• 제목/요약/키워드: acetal

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Reciprocating sliding wear behavior of plastics against steel (플라스틱재료의 왕복동마찰마멸거동)

  • 김충현;안효석;정태형
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 1999.11a
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    • pp.35-41
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    • 1999
  • Friction and wear test was performed for nylon, acetal resin, and PTFE(polytetrafluoroethylene) under reciprocating dry sliding conditions against a steel counterpart. Friction coefficient and specific wear rate were analysed as a function of sliding distance and applied load. The worn surfaces of plate and disc specimens were observed using SEM(Scanning Electron Microscopy). The experimental results show that acetal resin exhibited lowest wear rates whereas PTFE possessed lowest friction coefficient. The prominent wear mechanisms found were adhesion and abrasion.

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Synthesis of Calycotomine via Pictet-Spengler Type Reaction of N,O-Acetal TMS Ethers as N-Acyliminium Ion Equivalents

  • Yang, Jung-Eun;In, Jin-Kyung;Lee, Mi-Sung;Kwak, Jae-Hwan;Lee, Hee-Soon;Lee, Soo-Jae;Kang, Han-Young;Suh, Young-Ger;Jung, Jae-Kyung
    • Bulletin of the Korean Chemical Society
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    • v.28 no.8
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    • pp.1401-1404
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    • 2007
  • An efficient Pictet-Spengler type reaction of N,O-acetal TMS ethers for the practical synthesis of 1-substituted tetrahydroquinolines, medicinally important alkaloids, has been accomplished. To demonstrate the versatility of this novel procedure, the total synthesis of calycotomine, a representative 1-hydroxymethyl substituted tetrahydroisoquinoline, is also described.

Isolation of an Unusual Aloenin-acetal from Aloe

  • Woo, Won-Sick;Shin, Kuk-Hyun;Chung, Ha-Sook;Lee, Jung-Mi;Shim, Chang-Sub
    • Korean Journal of Pharmacognosy
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    • v.25 no.4 s.99
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    • pp.307-310
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    • 1994
  • A hitherto unknown substance was isolated from the commercial sample of Aloe arborescens, which was shown to be the 4',6'-O-ethylidene-aloenin, most likely an artifact caused by hot-air drying procedure for the product preparation.

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Ring-opening Polymerization of an aliphatic seven-membered Cyclic Acetal (7원환 고리화합물의 개환중합)

  • Park, Jae-kyeung
    • Journal of the Korean Society of Industry Convergence
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    • v.4 no.3
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    • pp.253-255
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    • 2001
  • 기능성고분자재료 중의 하나인 7원환 고리아세탈 화합물인 1,3-dioxepan-2-one(1)을 합성하고 고온조건 하에서 중합반응을 조사한 결과 선택적인 개환중합이 일어났다. 그러나 낮은 농도에서 작은 분자량을 가지는 고분자가 얻어졌으며 넓은 분자량 분포와 낮은 수율이 얻어지며 이것은 중압반응 도중에 분자 내에서 상호반응을 일으킴을 보여준다.

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Wear Characteristics of Plastic Pinion Against Steel Gear (플라스틱기어의 마멸특성에 관한 고찰)

  • 김충현;김영민;안효석;정태형
    • Tribology and Lubricants
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    • v.16 no.5
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    • pp.324-331
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    • 2000
  • Wear characteristics of Plastic and Nylon pinions against steel gear were studied to gain a better understanding of their tribological behaviors. Wear tests were conducted with power circulating gear test rig under dry contact conditions. Specific wear rates were measured as a function of applied load and the number of revolution. The worn teeth surfaces were examined with a profile projector and a camera. Nylon pinion showed lower specific wear rates than acetal pinion, but suffered teeth breakage under high load per unit tooth width. The dominant wear mechanisms found were adhesion and abrasion.

Studies on the Viscoelasticities of Acetal Type Nonionic Surfactants (아세탈형(型) 비(非)이온성(性) 계면활성제(界面活性劑)의 점탄성(粘彈性)에 관한 연구(硏究))

  • Shon, Joo-Hwan;Lee, Seung-Youl;Nam, Ki-Dae;Kim, Yu-Bae
    • Journal of the Korean Applied Science and Technology
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    • v.5 no.1
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    • pp.53-62
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    • 1988
  • Properties of aqueous solution, that is, the viscosities and solubilities of benzene were observed in relation to critical micelle concentration of each alkyl aldehyde polyoxyethylene glycol acetal type surfactant. These showed that the mininum points in specific viscosity/concentration-concentration curves were corresponded with the critical micelle concentration obtained by surface tension and appeared the remarkable increase of non-Newtonics according to the increase of the number of carbon in hydrophobic groups. The fluidity of non-Newtonics is not observed by a little increase of the degree of polymerization in polyoxyethylene glycol groups.