• Title/Summary/Keyword: acid gas

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Fundamental Studies on the Manufactruring of prouse Electrode for Plosphoric Acid Fuel Cell. (인산형 연료전지의 다공성전극 제조에 관한 기초적연구)

  • 김영우;박정일;이주성
    • Journal of the Korean institute of surface engineering
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    • v.22 no.2
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    • pp.55-61
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    • 1989
  • A fuel cell which causes electrochemical ratio of conventional with oxygen consists of mainly there parts, such as electrolyte, fuel and oxidant electrode. IN this paper, most efforts were delivered to manufacturing PETE-bonded gas-diffusion electrode, and preparation methods of the porous electrodes has been discussd. A medio temperature, phosphoric acid fuel cell (PAFC) provided with fuel (hydrogen) and oxygen showed oxygen showed excellent performance characteristics with made electrodes. Performance data obtained from hydrgen-oxygen cell were presented to illustrate their properties. It was found that the optimum amounts of platinum in clectrode for hydrgen-oxygen PAFC were about 3mg/cm3 and the PTFE content of gas diffusion layer and catalyst layer were 25% and 15%, respectively.

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Volatile Flavor Components of Korean Sancho Fruit and Tree(Zanthoxylum schinfolium) (한국산 산초열매와 나무의 휘발성 향기성분)

  • 이종원
    • The Korean Journal of Food And Nutrition
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    • v.11 no.5
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    • pp.493-498
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    • 1998
  • An attempt was in this to analyzer volatile flavor components of sancho(Zanthoxylum schinfolium). Essential oils in sancho tree and fruit isolated by a simulataneous steam distillation (SDE) methods using n-pentane/diethyl ether as solvent. A total of 57 and 44 components were identified by gas chromatography(GC) and combined gas chromatography spectrometry (GC-MS), respectively. Granyl acetate(29.23%) geraniol (6.80%, p-isopropyl-2-chclohexenone(5.53%), phellandral (4.10%) in sancho fruit and 4, 6, 6-trimethyl-bicyclo(7.47%), T-carvelo(4.60%, ${\alpha}$-cypernone(3.58%) in sancho tree were found to be major volatile flavor. 22 compnents including myrcene, limonene, 1, 8-cinol in sancho fruit and 10 components including 4-(1-methylethyl)-cyclohexanol, methyl undecyl ketone in sancho tree were identified. The contents of unsaturated fatty acids of palmitic acid(24.34%), myristic acid(3,68%) in sancho tree was higher than that of the sancho fruit.

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A Study on Hydrogel-Based CK Agent Detecting Gel Using Konig Reaction (Konig 반응을 이용한 CK 작용제 탐지젤 개발에 관한 연구)

  • Kim, Kyungmin;Kim, Kyung-pil
    • Journal of the Korea Institute of Military Science and Technology
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    • v.18 no.6
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    • pp.829-834
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    • 2015
  • A simple and sensitive hydrogel-based detecting gel has been presented for the qualitative determination of cyanogen chloride(CK) using Konig reaction. To optimize Konig reaction conditions, the effects of pyridine and barbituric acid concentration were investigated. Under the optimized conditions, CK gas concentration was directly related with absorbance change at 567 nm. Based on aqueous solution test results, we finally prepared CK detecting hydrogel by absorbing pyridine and barbituric acid solution. Color change of the prepared CK detecting hydrogel was clearly observed when the detecting gel was exposed to 10 ppm CK gas.

Acid-gas Removal Characteristics of Coal Gasification System using FeMgO catalyst (FeMgO 촉매를 이용한 산성가스 정제 특성)

  • Park, Jun-Sung;Hwang, Sang-Yeon;Lee, Seung-Jong
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.11a
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    • pp.457-460
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    • 2007
  • 석탄가스화 기술은 석탄을 고온/고압 조건에서 가스화 반응시켜 CO와 $H_2$가 주성분인 합성가스(syngas)로 전환시키는 기술이다. 그러나 가스화 반응으로 인해 합성가스 내에는 불순물인 $H_2S$, COS, $NH_3$ 등의 오염 물질이 발생하게 되며, 가스터빈의 부식, 촉매의 피독, 전극의 성능 저하 현상 등을 일으켜 효율을 저하시키게 된다. 이에 본 연구에서는 FeMgO 촉매를 제거용매로 사용하여 $H_2S$를 효과적으로 제거하기 위하여 Lab-scale 탈황 설비를 제작하였으며, 석탄 가스화 운전에 연계하여 합성가스 내 포함된 산성가스 정제 특성에 관한 연구를 진행하였다.

