• Title/Summary/Keyword: acid gas

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STUDY ON THE PYROLYSIS OF TRANS-9-OCTADECENOIC ACID AND TRANS-9-OCTADECENOIC ACID. (Cis-9-Octadecenoic acid와 trans-9-Octadecenoic acid의 열분해에 관한 연구)

  • Lee, Moon-Soo;Lee, Un-Cheoul;Kwag, Jae-Jin
    • Journal of the Korean Society of Tobacco Science
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    • v.9 no.1
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    • pp.57-64
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    • 1987
  • The pyrolysis of geometrical isomers of 9-octadecenoic acid were conducted at $600^{\circ}C$ under nitrogen, and its pyrolytic behaviors were investigated. The pyrolytic products of both fatty acids, cis-9-octadecenoic acid(oleic acid) and trans-9-octadecenoic acid(elaidic acid), were analyzed using a gas chromatograph and GC/MS spectrometer. Twenty-seven different compounds were identified from these pyrolyzates, and the chief products of them were ketones, alcohols and aromatic hydrocarbons. And also, the pyrolytic mechanisms of two geometrical isomers of this fatty acid were discussed by a comparison of experimental results.

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Production of Auxins and Auxin-like Compounds by Ginseng Growth-promoting Bacterium Pseudomonas fluorescens KGPP 207

  • Ten, Leonid N.;Lee, Mi Ja;Lee, Mee-Kyoung;Park, Hoon;Yoon, Jong Hyuk
    • Journal of Applied Biological Chemistry
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    • v.43 no.4
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    • pp.264-268
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    • 2000
  • High activity of acidic ethylacetate extract from the culture supernatant of ginseng growth-promoting bacterium Pseudomonas fluorescens KGPP 207 and its fractions were demonstrated through wheat coleoptile bioassay. The following auxins and auxin-like compounds were identified in these fractions by combined gas chromatography-mass spectrometry: indole-3-acetic acid, indole-3-acetic acid methyl and ethyl ester, indole-3-butyric acid, indole-3-lactic acid and its methyl ester, indole-3-propionic acid, indole-3-pyruvic acid, p-hydroxyphenyl acetic acid, p-hydroxyphenyl acetic acid methyl and ethyl ester, phenyl acetic acid and its methyl ester. The bacterium KGPP 207 belongs to the strain of P. fluorescens which produces plant growth regulators and its beneficial effect on the ginseng growth may be due to the formation of the identified compounds.

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Cellular fatty acid composition in comamonas terrigena (Comamonas terrigena의 균체지방산 조성)

  • 하덕모;안병학
    • Korean Journal of Microbiology
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    • v.25 no.1
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    • pp.67-72
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    • 1987
  • Cellular fatty acid composition of eight strains, indluding six strains of Comamonas terrigena, and two type strains of Pseudomonas acidovorans, and P. testosteroni was determined by gas-liquid chromatography. Almost the same composition was found in all the strains tested, and hexadecanoic acid, hexadecenoic acid, and octadecenoic acid were accounted more than 70% of total fatty acid. However, P. testosteroni differed from C. terrigena and P. acidovorans by the presence of comparatively large amonuts of 2-hydroxy-hexadecanoic acid, and C. terrigena contained three to eight times as much tetradecanoic acid in P. acidovorans and P. testosteroni. According to the similarity values calculated on the basis of fatty acid composition, C. terrigena strains were divided into three groups differentiated in the requirement of growth factors, and C. terrigena, P. acidovorans, and P. testosteroni strains occupied separate position each other in the dendrogram.

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Preparation of Manganese Oxide Porous Nanostructures using Amino-acid and its Selective C3H8 Sensing Properties (아미노산을 이용한 망간 산화물 기공성 나노 구조의 합성 및 C3H8 가스에 대한 선택적 감응 특성)

  • Choi, Kwon-Il;Lee, Jong-Heun
    • Journal of Sensor Science and Technology
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    • v.20 no.1
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    • pp.64-69
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    • 2011
  • Porous manganese oxide porous nanostructures were prepared by amino-acid-mediated solvothermal self assembly reaction and subsequent heat treatment at $600^{\circ}C$. When Mn-precursors were heat-treated at $400-550^{\circ}C$, the sensors did not show significant gas responses. In contrast, the manganese oxide heat-treated at $600^{\circ}C$ showed the significant gas responses, that is, the resistance decrease to 100 ppm $C_3H_8$ ($R_a/R_g$ = 2.17, $R_a$ : resistance in air, $R_g$ : resistance in gas) and the resistance increase to 100 ppm $C_2H_5OH$ ($R_g/R_a$ = 1.92). The opposite change of resistance upon exposure to $C_3H_8$ and $C_2H_5OH$ was discussed in relation to the mixed phases of manganese oxides with different valences.

A Study About Improvement of Experiment of Carbon Dioxide Production on Elementary School Science Textbook (초등학교 과학과 이산화탄소 발생실험의 개선에 관한 연구)

  • 고영신;김세경;이혜경
    • Journal of Korean Elementary Science Education
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    • v.23 no.2
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    • pp.152-158
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    • 2004
  • The purpose of this study was to find the difficulties and problems in the carbon dioxide production experiment and to suggest the device for the improvement. Many students have misconception for the smell of carbon dioxide. I found that the smell of carbon dioxide of producting through the experiment didn't concern with the quantity of calcium carbonate. I certificated that the smell of carbon dioxide was related with the concentration of hydrochloric acid. I built two trap applicaing suction in the gas production device to exclude fully the smell of carbon dioxide. So the smell of carbon dioxide was not present by passing the two trap. To find the ideal experimental conditions I perform the experiment step by step. As the result enough carbon dioxide to use for the property experiment was collected under the condition that is 60 mL of 3 molarity hydrochloric acid and 30 g calcium carbonate. I certificated to mesuring flowing quantity of carbon dioxide using the flow meter of carbon dioxide. In the improvement experiment of the property of carbon dioxide, I proposed the experiment device regarding as spreading of the gas and children's interest. To improve the problem of gas production experiment, I proposed the gas certification device using a thread.

