected by other harmful agents were sampled on the 18th of September, and UV-visible spectrophotometer was used. With decrease in pH values of acid rain, the content of chlorophyll a and chlorophyll b decreased in both species. The decrease in chlorophyll a could be confirmed through statistical significance, but not in chlorophyll b. And when we discussed the chlorophyll decrease index which was explained in detail in the paper, an attention might be given to similarly decreasing values in both chlorophyll a and chlorophyll b, according as pH levels of acid rain decreased. The ratios of chlorophyll a to chlorophyll b in both species were not affected by different pH leaves of acid rain.

• Proceedings of the KIEE Conference
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• 1997.07e
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• pp.1813-1815
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• 1997

In this study, in order to develop outdoor insulating materials, SIN(simultaneous interpenetrating polymer network) was introduced to Epoxy resin and the environment resistance was investigated. Six kinds of specimen were manufacture by filler($SiO_2$) content. SEM was untilized in order to confirm their network structure changes. Also, tracking test, UV test and acid rain test were carried out investigate the environment resistance characteristic. Therefore it was confirmed that simultaneous interpenetrating polymer network specimens were more excellent than single network structure specimens. But, acid rain almost never changed resistance.

• Proceedings of the Korea Air Pollution Research Association Conference
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• 1999.04a
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• pp.121-124
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• 1999

• Journal of Korean Society for Atmospheric Environment
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• v.8 no.1
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• pp.45-51
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• 1992

A study on acidity in fog, dew and frost was carried out. Samples were taken during May 1990-February 1991 at two sites in Chongwon, Choongbook. The acidity of dew and of fog collected from grass at site A was 4.89 and 5.46, respectively. Dew in summer showed very strong acidity. The volume of dew deposited on grass was much less than the volume of rain, but dew is effective to diffuse acid predursors and acid materials. Dew and fog can remove more effectively atmospheric acid materiasl deoposited on grass by diurnal turbulent motion rather than direct absorption of acid predursors and materials in the atmosphere. In a polluted area, acidic dew and fog can be occurred by the direct absorption and oxidation of acidic predursors in the atmosphere as well as the role of wet removal on grass surface. Acidity of frost collected on teflon surface showed little difference to acidity of dew and fog on teflon surface. This suggests a similar absorption mechanism of atmospheric precursors and materials into dew and frost in the atmosphere. Strong acidity in dew, fog and frost appeared to occur from local pollution sources of several ten kilometres. In particular, strong acidity in dew, fog, and frost together with acid rain can accelerate a damage in ecosystems. Discussion is made on scientific analyses and seasonal variations of acidity of fog, dew and frost. A mechanism on acidification of fog, dew and frost is also discussed.

• KOREAN JOURNAL OF CROP SCIENCE
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• v.42 no.1
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• pp.56-60
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• 1997

In order to investigate the relationships between the responses of four crops (rice, soybeans, potatoes, and red pepper) to acid rain, the simulated acid rain(SAR) of pH 1.8, 2.3, and 2.8 and normal rain of pH 6.0 were applied from 30 days after emergence to harvest at the two-week interval for rice, soybeans and red pepper and at a week interval for potatoes. SAR of pH 1.8 and 2.3 caused brown spots in the leaves of rice, soybeans, and red pepper and the damages were severer as the pH of SAR lowered, while no visual damages were observed in potatoes. The SARs did not affect chlorophyll content of rice and potatoes, while chlorophyll content of soybeans and red pepper decreased as the pH of SAR lowered. Photosynthetic activity was not significantly different among the pHs of SAR in rice, while decreased as pHs of SAR lowered from pH 2.8 to 1.8 in soybeans, potatoes, and red pepper. Yield of rice, soybeans, and potatoes was not affected by the pHs of SAR, but in red pepper the length, diameter, and weight of a fruit, the number of fruits per plant, and total matured fruit yield decreased as the pHs of SAR lowered. In rice and potatoes visual damages caused by SAR did not correlated with other observed traits. However, visual damages were negatively correlated with chlorophyll content and photosynthetic activity of soybeans and photosynthetic activity and yield of red pepper.

• Applied Science and Convergence Technology
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• v.26 no.6
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• pp.218-222
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• 2017

This study was conducted to remove $NO_x$, which is the main cause of fine dust and air pollution as well as acid rain. $NO_x$ was tested using 3% NO (diluted in He) as a simulated gas. Experiments were sequentially carried out by oxidizing NO to $NO_2$ and absorbing $NO_2$. Especially, we focused on the changes of NO oxidation according to both oxidant ($NaClO_2$) concentration change (1~10 M) and oxidant pH change (pH = 1~5) by adding HCl. In addition, we tried to suggest a method to improve $NO_2$ absorption by conducting $NO_2$ reduction reaction with reducing agent (NaOH) concentration (40~60%). It was found that NO removal efficiency increased as both concentration of oxidant and flow rate of NO gas increased, and NO decreased more effectively as the pH of hydrochloric acid added to the oxidant was lower. The $NO_2$ adsorption was also better with increasing NaOH concentration, but the NO removal efficiency was ~20% lower than that of the selective NO reduction. Indeed, this experimental method is expected to be a new method that can be applied to the capture and removal of fine dust caused by air pollution because it is a method that can easily remove NO gas by a simple device without expensive giant equipment.

