• Title/Summary/Keyword: acid corrosion

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The Characterization and Coatings on 304 Stainless Steel by Laser Induced Fluorescence Spectroscopy using the High Resolution Charge Coupled Device (레이저 유도형광분광기에서 고정밀 전하장치를 이용한 304 스테인레스 스틸의 코팅과 특성)

  • Kim, Ki-Jun;Lee, Jou-Youb;Sung, Wan-Mo
    • Journal of the Korean Applied Science and Technology
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    • v.33 no.2
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    • pp.385-390
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    • 2016
  • In our study, ceramics coatings by additives of nano alumina and magnesia have cured on 304 stainless steel at $170^{\circ}C$ 2h. We designed and experimented the coated specimens that were characterized by laser induced fluorescence spectroscopy using the charge coupled device and scanning electronic microscopy(SEM). The result was revealed the ceramic coatings added fillers has more excellent on adhesive property and scratch resistance, and less weight loss in acid solution than ceramic coatings non-added fillers. Therefore, this study has designed and manufactured the electromagnetic spectrometry with CCD and then analyzed the coatings on 304 stainless steel using the High Resolution Charge Coupled Device in improving the corrosion resistance of 304 stainless steel. Nowadays, coatings of stainless steel have increased by industrial demand in hygienes, aviation, instrumentations and robotics as the industry special application develops.

Increased Osteoblast Adhesion Densities on High Surface Roughness and on High Density of Pores in NiTi Surfaces

  • Im, Yeon-Min;Gang, Dong-U;Kim, Yeon-Uk;Nam, Tae-Hyeon
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2009.11a
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    • pp.39.1-39.1
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    • 2009
  • NiTi alloy is widely used innumerous biomedical applications (orthodontics, cardiovascular, orthopaedics, etc.) for its distinctive thermomechanical and mechanical properties such as shape memory effect, super elasticity, low elastic modulus and high damping capacity. However, NiTi alloy is still a controversial biomaterial because of its high Ni content which can trigger the risk of allergy and adverse reactions when Ni ion releases into the human body. In order to improve the corrosion resistance of the TiNi alloy and suppress the release of Ni ions, many surface modification techniques have been employed in previous literature such as thermal oxidation, laser surface treatment, sol-gel method, anodic oxidation and electrochemical methods. In this paper, the NiTi was electrochemically etched in various electrolytes to modify surface. The microstructure, element distribution, phase composition and roughness of the surface were investigatedby scanning electron microscopy (SEM), energy-dispersive X-ray spectrometry(EDS), X-ray diffractometry (XRD) and atomic force microscopy (AFM). Systematic controlling of nano and submicron surface features was achieved by altered density of hydro fluidic acid in etchant solution. Nanoscale surface topography, such as, pore density, pore width, pore height, surface roughness and surface tension were extensively analyzed as systematical variables.Importantly, bone forming cell, osteoblast adhesion was increased in high density of hydro fluidic treated surface structures, i.e., in greater nanoscale surface roughness and in high surface areas through increasing pore densities.All results delineate the importance of surface topography parameter (pores) inNiTi to increase the biocompatibility of NiTi in identical chemistry which is crucial factor for determining biomaterials.

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Degradation Characteristics of Aqueous AMP Solution Containing Additives in Separation of $CO_2/H_2S$ ($CO_2/H_2S$의 분리시 첨가제에 따른 AMP 수용액의 열화특성)

  • Choi, Won-Joon;Lee, Jae-Jeong;Cho, Ki-Chul;Oh, Kwang-Joong
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.3
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    • pp.280-285
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    • 2005
  • The method of chemical absorption has been presented to separate and recover acid gases like $CO_2\;and\;H_2S$. But, this method has some problems such as loss of valuable amine and operational problems (forming, corrosion and fouling) by degradation. In this study, we investigated the degradation characteristics of aqueous AMP solution containing additives such as HMDA, MDEA and piperazine. The degradation was affected by temperature and process time. AMP solution absorbing $CO_2\;and\;H_2S$ was degraded 105% and 23% more than pure AMP at $120^{\circ}C$ respectively. In addition, all the additives were degraded significantly as the temperature increased. The order of the degraded amount of additives mixed in the AMP solution containing absorbed $CO_2$ was as followings : HMDA > piperazine > MDEA.