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A Study on The Variation of Penetration According to The Shielding Gas in A1100 Aluminum Welding (A1100 알루미늄 용접에서 실드가스의 종류에 따른 용입부의 변화 연구)

  • Kim, Jin-Su;Kim, Bub-Hun;Kim, Gue-Tae;Park, Yong-Hwan
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.12 no.2
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    • pp.49-54
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    • 2013
  • Recently welding of aluminum material is actively carried out to make lightweight in the fields of LNG vessels, aircraft, chemical plants, etc. To obtain high strength, hardness and elongation, elements such as manganese, zinc, silicon, etc should be added in aluminum alloy, which has been improved on the mechanical properties like precipitation hardening, age hardening, loosening, corrosion resistance acid resistance. Ar gas is used as a shielding gas of MIG welding for aluminum, also $N_2$, $O_2$, $CO_2$, $H_2$ etc can be added depending on the composition of the alloy. In this study, Ar + $O_2$, Ar, and He were used for welding, hardness, penetration status and changes in composition of penetrated parts were compared and analyzed. This made it possible to know the status and changes of the process in the penetrated parts depending on used gas throughout this study.

Highly Sensitive and Selective Trimethylamine Sensor Using Yolk-shell Structured Mo-doped Co3O4 Spheres

  • Kim, Tae-Hyung;Kim, Ki Beom;Lee, Jong-Heun
    • Journal of Sensor Science and Technology
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    • v.28 no.5
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    • pp.271-276
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    • 2019
  • Pure and 0.5, 1, 2, 5, and 10 at% of Mo-doped $Co_3O_4$ yolk-shell spheres were synthesized by ultrasonic spray pyrolysis of droplets containing Co nitrate, ammonium molybdate, and sucrose and their gas sensing characteristics to 5 ppm trimethylamine (TMA), ethanol, p-xylene, toluene, ammonia, carbon monoxide, and benzene were measured at $225-325^{\circ}C$. The sensor using pure $Co_3O_4$ yolk-shell spheres showed the highest response to p-xylene and very low response to TMA at $250^{\circ}C$, while the doping of Mo into $Co_3O_4$ tended to increase the overall responses of gas sensors. In particular, the sensor using 5 at% Mo-doped $Co_3O_4$ yolk-shell spheres exhibited the high response to TMA with low cross-responses to other interfering gases. The high response and selectivity of Mo-doped $Co_3O_4$ yolk-shell spheres to TMA are attributed to the electronic sensitization by higher valent Mo doping and acid-base interaction between TMA and Mo components.

Gas and particle removal characteristics of a novel electrostatic precipitation type air cleaner using an activated carbon filter as an electrode (활성탄 섬유 필터를 전극으로 활용한 정전 방식의 공기정화장치의 가스 및 입자 제거 특성 분석)

  • Lim, Gi-Taek;Kim, Yong-Jin;Han, Bangwoo;Woo, Chang Gyu;Shin, Weon Gyu;Kim, Hak-Joon
    • Particle and aerosol research
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    • v.14 no.1
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    • pp.9-16
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    • 2018
  • We have developed an electrostatic precipitation (ESP) type air cleaner for indoor air quality and investigated its performances regarding CADR (Clean air delivery rate), single-pass efficiency and gas removal efficiency. The ESP air cleaner used an ACF (Activated carbon fiber) filter for gas removal and the ACF as a high voltage electrode for particle removal. The ESP air cleaner was tested in a chamber with the volume of $1m^3$ regarding CADR and gas removal efficiency. The applied CADR area of the ESP was $1.8m^2$. Gas removal efficiency was tested with 3 gases (Acetaldehyde, Acetic acid, Ammonia). As the results of the gas removal efficiency, the ESP air cleaner shows the removal efficiencies of 90, 98 and 85% for acetaldehyde, acetic acid and ammonia, respectively.

Recovery of Ammonia Nitrogen using Gas-permeable Membranes (기체투과막을 이용한 암모니아성 질소 회수방안)

  • Lee, Sang-hun;Chae, Sang Yeop
    • Membrane Journal
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    • v.32 no.3
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    • pp.191-197
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    • 2022
  • Ammonia nitrogen can be effectively recovered from livestock manure waste, etc. by using the gas permeable membrane technology. In this case, ammonia gas in the waste passes through the pores in one-side of membrane, impregnated in waste, and then reach the opposite side of the membrane. The permeated ammonia gas molecules are captured and recovered by acid (such as sulfuric acid) in the solution existing on the opposite side of the membrane. In order to improve ammonia nitrogen removals in the inlet part, high pH should be maintained in the feed waste including ammonia nitrogen to recover, which requires the cost of the chemical. To resolve this issue, previous studies tested various methods, for example, utilization of cheap calcium hydroxide or aeration together with inhibition of unwanted nitrification. The gas permeable membranes used for the recovery of ammonia nitrogen may be characterized, not only by proper heat and chemical resistance, but also by hydrophobicity, allowing selective ammonia gas permeation through the hydrophobic membrane pores. Future research should consider the relevant pilot or upscale processes using on-site wastes with various properties, and identify the optimal design/operation conditions as well as economic feasibility improvement plans.