• Title/Summary/Keyword: acid chloride

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Effect of Cingulate Cortical Ablation upon Gastric Secretion in Rats (흰쥐에서 대상회전 제거가 위액분비에 미치는 영향)

  • Park, Hyoung-Jin;Ahn, Byung-Tae;Jo, Yang-Hyeok
    • The Korean Journal of Physiology
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    • v.11 no.2
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    • pp.67-71
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    • 1977
  • This study was undertaken to investigate the effect of cingulate cortical ablation upon gastric secretion and its components in rats. 23 male rats were divided into the cingulate(N=9) and the operated control(N= 14) groups. Cingulate cortex was ablated through a slit-shaped opening(1 mm in width, 5 mm in length) which was made symmetrically on both sides of, and parallel to, the sagittal suture by removing a bone flap from frontal bone on each side. In the operated control group, the surgical procedure was ended by the removal of the bone flap. Under light ether anesthesia, experimental animals were placed in a restraining jacket of fine mesh wire and gastric juice was collected for 5 hours via a canula which had been inserted through the anterior abdominal wall into the antral portion of the lumen of the stomach. Volume of the gastric juice was measured, and total acid output and free acid output were titrated with 0.04 N NaOH solution by using phenolphthalein and Topfer's reagent at indicator, and chloride ion output was estimated by means of chloridometer. Results obtained were that volume, total acid output, free acid output and chloride ion output of the gastric juice were higher significantly in the cingulate group than in the operated control group. It is inferred from the above results that the cingulate cortex exerts a fascilitatory influence upon gastric secretion and acid output in rats.

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Characteristics of Conversion Coating of AZ31 Magnesium Alloy Formed in Chromium-Free Cerium-Based Solution (크롬 프리 세륨 용액에 의한 AZ31 마그네슘 합금의 화성 피막에 대한 특성 평가)

  • Kim, Myung Hwan;Lee, Dong Uk;Kwag, Sam-Tag;Moon, Myung-Jun
    • Journal of the Korean institute of surface engineering
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    • v.49 no.1
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    • pp.62-68
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    • 2016
  • A chromium-free Ce-based conversion coating formed by immersion in a solution containing cerium chloride and nitric acid on AZ31 magnesium alloy has been studied. The effects of acid pickling on the morphology and the corrosion resistance of the cerium conversion coating were investigated. The corrosion resistance of the conversion coating prepared on AZ31 Mg alloy after organic acid pickling was better than that of inorganic acid pickling. The morphology of the conversion-coated layer was observed using optical microscope and SEM. Results show that the conversion coatings are relatively uniform and continuous, with thickness 1.0 to $1.1{\mu}m$. The main elements of the conversion coating of AZ31 Mg alloy are Mg, O, Al, Ce and Zn by EDS analysis. The electrochemical polarization results showed that the Ce-based conversion coating could reduce the corrosion activity of the AZ31 Mg alloy substrates in the presence of chloride ions.

Influence of supplementary cementitious materials on strength and durability characteristics of concrete

  • Praveen Kumar, V.V.;Ravi Prasad, D.
    • Advances in concrete construction
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    • v.7 no.2
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    • pp.75-85
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    • 2019
  • The present study is focused on the mechanical and durability properties of ternary blended cement concrete mix of different grades 30 MPa, 50 MPa and 70 MPa. Three mineral admixtures (fly ash, silica fume and lime sludge) were used as a partial replacement of cement in the preparation of blended concrete mix. The durability of ternary blended cement concrete mix was studied by exposing it to acids HCl and $H_2SO_4$ at 5% concentration. Acid mass loss factors (AMLF), acid strength loss factor (ASLF) and acid durability factor (ADF) were determined, and the results were compared with the control mix. Chloride ions penetration was investigated by conducting rapid chlorination penetration test and accelerated corrosion penetration test on control mix and ternary blended cement concrete. From the results, it was evident that the usage of these mineral admixtures is having a beneficiary role on the strength as well as durability properties. The results inferred that the utilization of these materials as a partial replacement of cement have significantly enhanced the compressive strength of blended concrete mix in 30 MPa, 50 MPa and 70 MPa by 42.95%, 32.48% and 22.79%. The blended concrete mix shown greater resistance to acid attack compared to control mix concrete. Chloride ion ingress of the blended cement concrete mix was low compared to control mix implying the beneficiary role of mineral admixtures.