Development of Thermoplastic Carbon Composite Bipolar Plates for High-temperature PEM Fuel Cells (고온 양성자 교환막 연료전지용 열가소성 탄소 복합재료 분리판 개발)

  • Lim, Jun Woo;Kim, Minkook;Lee, Dai Gil
    • Composites Research
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    • v.29 no.5
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    • pp.243-248
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    • 2016
  • Although thermoset carbon fiber composite bipolar plates not only have high mechanical properties but also high corrosion resistance in acid environment, high manufacturing cost and low bulk electrical conductivity are the biggest obstacle to overcome. In this research, thermoplastic polymer is employed for the matrix of carbon composite bipolar plate to increase both the manufacturing productivity and bulk electric conductivity of the bipolar plate. In order to increase the electrical conductivity and strength, plain type carbon fabric rather than chopped or unidirectional fibers is used. Also nano particles are embedded in the thermoplastic matrix to increase the bulk resistance of the bipolar plate. The area specific resistance and the mechanical strength of the developed bipolar plate are measured with respect to the environmental temperature and stack compaction pressure.

An Electrochemical and Optical Study on the Corrosion and Passivation of Metals. An Electrochemical and Optical Study on the Passivation Film of Electrolytic Iron (금속 부식과 부동화에 관한 전기화학적 및 광학적 연구. 순철의 부동화 피막에 관한 전기화학적 및 광학적 연구)

  • Park Byung So;Paik Woon-Kie;Yeo, In Hyeong
    • Journal of the Korean Chemical Society
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    • v.22 no.6
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    • pp.365-369
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    • 1978
  • Ellipsometric and reflectance measurements were made on an iron surface in a cathodically reduced state and in an anodically passivated state. From the differences in the optical parameters (${\Delta},\;{\psi}$, and reflectance) between the reduced (film-free) and passivated (film-covered) states the thickness and optical constants of the surface film were determined. In the passive state at -400 mV vs. SCE in borate-boric acid buffer solution the anodic film had a thickness of about 11${\AA}$ and optical constants of ${\tilde{n}}$= 2.8 - 0.8 i. This value indicates a substantial electronic conductivity of the anodic film.

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Performance and Emission Characteristics of a Diesel Engine Operated with Wood Pyrolysis Oil (목질 열분해유를 사용하는 디젤엔진의 성능 및 배기특성에 관한 연구)

  • Lee, Seok-Hwan;Park, Jun-Hyuk;Choi, Young;Woo, Se-Jong;Kang, Kern-Yong
    • Transactions of the Korean Society of Automotive Engineers
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    • v.20 no.5
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    • pp.102-112
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    • 2012
  • The vast stores of biomass available in the worldwide have the potential to displace significant amounts of fuels that are currently derived from petroleum sources. Fast pyrolysis of biomass is one of possible paths by which we can convert biomass to higher value products. The wood pyrolysis oil (WPO), also known as the bio crude oil (BCO), have been regarded as an alternative fuel for petroleum fuels to be used in diesel engine. However, the use of BCO in a diesel engine requires modifications due to low energy density, high water contents, low acidity, and high viscosity of the BCO. One of the easiest way to adopt BCO to diesel engine without modifications is emulsification of BCO with diesel and bio diesel. In this study, a diesel engine operated with diesel, bio diesel (BD), BCO/diesel, BCO/bio diesel emulsions was experimentally investigated. Performance and gaseous & particle emission characteristics of a diesel engine fuelled by BCO emulsions were examined. Results showed that stable engine operation was possible with emulsions and engine output power was comparable to diesel and bio diesel operation. However, in case of BCO/diesel emulsion operation, THC & CO emissions were increased due to the increased ignition delay and poor spray atomization and NOx & Soot were decreased due to the water and oxygen in the fuel. Long term validation of adopting BCO in diesel engine is still needed because the oil is acid, with consequent problems of corrosion and clogging especially in the injection system.

A Study on Development of Automatic Path Tracking Algorithm for LNG Aluminium Plate and Selection of Process Parameters by Using Artificial Intelligence (LNG 알루미늄 판재 가공용 자동 궤적 추적 알고리즘 개발 및 인공지능을 이용한 공정조건 선정에 관한 연구)