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STUDIES ON THE SEPARATION & DETERMINATION OF CIS-TRANS FATTY ACIDS IN CIGARETTE SMOKE CONDENSATE BY GLASS CAPILLARY GAS CHROMATOGRAPHY (유리모세관칼럼에 의한 담배연기응축물중의 cis-trans형 지방산의 분리정량에 관한 연구)

  • Rhee, M.S.;Lee, U.C.;Kim, C.H.
    • Journal of the Korean Society of Tobacco Science
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    • v.7 no.1
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    • pp.67-74
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    • 1985
  • Cis-trans forms of fatty acids in cigarette smoke condensate were separated and characterized using SP 2340 glass capillary gas chromatography. The transforms of fatty acids, palmitoeladic , 1-vaccenic, eladic and linoeladic acid were identified. These components were not present only 3% of the total fatty acid fraction, but they showed a very low transfer rate.

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The Future of Planetary Entry Technology

  • Park, Chul
    • International Journal of Aeronautical and Space Sciences
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    • v.12 no.3
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    • pp.211-224
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    • 2011
  • This is a written version of an hour-long lecture delivered by the author on June 30, 2011, as Plasmadynamics and Lasers Award Lecture at the AIAA 2011 summer conference in Honolulu, Hawaii. The author proposes that two areas of planetary entry physics be pursued in the future: outer planet aero-capturing and study of aerodynamics of meteoroid entries, both for the purpose of advancing the understanding of the possible extraterrestrial seeding of building blocks of life. For outer planet aero-capturing, the author proposes to develop new shock tube facilities that will produce up to 30 km/s of shock speed without causing photo-ionization of the driven gas by the radiation from the hot driver gas. Regarding meteors, the author proposes to carry out laboratory testing of the Tunguska event and of the seeding of amino acid molecules using a ballistic range which shoots a snowball laden with amino acid molecules toward a water surface.

Separation of Amino Acid Enantiomers by Gas Chromatography (III) -(S)-5-isobutyl-$N^3$-phenyl-2-thiohydantoin as chiral stationary phase- (가스 크로마토그라피에 의한 아미노산 광학 이성질체의 분리(III) -(S)-5-isobutyl-$N^3$-phenyl-2-thiohydantoin의 광학 활성 고정상으로의 응용-)

  • Park, Man-Ki;Yang, Jeong-Seon;Ko, Chang-Bum
    • YAKHAK HOEJI
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    • v.32 no.2
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    • pp.112-116
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    • 1988
  • The resolution of N-trifluoroacetyl (N-TFA) ter-isopropylesters of Ala, Ile, Leu, Val and Phe by gas chromatography on the (S)-5-isobutyl-$N^3$-phenyl-2-thiohydantoin as stationary phase was investigated. The phase was employed at several column temperatures $(140^{\circ}C{\sim}200^{\circ}C)$ and the separation factors were $1.18{\sim}1.45$ range for five amino acid enantiomers. The possible mechanism of chiral recognition was investigated by NMR technique and the association constant$(K_c)$ was calculated as 201.3(r=0.98) for alanyl derivative.

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Separation of Tetrodotoxin, DHA and EPA from Pufferfish Liver Waste (복어간 폐기물로부터 Tetrodotoxin, DHA 및 EPA의 분리)

  • 차병윤;최진석;임정규;이동익;이원갑;이은열;김희숙;김동수
    • Journal of Life Science
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    • v.10 no.2
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    • pp.115-124
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    • 2000
  • The present study was undertaken to separate the available components effectively, such as tetrodotoxin(TTX), docosahexaenoic acid(DHA, C22:6,ω-3) and eicosapentaenoic acid (EPA, C20:5,ω -3) from pufferfish liver waste, which are known to have high values as bioactive materials. By using ultrafiltration, it was possible to separate high contents of 68mg TTX from pufferfish liver waste. In contrast, by activated charcoal column, it was to obtain about 54mg TTX. The recovering ratios were 65.3% and 45.0% in the two different methods of ultrafiltration and activated charcoal column, respectively. From the results of HPLC and gas chromatography-mass spectrometry(GC-MS), the obtained toxins were identified to be TTX and its derivatives. In addition, it was also possible to obtain 72.3g DHA and 11.4g EPA from 1kg of pufferfish liver by high performance liquid chromatography (HPLC). These amounts of DHA and EPA were also 17.70% and 1.04% in the total lipid of pufferfish liver oil from analysis of gas chromatography(GC), respectively.

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A study for an association of acetic acid with n-heptane based on the chemical theory (초산과 n-heptane 이성분계의 회합성에 대한 화학적 이론을 이용한 연구)

  • Hong Sungho;Lee Jinyub;Lee Taejong
    • Journal of the Korean Institute of Gas
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    • v.3 no.3 s.8
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    • pp.34-38
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    • 1999
  • To propose a model equation, an acetic acid and n-heptane binary vapor liquid equilibrium system were investigated at 298.15K and 318.15K. Pressure was theoretically estimated using an association model based on the chemical theory, in conjunction with Margules, Wilson, NRTL models. Results were compared with those of calculated values without considering association. The theoretically calculated results of association model equations show a good agreement with the experimentally observed values.

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