Chloride Penetration Resistance of Ternary Blended Concrete and Discussion for Durability (삼성분계 혼합콘크리트의 염화물 침투 저항성 및 내구성에 대한 고찰)

  • Song, Ha-Won;Lee, Chang-Hong;Lee, Kewn-Chu;Kim, Jae-Hwan;Ann, Ki-Yong
    • Journal of the Korea Concrete Institute
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    • v.20 no.4
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    • pp.439-449
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    • 2008
  • Mineral admixtures are used to improve the quality of concrete and to develop sustainability of concrete structures. Supplementary cementitious materials (SCM), such as silica fume (SF), granulated blast furnace slag (GGBS) and pulverized fly ash (PFA), are gradually recognized as useful mineral admixture for producing high performance concrete. The study on ternary blended concrete utilizing mainly three major mineral admixtures is limited and the study on durability and chloride induced corrosion resistance of ternary blended concrete is very few. This study examines the durability characteristics of the ternary blended concrete composed of different amount of the SCM with ordinary Portland concrete and the study experimentally focuses on corrosion resistance evaluation of ternary blended concrete subjected to chloride attack. In this study, 50% replacement ratio of mineral admixture to OPC was used, while series of combination of $20{\sim}40%$ GGBS, $5{\sim}15%$ SF and $10{\sim}45%$ PFA binder were used for chloride corrosion resistance test. This study concerned the durability properties of the ternary blended concrete including the corrosion resistance, chloride binding, chloride transport and acid neutralization capacity. It was found that the ternary blended concrete utilizing the SCM densified the pore structures to lower the rate of chloride transport. Also, increased chloride binding and buffering to acid were observed for the ternary blended concrete with chlorides in cast.

Changes of Chemical Components During the Storage of Fresh Red Pepper Homogenates (파쇄(破碎) 생(生)고추의 밀봉(密封) 저장중(貯藏中) 품질(品質) 성분(成分)의 변화(變化))

  • Lee, Gye Hee;Oh, Man Jin
    • Korean Journal of Agricultural Science
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    • v.13 no.1
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    • pp.130-138
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    • 1986
  • In order to obtain the basic data for development of raw pepper homogenates as instant spice, effects of preservatives, packaging materials, storage temperature and period on chemical components of raw pepper homogenates were investigated during storage after sealing up. The results are as follows: 1. Raw pepper homogenates added 15% sodium chloride was effective prominently than raw pepper homogenates on residual contents of acidity, capsanthin and capsaicin. 2. P. V. D. C film was effective than P. E film in sealing of raw pepper homogenates. 3. Decomposition of capsanthin was exceeded at high temperature during the sealed storage of raw pepper homogenates and decomposition of capsaicin was accelerated at initial stage of storage and also it was decreased prominently by adding of sodium chloride. 4. Decomposition of vitamin C during the storage was exceeded at high temperature and it was prominently suppressed by adding of sodium chloride. 5. Increase of total viable cell count and lactic acid bacteia count was prominently suppressed by adding of sodium chloride and its difference for storage temperature was disregarded.

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Antiviral Activity of Ascorbic Acid Against Herpes Simplex Virus

  • Yoon, Joo-Chun;Cho, Jeong-Je;Yoo, Seung-Min;Ha, Youn-Mun
    • The Journal of the Korean Society for Microbiology
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    • v.35 no.1
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    • pp.1-8
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    • 2000
  • In order to explore the potential of ascorbic acid supplementation for the prevention and treatment of herpes simplex viral diseases, plaque reduction assays were performed. Ascorbic acid as well as copper chloride/ferric chloride were added to wells containing Vero cells infected with herpes simplex virus type 1 (HSV-1), and the infectivity of HSV-1 was determined. Since copper and iron are major transition metals in human plasma, near the normal human plasma concentrations of them were used for experiments. When Cu(II) and Fe(III) were applied, there were no significant differences between virus control and Cu(II)/Fe(III)-treated groups. But, when appropriate concentrations of ascorbic acid were added to wells, meaningful differences between control and ascorbate-treated groups were found. In the presence of Cu(II)/Fe(III) at $5.8/3.7\;{\mu}M$, 72-h treatment with ascorbate at $50\;{\mu}M$ reduced HSV-1 infections to $10.77%{\pm}4.25%$ (P < 0.001) and $500\;{\mu}M$ did to $3.06%{\pm}1.62%$ (P < 0.001). Moreover, the cytotoxicities for Vero cells at those concentrations were insignificant (P > 0.05). Current recommended dietary allowance (RDA) of ascorbic acid is 60 mg/day, and the oral intake of 60 mg/day of ascorbic acid yields plasma ascorbic acid at 45 to $58\;{\mu}M$ in a healthy adult man. Therefore, the results of this study suggest that the maintenance of appropriate level (more than $50\;{\mu}M$) of ascorbic acid in human plasma by appropriate amount (more than the RDA) of ascorbic acid supplementation may be helpful for the prevention and treatment of diseases caused by HSV -1 in an adult man. In addition, this study also suggests that ascorbic acid may be useful for the prophylaxis of fatal HSV-1 infections in neonates and the prevention of HSV-1 reactivation in immunocompromised hosts.