  • 문형순;권봉재;정문영;신상룡
    • Journal of the Korean Society for Precision Engineering
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    • v.15 no.8
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    • pp.17-25
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    • 1998
  • Aluminum alloys have low density, relatively high strength and yield strength, good plasticity, good machinability, and high corrosion and acid resistance. Therefore, they are suitable for large containers for the food, chemical and other industries. Large containers are often bodies of revolution consisting of shell courses, stiffening rings, heads and other elements joined by annular welds. Larger containers have longer welds and require greater leak-tightness and higher weld mechanical properties. The LNG tank consists of aluminum plates with various sizes, so its construction should by divided by several sections. Moreover, each section has its own sub-section consisted of several aluminum plates. To guarantee the quality of huge LNG tank, therefore, the precise control of plate dimension should by urgently needed in conjunction with the appropriate selection of process parameters such as cutting speed, depth of cut, rotational speed and so on. In this paper, a manufacturing system was developed to implement automatic circular tracking in height direction and automatic circular interpolation in depth of cut direction. Also, the neural network based on the backpropagation algorithm was used to predict the cutting quality and motor load related with the life time of the developed system. It was revealed that the manufacturing system and the neural network could be effectively applied to the bevelling process and to predict the quality of machined area and the motor load.

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Development of Automated Nondestructive Inspection System for BMI Nozzles in Nuclear Vessel (원자로 BMI 노즐 검사를 위한 자동화 비파괴검사 시스템 개발)

  • Park, Joon Soo;Lee, Won Kun;Han, Won Jin;Lee, Sun Ho;Seong, Un Hak
    • Journal of the Korean Society for Nondestructive Testing
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    • v.33 no.1
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    • pp.26-33
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    • 2013
  • BMI nozzles in bottom head of the nuclear vessel are one of major components in nuclear power plants. The BMI nozzles have high possibility to generate PWSCC(primary water stress corrosion crack) according to recent foreign case although operation temperature is lower then the upper head of the nuclear vessel. Thus, nondestructive inspection of the BMI nozzles is required. But, inspection of BMI nozzles is not easy since the BMI nozzles placed in high radiated area and inside the nozzles filled with boric acid. Thus, in this study, a TOFD transducer for inspection of BMI and automated scanner system with water were developed. Also, validation of performance of the developed transducer and system are performed using specimens with artificial defects.

A fundamental study on the sulphate-resistant mortar using waste glass fine powder and meta-kaolin according to various fine aggregates (잔골재 종류에 따른 폐유리 미분말 및 메타카올린을 사용한 내황산염 모르타르에 관한 기초적 연구)

  • Jeong, Dongwhan;Park, Junhui;Ahn, Taeho;Park, Yeongsik;Sho, Kwangho
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.27 no.3
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    • pp.115-121
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    • 2017
  • The degradation of the concrete due to deterioration factors, such as corrosion of steel bars, cracks and structural strength of reinforced concrete structures, is a social problem. Especially, concrete structures constructed in seawater, underground water, waste water treatment facilities and sewerage are subject to chemical attack by acid and sulphate. Therefore, this study was conducted to compare sulfated glass and fine aggregate of slag using waste glass fine powder and meta kaolin. The results showed that the slag fine aggregate showed better sulfate resistance than the river sand, and the fine powder of waste glass showed the best performance at 3 % displacement.

Evaluation of Ceramics, Alumina and Silicone Carbide Added Concrete Surface Protecting Agent (세라믹스, 알루미나 및 실리콘 카바이드 혼합물이 첨가된 콘크리트 표면보호재의 성능 평가)

  • Kong, Jin-Hee;Kim, Young-Geun;Oh, Sang-Keun
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2009.11a
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    • pp.43-46
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    • 2009
  • The purpose of this study is to enhance durability of concrete structures that uses this surface protecting material by carrying out the performance test of the surface protecting material of concrete, and as s result, we reached out the conclusion as follow. 1. As a result of the test measuring the stability and adhesive power of conductive film against ultraviolet, freezing & thawing, and damage from seawater that deteriorate the surface protecting material, it was turned out to meet the performance criteria specifying in the KS standard enough to gain a good evaluation to use as a surface protecting material. 2. As a result of the test identifying the neutralization-furtherance, it was assessed to be capable of protecting effectively concrete structures from carbonic acid gas by a very low depth of 0.1mm of neutralization. 3. As a result of the test identifying Penetrated Resistance Properties of chloride ion, as it was turned out to have a very low value of 819 Coulombs, it was assessed that even in the environment where the corrosion by chloride such sea environment is very affective, the film can effectively protect the concrete structure. 4. As a result of the test identifying freezing & thawing, as there was no change in reduction of mass after 400 cycle, it was assessed that the film has a good resistance against freezing & thawing. According to the results of study above, it is expected that this technology can extend its durability of concrete structure and be widely used for concrete structure through means (methods) to prevent the neutralization and damage from seawater as original purposes of the surface protecting material.

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