• Journal of Korean Society of Forest Science
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• v.76 no.3
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• pp.230-240
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• 1987

Half-sib seedlings of Ginkgo biloba (one-year-old) were treated with various simulated acid rains(pH2.0, pH3.0, pH4.0 and pH5.0) to examine the effects of acid rain on leaf surface area, leaf injury, leaf chlorophyll content and photosynthetic ability of the leaf tissue. The seedlings were grown in a pot($4500cm^3$) containing one of three different soils(nurseryy soil, mixed soil and sandy soil). Simulated acid rain was made by diluting sulfuric and nitric acid solution($H_2SO_4:HNO_3=3:1$, V/V) with tap water and tap water(pH6.4), and treated by 5mm each time for three minutes during the growing seasons(April to October 1985). Acid rain treatments were done three times per week to potted seedlings by spraying the solutions. The results obtained in this study were as follows : 1. Leaf surface area per seedling at pH2.0 level was the lowest among the levels of pH, but those at other pH levels were not significantly different. 2. Leaf injury(injured leaf rate and injured leaf area) increased with decreasing pH levels of acid rain. 3. Leaf chlorophyll content measured during the period June through October was significantly different among the soil types, and that of the seedling in nursery soil was the highest. The lower pH levels of simulated acid rain was treated ; more leaf chlorophyll content was measured at the beginning of treatment, and the more it severely decreased at the late growing period. 4. Photosyntetic abilities, and the highest value was shown in nursery soil. Significand difference in photosynthetic ability among the levels of pH was observed only in August. Photosynthetic ability increased with decreasing pH levels at the beginning of treatment, but decreased rapidly after July.

• Korean Journal of Environmental Agriculture
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• v.10 no.1
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• pp.59-66
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• 1991

This study was carried out to investigate the chemical characteristics of the rain water in rural, urban and industrial areas which are located in Kyongbuk province, namely. Songju, Kumi, Kimchon, Yongdok and Teagu. The experiments were sampled the rain by amount of rain water from July to August in 1989, and analyzed the pH. EC, $SO_4\;^{2-}$, $NO_3^-$ and $Cl^-$ contents in the rain water. The results are summarized as follows : 1. The acid rain showed at the begining rain water of all surveyed sites, but there were difference by sites, and particulary severe in Kumi. 2. The content of $SO_4\;^{2-}$ in rain water was high in urban and industrial area, such as Teagu, Kumi and Kimchon. 3. According to the increasing rain water amount, the pH in rain water was high, and the contents of other components were low. This phenomenon remarkably presented at higher concentration of components and earlier rain water. 4. The electric conductivity was high significantly positive correlation with contents of $SO_4\;^{2-}$, $NO_3\;^-$ and $Cl^-$ in rain water, and pH was high significantly negative correlation with contents of $SO_4^{2-}$ and $NO_3\;^-$ in rain water, respectively.

• Korean Journal of Environmental Agriculture
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• v.13 no.2
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• pp.168-174
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• 1994

The experiments were performed to examine the effects of simulated acid rain (pH 1.0${\sim}$5.0) prepared by mixing sulfuric acid and nitric acid at the ratio of 3 : 1 on germination and growth of seedlings of some floricultural crops. Days to germination showed a one to three days' interval among crops, but pH level did not show any effect on germination for each crop. All seeds used in this experiment did not germinate at pH 1.0. At pH 2.0, the flowering cabbage and geranium still did not germinate, and even though the radicles of seeds were germinated, root hairs did not develop. The length of hypocotyls and radicles appeared to be significantly different according to the pH levels.

• The Korean Journal of Ecology
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• v.21 no.5_1
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• pp.449-456
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• 1998

This study was carried out to investigate the characteristics of acid deposition by stemflow, throughfall, rainfall and $SO_{2}$ in the industrial, urban and rural areas where were affected by the acid rain areas air pollution in Pinus thunbergii than Quercus spp. forest. As the stemflow pH in industrial and urban area were lowed that of rural area, the result industrial and urban, and correlation of negative ($r=-0.9415^{**}$) between pH and EC. The concentration of acid ion by stemflow, throughfall, rainfall were high $SO_{4}^{2-}$ ion at industrial areas, especially of $NO_{3}^{-}$ ion at urban areas. The concentration of basic ion all rain fall were high $Ca^{2+},\;Na^{+}$ ion at industrial areas, but there were high $Ca^{2+}$, $Na^{+}$ ion at urban areas. The concentration of $SO_{2}$ at survey areas were high $SO_{2}$ concentration at industrial and urban areas, but there was low at rural areas. There was correlation of negative ($r=-0.8007^{**}$ between pH and $SO_{2}$ concentration at survey areas. Soil acidity was also affected by stemflow and showed sigificantly low pH in industerial and urban areas.