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Stratum Corneum Exfoliation Effect with Hydroxy Acid according pH (pH에 따른 하이드록시 산(Hydroxy Acid)의 각질 박리 효과 연구)

  • Nam, Gaewon
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.42 no.4
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    • pp.413-420
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    • 2016
  • Hydroxy acid has been used to enhance anti-aging and skin moisturization by peeling effect on the skin stratum corneum, and thus it has been widely used in topical products and cosmetic products. Among them, the effect that appears most effectively in a short period of time has been reported to be effected by the pH of the cosmetic formulations. However, there are many difficulties in use due to irritation caused by pH and concerns about side effects. The purpose of this study was to evaluate the effect of applying cosmetics with (1) varying concentrations, (2) types and (3) pH of hydroxy acid on human skin. 22 healthy adults were stained with DHA (dihydroxyacetone) and DC (dansyl chloride) on the forearm, and the skin exfoliation effect was measured after application of the test products. (1) The application of GA (glycolic acid) increased the desquamation by concentration dependent. (2) the test product prepared with neutral pH showed no exfoliation effect. In contrast, SA (salicylic acid) showed a statistically significant exfoliation effect at both acidic pH and neutral pH. (3) The neutral pH SA showed excellent exfoliation effect on bot DHA and DC stained stratum corneum. These results suggest that it is possible to manufacture safe cosmetics without damaging the skin barrier, providing an opportunity to use cosmetics that are expected to exfoliate to people, whose skin is sensitive to pH.

Study of Chloride Corrosion Organic Inhibitors in Alkaline Pore Solution

  • Cabrini, M.;Lorenzi, S.;Pastore, T.;Pellegrini, S.
    • Corrosion Science and Technology
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    • v.17 no.5
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    • pp.203-210
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    • 2018
  • This paper compares the inhibition properties of aspartic and lactic acid salts with nitrite ions and their effect on critical chloride concentration. The tests were carried employing carbon steel specimens in saturated lime solution with varying pH in the range between13 to 13.6. The critical chloride concentration was estimated through multiple specimen potentiostatic tests at potentials in the usual range for passive rebar in the alkaline concrete of atmospheric structures. During tests, chloride salt was added every 48 h until all the specimens showed localized attacks. The cumulative distribution curves, i.e. the number of corroded specimens as a function of the chlorides concentration was obtained. Furthermore, IR spectra were recorded for the evaluation of the presence of the organic inhibitors on the passivity film. The results confirmed the inhibitory effect of 0.1M aspartate comparable with nitrite ions, at a similar concentration. Addition of calcium lactate did not result in an increase in the critical chloride concentration. However, the formation of a massive scale containing the substance that could reduce the corrosion propagation was observed.

Influence of Binder Type on the Chloride Threshold Level for Steel Corrosion in Concrete

  • Moon Han-Young;Ann Ki-Yong;Jung Ho-Seop;Shin Dong-Gu
    • Journal of the Korea Concrete Institute
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    • v.17 no.4 s.88
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    • pp.663-670
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    • 2005
  • The present study concerns the influence of binder type on the chloride-induced corrosion being accompanied by the chloride threshold level (CTL), chloride transport and as their results the corrosion-free lift. Two levels of cement content, $30\%$ PFA and $65\%$ GGBS concrete were employed. It was found that the most dominant factor to the CTL is the entrapped air void content at the steel-concrete interface, irrespective of the chloride binding capacity, binder type and acid neutralisation capacity of cement matrix. The CTL for lower interfacial air void contents was significantly increased up to $1.52\%$ by weight of cement, whereas a same mix produced $0.35\%$ for a higher level of voids. Because of a remarkable reduction in the diffusion fur GGBS concrete, its time to corrosion ranges from 255 to 1,250 days, while the corrosion-free life for control varies from 20 to 199 days sand for $30\%$ PFA concrete from 200 to 331 days.

Effects of Chloride Concentration and Applied Current Density on Stray Current Corrosion Characteristics of 6061-T6 Al Alloy for Electric Vehicle Battery Housing (전기자동차 배터리 하우징용 6061-T6 알루미늄합금의 전식 특성에 미치는 염화물농도 및 인가전류밀도의 영향)

  • Shin, Dong-Ho;Kim, Seong-Jong
    • Corrosion Science and Technology
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    • v.21 no.5
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    • pp.348-359
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    • 2022
  • Interest in electric vehicle is on the rise due to global eco-friendly policies. To improve the efficiency of electric vehicles, it is essential to reduce weights of components. Since electric vehicles have various electronic equipment, the research on stray current corrosion is required. In this research, a galvanostatic corrosion experiment was performed on 6061-T6 Al alloy for electric vehicle battery housing using chloride concentration and applied current density as variables in a solution simulating an acid rain environment. As a result of the experiment, when chloride concentration and applied current density were increased, corrosion damage became larger. In particular, pitting damage was dominant at an applied current density of 0.1 mA/cm2. Pitting damage over the entire surface was found at a current density of 1.0 mA/cm2. In conclusion, chloride concentration had a relatively large effect on localized corrosion. The applied current density had a great effect on uniform corrosion. However, in the case of applied current density, localized corrosion was also greatly affected by interaction with chloride.